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By M. M. Monte

A method for removing metallic mercury from contaminated tailing, using the flotation process, is described. In order to define some relevant parameters for the mercury flotation system, microflotation and electrophoretic mobility tests were carried out on (pure) metallic mercury in the presence of several surfactants. Based on the results obtained from fundamental studies a series of bench scale flotation experiments with mercury containing tailings from two wetland sites in Brasil were done. The results of microflotation tests with mercury showed that by using cetyl trimethyl ammonium bromide, an increase in mercury flotability is observed in the acid pH range, whereas in the presence of potassium oleate the highest mercury flotability was found in the alkaline pH region. The mercury flotability using potassium amyl xanthate was improved by the addition at sodium dithionate as an activator. The bench scale flotation tests with contaminated tailings from Poconé (brazilian wetland site) showed a recovery of 70% when sodium dithionate was used as activator and potassium amyl xanthate as collector. The resulting coefficient of separation is around 60%. However, the results of the flotation experiments with fine fractions from amalgamation tailings from Peixoto de Azevedo (brazilian wetland site) showed a low mercury recovery (32%).The results from this work suggest that since in the Poconé site tailings, the metallic mercury is not completely associated to the finer particles, the flotation process to recover the metallic mercury seems very promisor.

Jan 1, 1996

By Phil Allen

A synthetic fiber manufactured by one chemical company has been treated by another chemical company to produce a cloth fabric capable of performing ion-exchange functions. Only a few delimiting parameters have been established. This paper will discuss briefly the highlights of a functioning ion-exchange cloth. Throughout the paper this fabric will be referred to as "Fabric Z".

Jan 1, 1970

By Matheus Tocchini, Henrique Kahn, Juliana Antoniassi, Carina Ulsen, Eldon Masini

"Sand and gravel are the second and third largest minerals in production in Brazil, and this is increasing noticeably. The extraction of natural sand from river beds is increasingly restricted and most of the sand used in large cities comes in from more than 150 km away, resulting in high transportation costs. As a result, it has become more common to use crushed rock as artificial sand. The main difficulties in this process are controlling the shape of the particles and the content of deleterious materials, such as mica. Within this situation, this paper presents an alternative to using artificial sand for concrete use. Our procedure involves the following steps: a) sampling sand from different production days, b) characterizing the bulk sample by particle size and shape distribution, chemical composition by X ray fluorescence and mineralogical composition by X ray diffraction, c) removing fine grains by air classifier, d) performing intensive attrition with high pressure washing and e) characterizing products. The results demonstrated that this sample contains a huge proportion of fine grains and a notable content of mica, which is distributed along all sieve fractions. The presence of mica makes the use of sand in concrete unfeasible, moreover scanning electron microscopy analysis demonstrated that this phylossilicate is finely grained and associated with coarse fractions. Thus, the removal of fine fractions made possible a partial reduction in mica content. Furthermore, intensive attrition demonstrated that the procedure was efficient to remove most of the mica while also reducing sharp edges, which improved the shape of these particles."

Jan 1, 2014

By J. Seo, W. Kim, I. Bae

"Microcrystalline silica impurities such as quartz and opal-CT commonly associated in bentonite should be controlled and removed as far as possible when bentonite is used as biocompatible raw material because they show sufficient evidence of carcinogenicity. Since opal-CT contained in bentonite in trace amounts cannot be well separated by conventional sedimentation method, in this work, the ultrasound-assisted removal of the impurity was attempted. Irradiating ultrasound into bentonite-water suspension promoted the production of fine montmorillonite particles in the suspension and the production markedly increased when montmorillonite was activated by Na2CO3. Subsequent centrifugation of the suspension made it possible to recover pure montmorillonite particles as an overflow product. Only 16.2 mass % of total solids was recovered as an overflow from the non-activated suspension, whereas 63.5 mass % was recovered from the activated suspension at centrifuging speed of 10000 rpm. Increasing sonicating time enhanced the yield of overflow, however, excessive sonication up to 10 min hindered the purification of montmorillonite. It was observed that the peak reflection of (101) plane of opal-CT in overflow increased as sonicating time increased during prolonged sonication. INTRODUCTION Bentonite consisting predominantly of mineral montmorillonite is clay-rich soft rock generated frequently from the alteration of volcanic ash. Depending on the nature of its genesis, bentonite contains a variety of accessory minerals, which may include mainly quartz, feldspar, opal cristobalite/tridymite (opal-CT), calcite, illite and mica. The presence of these accessory minerals can impact the industrial value of the deposit, reducing its commercial value depending on its applications. Therefore, bentonite is often purified by removing these impurity minerals for special applications where specific properties and characteristics are required (Murray, 1999). Among the special applications, bentonite is often used in the cosmetic and pharmaceutical industry as both excipient and active ingredient in the forms of liquid (suspensions, emulsions), semi-solid (creams, ointments) and solid (powder, capsules and tablets). The basic requirements for bentonite to be used as raw material are pure, microbiological and mineralogical inertness. Physical properties such as swelling volume and gel formation are also important. Particularly, microcrystalline silica polymorphs such as quartz, cristobalite and opal-CT should be controlled and removed as far as possible because they show sufficient evidence of carcinogenicity in humans."

Jan 1, 2018

By Jiangtao Li, Zhongwei Zhao, Xingyu Chen, Xuheng Liu

In tungsten ion-exchange process, excessive sodium impurity enters into ammonium tungstate solution. However, the Na content of the final ammonium paratungstate (APT) product must be strictly controlled. Consequently, it is necessary to remove Na from the ammonium tungstate solution during processing in order to obtain the required purity of APT. In this study, porous Na specific absorbent, Na1+xAlxTi2−x(PO4)3, is used to remove Na from the ammonium tungstate solution. Through experiments, the effect of reagent concentration of Na1+xAlxTi2−x(PO4)3, reaction time, reaction temperature and Na concentration on the Na removal were investigated. The results showed that under optimal reaction conditions of reagent amount of NATP 1.0 times of theoretical amount, reaction temperature 25 °C and reaction time 15 min, the Na removal from commercial (NH4)2WO4 solution can reach 98%. Na1+xAlxTi2−x(PO4)3 has a good applicability to different Na+ concentrations. The obtained APT product reaches the national standard purity of zero level.

Jan 1, 2014

By Jerry D. St. Clair

A multidisciplinary team of scientists and engineers at Wont has been working to understand heavy metal contamination of DuPont process waste streams and technologies for abatement of these metals. As part of this effort, an extensive study was made of a specific waste stream of importance in DuPont's environmental commitment. This 200 gpm stream contains 5-5000 ppm of nickel plus a variety of inorganic and organic constituents. The chemical complexity of the waste rendered conventional. alkaline precipitation ineffective, and only through the simultaneous application of analytical characterization, fundamental chemical understanding, and process engineering did effective technical approaches emerge. In this instance, ion exchange, sulfide precipitation, and caustic digestion ultimately proved successful in reducing the nickel to below the 1 ppm target. The results of this study will be presented, along with key learnings about the process of solving heavy metal contamination problems.

Jan 1, 1994

By Pollard D. M

The removal of nickel from lead by sulfur drossing was investigated using a technique which models industrial batch decoppering practice. Successful denickeling to 0.005% (Ni)pb was consistently obtained in the absence of silver, well below the experimental equilibrium value of 0.015% but still above levels obtained in industrial practice. Silver appeared to have little effect upon denickeling. The final nickel content was dependent upon the initial nickel content, the total sulfur addition and the stirring time. The presence of nickel was found to give no assistance to successful decoppering. Simul- taneous removal of nickel and copper was observed at silver contents in excess of 0.02%. Extended stirring resulted in a further lowering of the nickel content but reversion of copper to the bullion was observed. Experimental work has shown that nickel can be removed by a standard decoppering operation; a procedure which is used in secondary lead re- fining. Alternatively nickel can be removed during initial decoppering in primary lead re- fining operations.

Jan 1, 1987

By Yue Tian, Shengqian Wang, Lifeng Zhang

This paper is to discuss the removal of non-metallic inclusions from molten steel using a high frequency magnetic field. In experiments, a certain amount of aluminum was added to the molten steel in a crucible to generate aluminum inclusions. A layer of aluminum clusters were observed close to the wall of the crucible after the electromagnetic (EM) field was imposed. Three dimensional EM field and fluid flow simulation were performed and showed that over 91% inclusions transported to the skin depth (2.31 mm) of the molten steel. The calculation of inclusion removal agreed well with the experimental observation. The separation mechanisms of inclusions from the molten steel by the high frequency EM field were discussed.

Jan 1, 2014

By Todd Smith, Brigitte Lacouture, Greg Anderson, David Lin

"The lead and zinc flotation circuits at Red Dog Mine are preceded by a preflotation circuit which recovers naturally-floating organic carbon contained in the ore. Organic carbon is a potential contaminant in the lead concentrate and is detrimental to lead-zinc selectivity. Prior to 2007, the Red Dog preflotation circuit consisted of a single stage bank of tank cells which floated the organic carbon. The preflotation concentrate was discarded directly to tailings, however, this stream contained significant amounts of lead and zinc. Zinc loss to preflotation ranged from 2% to 6%, relative to the zinc in the mill feed and was proportional to the amount of organic carbon in the ore. The main mechanism of the zinc loss was entrainment.Pilot plant and modeling testwork were conducted to examine the use of a Jameson Cell to clean the preflotation concentrate. Results indicated that up to 90% of the zinc deporting to preflotation concentrate could be returned to the flotation circuit for recovery. The installation of a 5.4 m Ø Jameson Cell with 18 downcomers was initiated in June 2006. The new preflotation cleaning circuit was commissioned in March 2007. Conservatively, preflotation cleaning has resulted in zinc and lead absolute recovery gains of 1.0% and 1.5%, respectively. The $9.1M project has a payback period of approximately 1 year at current metal prices.INTRODUCTIONRed Dog Preflotation CircuitRed Dog Mine is located above the Arctic Circle in northwest Alaska. It is the world’s largest zinc concentrate producer with a production rate of more than 1.0M t/yr. Red Dog is operated by Teck Cominco Alaska Incorporated under an operating agreement with the Northwest Alaska Native Association (NANA). Due to the remote location of the mine, it is accessible only by air, or seasonally, by ocean-going barges.The Red Dog deposit is a rich sedimentary exhalative (sedex) zinc-lead-silver deposit. The major sulphides, in decreasing order of abundance, are sphalerite, pyrite, galena and marcasite. Due to the complex nature of the ore body, run-of-mine ore is blended in stockpiles before being crushed and processed through the concentrator. The average mill feed grade for 2006 was 6.1% lead, 20.6% zinc, 8.0% iron and 0.67 % organic carbon."

Jan 1, 2008

By V. T. Panayotov, M. I. Panayotova

Wastewater from mining and mineral processing activities is often polluted by anion forming metals, such as molybdenum and chromium. Low cost materials, including zeolites, are studied for removing heavy metals from wastewater. It is widely accepted that natural zeolites are not effective in removing metals in anionic form. The paper presents study on use of metal modified natural clinoptilolite to remove Mo (VI) and Cr (VI) ions from model soft wastewater. Modification with Pb, Fe(III), Zn and Ba increases clinoptilolite uptake capacity with respect to Mo(VI) at low pH values of the water subjected to treatment, the efficiency decreasing in the order Pb > Fe(III) > Zn > Ba. Only lead-modified clinoptilolite shows high uptake of Mo(VI) in acidic, neutral and slightly alkaline conditions. Modification with Pb, Ba and Fe(III) increases zeolite uptake capacity with respect to Cr(VI) from neutral water. The effectiveness of Ba-modified zeolite decreases in slightly acidic water. Over 90 % uptake of initially available Cr(VI) is achieved by lead-modified clinoptilolite both under neutral and slightly acidic conditions. Increasing the initial pollutant concentrations increases the removed amount both of Cr(VI) and Mo(VI) for Pb-modified clinoptilolite. The findings could be a basis for using the natural clinoptilolite to remove in consecutive steps: firstly Pb(II) and/or Fe(III) ions and then loaded zeolite to be used for Mo (VI) and/or Cr(VI) removal. The kinetics of Mo(VI) uptake by CL-Ba, CL-Fe(III), CL-Pb, and CL-Zn is best described by the pseudo-first order kinetic equation. The kinetics of Cr(VI) removal by CL-Ba, CL-Fe (II), CL-Fe (III) and CL-Zn is best described by the pseudo-first order kinetic equation. Kinetics of Cr(VI) removal by CL-Pb obeys the equation for the first order irreversible reactions. Finding way to remove anions-pollutants from the mineral processing wastewater will render this industry more environmentally friendly and socially acceptable.

Jan 1, 2016

By Chikabumi Yamauchi, Masami Tashiro, Toshiharu Fujisawa, Hiroyuki Snano

"Rare earth metals usually contain large amount of oxygen because of their reactiveness, and therefore oxygen removal is one of the major problems on the purification of rare earth metals. In the present research work, halide flux treatment at high temperature under inert gas atmosphere was applied to the oxygen removal from neodymium. NdF3 was used as a halide flux. Deoxidation reaction and its mechanism were discussed based on the experimental results. Halide flux treatment is very effective for oxygen removal from rare earth metals.IntroductionSolid Sate Electrotransport (SSE) process has been successfully applied for the elimination of interstitial gaseous impurities from chemically active metals[l]-[5]. However, to achieve a higher effectiveness of the SSE process, it is required a very low initial impurity content in the metal. In case of rare earth metals, it is known that they usually contain large amount of oxygen that should be lowered as much as possible before applying the SSE process. In addition, if effective oxygen removal is achieved by simple process, it is significant also from the industrial viewpoint. In the present work, the application of a halide flux treatment is investigated to remove oxygen from neodymium by using NdF3 as a flux. At first, deoxidation reaction and its mechanism were discussed based on the phase diagram of the Nd-NdF3-Ndp3 quasi-ternary system. Based on the results, oxygen content in deoxidized neodymium was calculated theoretically and it was verified by deoxidation experiments."

Jan 1, 1998

By T. H. Udayashankara

Soil pollution, a very serious environmental problem, has been attracting considerable attention in recent years. It is now generally recognized that land as a component of the environment deserves the same attention and protection as water and air. This recognition has arisen perhaps because of increased incidents of land pollution, the scarcity of land, and increased awareness and concern about long-term effects of land pollution on terrestrial and aquatic eco-systems and on ground water quality. Contamination of land results from a wide range of human activities, including industrial discharge process, disposal of wastewater and agriculture. The environmental impact of exploration, production and refining of crude oil is a major concern in developed and developing countries. Because of the known adverse effects of petroleum hydrocarbons on soil ecology and fertility there has been growing interest in the development of efficient technologies for the remediation of contaminated land, with a view toward making it available for further use. Crude oil is a natural product and as such is susceptible to degradation by naturally occurring micro flora. Bioremediation has become an important method for the restoration of oil-polluted environments. A bench scale study was conducted to evaluate the bioremediation technique in treating soil contaminated with transformer oil. The steps involved in this study are: (1) Preparation of contaminated soil, (2) Extraction of PAHs and PCBs from contaminated soil, (3) Treatment of contaminated soil in slurry batch reactor, and (4) Analysis of PAHs and PCBs by gas chromatography technique. The performance of reactor was assessed by measuring parameters like COD, PAHs and PCBs. The study was con-ducted for six different pulp densities ranging from 20% to 40%. The maximum removal of PAHs and PCBs was observed for 20% pulp density.

Jan 1, 2008

By Joo Hyun Park, Soo Sang Park

The distribution behavior of Pb between molten copper and FetO-SiO2 (-CaO, Al2O3) slags was investigated at 1473 K (1200 oC) and p(O2)=10-10 atm in view of the reaction mechanism of Pb dissolution into the slag. The distribution ratio of Pb (LPb) decreases with increasing CaO content (~6 mass pct) irrespective of Fe/SiO2 ratio (1.4~1.7). However, the addition of alumina into a slag with Fe/SiO2=1.5 linearly decreases the LPb, whereas a minimum value is observed at about 4 mass pct Al2O3 at Fe/SiO2=1.3. The log LPb continuously decreases with increasing Fe/SiO2 ratio, and the addition of Al2O3 (5 to 15 mass pct) into the silica-saturated iron silicate slag (Fe/SiO2 < 1.0) yields the highest Pb distribution ratio. The log LPb linearly decreases by increasing the log (Fe3+/Fe2+) value. The Pb distribution ratio increases and the excess free energy of PbO decreases with increasing Cu2O content in the slag. However, from the viewpoint of copper loss into the slag, the silica-saturated system containing small amounts of alumina is strongly recommended to stabilize PbO in the slag phase at a low Cu2O content.

Jan 1, 2014

By Qingzhu Li

The adsorption process of Pb2+ from aqueous solutions by spent grains modified with Imol/L NaCI solution was investigated. The effects of solution pH, contact time, adsorbent concentration, initial Pb2+ concentration, particle size on Pb2+removal were also studied. The initial adsorption process was rapid and 90.35% of Pb2+ adsorption occurred within 30 min. The absorption equilibrium was obtained at 4h. When pH was 5.5, Pb2+ concentration in aqueous solutions decreased from the initial content of 20 mg/L to 0.0 I mg/L after 5 hours by application of IOg/L adsorbent at 25?C, Pb2+ removal efficiency reached up to 99.95% and the Pb2+ remaining in aqueous solutions was under China Sanitary Standard for Drinking Water (GB5749-85). Adsorption data fitted well with Lanf+muir and Freundlich models. However,Langmuir isotherm model was better to descnbe Pb- adsorplion than Freundhch model, mdlcatmg that the applicability of monolayer coverage of Pb2+ on the surface of adsorbent.

Jan 1, 2008

By C I. Edwards

Phosphorous is typically present in iron ore either in the mineral apatite, Ca5(PO4)3OH, or associated with the goethitic fraction of the ore. In this paper, we present results that show that phosphorous associated with the goethitic fraction can be removed with a heating pretreatment around 300 176;C for 1 h, followed by a caustic leach with 1 - 5 M NaOH, or a leach with sulfuric acid at pH 0.5. The heating pretreatment is considered to dehydroxylate the goethite to form a haematite intermediate phase, ‘protohaematite’, that reacts during the leach making the phosphorous accessible to the leachant. In the acid leach, ten to 15 per cent of the sample was dissolved to obtain a leach product with 0.08 per cent P. In the caustic leach, as no weight loss occurs, it is proposed that iron species associated with the protohaematite have either not dissolved or have reprecipitated at the high pH values of the leach.For an ore containing apatite as the source of phosphorous, a leach with sulfuric acid dissolved the apatite, lowering the phosphorous levels in the sample. The sample treated contained carbonate minerals (including siderite) that also reacted with the acid, and in practice a balance between the dissolution of the apatite and the carbonate minerals may be needed to minimise acid consumption.

Jul 11, 2011

By A Batnasan, K Haga, A Shibayama, K Higuchi, H Takeuchi

High silica (SiO2), alumina (Al2O3), and phosphorus (P) contents in iron ore adversely affect the quality of iron products. The removal of those impurities from iron ore is an essential point in further iron ore processing. In this paper, the removal of P, SiO2 and Al2O3 impurities from iron ore by alkaline drying followed by reverse cationic flotation is discussed. The reverse cationic flotation experiments are performed using the iron ore samples without and with alkaline drying pretreatment. All other flotation conditions except pulp pH (4–12) and particle size distributions (-45 to -250 μm) are held constant. A typical collector and frother, such as dodecylamine acetate (DAA) and methylisobutylcarbinol (MIBC), are used in the flotation experiments. Alkaline treatment is conducted before flotation using sodium hydroxide at fixed conditions. The impact of alkaline drying on the performance of iron ore flotation is evaluated based on the removal rates of P and SiO2 + Al2O3, iron grade, and iron recovery compared with the iron ore flotation without alkaline drying (direct flotation). X-ray diffraction (XRD) analysis indicates hematite and goethite are the main minerals in the iron ore, which assays 62.8 mass per cent Fe, 0.232 mass per cent P, 7.1 mass per cent SiO2 + Al2O3 (total) determined by X-ray fluorescence analysis (XRF). Results indicate that a combined approach is more effective for removing P and SiO2 + Al2O3 impurities from iron ore than the direct processing technique because the maximum removal rates of P and SiO2 + Al2O3 are 48.2 per cent and 66.5 per cent from the alkaline dried iron ore when 8.4 per cent and 13.1 per cent from the non-alkaline dried iron ore.

Sep 18, 2023

The present study is devoted to improvement of the leaching efficiency during phosphorous removal from high phosphorous gravity-magnetic concentrate. Before leaching the concentrate has been subjected to roasting with the addition of either Ca(OH)2 or CaO. The oolitic iron ore is roasted at 900°C for one hour. This reflects in reaction between alkaline earth additive and quartz, aluminosilicates, phosphorus, and some other minor components of the gangue minerals. The application of leaching, physical separation, and wash out of salts has resulted in the decrease of phosphorus from 0.7 to 0.15 % and it is established that the major influencing factor is the concentration of acid and to a less extent duration of the leaching process. About two third of the phosphorus can be removed by roasting with 3 % CaO to hematite, coarse grinding to d50 0.3 mm, dry high intensity magnetic separation and leaching of the magnetic fraction with hydro-chloric or nitric acid.

Sep 1, 2012

By Andrew J. Gaber

Beginning in 1961 the Coal Research Bureau of the West Virginia University School of Mines began a program of research to investigate the potential of the magnetic separation process to remove sulfur of the pyritic form from pulverized coal. Using a so-called isodynamic magnetic separator (1) it was demonstrated that significant quantities of pyritic sulfur could be removed from coal. Pulverized coal samples representing several different coal seams were individually screened into sizes in the 48 mesh by 200 mesh (297 to 74 microns) range, and untreated and steam-air treated samples of each were processed by the magnetic separator. The results of the investigations to magnetically remove pyrite from coal were published in two separate reports issued by the Coal Research Bureau (2,3), The isodynamic magnetic separator was designed about 30 years ago for use in geological and mineralogical laboratories (1,4,5) to isolate one or more minerals exhibiting only small differences in their magnetic propertiese Specifically, to accomplish this, the air gap of the unit was designed to provide a nearly constant magnetic gradient both laterally and longitudinally in the separating zone. It is reported that mineral concentrates of 99.5 percent purity can-be produced on closely-sized fractions after several cleanings through the unit. The isodynamic magnetic separator, therefore, was not expected to process coal containing sizes smaller than 200 mesh, or to demonstrate commercial capability to process pulverized coal. The primary purpose of the Coal Research Bureau in using the unit was that of determining if the magnetic process could remove pyrite from coal, and thereby encourage further research directed toward development of acceptable full-scale processing equipment.

Jan 1, 1969

By Ralph B. S

Bacterial leaching of low grade quartz felspar porphyry copper ore was studied in large-scale laboratory percolation leaching columns.Limitations in the release of soluble copper showed up before fifty per cent recovery, due to occluding precipitates of iron oxides and hydroxides. Precipitates were removed by increasing the acidity of irrigation feed four-fold with respect to sulphuric acid. However, irrigation at low pH (pH 1.5) inhibited copper leaching. Resumption of bacterial leaching at pH2 was achieved by introducing a period of non-irrigation. The results suggest a &apos;direct&apos; attack by bacteria on the chalcopyrite substrate rather than an &apos;indirect&apos; ferric-leach mechanism.

Jan 1, 1981

By Arcy R., D&apos George

Removal of S02 from smelter gases is being investigated, using an innovative technique that results in the almost simultaneous recovery and production of elemental sulfur. S02 is removed from the gas stream by scrubbing with suitable aqueous salt solutions or high-boiling organic fluids. The S02-laden liquor is then reacted with H2S Crystalline, high-purity sulfur is instantly precipitated and, after filtration, the regenerated liquor is recycled. The H2S required for the process is produced by reacting a portion of the recovered sulfur with hydrogen or with methane and steam. The chemistry and results of preliminary laboratory research are discussed.

Jan 1, 1969