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By Laurance S. Reid, Joe A. Porter

Gas dehydration plays an important part in the production of natural gas. Effective dehydration prevents formation of gas hydrates and the accumulation of water in transmission Systems,2,6,7 insuring uninterrupted gas deliveries at maximum efficiency under the most adverse weather conditions. At the present time, most gas companies require a maximum water vapor content of seven lb per million standard cu ft of gas. so that virtually all gas tendered for sale must he dehydrated to meet this specification. For a number of years it has been common practice to produce gas and gather it at a common point for dehydration prior to discharge into the transmission system.1,3,11,16,17 However, higher transmission line pressures, long gathering lines and relatively low ground temperatures have made it necessary to dehydrate gas at. or near. individual. wells in order to gather gas from a number of newly developed fields without unusual difficulty. Where gas has been dehydrated at pressures ranging from 300 to 800 psi in the past. future trends indicate that these processes may be operated at pressures as high as 2,000 psi. Economics of gas dehydration are of great importance, partitularly where facilities must he provided to process relatively small quantities of gas, such as the production from an individual well. Although the adsorption of water vapor from gas on a granular sorbent material such as activated bauxite, activated alumina, or one of the alumina-silica gels is highly effective and produces virtually "bone dry" gas, the cost of a small unit of this type is substantially greater than that of an absorption process which, through proper selection of the absorbing liquid, will dehydrate the gas sufficiently to meet pipe line specifications. For this reason, a great deal of emphacis has been placed on the development of small, inexpensive dehydration units8,24 and the search for more effective absorb. ent liquids has been intensified. A wide variety of methods for dehydrating gas are known' and many of these have been used in industry. Earlier applications of the absorption process employed concentrated solutions of calcium and lithium chlorides as the absorbent. The severe corrosion problems inherent in handling these solutions and the relatively small dew point depressions obtained caused early abandonment in favor of, or conversion to. diethylene glycol when it was found that aqueous solutions of this organic liquid were more hygroscopic than the brines and were non-corrosive. Processes employing diethylene glycol-water solutions are widely used for gas dehydration at pressures ranging as high as 1,200 psi.13,14,15 At nominal pressures a dew point depression of 45° to 50°F may be be and the data of Russell et al." indicate that a minimum dew point is obtained from the effluent gas at a pressure of approximately 1,200 psi when the gas is in equilibrium contact with a 95 per cent by weight diethylene glycol solution. In a number of instances the dew point depression obtained with diethylene glycol-water solutions is not sufficient to produce a specification product without cooling the inlet gas. In a recent search for a better absorhent, triethylene glycol was used in a small commercial dehydration unit and subjected to rather exhaustive field tests.' The data obtained were encouraging and indicated that, at pressures ranging from 300 to 500 psi, triethylene glycol porduced a substantially greater dew point depression than diethylene glycol. These results led to an investigation of the system natural gas-water-triethylene glycol in an effort to obtain vapor-liquid equilibrium data, to determine pressure limitations, and to develop other data pertinent to the design of gas dehydration processes. A review of the literature has failed to reveal any data which permit reasonably accurate calculation of the vapor-liquid equilibrium conditions for a solution of water and triethylene glycol in contact with natural gas at high pressure. Since these constituents form a non-ideal system, the Poynting equation18,21 or the usual combination of Raoult's and Dalton's laws19,20,22 would not be valid. Correction of Raoult's and Dalton's laws by the use of activity coefficients2' is not feasible for available data are insufficient for the prediction of the actual increase in the ratio of the activity of one component in the vapor phase to its activity in the liquid. Therefore. experi-

Jan 1, 1950

By Y. A. Chang

The objective of the present study is to evaluate and compile the relevant phase equilibria and thermodynamic data reported in the literature for the ternary system Cu-Fe-S. It is hoped that the results presented here will be useful to practising engineers and scientists in industry who are attempting to improve continually the existing processes of copper extraction and refining. At the same time, the present work will undoubtedly reveal the lack of some basic data which are important for the improvement of our existing extractive processes. Lastly, this work will also show that the development of theoretical models for the alloy phases in the Cu-Fe-S system is essential before complete consistency between the phase equilibria and the thermodynamic data can be achieved.

Jan 1, 1976

By R. P. Ehrlich, D. A. Dahlstrom

In the hydrometallurgical circuit, many phase separation steps are usually necessary. Typical steps are pregnant liquor - leach residue separation by counter- current decantation or continuous vacuum filtration, clarification of liquids prior to precipitation, ion exchange or solvent extraction, dewatering of final product, etc. The paper discusses the more recent advances in these areas and considers general operating parameters and cost factors. In addition, emphasis is placed on future needs because of the growing importance and necessity of hydrometallurgical processing of minerals.

Jan 1, 1973

By R. R. Swanson

Liquid ion exchange is becoming more and more important in hydro-metallurgical processing and recovery of metals. The key to success for this process are reagents which have suitable operating characteristics. One of these important characteristics is a relatively fast phase separation rate in the extraction and stripping circuits, as this greatly affects the size of plant required. A test for measuring phase separation rate is needed to help evaluate liquid ion exchange reagents. Such "a test also would be useful for evaluating carrier solvents that are used for diluting the re-agents. In fact, one standard test method would be very desirable as it would provide a common basis for comparing reagents and sol-vents. The phase separation test described in this paper has been used successfully for several years with the copper reagent, LIX®64N. The test is set up for feed liquors containing low copper concentrations. For other types of systems, modifications in procedure probably would be necessary. However, this test and the associated apparatus could be the basis for a standard phase separation test.

Jan 1, 1972

By Dan Wang, Qian Xu, Guangshi Li, Xionggang Lu, Xingli Zou, Zhongfu Zhou, Hongwei Cheng, Changyuan Lu

The preoxidation of the ore has a profound significance to the concentration, separation and purification of nickel and copper from the lean complex ore. In this paper, the natural Ni-Cu sulfide mineral samples under the elevated temperature condition in air were investigated, as well as under isothermal condition at 600 oC in air. The mineralogical characterization was studied using XRF, ICP and the Rietveld method. The oxidation behavior and the element migration of the Ni-Cu sulfide ore were studied by XRD, SEM-EDS and TG. The XRD Rietveld method was successfully developed in the phase identification and quantification of this complex ore powder sample. The oxidative intermediates (Cu/Ni-ferrite) were detected by XRD, and the process of the element migration was obviously revealed by the line scans using SEM-EDS. It is the preoxidation of this mineral that provides guidance for the extraction of valuable metals from low-grade Ni-Cu sulfide ores in the future.

Jan 1, 2015

By Baozhong Ma, Qian Li, Yonggang Wei, Shiwei Zhou, Bo Li, Chengyan Wang, Hua Wang

The magnesium-rich nickel oxide ore (w (Ni) =1.09 %, w (MgO)=29.08 %) mixed with 6 % and 8 % anthracite were roasted at different temperatures. XRD and SEM/EDS techniques were utilized to characterize the phase and microstructure transformation of the ores. The results show that lizardite and chrysotile of raw ore were converted into forsterite and enstatite during reduction roasting process. Simultaneously, iron and nickel oxide were reduced and migrated from the initial magnesium silicate. Fe3Si were formed when the roasting temperature went up to 1300 ℃ and 1350 ℃, and a small amount of Ni was observed in it. Temperatures got too high were not benefit to the polymerization of ferronickel.

Jan 1, 2015

By Bowen Li

Andalusite is an excellent raw material for refractory applications due to its high aluminum oxide content and phase transformation to mullite at high temperature. Granular andalusite in particle sizes of about 1 to 2 mm was traditionally utilized for the manufacturing of refractory brick. However, if powder andalusite in micron particle size is utilized in high-alumina refractory products, reinforcement on the refractory brick can be obtained and the sintering temperature can be decreased. The phase transformation of powder andalusite plays a key role for the difference.

Jan 1, 2006

By Yingbao Yang, Jinyue Liu, Yonggang Wei, Bo Li

Due to the depletion of copper ore with high-grade and low impurity contents, the raw materials for copper smelting exhibit low copper contents and high impurities. High-impurity elements lead to the poor performance of the final copper product; thus, the removal of impurity elements during the oxygen-enriched copper smelting process is crucial. In this study, based on the production of high-grade matte, the occurrence states of impurity elements (such as As, Pb, and Zn) are analyzed in the input and output materials of the oxygen-enriched smelting process, and the phase transformation mechanisms of impurity elements are revealed during the oxygen-enriched smelting process. The effects of temperature, Fe/SiO2 ratio and oxygen concentration on the distribution behaviors of impurity elements in dust, slag and matte and the removal rates of impurity elements in matte are clarified. The results show that the impurity elements mainly exist as As4, As4S4, As2O3, Pb, PbS, PbO, Zn and ZnS in dust, as FeAsO4, As2O3, FeAsS, PbSiO3, Zn2SiO4 and ZnFe2O4 in slag, and as As, FeAsS, PbS, PbO and ZnS in matte. High smelting temperature, low Fe/SiO2 ratio and low oxygen concentration are beneficial for improving the matte grade and the removal rates of impurity elements Pb and Zn in matte. Low smelting temperature, low Fe/SiO2 ratio and high oxygen concentration are beneficial for removing impurity element As in matte.

Aug 8, 2023

By Yuanbo Zhang, Zijian Su, Bingbing Liu, Guanghui Li, Tao Jiang

With the depletion of rich manganese ores, high-Fe content manganese ores are becoming the mainstream resources for manganese extraction. Reduction roasting-magnetic separation process is reported as a relatively effective route to realize the separation of manganese and iron. This study investigated the phase transformation of MnO2 and Fe2O3 briquettes (molar ratio 1:1) roasted under various temperatures and CO–CO2 atmospheres. Results showed that when the CO content was in the range of 0–10 vol%, MnxFe3−xO4 (x = 0−1) phase was formed and its content increased with the rising of temperature. The formation of ferromagnetic MnxFe3−xO4 with strong magnetism resulted in an inferior separation of manganese and iron by magnetization roasting-magnetic separation process. With the increase of CO content to over 25 vol%, the MnxFe3−xO4 content decreased while the content of feebly magnetic substance (MnO)y(FeO)1−y(y = 0−1) increased. Further increasing the CO content to over 80 vol%, (MnO)y(FeO)1−y was reduced to MnO and metallic iron.

Mar 1, 2017

By Yuanbing Ling

Keywords: Calcium sulfate, Sulfuric acid, Phase transformations, Thermodynamic analysis As part of a boarder research project, seeking the development of a cost-effective process for direct production of the high value material, -calcium sulfate hemihydrate, from sulfuric acid at atmospheric as opposed to elevated pressure conditions, the fundamental work presented here has been undertaken. This includes experimental monitoring of phase transformation reactions and thermodynamic analysis of the relationships among the various phases, namely, calcium sulfate dihydrate, hemihydrate and anhydrite in aqueous sulfuric acid solution at temperatures ranging from 20oC to boiling point.

Jan 1, 2004

By N. Hanief

This research involves the investigation of phase transformations in the platinum-chromium coated system. Single-layer 0.1 µm platinum coatings were deposited via electron beam deposition on 99.98 percent pure chromium substrates. Specimens were subjected to systematic heat treatment in a vacuum furnace at 900°C for up to 20 hours. Phase formation and the changes in surface morphology were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM).Both CrPt and Cr3Pt phases are formed during heat treatment for different times at 900°C. Significant changes in the morphology of this coated system were detected after heat treatment at 900°C for 20 hours.

Jan 1, 2012

By N. Hanief

This research involves the investigation of phase transformations in the platinum-chromium coated system. Single-layer 0.1 µm platinum coatings were deposited via electron beam deposition on 99.98 percent pure chromium substrates. Specimens were subjected to systematic heat treatment in a vacuum furnace at 900°C for up to 20 hours. Phase formation and the changes in surface morphology were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM).Both CrPt and Cr3Pt phases are formed during heat treatment for different times at 900°C. Significant changes in the morphology of this coated system were detected after heat treatment at 900°C for 20 hours.

Jan 1, 2012

By M. S. Safarzadeh

Cu-As feedstocks are among the most problematic copper sources that have been avoided over the past years. The high arsenic content of such ores/concentrates combined with their refractory nature have directed the metallurgical industry towards developing efficient technologies for the treatment of high-arsenic copper ores/concentrates. As the most important member of Cu-As-S mineral system, enargite (Cu3AsS4) is frequently encountered in some of the important copper deposits. Several hydrometallurgical and pyrometallurgical processes have been examined for the treatment of enargite concentrates, but currently, no commercial operation exists. In an effort to develop an original processing option, an acid bake-leach process has been identified and applied to an enargite concentrate containing ~67% enargite, ~27% pyrite (FeS2), ~3% chalcopyrite (CuFeS2), ~6% sphalerite (ZnS) and <1% galena (PbS). Sulfuric acid baking of this concentrate resulted in the transformation of the concentrate to S8, As2O3, HFe(SO4)2?4H2O, PbSO4 and Cu0.47Fe0.53SO4?H2O, all of which (except elemental sulfur and PbSO4) dissolved during the water leaching step. More than 87% Cu and 64% As were leached when the concentrate was baked at 200°C over 7 h with a sulfuric acid to concentrate weight ratio of 1.6. Less than 1% As was lost to the gas phase. Upon water leaching, copper and arsenic were released to the solution at a concentration ratio of about 3:1. While enargite is very reactive during the sulfuric acid baking reaction, other minerals present in the concentrate such as pyrite, galena, and sphalerite may compete to consume sulfuric acid and be converted into their corresponding sulfates at different levels. The purpose of this paper is to evaluate phase transformations during the acid bake-leach process for the treatment of an enargite concentrate, and to study the effect of sulfuric acid dosage on the extraction of Cu, Fe, and As. In this regard, the concentrate, baked concentrate, and the leach residues are characterized and a conceptual process flowsheet is described for the acid bake-leach process for the treatment of enargite concentrates.

Feb 23, 2014

By Fjeldstad Karin Jusnes

Two quartz types used in the silicon and ferrosilicon industry were heated to temperatures of 1600 and 1700 °C. The parameters varied were the temperature and the holding time at maximum temperature. The amount of quartz, cristobalite and intermediate amorphous phase were measured using XRD and the internal standard method. Type P showed a much larger ability to transform to cristobalite at lower temperatures than type A. Type P had a larger amount of alkali and alkaline earth impurities. This could have enhanced the transformation to cristobalite. For quartz type A the amount of cristobalite was larger at 1600 °C than 1700 °C. This can also be seen for some of the samples of type P at shorter holding times.

By Jafar Safarian, Leiv Kolbeinsen, Stian Seim, Hossein Salehi

The present work aims to investigate the link between the oxidation and reduction of a weathered ilmenite concentrate in terms of phase transitions, microstructural changes, and element distribution. An ilmenite concentrate sample was pelletized and fired at 1000 °C in air, and as a result, the pellets were oxidized. The oxidized pellets were reduced by hydrogen gas at 1000 °C, which yielded almost complete metallization of the iron content of the pellets. The ore and the pellets were characterized in each step by XRD and SEM techniques, and distribution of elements and phases were investigated. Ilmenite, pseudorutile, and rutile were the main phases detected in the ilmenite concentrate sample, and depending on the weathering degree of the particles, different fractions of the phases were identified in their microstructure. It was found that irregular rutile grains dispersed in a pseudobrookite matrix is the morphology of the oxidized ilmenite phase. However, increasing microcracks and porosities were the only microstructural changes in the pseudorutile phase after oxidation in air. Studying the specific types of the ore particles and their oxidized and reduced forms indicated that the phase distribution in the ilmenite ore particles dictates the phase distribution in the oxidized and reduced ones. Results show that the morphology of the reduced particles includes a titanium (III) oxide matrix in which reduced iron globules are dispersed.

Feb 8, 2021

By Todd Wanless

This paper addresses the challenges experienced by the designer and three government agencies during implementation of major improvements for the Turkey Creek Tunnel in Kansas City, Kansas. The tunnel serves as a vital stormwater conveyance system for upstream flood control. Major structural deficiencies were identified within the tunnel including complete loss of sidewall and invert. Without immediate attention, complete loss of the tunnel arch could lead to blockage and extensive remedial repairs under difficult conditions. Considering that tunnel flows must be maintained during construction, a phased design and construction process has been implemented to expedite stabilization of the erosion cavities followed by tunnel liner repairs.

Jan 1, 2008

"3.1. IntroductionAmong the six platinum-group elements (POE), four have identical cubic symmetry, two identical hexagonal symmetry (Table 3.1). Despite crystallographic differences, there is a clear relationship expressed in the chemistries of the POE: they tend to be mutually soluble in one another and can frequently substitute for one another in compounds with other elements. This chapter consolidates the data on phase relations of the POE and the compounds they form with elements selected for their known or potentially important mineralogical significance- As, Bi, Cu, Fe, Hg, In, Ni, Pb, S, Sb, Se, Sn and Te-together with selected data for the occurrence of POE in certain elements such as Au and Ag, and compounds such as FeS. Resources used to compile the data are those available from the chemical, mineralogical and metallurgical literature. First each element is discussed, with composition limits of solid solutions drawn from binary phase diagrams. Single element data are followed by a discussion of the relevant binary systems and a tabulation of data for binary compounds found in those systems (Table 3.2). Tables and diagrams for the ternary and quaternary systems for which information is available follow, and finally the very limited information on the solubility of POE in mineralogically important elements and compounds is presented.The chemical, mineralogical and metallurgical literature on the unary and binary systems is extensive and widely scattered in many languages and publications; fortunately, most of the data needed to compile this chapter can be found in reliable compendia. The most useful and most recent of these works is by Moffatt (1979), because it provides a ready index to all material relating to binary systems listed in previous compendia; furthermore, the Moffatt compendium will reportably be kept up to date by annual supplements."

Jan 1, 1979

By M. Natarajan, C. J. Cutler, E. Mponda

Keywords: Pyrometallurgy, furnace, KCM Nkana, Zambia The Nkana smelter was initially commissioned in 1931, with two reverberatory furnaces, two Peirce-Smith converters, and blister copper casting facilities. Reverberatory furnaces were the mainstay of production up until 1994, when an El Teniente Converter (CT) was installed to upgrade reverberatory furnace matte to white metal, prior to converting in conventional Peirce-Smith (PS) converters. In 2000, a decision was taken to increase the proportion of concentrate smelted in the CT by introduction of bone-dry concentrate injection through the tuyeres. A flash dryer with a nominal capacity of 1 200 metric tons per day of dry product, and associated tuyere injection system was commissioned in March 2004. Based on the projected concentrate arisings from the KCM mines into the future, as seen in 2004, it was decided to develop the CT to be the primary smelting vessel at Nkana, to handle a minimum of 1 250 tons per day of concentrate, and to operate only one reverberatory furnace in slag-cleaning mode pending a full evaluation of alternative slag-cleaning technologies. The anticipated cathode production from Nkana was to be in the range 140 to 150 000 tons per annum. This paper details the outcomes from trials that were carried out in August and September 2004, using two reverberatory furnaces for slag cleaning. The results of these trials, plus further work in October and November, provided confidence to move to one reverberatory furnace for slag cleaning in December 2004. With the advent of Vedanta as the majority shareholder in KCM at the end of 2004, the approach has been to maximize the available smelting capacity. Currently, two reverberatory furnaces and the CT are on-line, with the higher silica concentrates going to the reverberatory furnaces with an appropriate amount of pyrite, and the cleaner concentrates going to the CT. Expansion of the smelter is currently under investigation.

Jan 1, 2006

By John Pilling

The concept of microstructure, its evolution through materials processing and its effect on the properties of the material is, perhaps, the foundation upon which the science of materials is built. PHAUST, a computer aided learning program, attempts to provide instruction in establishing the relationships between phase diagrams, thermal processing and microstructure. Using phase diagrams derived from a database or created by the user, the evolution of microstructure during processing is quantified using the lever rule and/or the Scheil equation and tracked through a doubly linked list (a form of binary tree). Microstructures, in the form of full colour cartoons are then drawn using the quantitative and logical information contained within the linked list using bitmapped templates and logigal operators such as NOT. AND, OR and XOR, giving the student a view of the structure as it would be seen under the optical microscope. The software provides complete diagnostics of student answers, locates errors and misconceptions as well as providing tutoring towards the correct solution method and answer.

Jan 1, 1991

By W. J. Mitchell

During the months of April and May 1992, the Phelps Dodge Hidalgo smelter underwent a major turnaround. This was the third such turnaround in the life of the facility which was commissioned in 1976. During the third furnace campaign, the smelter processed 5.2 million tons of concentrate producing 2.6 billion pounds of anode copper over a 7.5 year period. The critical path on the fifty-nine (59) day turnaround schedule was the reconstruction of the Outokumpo flash furnace which integrated some modifications with standard rebuild practices. Modifications included incorporation of horizontal cooling jackets throughout the furnace settler as well as the installation of castable refractory in the reaction and uptake shafts.

Jan 1, 1993