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By M. Rudolph, R. Tolosana-Delgado, G. van den Boogaart, M. Reuter, U. Peuker

This paper addresses the challenge to define a concept of entropy (state of order) for a textured particle system. Both the particle texture, the intergrowth respectively, and the particle size influence the order of a particle system. The smaller the particles become, the more particles form the solid system and the more permutations of the structure of the particle bed are possible. The texture within a particle is fixed, as long as it is not subjected to changes due to comminution, flocculation or agglomeration. The paper will present a definition of entropy, which is able to reflect qualitatively and quantitatively the intergrowth and the size (distribution) of the particles. Theoretical examples will show how different breakage mechanisms can be identified using the entropy definition. Furthermore, we will define the specifications for data sets to calculate the entropy of a particle system. Keywords: Milling, mineral liberation, intergrowth, statistical entropy, modelling

Jan 1, 2020

By P. D. R. Maltby

"1. INTRODUCTIONMy talk today will discuss a new development in the thickening of slurries and clarification of waste water - the Enviro-Clear thickener. Several industrial installations of the thickener have been made in North America in the following applications:1.,water clarification in sugar beet processing plants.2.,separation of pregnant liquors from solid wastes following acid leaching in uranium mills3.,clarification of waste water from coal treatment plants as described in a paper in the June 1975 transactions of the SME entitled ""Application and Utilization of the Enviro Clear Thickener in a U.S. Steel Coal Preparation Plant"" by A.A. Terchnik, D.T. King and J.S. Anderson.2. HISTORYThe application of the Enviro-Clear thickener can be traced back to the filing of U.S. Patent 3523889 in 1970 by the inventor F. Eis. The claims of this patent are shown in Slide 1.The new concept was developed for sugar beet processing by the Spreckels Division of Amstar Corporation, and several such thickeners have subsequently been installed in various sugar beet plants. The Enviro-Clear Co. or New York took over the world-wide manufacturing and marketing of the thickener. Experience in the sugar beet industry indicated that the Enviro-Clear thickener volume requirements could be reduced to as low as one tenth that of a conventional type thickener. Various coal samples were supplied by U.S. Steel Research Laboratories for testing. The tests indicated that feed rate loadings of 3 gpm/ft.2 could be obtained by the Enviro-Clear thickener. Such results led to several industrial applications in the coal industry. Subsequently other branches of the mineral processing industry have come to learn of the possibilities of using this thickener. Slide 2 shows a list of commercial Enviro-Clear installations at the end of 1975."

Jan 1, 1976

By Melvin S. Taylor

The environmental control program at Cassiar Mine is an active one involving government, unions and company personnel all working together to achieve a goal- "A clean and safe working environment". This can only be achieved by utilizing three of Cassiar's most important resources; i.e., people, time and money. Past environmental programs have more than proved that the goal can be reached and. with the future programs now in progress. Cassiar Asbestos will achieve its environmental goals.

Jan 1, 1978

By Shengli Tao, Hongxu Li, Hao Bai, Yu Chen, Daqiang Cang

"China is the world's largest steel producer, in order to give environment load comprehensive analysis of steel and iron industry in china using LCA method, the life cycle inventory was compiled and assessment model based on Gabi software was also established. Environmental impact of two different routes ofBF-BOF and the EAF were analyzed respectively and intercompared. The results show that the modem EAF route is superior to the traditional BFBOF route on almost all the environmental impact indexes, which including acidification potential, eutrification potential, global warming potential, ozone depletion potential, etc. In the whole life cycle ofBF-BOF route in China, the transporting process ranks the biggest contribution part to the overall global warming potential, which can be explained by the fossil fuel burning of transporting vehicles during the long distance from Australia to China as the iron ore used are mainly imported from Australia. Apart from transporting process, Coking, blast furnace and iron mining processes could induce great environmental problems, while for the EAF route, the electricity consumption is considerable, which causing large amount ofC02 emission indirectly. Based on the analysis, several further countermeasures were proposed. Key words: Iron and steel industry, LCA, Gabi software, C02 emissionIntroductionCrude steel of china which reached 101.24 million tons in 1999 ranked the first column in the world since1999, So far has been to keep the world's largest steel output. At the year of2009, China crude steel output of 568 million tons, accounting for 46.6% of the global crude steel production, more than the total sum of crude steel production produced by 20 countries ranked behind. In 2011, China's crude steel production which is expected to be or close to 700 million tons, an increase of 12% than last year, will account for half of the global steel production.The steel industry, however, is intensive resources industry with huge consumptions of energy and water together with mineral resources. Energy consumption of the iron and steel industry has been about 10% of the total energy consumption since 1980. Coal dominants, power next and other energies share least in the energy consumption structure, for example coal accounts for 72.19%, power 23.52% and other total sums less than 5% in the steel energy consumption at year of 2002[2,3]. The consumption of coal discharges much emission of CO2, yet emissions of C02 in China steel industry, secondary only to the power and cement industry, ranked the third, and the coal dominant energy structure and its process have a close relationship. The aim of this research is to target steel production of typical blast furnace-converter (BFBOF) and electric furnace, using GABI software to evaluate and analyze resources and environment influence of LCA, directing at the existing problems in the development of China steel as well as finding the possible way to improve ability of reducing pollution and energy consumption in order to realize the sustainable development of the steel industry [ 4-7]."

Jan 1, 2012

By S. Street

The Environment process, invented by Prof. H.K.Womer and developed at the University of Wollongong, simultaneously treats ferruginous and organic wastes via bath smelting. Conceived in the late 1980's, the patented process was originally developed using steelworks dust to settle solids from sewage, producing a composite material suitable for smelt reduction. Work began on the process in 1990 with the Australian patent having a priority date of February 1990. Early research focussed on settling of solids from sewage, while pyrometallurgical investigations examined smelting in small induction furnaces. By 1992 smelting trials had been undertaken in pneumatic and electric arc furnaces, the process being successfully demonstrated up to on 8 tonne scale. The success of this particular trial, and other smaller trials, resulted in construction of a 100kg DC arc furnace which was commissioned in 1993. By 1994 the main project focus was on development of the smelting technology. Over 3 years of trials on the DC arc furnace have identified and clarified many of the pyrometallurgical reactions. optimum operating parameters, as well as demonstrating the versatility of the process for treating a wide range of wastes. Currently the Illawarra Technology Corporation (lTC), the commercial arm of the University of Wollongong, is pursuing commercialisation of the process.

Jan 1, 1996

By M. D. Kaizer

PETROBRAS started its Oil Shale process development in 1953, the PETROSIX process which was developed and tailored to Irati Oil Shale formation. Since 1991, the industrial plant called MI (Industrial Module) has been operating, producing more than 20 million barrels of oil. In order to continue the oil shale exploration, a new shale mine is been opening. This article reports the planed measures taking in order to limit the environmental impacts and to return the land as close as possible to the original condition, as well as with the disposition of the process waste and the city garbage. It shows that the remediation process starts during the mining activities and continues after the mine exploration. Another characteristic of the Petrosix process, the pyrolysis of tires will be focused.

Jan 1, 2014

By Richard P. Roberts

This paper will discuss the methods for the cooling of aluminum melting furnace? dross .and their impact on the environment. Also discussed will be a case history of an AROS Dross Processor installation, which is designed to maximize the recovery of metal content of the dross in a manner which is not only environmentally cleaner, but which also prepares the output in such a way as to facilitate downstream processes. Handling of the discharged material will be discussed in regards to the recycling of the preserved metal content and deposition of the unusable-materials.

Jan 1, 1992

By Jasper Kwong

The recycling of MgO-C refractories as a slag conditioner in EAF (electrical arc furnace) foaming slags have been evaluated by the Albany Research Center. The amount of MgO in the slags is critical for the foaming quality. Good foaming slags provide the benefits of high energy efficiency and low refractory consumption and require saturation with MgO. A computer model predicting the chemistry of MgO saturated foaming slags was designed to predict suitable amounts of MgO additives from MgO-C spent refractories. This model can also help to reduce the amount of slags and to improve the economics of producing steel. The implementation of this recycling program is underway at steel plants and the experience of recycling spent refractories will be discussed.

Jan 1, 2002

Programmes of environmental investigations to identify and minimise impacts and satisfy government and community requirements have become an integral and rate determining component in the planning and development of new mines in Australia. This paper reviews the essential features of the environmental project management Function.

Jan 1, 1983

By C. Adcock, R. Farnfield, G. Adderley

The use of explosives to create special effects in the film industry is a well-known past time. A recent production required simulation of a large scale water splash from the effect of a statue falling from a cliff edge and impacting on an open body of water. This was to be achieved through the use of precisely delayed explosions detonated near the surface of the water. A survey of the area revealed a breeding farm for sea bass approximately 250 metres (273 yards) from the intended blast area. It was initially thought that the water pressures produced for the detonation of the explosives may cause harm to the fish. Much work has been carried out over the past few decades on the effect of open water blasting and its effects on aquatic wildlife; this includes water pressure modelling techniques which can be used as predictive tools.

Jan 1, 2010

By F P. Hao

Organo-sulphur-based collectors (eg xanthates, dithiocarbamates and dithiophosphates) are widely used in the flotation of sulphide minerals. Xanthates (ROC(=S)Sû), for example, adsorb strongly at sulphide mineral surfaces, in a reaction that is electrochemically coupled with the reduction of dissolved oxygen. One of the oxygen reduction products, hydrogen peroxide, reacts directly with dissolved xanthate, leading to its oxidative decomposition. Experimental work has been conducted, using ethyl xanthate, to understand the molecular mechanism by which hydrogen peroxide reacts with xanthates. A number of degradation products have been identified, some of which have not been reported previously. This oxidative decomposition reaction pathway is discussed in the broader context of xanthate decomposition in flotation systems. One of the identified ethyl xanthate decomposition products, ethyl perxanthate (ROC(=S)SOû), has been observed in the process water of a number of mineral processing operations. The interaction of this molecule with goethite (α-FeOOH) particles, typical of that found in tailings dams, has been studied in more detail using attenuated total reflectance (ATR)-FTIR. The ethyl perxanthate molecule has been found to coordinate to iron (FeIII) at the goethite surface, and undergo a surface-catalysed decomposition process. In the presence of both PbII and goethite, a ternary surface complex is formed, where ethyl perxanthate is coordinated directly to surface adsorbed PbII atoms. The results obtained give some insight into the environmental fate of ethyl xanthate in tailings streams, and a basis on which to consider the environmental importance of such species in tailings dams. Strategies for the destruction of residual xanthate levels in waste water streams are discussed in terms of the likely reaction products.

Jan 1, 2002

By D. Johansson, C. San Miguel, U. Stenman, N. Petropoulos

Blasting is a commonly utilized method in civil engineering projects and mining operations. Ammonium nitrate-based (AN-based) explosives are the most efficient explosives today in terms of handling and performance. However, a side effect is the production of gases. The reduction of these gases plays an important role in the safety and environmental aspects in the working place. Therefore, optimizing the recipes of explosives is vital for minimizing the environmental impact and increasing performance. The aim of the project is to provide results and recommendations on the use of emulsion commercial explosives to support the Swedish mining industry and tunnel-contractors as well as the explosives manufactures. The approach was to test various recipes of civil emulsion explosives to investigate the generation of toxic fumes (CO, CO2, NO, NO2 and NOx) during their detonation. To further increase the knowledge of the influence of different additives, ammonium nitrate prills were added in various percentages. The experimental configuration consisted of magnetite mortar cylindrical specimens with a 50 mm borehole at their center, filled with emulsion explosive. Several tests with different emulsion compositions regarding ammonium nitrate additives (10%, 20%, 25%, 30% and 35%) were carried out in a blasting chamber. The measurement equipment was composed of a flue gas analyzer. The instrument was meticulously cleaned after every test, as well as before and during the tests due to condensation (high humidity and dust) at the inlet of the instrument. The emulsion was manually sensitized with microballons and pumped into the cylinders to ensure lack of bubbles, which could introduce inhomogeneities. The acquired gas concentration data was complemented with temperature, humidity, and VoD measurements. The results showed a linear increase of nitrogen gases as the percentage of ammonium nitrate prills increased. On the other hand, carbon gases had a relatively low coefficient of determination. The VoD data showed a behavior that can be described with a simple quadratic equation.

Jan 1, 2024

By Patrick Moore

In 1971 the government of British Columbia issued a permit for the Island Copper Mine to commence disposal of 33,000 tons per day of mine tailings into Rupert Inlet, a marine fjord on the northwest coast of Vancouver Island. There was considerable controversy surrounding the development, public hearings were held, and as a requirement of the permit the company was obliged to carry out a comprehensive environmental monitoring program. The results of this program provide a thorough assessment of the environmental impact of submarine tailings disposal over the 24-year life of the mine. Following closure in December, 1995, the monitoring program continued for three years to determine the extent of marine ecosystem recovery and re-colonization. It is apparent from the findings of the monitoring program that the mine tailings were dispersed more widely than was originally predicted. It is also clear that widespread heavy metal contamination has not materialized. In retrospect it appears that submarine tailings disposal has resulted in far less severe environmental impacts than if the alternative of land disposal had been adopted. This review highlights significant aspects of public policy decision-making, design of environmental monitoring programs, and questions of interpretation of monitoring program data.

May 1, 2002

By J C. Carlile

Many low sulphidation epizonal gold and zinc-lead vein deposits within magmatic arcs are situated on basement highs, and post-date both the main volcanic episode and porphyry copper (gold) mineralisation. These features are best explained by emplacement of a flat batholith a few kilometres beneath each mineral district, as recently demonstrated by geophysical data in the Baia Mare district of Romania. The batholith provides heat for the hydrothermal system, and results in extensional faulting both through up-doming of the overlying rocks, and in some arcs through incipient collapse of the thermally weakened crust under regional extensional stress. More water-rich magmas emplaced at greater depths could explain some deep epizonal and mesothermal gold deposits situated outside magmatic arcs.

Jan 1, 1995

By Carlie JC

Many low sulphidation epizonal gold and zinc-lead vein deposits within magmatic arcs are situated on basement highs, and post-date both the main volcanic episode and porphyry copper (gold) mineralization. These features are best explained by emplacement of a flat batholith a few kilometres beneath each mineral district, as recently demonstrated by geophysical data in the Baia Mare district of Romania. The batholith provides heat for the hydrothermal system, and results in extensional faulting both through up-doming of the overlying rocks, and in some arcs through incipient collapse of the thermally weakened crust under regional extensional stress. More water-rich magmas emplaced at greater depths could explain some deep epizonal and mesothermal gold deposits situated outside magmatic arcs.

Jan 1, 1995

By Tim Bekhuys

Equator Principles ? Applies to projects > $10 million ? Voluntary agreement between 58+ EPFIs ? Categorized projects based on environmental risk, consequences ? Requirements for EA, EMP, use of safeguard policies, consultation ? IFC Performance Standards on Social and Environmental Sustainability ? Apply if the project is in a low or lower-middle income country ? Low-middle income countries defined by the World Bank Development Indicators Database

May 1, 2008

By J. U. MacEwan

Introduction The equilibrium between copper, zinc, and chlorine may be considered as the simultaneous equilibrium of the two separate chemical reactions of formation of the stable chlorides of copper and zinc at the temperature of the reaction i.e., l440°K. (1,167°C., 2,133°?F.)§ [Zn(g) +Ciz(g) ZnCl2z(g). ... (1) ] [2Cu(l)+Cbi'g) Cu2Cl2(l 1 ....... (21 ] Subtracting, [Zn(g) +Cu2(Clz(l i ZnClz(g) +2Cu!l) ... . (3) ] If this reaction is carried out with a copper-zinc alloy at some constant temperature above the melting point of brass, and at a total pressure of one atmosphere, the equilibrium concentrations obtained will depend on the free energy decrease .of the reaction as written in (3) and on the activities of the various components in. the reaction mixture. If the equilibrium is examined from the point of view of the phase rule, it is a three-component system, and if it exists in two phases (liquid and gas) it will have three degrees of freedom. If the restrictions of constant temperature and pressure are imposed, the degrees of freedom are reduced to one. This means that, in a two-phase system under these conditions, each different alloy phase will be associated with a gas phase of constant composition.

Jan 1, 1951

By E. C. Bain

THE more familiar compositions of iron-carbon-chromium1 and the iron-carbon-tungsten2 systems have been investigated with a degree of thoroughness which has permitted the construction of their three-dimensional equilibrium diagrams; and it is probable that these equilibrium diagrams are sufficiently accurate for the present metallographic needs. Strangely enough, in spite of their importance, the alloys of iron, carbon and manganese apparently have not been investigated in the same systematic manner, and so far as is known, no three-component equilibrium diagram for this system is available. Even iron-carbon-nickel alloys3 have been studied rather more thoroughly; for these the solidus and liquidus surfaces have already been determined, but the solid transformations in this, as in the manganese system, have not been reported systematically. The present paper deals with the constitution at equilibrium of a series of 36 iron-carbon-manganese alloys of commercial purity limited by 1.5 per cent carbon and 15 per cent manganese, a range of compositions including most of the manganese steels. The temperature range of melting has not been determined, nor has the high-temperature (delta iron) ferrite equilibrium been included in the study, it being considered that the more important characteristics of the manganese steels are their ordinary transformations in the solid state. The delta iron region is almost certain to be a small tetrahedron not very different in magnitude or contour from that in the iron-carbon-nickel diagram. It is probably true

Jan 1, 1932

By R. G. Horvath

The Statnamic loading test is a new and innovative method for testing deep foundations. The test is relatively inexpensive, quick, easily mobilized, provides for direct measurement of applied load and corresponding displacement, and is capable of very high loading capacities. The long duration of the applied loading, as compared to a dynamic loading test, allows for a straightforward determination of the static behaviour of the foundation tested. A new method of analysis of the Statnamic loading test, the Equilibrium Point Method, is presented. A description is given of the pile-soil model and a demonstration of how the static load-displacement behaviour of deep foundations may be predicted from the Statnamic loading test data. The Equilibrium Point Method of analysis is applied to three types of deep foundations in soils which respond differently to fast loading rates. These case histories, from Canada and the United States, include data from static loading tests for direct comparison, and demonstrate the ability of the Equilibrium Point Method to predict static behaviour of the deep foundations.

Jan 1, 1993

By C. H. White

Discussion of a Paper by Mr. C. H. White, read at the Atlantic City Meeting, February, 1904. (Annual Meeting, February, 1005.) ARTHUR JARMAN, Sydney, New South Wales, Australia (communication to the Secretary*) : All designs for modern metal¬lurgical and chemical laboratories should provide each student's desk with a hood or cupboard for the removal of fumes, but I doubt the advisability of placing air-baths and similar apparatus close to the hot plate. It seems to me that unless the draft be exceptionally strong the fumes from ordinary wet assay work will corrode the iron-work of the fittings, in which case the baths would have to be removed to a general desk in order to lighten the work of the laboratory attendant. Since the laboratory described by Mr. White has been in use for two years, I should like to ask if any inconvenience has resulted from this corrosion. If not, it is certainly an important improvement to have the air-baths and similar apparatus placed -on the student's desk. The hoods described by Mr. White are supplied with a good draft by means of a fan, which gives them a great advantage over those at the metallurgical laboratory at the University, Sydney, in that no doors to the hood are needed. Each hood in the laboratory at Sydney is connected by a glazed earthenware drain-pipe with a vertical flue, 20 ft. high, having a lighted gas jet at the bottom to assist the draft. Although the draft is good, fumes of sulphuric acid cannot be drawn o$ unless the doors of the hood are lowered more than half-way. In my opinion, a fan should be used for the purpose of creating the draft, and glazed drain-tile should invariably be used for the flues because no other material possesses the same advantages. I know of a recent instance in which a laboratory containing

Mar 1, 1905