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By Robert A. Westin

Polychlorinated biphenyls (PCBs) are a group of chlorinated chemicals that were used in many different fire resistant hydraulic fluids, heat transfer fluids, and in electrical equipment as dielectric liquids. PCBs were manufactured primarily by Monsanto Chemical Company under the tradename Aroclor, and were used by many different electrical equipment manufacturers. PCBs are noted chiefly for their extreme chemical inertness. This resulted in exceptional fire resistance and long life in applications involving exposure to high temperatures and intense electrical fields. This combination of properties resulted in PCBs being widely used in electrical equipment used in mines, including transformers, capacitors, and some electric motors. PCBs were also used as working fluids in some heat transfer and hydraulic sys terns. The same chemical resistance that gave PCBs long life in industrial applications give PCBs essantially eternal life when they are released into the environment. PCBs are not highly toxic in the sense that exposure does not cause immediate health problems. However, PCBs accumulate in the human body and neither degrade nor are eliminated from the body, and long-term exposure to PCBs can result in changes in liver function which may increase susceptibility to the carcinogenic effects of other chemicals. PCBs also accumulate in the food chain; the concentration of PCBs in fresh water fish may be several hundred thousand times as high as in the water the fish are taken from.

Jan 1, 1981

Krupp Polysius AG, FRG, in close cooperation with Prof. Dr. K. Schoenert, FRG have developed the principle of the high pressure grind- ing roll POLYCOM. The POLYCOM mill basically consists of two counter-rotating rolls of large diameter and relatively small width, one of which is fixed and the other moving in slide blocks. The pressure required for comminu- tion is applied via the sliding roll by a powerful hydraulic system. The comminution takes place between the rolls under high pressure in the bed of material by nipping and compacting. The top feed size-depending on the rolls diameter -may be as coarse as conventional secondary crusher feed and the product is a compacted cake containing a high amount of fines created by micro-cracking. The amount of fines depends on the pres- sure (grinding force) applied. Operating results show that even in wet griding circuits capacity increases at downstream connected grinding mills of up to 100010 can be accomplished with an interconnected POLYCOM machine and energy savings of up to 25070 may be achieved depending on application. POLYCOM can be used in existing grinding plants for low-cost upgrad- ing of capacities but also as an advanced alternative to conventional crush- ing and grinding equipment in open or closed circuit configuration. A single industrial size 2.8m roll diameter POLYCOM machine may be fed with top feed size of up to 200mm and produce a finish product as fine- grained as known from rod and ball mills but with less energy consumption. Meanwhile, the POLYCOM high pressure grinding roll has established itself world-wide in the cement industry and is now entering the mining industry. POLYCOM machines are currently designed in industrial standard sizes of 1.0m to 2.0m rolls diameter and drive units of up to 2400 kW. This paper includes: principles of high pressure grinding, main fea tures of the POLYCOM machine, results of tests on various materials including Australian gold and copper ores carried out at the POLYSIUS research centre in Germany. Some examples of industrial applications of high pressure grinding will also be presented.

Jan 1, 1988

In the present work, the influence of coagulant, polymeric flocculant structure type and mode of addition on flocculation performance and dewatering behaviour of plant mineral waste tailings of diverse mineralogy (kaolin, quartz, goethite/hematite feldspar, gibbsite, rutile, and Illite) is investigated. High molecular weight, non-ionic polyacrylamide homopolymer and anionic (acrylate) and cationic (quaternary acrylate) copolymers were used in orthokinetic flocculation of colloidal-ly-stable, aqueous dispersion of negatively charged particles. It is demonstrated that, through prudent selection and mode of addition of polymer structure types, synergistic effect between certain cationic and anionic flocculants can be readily achieved, leading to significantly improved dewaterability of the heterogeneous mineral waste tailings.

Jan 1, 2014

By S. E. Valji

Clay slurries are normally dewatered using flocculents like sulfuric acid or aluminum sulfate. This type of flocculation is based on the electrolytic mechanism. For certain clay dewatering applications, this method of flocculation is unsatisfactory. Flocculation, based on the bridging mechanism, using organic polymers has been utilized to overcome such problem situations. This method of flocculation offers solutions not possible by previous methods. Normally these flocculents are used to assist dewatering. In this case, not only is dewatering promoted, but also further processing is assisted by a change in the dilatant character of the filter cake that is formed. Discharge of filter cake is easier, extrusion of filter cake on to conveyor dryer is possible or improved, and heat transfer and drying rates of the extruded filter cake are substantially higher. Both natural and synthetic organic polymers have been utilized for this purpose. Selection, application techniques, and economics are described.

Jan 1, 1965

By F. H. Seymour

Central to Newmont Gold's Mine planning system is the ability to interactively perform cut and fill operations on topographic contours and to accurately evaluate grades and tonnages within contour outlines using polygon set manipulation routines. This paper develops the applied geometry concepts that underlie these routines. Included are representation of volumes with contours, point in polygon test, block proportion in polygon calculation, polygon area and centroid calculation, and intersection, union, and complement between polygon sets.

Jan 1, 1990

By R. J. Mirville

Flocculation is an important step in the treatment of coal preparation waste waters. The effects of polymer charge and molecular weight and solution pH and ionic strength on the adsorption and flocculation characteristics of a series of polymeric flocculants on some typical waste water constituents have been studied experimentally. The results indicate that the nature and extent of flocculation are strongly system-dependent. For the case of coal, both adsorption and flocculation behavior can be correlated with the polymer conformation in solution. For the mineral constituents, on the other hand, adsorption and flocculation depend also on the surface properties of the solid.

Jan 1, 1979

By Rita C. L. B. Rodrigues, Esperidiana A. B. Moura, Gisele D. Lazo, Renata D. S. Coiado, Rene R. Oliveira

Agricultural residues, which are produced with large quantities annually throughout the world, may be used as reinforcement plastic to replace the wood and produce particleboard for application in the development of low cost construction elements and reduced environmental impact. The main aims of this study was to investigate the effects of agricultural wastes and glass residues addition on the properties of recycled-HDPE/EVA blend for use in particleboard manufacture. The recycled-HDPE/EVA blend reinforced with corncob fiber (15 wt%), coffee parchment (15 wt%) and glass residues (1 wt%) were processed by melt extrusion, using a twin screw extruder and injection molding machine to obtain specimen test samples. The samples were characterized by mechanical test, XRD, TG, DSC, and FE-SEM analysis to understand the nature of interaction between the fillers reinforcement and recycled-HDPE/EVA blend matrix and their properties were discussed.

Mar 1, 2017

Carrying Energy ?Energy ?Power, data, signal, hydraulics, pneumatics? ?Needs to be conveyed from a stationary point to a system in motion ?Cable Carriers (steel and plastic), Festoon Systems, Cable Reels and Bus Bars Polymer Cable Carriers ?Life Line for modern machinery ?Transmitting power, data, signal, hydraulics or pneumatic energy ?Constructed and designed to work in harsh environments, at high speeds and to do this continuously ?Meet a wide variety of cable (Media) requirements ?Virtually maintenance free ?High efficiency

Nov 1, 2011

By Felicia F. Peng

Employing the combination of two types of polyelectrolyte might become necessary to enhance both settling rate of the flocs and water clarity of fine particle suspension in high capacity thickening process. The sequence of addition, mixing, type and dosage of polymer affect the overall performance and capacity of a thickening process. For the sedimentation of copper flotation tailings, the cylinder test results showed that two different techniques may be used to achieve the required performance including high settling rate of flocs, underflow density and overflow water clarity, by either adjusting pH prior to anionic polyelectrolyte flocculation, or using a combination of polymer flocculant and coagulant (dual polymer system). The dynamic thickening testing results showed that only the approach using a dual polymer system is able to meet the required performance. The effects of polyelectrolyte dosage, the sequence and numbers of polyelectrolyte addition, feed concentration, bed level and rake speed on the settling rate, underflow solid, and water clarity were studied in cylinder test and a laboratory dynamic thickening unit with various conditions related to the thickening process. The dynamic test is especially valuable in evaluating the addition and mixing of polymers. The results were evaluated quantitatively, using total suspended solids in supernatant, underflow density and capacity per unit settling area per unit time as the measure of effectiveness. The objective of this study is to quantify and explain some of the parameters involved in the sedimentation of copper flotation tailings.

Jan 1, 1997

By T. J. Dudek

To be competitive in automotive applications, polymer composites must be processable by high production rate processes like injection molding (IM), reaction injection molding (RIM), structural rim (SRIM) and compression molding. With current fiber reinforced composite materials, performance properties are sometimes compromised to make them compatible with these processes. This is done by decreasing the amount and length of the reinforcing fiber and the viscosity and molecular weight of the polymer matrix. Sheet molding composite (SMC) and thermoplastic polymer blends are examples of polymer composites which are cost effective in many applications and meet the high speed processing requirements for automotive parts.

Jan 1, 1993

By Alex Joseph

A tertiary amine containing polyamine in its back bone was grafted to exfoliated graphite oxide by means of a series of chemical reactions.The synthesized amine functionalized polyaniline grafted to exfoliated graphite oxide (EGAMPANI) was characterized using various techniques such as, FTIR, TGA, Raman, and X-Ray diffraction.The synthesized EGAMPANI was blended with carbon paste electrode, and used to study the response of Hg2+ in acetate buffer solution.Preliminary analysis showed that the anodic current intensity using the EGAMPANI modified electrode was higher during a potential sweep and 10-4 M concentration of mercury could be detected which could be improved to 10-6 M using anodic stripping voltammetric technique. Keywords: metal sensor, exfoliated graphite oxide, functionalization, polyaniline

Sep 1, 2012

By J. Iannicelli

Kaolin, normally an inert filler when compounded with polymers, is converted into a strongly reinforcing pigment by prereaction with certain functional silanes. Modification of kaolin with amino and mercapto silanes allows it to form crosslinks and confers significant improvements in modulus, abrasion resistance, compression set and other physical properties of a broad range of polymers.

Jan 1, 1990

By T Baumgartl, A Costine, B Boshrouyeh, M Edraki

In mineral processing, the management of tailings may become increasingly more challenging with a change of ore type and the quality of water used in the plant. This, in turn, may affect the overall costs of the operation and water usage and, in the long-term, pose challenges for mine closure and rehabilitation. Depending on the applied treatment technique, the short and long-term properties of tailings are largely determined by the fine particles. Most clay materials and ultrafine particles exist in tailings from oil sands, coalmines and base metals, bringing about challenges in dewatering performance. Moreover, given the growing concern for water scarcity, the minerals industry is increasingly turning towards the use of saline water, which poses yet another challenge for tailings management. The high salt content alters the behaviour of clay particles, making dewatering a more complex process than in freshwater systems (Boshrouyeh Ghandashtani et al, 2022; Costine et al, 2018). High-density techniques for tailings management have been used for several years in the mineral industry. In this regard, one of the novel and promising dewatering methods is in-pipe or inline flocculation, where the polymer is added at high dosages to thickener underflows, giving additional (likely denser) aggregation, releasing more water on deposition compared to low solids thickening. Previous research in the field of flocculation has primarily focused on the process of flocculation itself, specifically the settling rate and size of aggregates, rather than the long-term impacts of the produced tailings materials (Liu et al, 2020; Jeldres et al, 2017). This is particularly true for the novel method of this technology, where polymer is added to the thickener underflow. Furthermore, these studies have used small-scale set-ups using buckets/beakers, plungers and mechanical stirrers for the flocculation process. Unfortunately, these methods lack the necessary control over the properties of the treated tailings, which can lead to irreproducible mixing and dispersion of viscous polymer solutions (Fawell, Costine and Grabsch, 2015). Consequently, a system that can work with a wide range of operational conditions for high-solid tailings material is essential for reliable and reproducible results. The objectives of this study were to determine the effect of different type of polymers in the presence of monovalent and divalent salts on the inline flocculation of artificial tailings. The next step was to evaluate the impact of high-dosage polymer addition on geotechnical properties such as settling rate, consolidated density, rate of consolidation and the hydraulic conductivity of tailings. In addition, this research aimed to fill a knowledge gap and investigate the feasibility of using polymer-treated tailing in removing the copper ions and then quantify the performance of produced aggregates under time-dependent processes.

Aug 2, 2023

By Yuchun Wang

In principle, supported liquid membranes could be an exceedingly elegant separation process. However they tend to fail by displacement and emulsification of the organic solution in the pores, which allows mixing of the feed and strip solutions. We have stabilized supported liquid membranes comprising moctylamine in nylon and PVDF supports by covering the pores with semi-permeable polyamide films, using an in-situ polymerization technique. Scanning electron microscopy demonstrates that the polyamide films are sensitive to production conditions and the nature of the support. The transport properties of stabilized supported liquid membranes for Cr(VI) are compared with those of unstabilized membranes.

Jan 1, 1998

By P. Braga, A. Chaves, S. França, A. Luz

"In Brazil, there are no official reserves of molybdenum, and the unofficial reserves are modest. Therefore, the molybdenum ore (molybdenite) produced as a co-product or by-product of emerald mining in the region of Campo Formoso, BA, has arisen as the only economic option. The flotation process is commonly used in Brazil for the recovery of molybdenite from emerald mining tailings, but it produces low-content molybdenite concentrates, thereby resulting in a product with low economic value. The molybdenite concentrate produced in Campo Formoso contains 83.5% MoS2 (50% Mo), which is less than the international standard product that contains > 90% MoS2 (54% Mo).This low value is due to the presence of talc, which is a naturally hydrophobic mineral that is also floated with the molybdenite during the flotation process. Separability studies were done in a Partridge-Smith cell using dextrin and quebracho as a molybdenite depressor in solution at different concentrations and pH values to produce a technical-grade concentrate (i.e., 90% MoS2). These basic studies were accompanied by measurements of the zeta potential and contact angle, which was determined by the capillary rise method. The results of these floatability studies were used in bench flotation tests, which were performed in a Denver laboratory flotation cell. A molybdenite concentrate of 93.4% MoS2 was obtained when dextrin was used at a concentration of 100 g/t."

Jan 1, 2014

By M. B. Freeman

Acrylic polymers have been found to be effective dispersants and stabilizers in a wide variety of mineral processing applications including rheology control in concentrated slurries. This paper will describe these low molecular weight, water-soluble polymeric dispersants and provide a basis for how they function in concentrated slurries based on computer molecular modeling and applications results. Data on homopolymers as well as copolymers of acrylic acid will be presented to demonstrate the optimization of a polymeric dispersant in preparing high solids slurries of inorganic materials such as kaolin, calcium carbonate, lime, and magnesium hydroxide.

Jan 1, 1996

By J. C. Franklin

The Bureau of Mines substantially reduced shale degradation in a coal mine by two spray coat applications of a water-base epoxy sealant. More than 12,700 square feet of passageways were treated, and in 18 months only one failure occurred. This failure was due to improper spray application, Material costs averaged 13 cents per square foot, and labor costs were 7 cents per square foot. Labor included moving all materials into the mine, the setup time for each of the areas coated, and application of coatings.

Jan 1, 1977

By G. L. Schroeder, C. H. Summers, D. B. Lindsay

INTRODUCTION The requirement that is placed on owners and operators of underground mines to protect workers against the health hazard of inhaling radioactive materials which are short-lived decay products of 222Rn can be satisfied by applying a considerable variety of what we may call "engineering" solutions as well as a number of "administrative" remedies to the problem. The most obvious of the "engineering" approaches has always been that of forced ventilation, in which relatively clean (i.e., radon-free) air from aboveground is drawn or pushed through the mine workings by a system of fans and ducts. This relatively clean air, in sweeping through the drifts, stopes and haulageways, dilutes the radon and radon-daughter concentrations in the air of the mine, and performs the added beneficial function of removing the daughter-mixture quickly enought to limit grow-in of the longer-lived nuclides in the group that make up the "toxic trio" on which the Working Level (IM) unit is based. Effective as the dilution-ventilation method is for control of WL in most underground mining situations, however, the increasing strictness of control measures that have been imposed on the mining industry over the last two decades have demanded measures of even greater effectiveness. In times of poor markets for yellow-cake and other products of the mines, mine operators are pressed to reduce operating costs, and the installation of additional primary ventilation capacity can be a severe burden on a mine that is already laboring under an unfavorable earning power. When traditional dilution-ventilation systems alone cannot meet the requirement for WI, control, radiation safety engineers and ventilation engineers begin to look at alternatives and auxiliary methods. Since the radon which produces the toxic daughter products originates in the rock of the mine walls, and since, in most United States mines, that rock is a porous sandstone through which air can move under the effect of atmospheric pressure gradients, and through which radon can diffuse relatively freely, one way to help control the growth of WL would be to hinder the escape of radon from that reservior of porous rock. An appealing; method for hindering that natural flux of radon-polluted air from the walls of the mine has long been apparent; namely, to apply a low-permeability coating over the surface of the rock, thus sealing the radon in place and, in theory at least, preventing its escape into the mine air. Our 1970 report to the U.S. Federal Radiation Council on the subject of cost impacts of proposed changes in the occupational standards for exposure of underground uranium miners to airborne radon daughters noted the possibility of using polymeric wall sealants as a means of controlling radon-pollution of mine air. Since that time a number of reports have appeared in the technical literature advocating this technique for restraining the escape of radon from building materials, mill tailings, and other materials containing 226Ra, in addition to the surfaces of underground mine workings. During this period, some controversy has occurred over the question of the probable effectiveness of wall sealants in limiting the escape of radon from the rock. Our 1970 report speculated that flaws (cracks and "pinholes") in the coating might be all but unavoidable in practice, and that even a conservative estimate of the frequency of such flaws would lead to a prediction of ineffectiveness. Hammon et al, in a laboratory evaluation of radon sealants conducted by Lawrence Livermore Laboratory of the University of California in 1975 on behalf of U.S. Bureau of Mines, concluded that a wide variety of polymeric coatings would provide "nearly 100% effectiveness" in restrain¬ing escape of radon from mine wall surfaces if applied in "thicknesses between 5 and 10 mil" (125-250 [y]pm). John Franklin and co-workers at the U.S. Bureau of Mines laboratories in Spokane, Washington, have carried the experiments with polymeric sealants through additional laboratory tests and into actual mine environments, reporting that selected sealants could provide attenuation of radon flux by a factor of four (75-80% reduction). Robert Bates and John Edwards of USBM developed a computer-assisted mathematical/physical model that predicts a relatively small effect of flaws in a low-permeability coating on the radon flux from a sandstone-type matrix. FIELD TEST Since all actual experimental work with wall sealants showed some beneficial effect on radon attenuation (even if not as exciting as the "nearly 100%" predicted by Hammon), USBM was encouraged to extend its evaluation to an actual operating uranium mine, and awarded a contract for that work to Arthur D. Little, Inc. in September 1979. We were fortunate in obtaining the voluntary cooperation of Atlas Minerals Division of Atlas Corp., who operate a mill and several underground mines in and around Moab, Utah. Atlas made available for our use a small T-shaped drift in their Pandora Mine in LaSal, Utah, and provided space for instrumentation and recordkeeping by our field crew in a surface building near the mine entry. Atlas also provided electricity and water to the test site, together with assistance in establishing necessary ventilation, removing rubble from the site, conducting periodic WL surveys and furnishing auxiliary man-power for the heavy hard work of coating the walls with gunite prior to application of the polymeric sealant. The generous coopera-

Jan 1, 1981

By Michael A. Markowitz, Alok Singh

"Molecular self-assembly of phospholipids and other amphipathic molecules offers a versatile approach to form self-organized microstructures in various morphologies. Stabilization of microstructures in specific morphologies by polymerization renders them useful for practical applications in areas ranging from controlled release technology to template mediated synthesis of metals. Our efforts are focussed on the development of polymerizable biomembranes derived from phospholipids, their properties and utility e.g., as stable templates for studying chemistry at the lipid interface. Polymerized vesicles formed from mixtures of 1,2-bis(tricosa-1 O,12-diynoyl)-sn-glycero-3-phosphocholine, 1, with corresponding lipids having phosphohydroxyethanol,2, or -hydroxypropanol,3, headgroups have been used in electroless metal plating of vesicle surface with gold utilizing selective binding of Pd(NH3)4 2 + to 2 or 3. The surface bound palladium ion served as catalyst for metalization. Metalization of polymerized vesicles constructed from charge neutral diacetylenic phosphocholine,1, did not occur using this process. The headgroup structure of the negatively charged phospholipids and the degree of vesicle polymerization had an effect on the stability of the vesicles after metalization. Vesicles formed from a mixture of 1 with polymerizable diacetylenic phosphatidic acid, nonpolymerizable 1,2- dipalmitoyl phosphohydroxyethanol or 1,2-diacyl phosphohydroxyethanol (from soy lecithin) were not stable to metalization process. The metal coating of the vesicles was examined by electron diffraction and revealed that the gold metal on vesicles was polycrystalline and face centered cubic. The results demonstrate the utility of polymerized synthetic membranes as template for easy and efficient synthesis of nanoparticles. IntroductionPhospholipids, synthetic or natural, provide a simple and straight forward route to construct membranes in a variety of morphologies due to their inherent property of selforganization in the presence of water[1]. Vesicles are closed spherical structures comprised of concentric walls made from lipid bilayers. Vesicles are morphologically simple structures with enormous technological potential. Polymerizable phospholipids prepared by incorporating a polymerizable group in the molecules demonstrate physical properties comparable to their non-polymerizable counterparts and have the added virtue of providing enhanced physical and chemical stability to the membranes[2,3]. The size, shape and properties of the organized assemblies are dependent on the lipid structure and the nature of the aqueous environment[4,5]. The headgroup geometry, surface charge density, and spatial arrangement of the phospholipids are known to affect the surface behavior of the lipid membranes, which is evident through their interaction with other molecular (hormones, antigens, antibodies etc) or lomc species. Since phospholipid headgroup structure and charge can be modified either synthetically or by chemical perturbation of the aqueous medium (e.g., pH or ionic strength), phospholipid membrane surfaces offer a potential for developing novel strategies in those areas which involve the use of molecular reactive sites. One such strategy which could be envisioned explores the use of molecularly engineered phospholipid assemblies to design and prepare template structures to regulate formation of ordered materials [6]."

Jan 1, 1994

By Rosario Lunar, Jesús Martínez-Frías, Egidio Marino, Trinidad Torres, Jose E. Ortiz, Juan A. Martín-Rubí, Luis Somoza, Ricardo León, Teresa Medialdea, Javier González

Seamounts, submarine banks, volcanoes and undercurrent channels are prominent geomorphic features that have become an important target for minerals research and exploration with the goal of future exploitation. Polymetallic ferromanganese deposits are common types of mineralization on these settings. Co-rich ferromanganese crusts are important as potential resources of Mn and Co, but also Ti, Ni, Tl, REEs, PGEs, and other metals. Many seamounts and channels along the Atlantic Spanish continental margin are known to hold mineral deposits but are poorly studied. This work presents and briefly describes the most recent activities of the Spanish Geological Survey (IGME) on exploration and investigation of ferromanganese deposits along the Atlantic Spanish continental margin. Different submarine areas from the northwestern margin of the Iberian Peninsula to the west off Canary Islands have been surveyed by geophysical, sampling and underwater observations from 89 to 4000 m water depth. The mineral deposits cover a large diversity of submarine geological and geomorphical features: mud volcanoes and diapirs related to hydrocarbon seeps, seamounts associated with hot spot volcanism, hydrothermal vents in active magmatic volcanoes, structural basement highs and banks or contourite channels. Considering the collected dataset, we present the preliminary results of the study of these mineral deposits, including ferromanganese nodules and crusts and phosphate pavements and nodules, which can be considered as potential sources of raw materials.

Sep 1, 2014