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By Alan Fricker, Bill Owers

Cyprus Gold NZ Ltd will be recovering residual cyanide from their CIT, operation in New Zealand. The process will use air to strip the cyanide from the acidified barren pulp. DSffi. Industrial Development, who were involved in the bench and pilot studies for Cyprus, have extended the concept to pregnant pulp. The stripping of pregnant pulp eliminates the substantial loss of cyanide through carbon catalysed oxidation during the adsorption stage. A 50% increase in cyanide recovery was obtained from an extensive laboratory investigation. The presence of a cyanide recovery circuit enables leaching to be conducted, without detriment, at pHs at least as low as 9, with consequential 50% reductions in the consumption of lime and sulphuric acid. There should be a small reduction in carbon consumption, and a significant improvement in the quality of the final effiuent, at least in terms of cyanide, cyanates, copper, zinc and sulphur. A small but significant increase in gold recovery can be expected too. There is a net economic advantage of NZ$1.20/tonne of ore by stripping pregnant rather than barren pulp.

Jan 1, 1990

By Amir Rehmat

The Institute of Gas Technology has developed a fluidized-bed process for recovering direct reduced iron from blast furnace flue dust a material currently considered to be a waste from the iron and steel industry. In the process, a portion of the carbon in the flue dust is combusted to supply energy for the endothermic reaction between carbon and steam. The reaction produces reducing gases comprised of carbon monoxide and hydrogen both of which react with iron oxides to produce reduced iron. Up to 95 percent of the iron oxides contained in the waste stream can be reduced to elemental iron. The vitiated reducing gases emanating from the process can be used as fuel in the plant. The yield of iron depends upon the quantity of iron oxide present in the flue dust and generally ranges from 20 to 30 percent of the waste stream. The investment cost estimated for a single processing train dedicated to one steel plant can be recovered in less than one year.

Jan 1, 1996

Namakwa Sands, an Anglo Operations Limited subsidiary, is a world-class producer of heavy minerals. A layer of duricrust imposes a pseudo-stratigraphy to the primary deposit and has sterilized part of the generally unconsolidated ore in the open cast mine. The bulk of this ore cannot be treated by the present infrastructure, which employs conventional mineral separation technology. The mineralogy of the cementing agent consists of magnesium and calcium silicates and minor carbonates in addition to clay minerals such as sepiolite and those from the smectite group. Although the duricrust ore is friable and can be easily crushed, the significant clay-sized slime fraction produced, in particular the highly sorptive sepiolite, adversely affects mineral separation. The geometallurgical challenge is to cost-effectively remove the slimes from the ore before it is delivered to the concentrator.

Jan 1, 2007

By Ho-Sung Yoon, Jyothi Rajesh Kumar, Chul-Joo Kim, Sung-Don Kim

A recovery process for rare earths (REs) such as dysprosium and neodymium from the leach liquor of permanent magnet scrap (PMS) was developed. The two hydrometallurgical routes namely liquid-liquid extraction (solvent extraction) and selective stripping were implemented. The present study deals with the separation and recovery process development by using organo-phosphorous based extractant di-(2-ethylhexyl phosphoric acid (D2EHPA) as reagent for REs processing. Initial studies considered the influence of time on the extraction process, as well as pH and extractant concentration effects. This suggested the aqueous mechanism and separation factors played a role in process during development. McCabe-Thiele diagrams for extraction isotherms were developed. Counter current extraction (CCE) using various phase ratios influenced metals separation. Maximum loading capacity of the D2EHPA was determined. The loaded organic generated by the CCE process was water washed followed by a scrubbing process to remove the other metal ion from targeted metal. Finally, a stripping process was tested using various mineral acids.

Jan 1, 2015

By E. Allain

Extraction of basic metals from sulfides by conventional pyrometallurgical processing leads to the emission of SO2. To avoid this inconvenient, low temperature selective chlorination of sulfide concentrates could be an alternative. However, such process generates hazardous chlorides SxCly. A part of sulfur chlorides such as SCI2 can be recycled as a chlorinating agent of metal sulfides. Hydrolysis of sulfur chlorides, using a solution containing Na2S.9H2O, led to the recovery of more than 90 pct of elemental sulfur. Reduction of SxCly by hydrogen was investigated between 300 °C and 800 °C. About 70 and 90 pct of elemental sulfur were recovered from SC12 and S2C12, respectively. A flow sheet for the chlorination of metal sulfides and the treatment of sulfur chlorides was suggested.

Jan 1, 1998

By C. J. Lewis

Considerable amounts of the world's known reserves of elemental sulfur are found near the surface in areas of volcanic activity both active and inactive. Because such deposits cannot in general-be mined by the well-known Frasch process, and because other methods of recovery have not proven to be economically competitive except in isolated instances, at present these reserves remain relatively undeveloped. However, projections of world sulfur demand indicate that new sources of marketable sulfur will be needed in future years 2/, 19/. For this reason, recovery of elemental sulfur from these near-surface deposits is of continuing interest. Solvent extraction as an approach to recovery of elemental sulfur from open pit-mined ores of these non-Frasch deposits has received considerable attention particularly at the research and development level 3 /, 7/, l l /, 16/, 21/,23/, 29/ This method has been and continues to be attractive because it presents the potential of high sulfur recovery and purity of product coupled with a relatively simple process flowsheet in which low energy requirements and reasonable operating costs are thought to be possible. However, the physical and chemical characteristics of the native-sulfur ores, of elemental sulfur, and of the known solvents, have presented difficulties in the development of solvent extraction processes. Up to the present time, viable processes have not been realized within the framework of sulfur marketing conditions.

Jan 1, 1970

By S. K. Pan, M. P. Srivastava, N. Prasad

"Dalli mines of Bhilai Steel Plant, India is fully mechanized iron ore mine having wet processing system. It has a capacity to treat 5 Mt of ROM. In processing circuit of Dalli mines, scrubbing, wet screening and classification operation is being carried out. Average slime generation for the last five years is about 14% of ROM. As the mining has reached to the lower benches, fines generation is more. As a result, very fine and heavy particles, which settle fast, are being discarded with the slime to tailing pond. These heavy and faster settling particles were causing jamming in the thickeners.Laboratory investigations were carried out at Research and Development Centre for Iron and Steel (RDCIS) to suggest a suitable scheme to recover high quality fines so that the availability of thickener can improve. The slime samples were first treated in a floatex density separator. The concentrate obtained from the floatex density separator was treated in hydrocyclone. Laboratory investigations indicated that the slime with 49% Fe, 12.7% silica and 10.7% alumina can be upgraded to 62.1% Fe, 3.3% silica and 2% alumina with 36% material recovery. Based on the laboratory studies ,a system was installed at Dalli minesThe general arrangement of the system is shown in Fig. below."

Jan 1, 2003

Large deposits of eudialyte, a low grade zirconium bearing mineral, occur on the Southern Coast of Greenland in the Ilimaussaq intrusion. Various processes were tested in the laboratory to recover eudialyte from these ores, including flotation, leaching, gravity and magnetic separation. A combination of dry and wet magnetic separations has the advantage of simplicity and the least environmental impact for the location. This paper summarizes the results of laboratory testwork to develop a two-stage treatment process to recover the eudialyte by magnetic separation.

Jan 1, 1993

By C. A. Morais, L. V. Resende

"The technological development observed in recent years has stimulated the application of rare earth (RE) elements. Amongst their various applications it is well worth mentioning their use in electronics, superconductors, nuclear medicine, as well as in special inks - as those used in radar invisible airplanes. TV and computer monitor screens present as coating a powder containing some rare earth elements, mainly Europium and Yttrium. The recovery of the RE elements from electronic scrap is extremely important as the economic and environmental issues are concerned. This paper describes the study of the Eu and Y recovery from e-scraps. The first step of the process was the leaching of the powder obtained by manually scraping the inside surface of the screen. After the optimization of the leaching, the dissolution of Eu and Y was higher than 98 w/t% and a pregnant sulfuric liquor containing 11.9 g L-1 Y and 0.72 g L-1 Eu was obtained. The second step was the separation of the metals found in the liquor by the solvent extraction technique. The separation of Eu and Y was carried out in a counter current circuit compound of 3 extraction stages, 7 scrubbing stages and 15 stripping stages. DEHPA was used as the extractant, whereas a diluted sulfuric acid solution was applied as scrubbing agent and a hydrochloric acid solution at high concentration was used as the stripping agent.INTRODUCTIONThe rare earths (RE) are a moderately abundant group of 17 elements composed of lanthanides, scandium and yttrium. Amongst the RE, promethium (Pm) is extremely rare, however several of the RE elements are not very rare and occur dispersed in a variety of forms (Greenwood & Earnshaw, 1984; Tyler, 2004).The innumerable applications of the RE elements are based on their particular properties, mainly their spectroscopic and magnetic properties (Martins & Isolani, 2005). The technological development observed in recent years has stimulated the application of rare earth (RE) elements. They have been used in agriculture, electronics, superconductors, nuclear medicine, automobile industry, special inks – as those used in radar invisible airplanes, X-ray screens, high intensity mercury vapour light bulbs, neutron scintilators, charged-particle detectors and optical memory reading systems (Maestro & Huguenin, 1995; Nagaosa & Binghua, 1997; Sánchez et al., 1999)."

Jan 1, 2012

By M. A. Rabah

This study aims to recover europium, yttrium metals, some valuable salts or oxides from the white powder (apatite) coating the inner surface of spent florescent lamps (SFLs). Pressure leaching using sulphuric/nitric acid successfully dissolved the metals of interest. Europium or yttrium metals were obtained by hydrogen reduction of their oxides. Addition of potassium thiocyanate converted the dissolved sulphates to thiocyanates. Selective separation of Eu and Y was then carried out by solvent extraction from the thiocyanate solution. The used solvent was trimethyl-benzylammonium chloride. N-trihutylphosphate in 1 M nitric acid was used to strip the metal loaded in the organic phase. Results showed that the quality of the cleaned glass tubes of the SFL met the standard requirement for the lamp manufacture. The white powder (WP) is composed of calcium sulphate 35.2%, phosphate 61.5% and oxides of europium and yttrium 1.65%wt. respectively. Autoclave digestion of the WP for 4 h at 120°C and 500 kPa in sulphuric acid/nitric acid mixture dissolved 96.4% of yttrium and 92.8% of europium. The conversion rate of sulphate to thiocyanate was favoured at low temperature. Stripping of Eu and Y from the loaded organic phase behaved in an opposite way. A metal separation factor of 9.4 was obtained. ate recovered europium and yttrium salts were selectively separated using ethyl alcohol or dilute nitric acid. Yttrium was very soluble while europium was not. Europium and yttrium metals were obtained by hydrogen gas reduction at 850°C and 1575°C respectively.

Jan 1, 2004

By J. Drelich, J. Pletka

Lost foam casting patterns are foamed polystyrene shapes glued together into the shape of the part to be cast and are coated with a refractory material consisting of a mineral mixture and binders. Prior to casting, a significant number of the patterns are damaged and inevitably land-filled. In this study, a process is developed for the recovery of foamed polystyrene from the coating and glue contaminants. The process consists of shredding, impact comminution, size classification and density separation. It is successful in separating up to 97% of the contaminants, while recovering 95% of the polystyrene.

Jan 1, 2001

By Mario Sanchez, Jose Palacios, Fernando Parada

Carbon steels have less than 0.02% copper and have low atmospheric corrosion resistance. The addition of at least 0.20 wt% Cu improves this property. Also, 0.8 wt% Cu in steel shows a hardening potential for developing high strength corrosion resistant steels. Copper slags containing 42–45% of iron, silica and minor amounts of copper were used for producing Fe–Cu alloys by reducing the oxides contained in the slag to obtain a Fe-0.84 wt% Cu alloy, which could be suitable as feeding material to manufacture a corrosion resistance steel, and also would be an alternative for minimizing the copper industry ’s environmental impact, and to introduce the application of the Circular Economy concept to the natural resources exploitation, especially in countries where their economy is strongly based in mining and metallurgical extraction.

Mar 1, 2018

By J. G. Groppo, A. E. Bland, B. K. Parekh, W. F. Stotts

Many coal preparation plants discard fine coal (generally minus 100 mesh) because it is difficult to beneficiate economically. At the Kentucky Energy Cabinet Laboratory (KECL), the waste streams from several Kentucky preparation plants were evaluated for cleaning with counter-current column flotation. A series of performance evaluations were conducted using a 0.05 m (2 in.) internal diameter (I.D.) 7.9 m (26 ft.) high laboratory column. The objectives of these tests were to assess the performance in terms of recovery and percent ash in clean coal and to optimize the operating parameters relative to combustible recovery and grade. Refuse streams containing 30-50 percent ash were upgraded to 2-8 percent ash with Btu recoveries of nearly 90 percent. A pilot scale column flotation cell was installed at the Bell County Coal preparation plant. This pilot plant utilized a 5.79 m (19 ft.) high and 0.15 m (6 in.) I.D. column to verify the performance data of the 0.05 m (2 in.) I.D. column for two different waste streams. Performance evaluation and pilot plant testing results related to scale-up are discussed.

Jan 1, 1988

By B. K. Parekh, Z. Chen

INTRODUCTION The need for cleaning and recovery of fine (minus 28 mesh or 0.5 mm) coal fraction has increased in recent years. This results from realizing a substantial recovery of ultraclean coal from the waste stream improving overall Btu (heat) recovery, providing extra revenue for the coal industry. Also the potential of using the clean coal so obtained for making coal-water mixture which could replace oil. An additional benefit of recovery clean coal from the waste stream is reducing environmental concern of burning uncleaned coal and in waste disposal. Deashing of coal by physical beneficiation processes is limited by the degree to which ash components are liberated from coal. Conventional processes have been inefficient in terms of Btu recovery, for ultrafine coal. Chemical cleaning methods, which involves leaching of ash material from coal, have provided ultraclean coal at high Btu recoveries, are more costly than the physical cleaning methods. An advanced physical separation technique that appears to address the need discussed above is selective flocculation. This technique which has been successfully utilized in iron ore beneficiation offers the potential of processing fine and ultrafine coal to produce a clean fuel. OBJECTIVES The main objective of the present study is to investigate applicability of selective flocculation technique for recovery of clean coal product from the waste coal slurry supplied by the Peabody Coal co., from their three different coal preparation plants. It is also the objective of the program to conduct preliminary economic study of the selective flocculation process.

Jan 1, 2002

Recovery of Fine Gold Particles from Philippine Gold Deposits by Enhanced Gravity Concentration and Flotation The objective of the study is to determine the applicability of enhanced gravity concentration (EGC) and flotation for gold recovery. While gravity concentration methods have long been applied to gold ores, especially to free-milling types that requires minimal beneficiation, flotation for gold recovery has not yet taken hold as a major operation in the Philippine setting. In this study, the application of EGC and flotation for gold is applied and compared to the existing methods for gold recovery. Two samples, with assays of 7.315 and 5.333 g Au/MT (samples 1 and 2, respectively) are used for this study. These samples are subjected to mineralogical studies and is found to have a gold-particle size ranging 10 to 200 microns. To verify the separation size, the mesh-of-grind (MOG) is used as the primary parameter for experimentation. Initially, the samples are stage-crushed, ground, and subjected to EGC using a Falcon SB40 Concentrator. Based on the results, the two samples showed that recovery increases with a finer MOG. The ratio of concentration (K) decreases with a finer MOG. This shows that there should be sufficient liberation of the gold values for EGC to be effective. The effect of the enhancement is to pronounce the difference in specific gravity of the minerals, promoting better separation. This is validated by the high recovery values of 86.97 per cent and 98.73 per cent exhibited respectively for samples 1 and 2 (at 54 microns). For the flotation runs, sample 2 with an average particle size of 80 per cent passing 74 microns is examined using thiocarbamate-based collectors for roughing and subsequently exhibited a recovery of 96.32 per cent. At this point, the concentration ratio (K) is noted as an important efficiency indicator for flotation process since it yielded a very low-mass and high-metal content concentrate.

Sep 13, 2010

By S. Gregory

Many gold treatment plants have sulphides and coarse particle gangue components that contain gold in their tailings (cyanide leach residues and flotation tailings). Coarse and very fine liberated gold may also be present in some tailings streams. Two issues usually govern the economics of recovering additional gold from gold occluded in sulphide and gangue particles. The liberation characteristics of the gold in the sulphide and coarse gangue (gold liberation versus grind size) is the first and most important of the two. If fine grinding can liberate a reasonable amount of the gold, then the next important issue is how effectively these two constituents can be concentrated. Flotation will achieve high sulphide recovery but is usually costly. Selectivity is also an issue because of entrainment. Continuous centrifugal gravity concentration offers a viable solution to the recovery of both sulphides and coarse gangue however selectivity is also likely to be a problem. The possibility of improving concentrate grade by using a Falcon B separator was investigated. This paper describes a program of test work carried out on a gold leach tailings using a laboratory Falcon '13' separator. The program involved three different bowl angles: 10, 12 and 14 degrees and two bowl speeds (giving 250 and 350G accelerations). A number of tests were also performed on samples that had free gold present to ascertain the size-by-size recovery of gold in these samples.

Jan 1, 2005

By V. Nudo, R. del Villar, A. R. Laplante

"Fine iron ore recovery from the tails of Les Mines Quebec Cartier was investigated using Reichert trays and spirals. The effect of feed rate, density and splitter setting on the performance of rougher, cleaner and recleaner stages of a 2DS tray assembly was determined using 2- and 3- factorial experimental designs. The tray concentrate, assaying 27% Fe, was further upgraded by spiral to yield a concentrate assaying 55% Fe. Further laboratory scale testing showed this material to be easily upgraded to 65-66% Fe with high Fe recoveries.This paper presents the metallurgical results of the three tray stages. The model used to predict the performance of a full recovery circuit is then described. Simulation results are presented and their reliability assessed. Finally, an economic evaluation of the proposed scavenging circuit is summarized.INTRODUCTIONThe Mount Wright plant (UWP), located near Fermont, Quebec, processes daily 130,000-150,000 tonnes of iron ore assaying between 27 and 33% Fe, to upgrade it with three stages of 44.5 cm pitch GEC spirals to 66% Fe, while rejecting approximately 80,000 tonnes assaying between 6 and 11% Fe (1-3). Heavy liquid separation (at 3. 3 g/mL) of the plus 37 µm fraction (+400 mesh) of the tails reveals that a significant fraction of the iron is in the sink product, below 150 pm (100 mesh), as shown in Table 1. Also shown is the iron grade of the sink and float fractions. The high grade of the fine sink indicates that hematite ls well liberated below 105 µm (150 mesh), as previous studies have shown (4,5). The iron grade of the floats is very low in the fine size range, but increases with increasing size above 105 pm, because of incomplete liberation. Overall, two thirds of the plus 37 µm iron ls in the sink product, which constitutes less than 10% of the total tail."

Jan 1, 1987

By B. K. Parekh

Silicon carbide (SiC) can be produced by heating rice hulls to elevated temperature, The product is a mixture of beta crystalline silicon carbide whiskers, particles and unreacted carbon. The silicon carbide whiskers are 0.5 micron in diameter and 50 to 100 micron in length and have been found useful for reinforcing metal and other composite materials. The carbon can be removed by combustion, but this makes separation of the silicon carbide whiskers from particles difficult and a high grade whisker product cannot be made. However, a clean high grade Sic whiskers product can be obtained from the pre-burned converted rice hulls using physical separation processes that are based on differential wetting. Recovery of Sic whiskers from the pre-burned material was found to exceed 90 percent. A modification of the froth flotation process developed during this study is now being used commercially to separate silicon carbide whiskers and particles and to recover a high grade whisker product.

Jan 1, 1985

By John Hanna

Over the years the coal industry in Alabama has generated about 150 million tons of fine waste coal, increasing at a rate of 2 million tons/year, during mining and cleaning operations. Reclamation of the fine-size wastes containing 20-60% by weight clean coal provides, free of charge, mined and crushed feedstocks for coal recovery and eliminates a major source of acid water pollution. Tests were made on the impounded wastes and current plant discharges to recover the coal fraction by sizing, gravity and flotation techniques. Gravity separation of the plus 100 mesh material produced commercial grade coal averaging 8.2% ash, 0.8% sulfur and 13,350 Btu/lb. However, the coal recovery was relatively low at 50-65%. Froth flotation using mechanical and froth column methods gave similar coal products at much higher coal recovery of 87-93%. The coal produced analyzed 10% ash and 1.1% sulfur.

Jan 1, 1991

By Jr. Foot

The Bureau of Mines, U.S. Department of the Interior, investigated flotation methods for recovering fluorite and byproduct beryllium from the Fish Creek deposit of Nevada. The preferred method includes (l) fluorite rougher and cleaner flotation, (2) de sliming at 20 micrometers, (3) muscovite flotation, (4) silicate flotation, (5) hypochlorite wash of silicate concentrate, and (6) beryllium rougher and cleaner flotation from the silicate concentrate, Laboratory results showed that over 94 pct of. the fluorite was recovered in a concentrate containing 96 pct CaFz. Beryllium flotation produced .concentrates .containing in excess of 5 pct BeO with recoveries over 70 pct. A 1.00-lb/h continuous flotation unit was constructed to demonstrate this procedure,

Jan 1, 1985