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"11.1. IntroductionThe recovery of platinum-group elements (POE) from ores is a subject which has received almost no mention in the literature. Edwards (1975) refers to the process used for refining of the POE, throughout the Western World, as a so-called ""conventional"" process .... ""not because of the simplicity or convenience of the operations, but more probably because of the inertia of established processes and the aura of secrecy with which the major platinum refiners have surrounded this process."" There is no doubt in this writer's mind that the latter is also applicable to the dearth of knowledge of the mineralogy, geochemistry and ore deposits of PGE and that the poor recoveries, mainly attributed to the mineral beneficiation stages of concentration, are also affected by this traditional secrecy. Fortunately, this attitude is changing, due no doubt to the advantages that accrue from more open research which may be critically assessed in the literature in the traditional manner. Examples of this more open approach to recoveries and recovery problems are represented by Newman (1973), who gave some typical recovery percentages for Merensky Reef ores, and the recent encouragement and cooperation on mill samples from the Sudbury area by lnco Metals Company (cf. Cabri, 1981a).In general, platinum-group elements are recovered from an ore by the use of a physical concentration method, such as gravity separation or flotation, followed by further upgrading using further physical, wet chemical or pyrometallurgical techniques. The final process of refining in which the individual platinum-group elements are produced in pure form is outside the scope of this chapter.Platinum-group element deposits naturally fall into different categories according to the recovery process best suited for them, viz. those amenable to gravity separation, those amenable to flotation, and those where platinum-group elements are by-products of base metal sulphide, chromite and miscellaneous other deposits."

Jan 1, 1979

By T. M. Williams, P. M. Green

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. The sediment geochemistry of streams draining Southern Uplands and Lake District turbidites was compared with lithogeochemical data for the source greywackes, using stratigraphically defined catchments. Several systematic trends in element abundance variation between source and stream sediment can probably be applied more widely to interpretation of drainage geochemistry. Pb and Zr increase markedly from source rock to sediment, by adsorption on clay and zircon grain concentration. Variation of feldspar-related elements Rb, Sr, K and Ba appears to be controlled by source grain size and compositional maturity. Ni shows surprisingly little change and Fe and Co are only slightly raised. Cr is particularly useful, with variations superimposed in anomalously high regional levels. Abrupt changes in Cr distribution in stream sediment coincide with stratigraphical boundaries, allowing drainage data to be used as a surrogate for whole-rock values

Jun 19, 1905

By Frank Ebbutt

Introduction The property of the Britannia Mining and Smelting Company, Limited, is situated on the east side of Howe sound, about six miles from its head. It is roughly thirty miles by water from Vancouver, one of the important ports of the Pacific and the industrial and financial centre of British Columbia. Howe sound is navigable for ocean-going vessels and Britannia Beach is a daily port of call for the commodious boats of the Union Steam-ship Company, sailing from Vancouver. Few mines are so ideally situated or have so many or varied natural advantages. Copper was first found on Britannia mountain in 1888, by Forbes, but it was not until 1898 that five claims were staked here by Oliver Furry, a trapper. It is from these claims that the major production during the past thirty years has come. In 1900 the Britannia Copper Syndicate was formed and development of the property was commenced. In 1903 the late Grant B. Schley obtained control, and through his efforts the Britannia Mining and Smelting Company was organized in 1908 as a subsidiary of the Howe Sound Company. Since that time, a persistent and progressive policy has been followed, which has resulted in a prolonged and profitable operation. The country in the immediate vicinity of the mine is marked by strong relief, with mountains rising abruptly from tide-water to elevations of 5,000 feet and more. Two broad transverse valleys deeply dissect the area. These are the valleys of Britannia creek and Furry creek. The region has under-gone prolonged and relatively recent glaciation. Over much of the surface there is deep overburden and dense vegetation. The geology of the mine and vicinity has been described in reports by S. J. Schofield (1), H. T. James (2), J. G. Barry, and others (3). The present writer is in accord with much of this literature on Britannia, but during recent years, extended observations made underground have shown that the 'quartz porphyry', or 'mine porphyry', of several of the earlier writers is not the host rock to the commercial mineralization; and he contends that the mineralization occurs in highly altered phases of a complex series of ruffs, flows, and pyroclastics and their autoclastic metamorphosed products.

Jan 1, 1935

By R. V. Ramani, R. Srikanth, R. Zhao

"A two-pan study was conducted to understand the factors affecting respirable dust generation potential or dustiness of coal seams. In the first part, the data from three prior comprehensive laboratory studies was analyzed to establish quantitative relationships between respirable dust generation potential and coal characteristics. This analysis indicates that respirable dust generation rate is positively correlated with Hardgrove Grindability Index (HGI), fuel ratio (fixed carbon/volatile matter), Vitrinite Reflectance (VR), and Level of Organic Metamorphism (LOM). In the second part, specially-designed single breakage experiments were conducted to determine the primary dust generation potential of 17 coal samples obtained from four continuous miner sections, three longwall sections, and the Penn State Coal Data Bank. The single breakage study indicates that primary dust generation rate is positively correlated with fixed carbon content, fuel ratio (fixed carbon/volatile matter), VR, and LOM. Since VR and LOM are strongly influenced by the process of coalification, differences in respirable dust generation rates in different coal seams may be explained by the thermal metamorphism of sedimentary organic matter during subsurface burial.Mineral particles in the range of one to five microns, if inhaled in sufficient amounts, lead to a number of lung diseases generally referred to as pneumoconiosis. A priori knowledge of the mechanisms and rates of fine particle generation during mining can aid in the development of more effective technology for controlling primary dust generation. Unfortunately, the data and knowledge currently available are not adequate for this purpose. In fact, a committee of the National Academy of Sciences on the measurement and control of dust concluded that the knowledge of the fundamental mechanisms by which coal mine dust is generated and a part of it is entrained in the mine atmosphere as respirable dust is not sufficient to clarify, let alone control, the processes involved (Anon., 1980). Under a research contract from the U.S. Bureau of Mines, Stecklein et al. (1982) have identified a number of fundamental research issues for understanding the coal fragmentation and entrainment processes.Reduction of dust generation is the best means of control since fine particles are difficult to control once they become airborne. Therefore, considerable research efforts have been directed to understand the factors influencing dust generation and entrainment, including machine design, water sprays, and ventilation. Laboratory studies have been conducted on the mechanical action of bits and machine power requirements (Evans and Pomeroy, 1966; Roepke, 1984). Since the physical characteristics of coal play an important role in the process of breakage, a number of laboratory studies have been conducted to study the relationship between coal characteristics and respirable dust generation (Baafi, 1977; Moore, 1986; Polat, 1990; Thakur, 1971). Several studies have been conducted on the relationships between coal characteristics and airborne dust concentrations (Hamilton and Knight, 1958; Khair and Xu, 1991; Organiscak and Page, 1993; Page et al., 1993). A limited number of studies have also been conducted on the relationships between coal characteristics and airborne dust concentrations in mines (Organiscak et al., 1990). Yet, no reliable method has been developed to rank coal seams according to their respirable dust generation potential. The conclusions derived from previous studies can be summarized as follows:"

Dec 1, 1996

By R. V. Ramani, R. Srikanth

A three-part study was conducted to relate the dust generation propensity of a coal sample, defined here as the dust generation rate (grams of dust generated per tonne of coal broken), to its characteristics, in order to rank coal seams according to their respirable dust generation potential. In this paper, the results of a single breakage study on a variety of coal samples encompassing all coal ranks, and samples from operating mines are discussed. Further, where data are available, the primary dust generation rates of coal samples collected from underground coal mines are compared with the in-mine dust generation rates. The results of this analysis are then used to apply the results of this study to longwall face ventilation design. Vitrinite reflectance, and level of organic metamorphism are highly correlated with primary respirable dust generation rates of bituminous coal samples. The dust generation rates in underground coal mines are an order of magnitude higher than the primary dust generation rates in the laboratory. Depending on the type of coal, production rates, and dust control procedures, the air quantity required for airborne dust control can vary significantly. The air quantities on some high production longwalls are approaching the limits beyond which it may not be possible to reduce ambient ARD concentrations to less than 2 mg/m3 by dilution ventilation alone. In these cases, the miner's exposure should be controlled through the use of personal protective de- vices and administrative practices.

Jan 1, 1997

An extensive laboratory grinding study was carried out on a magnetite ore in order to assess the grinding behaviour of magnetic concentrate and tail from low intensity magnetic separation (LIMS).The test work involved Bond ball mill testing, rod milling, low intensity magnetic separation (LIMS), and batch ball milling down to product sizes of around P80~25 microns. A total of 18 Bond tests and over 150 batch grinding tests and sieve sizing were carried out. Throughout the grinding tests, power draw was continuously monitored. The relationship between the grinding energy and product size was analysed using the conventional energy-size concepts. It was found that the Rittinger equation fits the experimental data well. However, Bond?s equation does not fit the experimental data well, and therefore a modified Bond equation was developed. Differences in grinding properties between the magnetic and non-magnetic component were analysed and compared to the bulk ore. It was found that grinding properties differ significantly and therefore separate grinding test work may be required for each grinding step in the magnetite ore beneficiation flowsheet. Keywords: grinding, iron ores, particle size, modelling.

Jan 1, 2010

By D. F. Sangster, P. J. Hood, G. A. Gross

"Some results are presented of an integrated geological and geophysical study of Precambrian magnetite-quartz iron-formation in the Kapiko Iron Range north of Nakina, Ontario. Detailed geological and topographical mapping was carried out in conjunction with detailed geophysical investigations such as vertical magnetic field, vertical magnetic gradient, hammer seismic, horizontal-loop electromagnetic and magnetic susceptibility surveys. In addition, oriented drill cores were obtained for magnetic polarization studies.Vertical-force magnetic anomalies within individual rock units showed a strong positive correlation with topographic relief. Moreover, magnetic intensity was found not to be quantitatively proportional to the magnetite content in the rocks, due to the presence of high remanent magnetization of the magnetite. Also, the remanent polarization direction was sub parallel to the plunge of the fold structure and mineral lineation in associated rocks.Vertical magnetic gradient measurements were found to be more accurate in locating buried contacts between magnetite-quartz iron-formation and country rock than the vertical magnetic force data.An in-situ magnetic susceptibility meter was used to measure the magnetite content of iron-formation, and the measurements were subsequently compared with vertical-force magnetic results.The results of the EM survey were inconclusive; some magnetite-rich zones produced anomalies in the out-of-phase component. whereas others did not. The reasons for such inconsistencies are not yet apparent.Longitudinal seismic wave velocities measured parallel to the bedding in magnetite-quartz iron-formation ranged from 10,600 ft/sec. to 14,500 ft/sec. The seismic velocity appears to increase with an increase in deformation of the rocks."

Jan 1, 1966

By C J. Adams, H J. Campbell, A J. Tulloch, I J. Graham

New Zealand can be regarded as a rifted part of mineral-prospective eastern Australia. Geologically credible comparisons between selected trans-Tasman and SW Pacific geological provinces and units, especially those that contain significant mineralisation in Australia, can help provide a useful exploration framework for New Zealand. As part of a six-year Mineral Wealth of NZ and its EEZ (MWE) research programme, we have targeted selected geological units in eastern Australia for comparison and contrast with their potential New Zealand counterparts. In future years, the programme will focus on geological units in New Caledonia.

Jan 1, 2005

By Amauri Garcia, Rodrigo Valenzuela Reyes, Noé Cheung, José Eduardo Spinelli, Leonardo Fernandes Gomes, Rafael Kakitani

"The present research work deals with directional solidification (DS) of both Al-15wt.%Si and Al-15wt.%Si-1.5wt.%Mg alloys and further characterization of the related microstructures. The growth of refined primary Si and refined eutectic is well-known as positive in order to improve mechanical properties of the Al-Si based alloys. Alloying is also an effective method to strengthen the Al-Si based alloys, in which Mg is considered an important alloying element. However, lack of investigation regarding the effects of Mg on microstructure of these alloys is noted. So, in the present research work emphasis is given on both dendritic and eutectic growth being affected by solidification kinetics (V-growth rate and G-thermal gradient) during transient directional solidification. Experimental evolutions of microstructural spacing of both alloys have been determined which becomes possible to understand the effects of Mg coupled with the effects of growth rate on the final microstructural arrangements. A direct comparison of the tensile mechanical properties obtained for the alloys is also performed. It is shown by these correlations that the addition of Mg generally improves the tensile mechanical resistance with a minor decrease in ductility. Furthermore, the Scheil solidification path of the ternary Al-Si-Mg alloy was determined using the computational thermodynamics software Thermo-Calc, resulting in the following sequence of precipitation: Liquid-Si-a (Al)+Si- a(Al)+Si+Mg2Si. This sequence is compared with the experimental microstructure findings.INTRODUCTION Al-Si alloys containing from 4wt.% to 22wt.% Si comprise more than 90% of all Al-based castings. Parts manufactured with these alloys have a wide range of industrial applications due to their excellent castability, crack resistance, good corrosion resistance, good weldability, low density and high strength (Bray, 1976; Zolotorevsky, 2007; Reyes, 2017). Hypereutectic Al-Si alloys are widely used and researched in the automotive and aerospace sectors due to the low coefficient of thermal expansion, resistance at high temperatures, good wear resistance and high strength (Reyes, 2017; Tebib, 2013). Above the equilibrium eutectic composition (~12.5wt.%Si) the amount of primary Si particles becomes significant (Lasa, 2003). In the place of conventional hypoeutectic Al–Si, there is growing interest in hypereutectic Al–Si alloys as a candidate material for the high-quality engines because a higher volume fraction of silicon may bring about superior properties (Matsuura, 2003)"

Jan 1, 2017

By J. P. Weiler

The increasing use of high-pressure die-cast magnesium alloys in the automobile industry requires a better understanding of the mechanical properties, the microstructure, and particularly, the relationship between these two. The goal of this study is to first understand the microstructural features which control the mechanical properties observed from an AM6OB magnesium alloy, and second, to be able to predict the local mechanical properties based on microstructural features encountered in different areas of the die-cast component. The two main tools used in this study are spherical indentation testing, used on local areas of the die-cast magnesium alloy AM6OB to detect changes in microstructure and mechanical properties, and X-ray tomography, used to non-destructively investigate the internal porosity in a sample. The results from these tests are then used to predict the local mechanical properties such as the yield stress, the strain-hardening characteristics, and the fracture properties of the AM6OB component.

Jan 1, 2006

By Alan D. Smith

Mine roof fall characteristics of 250 falls in 5 different room-and-pillar coal mines, located in Pike, Martin, and Floyd counties, were investigated to determine the relationship of selected parameters associated with roof failure and the assumed condition of the mine roof before failure. The selected parameters used in the study included: presence of cracks and water before the occurrence of fall, sloughing of coal ribs, floor heave condition, type of roof support (resin or mechanical anchor bolts), distance to coal face, and time of occurrence of fall after initial coal extraction. In addition, research hypotheses, utilizing multiple linear regression techniques, were generated to test the relationship among the selected parameters and mine roof condition. The results indicated that the vast majority of falls portrayed some presence of water before the actual fall, occurred in less than 30 weeks after initial coal excavation, located usually greater than 30 meters from nearest coal face, gave evidence of cracks in mine roof before occurrence of fall, generally portrayed a good roof condition before the fall, showed presence of sloughing of coal ribs, and gave no occurrence of floor heave before occurrence of fall. In terms of the characteristics of the original support systems in the mine roof falls studied, most roofs were either supported by mechanical-anchor bolts or resin or full-column bolts; very rarely did the roof appear to fail if supported by posts or cribs. A detail inspection of the hypothesis and model comparison results gave supporting evidence that the condition of the roof is not dependent on the usual indicators of potential failure, such as presence of cracks and moisture. In fact, in most cases of mine roof failure, the immediate roof condition was rated as good or better, which gives little or no indication of pending failure and collapse. Hence, a combination of factors that are not easily accessible to measurement, are the dominant factors in the determination of roof fall-potential areas.

Jan 1, 1984

By P Mitchell, J Proffett, I Munajat

Batu Hijau is an island arc porphyry copper-gold deposit located in the southwest corner of Sumbawa Island in the Sunda-Banda archipelago of Indonesia. Southwest Sumbawa Island is underlain by Early Tertiary, low-K calc-alkaline to weakly alkaline volcanic and intrusive rocks. Within the mine area the oldest exposed rocks are medium- to thick-bedded, medium to coarse andesite volcanic lithic breccia, thin bedded, fine-grained volcaniclastic sandstones and mudstones and hypabyssal porphyritic andesite. In the eastern portion of the mine area there is a thick sequence of quartz diorite that postdates the andesites. A small stock of Equigranualar Quartz Diorite predates the Batu Hijau deposit and occupies the contact between the andesitic volcaniclastic sequence of rocks and the Porphyritic Quartz Diorite. Batu Hijau is a world-class copper-gold deposit that has a drill indicated mineable reserve of 914 million metric tonnes grading 0.525 per cent copper (10.58 billion pounds copper) and 0.403 g/t gold (11.8 million ounces gold). Mineralised material not in reserve accounts for an additional 580 million metric tonnes at 0.328 per cent Cu (4.19 billion pounds copper) and 0.171 g Au/T (3.19 million ounces gold), and including an oxide copper resource of 57 million tonnes at 0.37 per cent Cu and 0.12 g Au/T. Copper and gold mineralisation is directly related to quartz veining and wall rock alteration that developed with multiple tonalite porphyry intrusions. The tonalites were emplaced along the contact between the andesitic volcaniclastic rocks and quartz diorite intrusives. Copper and gold are zoned around the porphyry intrusions, which are designated by their contact-age relationships and other features as Old Tonalite, Intermediate Tonalite(s), and Young Tonalite(s). The Old Tonalite was the first copper-bearing intrusion, and although it is the smallest intrusion it has the highest quartz vein density, the strongest alteration and the highest grade. At least two tonalite porphyry intrusions followed the emplacement of the Old Tonalite. Each of these intrusions was associated with less quartz veining, weaker hydrothermal alteration and lower grade copper and gold than the previous intrusion. The intrusive cycle culminated with the emplacement of the Young Tonalite, which contains relatively few quartz veins, is weakly altered and mineralised. Hypogene hydrothermal alteration and sulphide mineralisation developed in five temporally and spatially overlapping stages. These stages consist of Early, Transitional, Late, Very Late, and I Zeolite alteration. Early alteration and sulphide mineralisation accompanied each tonalite porphyry intrusion, but with diminished intensity in each subsequent intrusion. Transitional and later stages of alteration and mineralisation postdate the tonalite porphyries and overprint Early stage alteration and mineralisation. Early alteration and mineralisation consisted of biotisation, secondary magnetite and plagioclase development, fine porphyry-style stockwork veining and ore mineralisation. Magnetite-biotite????quartz stringers and dark micaceous (biotite-sericite) veinlets were developed. The veinlets were accompanied by biotisation of magmatic mafic minerals and groundmass. Thin, irregular and discontinuous æAÆ type quartz veinlets and fine-grained chalcocite, digenite and bornite mineralisation accompanies the Early alteration. It is hypothesized that most of the copper mineralisation was originally deposited as bornite, digenite and chalcocite. Secondary plagioclase was added along the selvages of the early quartz veinlets. Early alteration is pervasive within and proximal to the tonalite porphyries. In the distal portions of the deposit, andalusite and anthophyllite formed at intermediate to shallow depths, and in the deeper portions of the deposit, respectively. The andalusite and anthophyllite probably developed at the same time as the early magnetite-biotite-quartz alteration in the core of the deposit. Transitional-age alteration consists of oligioclase/albite-sericite-chlorite- quartz-¦vermiculite and is associated with æBÆ quartz veins. Through-going planar æBÆ veins are thicker than æAÆ and æA-familyÆ veinlets and have chalcopyrite????bornite along vuggy centrelines and narrow oligioclase????albite alteration envelopes. Rare æCÆ chalcopyite¦quartz veinlets were also formed during Transitional alteration. During Transitional alteration early copper sulphide minerals (chalcocite, digenite and bornite) are converted to bornite and chalcopyrite. The majority of the copper (50 - 70 per cent) in the deposit is contained in ores in which chalcopyrite is the predominant sulphide. Late alteration consists of feldspar destruction and replacement by sericite and other minerals. The late alteration is accompanied by the development of æDÆ sulphide veinlets and veins. These veins consist of pyrite and quartz????chalcopyrite. Within the halos of the late pyritic veinlets biotite is replaced by sericite, quartz-sericite, quartz-andalusite, or quartz-pyrophyllite+kaolinite replace plagioclase, and magnetite is converted to specularite and/or pyrite. In the periphery of the deposit, the feldspar destructive alteration, together with outer zones of Transitional-age alteration, constitutes what is commonly referred to as a æpropylitic zoneÆ. Very Late hydrothermal alteration is also characterised by feldspar destruction, but differs from Late alteration in that feldspar is replaced by smectite in association with sericite and chlorite. Sulphide mineralisation in this stage consists of sphalerite, galena, tennantite, pyrite and chalcopyrite. The last stage or I Zeolite alteration consists of low-temperature, open space filling consisting of stilbite or laumontite¦calcite. Supergene oxidisation of the orebody extends to a maximum depth of 210m. Isolated deep oxidation occurs along open fracture zones to depths of ~400 metres along æDÆ vein filled fracture zones. Weak supergene copper enrichment occurs in a thin horizon (15 to 60 m thick) that blankets the top of the deposit. The main supergene copper mineral is secondary æsootyÆ chalcocite replacement of sulphide grains and as veins.

Jan 1, 1999

By John R. Keith

Keith, John R. 1968. Relationships of lead and zinc contents of trees and soils, Upper Mississippi Valley District. Preprint, Fall 1968 Meeting, Soc. Mining Engineers of AIME. Lead and zinc contents of elm, maple, and oak trees and of soils in which the trees grew were determined in samples from the Upper Mississippi Valley mining district, and from an area outside but contiguous to the district. The lead and zinc analyses of plant materials served to differentiate the mineralized and non-mineralized areas. Stems contained about two times as much lead and about 2-5 times as much zinc as did leaves taken from the same stems. Lead and zinc analyses of all soil horizons could be used to differentiate between the two areas. Soils at most sample sites in the mineralized district seemed to be more reliable than plants for geochemical prospecting and are a more practical sampling medium. Soil samples from areas with thick loess cover, however, failed to indicate the presence of mineralized bodies whereas tree samples from the same sites contained anomalous amounts of lead and zinc. It is suggested that in areas of thick loess cover plant samples could be used in prospecting for lead and zinc.

Jan 1, 1968

By Frank Ebbutt

In this paper it is proposed to point out certain structural factors that; have an important bearing on gold deposition. The subject will be treated; more or less generally. Although the writer has had access to a great many; of Canada's gold mines he does not wish to take the liberty of discussing; details of any particular mine or mines; the aim will be to discuss controls; that are evident in many places.

Jan 1, 1954

By Kevin O?Callaghan

Applying Legal Concepts - The Crown must consult, and where necessary accommodate, when: - Crown has knowledge, real or constructive, of the potential existence of Aboriginal rights or title and contemplates conduct that might adversely affect it - Duty to consult is triggered at a low threshold - How much consultation necessary? - Proportional to the strength of claim and potential impact - Spectrum: notice to direct involvement in decision making - Not duty to agree or to get consent (no veto) - Reciprocal: Duty requires good faith and sincere engagement on both sides Role of Proponents: Crown may delegate procedural aspects of its legal duty

May 1, 2010

By W. F. Holbrook

IN a previous paper1 a method for the measurement of the comparative desulphurizing power of slags was described and data were presented covering the range of likely slags containing up to 10 per cent MgO In the present work the range is extended to include slags containing up to 20 per cent MgO, and the effect of temperature on 5 per cent and 15 pen cent MgO slags over the range 1475° to 1525° C is included The method used was that described in the previous paper except that some of the temperature measurements were made with a noble-metal thermocouple instead of a tungsten-graphite thermocouple Twelve-gram charges of 0 8 per cent sulphur-metal and 5-gram charge-, of slag were subjected to heating for 30 nun at a prescribed temperature The charges were analyzed for sulphur content For purposes of comparison, desulphurizing power is defined as the ratio of the percentage of sulphur found in the slag to that found in the metal Six slag and metal charges were made coincidentally in 5/8-in holes in a section of an electrode graphite rod One slag and metal charge was used as a control by means of which adjustment in the desulphurization value could be made for small variations in temperature and other factors For convenient presentation of the data, the slags are arranged in groups in each of which one of the four main slag components is constant Thus, the 15 per cent MgO slags are presented separately from those containing 20 per cent MgO SLAGS WITH MAGNESIUM OXIDE CONSTANT 15 Per cent MgO -The data on slags containing 15 per cent MgO cover a composition range of 24 to 50 per cent SI02, 5 to 27 per cent A1203 and 24 to 53 per cent CaO Variation in composition has been in steps of 2 per cent over much of the area Because the change in desulphurization power is generally gradual with gradual change in composition, certain sections have been covered m steps of 4I per cent and even

Jan 1, 1938

By W. F. Holbrock

IN a previous paper1 a method for the measurement of the compara-tive desulphurizing power of slags was described and data, were presented covering the range of likely slags containing up to 10 per cent MgO. In the present work the range is extended to include Tags containing up to 20 per cent MgO, and the effect of temperature on 5 per cent and 15 per cent MgO sings over the range 147.5° to 1525° C. is included. The method used was that described in the previous paper except that some of the temperature measurements were made with a noble-metal thermocouple instead of a tungsten-graphite thermocouple. Twelve-gram charges of 0.S per cent sulphur-metal and 5-gram charges of slag were subjected to heating for 30 min. at a prescribed temperature. The charges were analyzed for sulphur content. For purposes of comparison, desulphuriz-ing power is defined as the ratio of the percentage of sulphur found in the slag to that found in the metal. Six slag and metal charges were made coincidentally in holes in a section of all electrode graphite rod. One slag and metal charge was used as a control by means of which adjustment in the desulphurization value could be made for small varia-tions in temperature and other factors. For convenient presentation of the data, the slags are arranged in groups -in each of which one of the four main slag components is constant. Thus, the 15 per cent MgO slags are presented separately from those containing 20 per cent MgO.

Jan 1, 1938

By C. J. Sullivan

"The outlook for supplying the world's metal needs in the next twenty-five years is good, although in several cases basic costs are likely to increase with rising demand. Metal prices calculated at a constant dollar from 1900 to the present show that for nickel, copper, silver, lead, zinc and tin, prices -and presumably production costs -fell from 1900 to the early 1930s. Since then, they have generally risen, apparently reflecting some depletion in relation to demand. This tendency has been accentuated since the post-World War II adoption of managed, full-employment, growth economics, which have resulted in a sharp escalation in world demand for metals. (Abandonment of such policies, apparently now under consideration in North America, would, of course, affect the pre-dictions of this paper.) Nevertheless, metal prices generally are still below those prevailing in 1900. Exploration potential exists for disseminated ores of many metals still thought of as characteristic of lode and vein deposits. These include uranium, silver, gold, tin and nickel and, to a lesser extent, lead and zinc. Considering the discovery potential for some principal metals in relation to expected demand and prices, I would tend to rate them as follows: molybdenum, zinc, lead, uranium, silver, gold, tin, nickel and copper."

Jan 1, 1970

By Ralph Sherman

IN these days of intense competition for the domestic fuel market much is heard of the low efficiencies with which solid fuels, and most particularly bituminous coal, are burned in domestic heating equipment. In contrast to the every-day operating efficiencies of 85 and 90 per cent in large, central, electric-generating stations, efficiencies of 50 per cent and lower are cited for the hand-fired home furnace. Just as the miles per gallon of gasoline is only one of the factors that determine the cost of operation of an automobile, so the thermal efficiency is only one factor in the cost of domestic or other heating. The purpose of this paper is to analyze the total costs of domestic heating by various fuels and types of equipment, to determine the relative importance of efficiency and other factors, and to discuss what this signifies relative to the future of the use of fuels in the home.

Jan 1, 1933

By E. P. Mathewson

THE experiments described in this paper were made at the Washoe Reduction Works, Anaconda, Mont., for the purpose of determining the relative speed of elimination of the iron, sulphur and arsenic during the process of bessemerizing copper-mattes. The samples were taken from a horizontal "barrel" converter, 8 ft. in diameter and 12 ft. 6 in. long, having an average charge of 9 tons of matte, and blown with a 16-1b. air-pressure. All samples were taken with the blast on, turning the converter from its normal blowing-position to nearly verti¬cal, so that a conical mold, with a long handle attached to a horizontal rod, could be introduced from a platform above the converter into the mouth of the converter and a sample taken. The difficulties of taking a sample with the blast on are appar¬ent, and the irregularities of the lines in Figs. 1, 2 and 3 can be readily accounted for by the amount of slag in the samples. On the whole, the plotting of the results gives comparatively uniform lines, considering the conditions. The samples were taken by the regular sampling-force of the works at 10-min. intervals, as shown in Tables I., II and III, which also give the chemical analysis of the samples so taken. The test shown in Table I. was made with a new converter; that of Table II with a converter that had made three charges and had been cleaned out; that of Table III with a converter that bad blown one charge to white metal, and had then been " washed " out and used for the test. In plotting these results, it was necessary to take, as a basis, the percentage of copper in the samples. This basis does not exactly represent the true condition, since the volume is constantly decreasing and a certain quantity of copper passes into the slag, but it is as near as can be obtained in practice. Take, for instance, in Table I., the sample No. 5, which shows : Cu, 59.9;

Jan 1, 1907