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By Ann G. Kim

Methane in coal constitutes a serious hazard in coal mining. Draining the methane in advance of mining can mitigate this hazard, conserve energy, and offer economic benefits. This Bureau of Mines report evaluates the Pittsburgh coalbed in Greene County, Pa., to determine if advance drainage is feasible. The gas content of virgin reserves in Greene County is estimated at 100 to 200 ft3/ton, a total of over 370 billion ft3 of gas in an area approximately 310 mi2. Because of the similarity to natural gas, drained coalbed gas could be recovered and added to pipeline supplies of natural gas. The value of conserved gas would offset the cost of drainage and extend energy resources.

Jan 1, 1975

By R. E. Siemens

A process is being developed by the Bureau of Mines to selectively recover nickel and cobalt from low-grade domestic laterites. In laboratory evaluation of the process, the oxides in the laterite were selectively reduced with carbon monoxide at temperatures from 350° to 600° C. For material containing more than about 5 percent magnesia, pyrite additions or post-reduction heat treatments were necessary to achieve satisfactory nickel and cobalt extraction for this range of reduction temperatures. Multistage leaching of the reduced material at ambient temperature and pressure in the presence of oxygen, ammonium sulfate, and ammonium hydroxide extracted up to about 90 and 85 percent of the contained nickel and cobalt, respectively. The nickel was selectively recovered from the leach solution by solvent extraction and was then stripped from the loaded organic with dilute sulfuric acid to provide a nickel-rich electrolyte. Treatment of the raffinate with hydrogen sulfide resulted in the recovery of cobalt as a sulfide. The only contaminant in solution was magnesium which was removed by ion exchange or precipitation. In this process the energy requirements are relatively low and except for minor operation losses, only coke and oxygen are consumed.

Jan 1, 1975

By Joan C. Biordi

[Composition profiles for atomic, radical, and stable species, as well as temperature and area expansion ratio profiles, have been determined for a nearly stoichiometric CH4-02-Ar flame and one to which 0.3 percent CF5Br inhibitor had been added. Net reaction rate profiles were calculated for all the observed species. For the normal flame, these and the mole fraction profiles gave rate coefficient information about the elementary reactions in the methane flame, for example, CH. + 0 4- H2CO 0 H, k4 = 1.05 X 1014CM3 mole-1sec-1 for 1,550§T 0,725' K; CO + OH 4 C02 + H, k6= 4.7 X 1011 for 1,350{T X1,750° K. Comparison between the inhibited and normal flame showed that A] and [CH3] were significantly reduced at the lower temperatures in the inhibited flame even though in the hot gas region the [E] [OH!, and [0] were essentially the same in both flames. The CF3Br disappears very early in the flame, relative to the fuel, and the reaction primarily responsible for its disappearance is H v CF3Br 4 HBr + CF3, where k7 is found to be 2.2 X 1014 exp(-9460/RT) for 700-1,550° K. Reaction of the inhibitor with methyl radicals provides for the relatively small amounts of CH3Br observed, but CH3 + Br2 - CHs Br + Br must also occur. The HBr formed reacts rapidly with H atoms to form H2 and Br, but the reaction is soon "balanced" in the flame as may be demonstrated by calculation of the equilibrium constant at various temperatures. The fluoro-carbon fragment produced in reaction (7) also reacts rapidly, in part with methyl radicals to give the observed elimination product CH2CF2 Later in the flame, above -1,400' K, F2CO is formed from the reaction CH2CF2 + 0 P F2CO + CH2 and k., -1.5 X 1013 at 1,600° K. The rather slow decay of carbonyl fluoride is attributed to reaction with H atoms according to the sequence F2CO I H - HF + FCO and FCO + H HF + CO.]

Jan 1, 1975

By G. L. Gates

The waters used to waterflood the Wilmington oilfield were studied by the Bureau of Mines, in cooperation with the city of Long Beach, Calif. Increases in the pressure of the injection wells indicated that they were being plugged by materials suspended in the waters. This study was made to identify the suspended materials, determine their origin, and find methods of preventing their formation. The suspended oil-coated materials were iron sulfide, barium sulfate, calcium carbonate, clay, and sand (or silica). Results indicated that the sulfide, which was as high as 90 milligrams per liter, was the product of sulfate-reducing bacteria. The injection of ocean water increased the sulfate content of the waters in the petroleum reservoirs from 3 to 250 milligrams per liter, thereby furnishing sulfate for growth of the bacteria. The waters were supersaturated with barium sulfate. Laboratory tests showed that sulfide could be removed from the waters by adding iron at a cost of 1 to 2 mills per barrel. The solubility of iron sulfide and calcium orthophosphate in the injection waters was also determined.

Jan 1, 1975

By Martin Hertzberg

In this Bureau of Mines report, the optical detection of fires and explosions is considered fundamentally. The measured spectral radiances from methane-air ignitions are compared with the background irradiances from stray and ambient sources, and with the spectral sensitivites of various sensors. The comparison naturally suggests the optimum spectral ranges and signal processing logic that can uniquely characterize the ignition event. Both ultraviolet (UV) and infrared (IR) are considered. Several alternate sensing methods are proposed and discussed. The development and testing of an IR system designed for use in ignition suppression devices in mines is described.

Jan 1, 1975

By A. W. Hall

A neutron meter was developed for monitoring the sulfur content of coal streams. Neutrons from 80 micrograms of californium-252 penetrate the coal, producing thermal neutrons that are captured by atoms of elements present in the coal. The excited atoms emit prompt gamma rays with energies characteristic of the capturing element. These gamma rays are detected with a 6-by 7-inch sodium iodide detector and processed by electronic equipment to produce a gamma ray energy spectrum of the elements. Tests of the meter at a commercial coal preparation plant showed that sulfur in moving coal can be determined to a precision of 0.05 percent sulfur within 2 minutes. Based on this report by the Bureau of Mines, reliability of the coal-handling system proved inadequate for long-term operation, however, and improvements are planned.

Jan 1, 1975

By J. R. Allsup

The Bureau of Mines studied the characteristics of simulated coal gas as an automotive fuel in two multicylinder vehicles in a standard and high-compression-ratio engine configuration. While using simulated coal gas fuel, increasing the engine compression ratio improved the fuel economy and vehicle performance but increased hydrocarbon emissions by 40 pct. photochemical reactivity of exhaust hydrocarbons was found to be extremely low using the coal gas fuel. An oxidizing catalyst used with the simulated coal gas fuel eliminated all but trace amounts of carbon monoxide and reactive hydrocarbons in the exhaust. Spark gap geometry and firing voltage were varied and, within the range tested, had little effect on vehicle performance and emissions using simulated coal gas fuel.

Jan 1, 1975

By Kelly C. Strebig

Laboratory tests were conducted by the Bureau of Mines to determine the effect of depth of cut and bit type on respirable coal dust generation. Apparatuses were constructed to contain the coal samples, measure the linear cutting forces, and analyze the dust generated. Single-bit tests were conducted in Illinois No. 5 and Pittsburgh seam coals with five bit types at four depths of cut. The results showed that bit type did not significantly influence dust production. On the other hand, deep-cutting bits were more efficient and generated substantially less respirable dust per pound of coal broke than shallow-cutting bits.

Jan 1, 1975

By F. N. Kissell, C. M. McCulloch, Maurice Deul, J. R. Levine

The methane content of virgin bituminous coalbed can now be measured accurately in the field with exploration core samples from vertical boreholes. The gas content of the coal per unit weight can be used either to design a mine ventilation system or to determine if degasification of the coalbed will be necessary before mining, and to determine the gas resources in the coalbed. The equipment necessary to conduct the test costs less than $50. The gas content of the coal in place in the ground is determined by summing the gas lost from coring, gas measured during desorption, and the residual gas in the coal. Upon removal from the borehole, the core sample is placed in an airtight container and desorbed for several weeks until the desorption rate is below 0.05 cm3/g for 5 consecutive days. The gas lost from the core while it was being cored and the residual gas are estimated by a new graphical method. The amount of gas remaining depends upon whether the coal is friable or blocky. Friability appears to relate to the depth of the sample below the surface, fixed carbon percentage, Hardgrove grindability index, and proximity to tectonic disturbance. Friable coals emit nearly 96 pct of the total gas during desorption whereas a blocky coal emits only 60 pct of its total gas. Coalbeds that are ill defined as to their blocky or friable nature must be tested in the laboratory for unambiguous analysis.

Jan 1, 1975

By C. M. McCulloch

The methane content of virgin bituminous coalbed can now be measured accurately in the field with exploration core samples from vertical boreholes. The gas content of the coal per unit weight can be used either to design a mine ventilation system or to determine if degasification of the coalbed will be necessary before mining, and to determine the gas resources in the coalbed. The equipment necessary to conduct the test costs less than $50. The gas con-tent of the coal in place in the ground is determined by summing the gas lost from coring, gas measured during desorption, and the residual gas in the coal. Upon removal from the borehole, the core sample is placed in an airtight container and des orbed for several weeks until the desorption rate is below 0.05 cm3/g for 5 consecutive days. The gas lost from the core while it was being cored and the residual gas are estimated by a new graphical method. The amount of gas remaining depends upon whether the coal is friable or blocky. Friability appears to relate to the depth of the sample below the surface, fixed carbon percentage, Hardgrove grindability index, and proximity to tectonic disturbance. Friable coals emit nearly 96 pct of the total gas during desorption whereas a blocky coal emits only 60 pct of its total gas. Coalbeds that are ill defined as to their blocky or friable nature must be tested in the laboratory for unambiguous analysis.

Jan 1, 1975

By H. Schultz

Urban refuse that was mechanically separated at the U S Bureau of Mines pilot plant in College Park, Md., was successfully evaluated for its fuel values using standard coal analysis methods. Analyses performed on refuse samples taken from five sample points included moisture, ash, sulfur, chlorine, and heating value. It was recommended that characterization of the combustible portion of urban refuse by standard coal analysis procedures should be widely adopted.

Jan 1, 1975

By J. M. Stuve

Low-temperature heat capacities and the enthalpy of formation were deter-mined calorimetrically by the Bureau of Mines for CuO?CuS04. The derived standard entropy (S°298.15) was 40.36±0.04 cal/deg-mole, and the enthalpy of formation (?H°f) was -219.l±0.3 kcal/g-mole. A large thermal anomaly was observed in the heat capacity of CuO?CuS04 at 20±0.1 K. Gibbs energy of formation data are tabulated up to 1,200 K. Construction details of a precision low-temperature adiabatic calorimeter capable of determining heat capacities of solids in the temperature range 5 to 320 K are given. A calibrated miniature germanium resistance thermometer was incorporated into the calorimeter to extend the range of accurate measurements below 15 K. High-resistance dc heater windings were used throughout the cryostat to reduce heat conduction of inner connecting wires.

Jan 1, 1975

By Alexander May

The Bureau of Mines, in cooperation with the Florida phosphate mining industry, investigated the dewatering of waste phosphatic slimes. Part of this investigation was to determine the electrophoretic mobilities and cation exchange capacities of the slimes. The mobilities and exchange capacities are reported for samples of slimes taken from 15 plants operating in the Florida land-pebble phosphate district that includes Polk,Hillsborough, Manatee, Hardee, and DeSoto Counties. The electrophoretic mobilities determined were all negative, ranging from -0.24 to -1.93 (micrometers per second) per (volt per centimeter). Also reported are frequency distributions of electrophoretic mobilities, electrophoretic mobilities of slime diluted with distilled water and electrophoretic mobilities of sand-slime mixtures. The cation exchange capacities ranged from 17 to 45 milliequivalents per 100 grams of slime solids.

Jan 1, 1975

By C. H. Elder, Maurice Deul

Coal degasification boreholes drilled from the surface have been success - fully hydraulically stimulated to increase the flow of gas from the coal. This Bureau of Mines report describes the hydraulic stimulation procedure for a coalbed, the equipment required, and design criteria for the treatment. Three examples of stimulation treatment show from fivefold to twentyfold increases in gas production. The tests were conducted in the Pocahontas No. 3coalbed, Buchanan County, Va., the Pittsburgh coalbed, Washington County, Pa., and the Mary Lee coalbed, Jefferson County, Ala. Two sites where the coal was hydraulically stimulated and exposed by subsequent mining show no adverse effect on mining operations through the treated zones. The induced vertical partings were confined to the coalbed and did not in any way affect either roof or floor rock.

Jan 1, 1975

By C. H. Elder

Coal degasification boreholes drilled from the surface have been success-fully hydraulically stimulated to increase the flow of gas from the coal. This Bureau of Mines report describes the hydraulic stimulation procedure for a coalbed, the equipment required, and design criteria for the treatment. Three examples of stimulation treatment show from fivefold to twentyfold increases in gas production. The tests were conducted in the Pocahontas No. 3 coalbed, Buchanan County, Va., the Pittsburgh coalbed, Washington County, Pa., and the Mary Lee coalbed, Jefferson County, Ala. Two sites where the coal was hydraulically stimulated and exposed by subsequent mining show no adverse effect on mining operations through the treated zones. The induced vertical partings were confined to the coalbed and did not in any way affect either roof or floor rock.

Jan 1, 1975

By L. J. Froisland

An integrated process for recovering metal from nonmagnetic auto-shredder reject scrap was investigated by the Federal Bureau of Mines. The methods used were air classification, water elutriation, screening, magnetic separation, handpicking, and heavy-media separation. Metal recoveries in this process were projected at 39 percent copper and copper alloys, 53 percent aluminum, 96 percent iron, and 98 percent zinc die cast. An economic evaluation of the conceptual process indicated that a facility designed to reclaim the reject scrap from 200 shredded automobiles daily could be profitable. Total investment in this plant was estimated at $321,000; the discounted rate of return before taxes was 53 percent.

Jan 1, 1975

By R. D. Saltsman

Under contract with the Federal Bureau of Mines, Bituminous Coal Research, Inc., performed a statistical study to find less expensive and time-consuming methods of monitoring the noncombustible content of coal mine dust. Calculations based on thermodynamic considerations verified the reasonableness of Federal rock-dusting requirements. The results of extensive sampling in southwestern Pennsylvania mines indicated that, at the 95-percent confidence level, the present system of sampling at 200-foot intervals may be replaced by sampling at 500-foot intervals, and that a 1-inch scoop floor sampler may replace the standard 6-inch scoop for floor sampling. Further field testing is recommended.

Jan 1, 1975

By Richard J. Bielicki

The possibility of replacing the brattice cloth closest to the coal mine working face with an air curtain mounted on top of a continuous-mining machine or with a diffuser fan was explored by the Bureau of Mines. Preliminary tests conducted at a full-scale model working face with the brattice end set at 18 feet showed that the air curtain improved face ventilation only slightly and was not nearly as effective as placing the brattice at 10 feet. A 2,000-ft3/min diffuser was more effective than the air curtain. It is concluded that the air curtain probably could not function as a line brattice extension, although the diffuser fan may have some potential.

Jan 1, 1975

By Philip C. Tully

The Bureau of Mines, in a continuing effort to improve processes and methods of helium purification, has developed a differential distillation method for removing helium-3 from helium-4. Differential distillation at 4.2 to 1.6 K was used to reduce the helium-3 in helium-4 from about 200 to less than 1 part per billion. The results from four stills ranging in size from 1 to 25 liters are reported. The method has the potential to be adapted to commercial-scale separations.

Jan 1, 1975

By B. W. Madsen

A nearly dormant copper sulfide pilot-scale experimental leach containing 8.7 tons of are was injected with oxygen to determine its effect on the copper-leaching rate. Prior treatment of the uncrushed 0.25-percent-copper, mine-run stripping material consisted of 461 days of acid ferric sulfate leaching, which extracted 47 percent of the total copper. The permeability of the bed had decreased, and the percolation rate had decreased from an initial 20 gallons to 0.8 gallon per square foot per day. Copper extraction had nearly stopped. After injecting oxygen into the ore column and leaching for 30 days, the percolation rate was increased to 6 gallons per square foot per day. In an additional 298 days of leaching, an additional 40.7 percent of the copper was extracted. The improved leaching after the use of oxygen is attributed to stimulated bacterial action, better oxidation, and increased permeability.

Jan 1, 1975