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RAYMOND M. Howe (author's reply to discussion*).-Dr. Unger states that magnesite will hardly supersede dolomite in fettling after a heat; that it is hard to believe a slag composed of oxide of iron containing about 6 per cent. of phosphorus is the active corroding, agent in a boil in a furnace; and that boiling cannot be said to be the result of the chemical action of a high-phosphorus slag on a basic bottom. These are well-established facts that no one would venture to question. The authors were misinterpreted in the statement that "in the summary, it is claimed that magnesite low in lime, or of greatest purity, ranks first in resistance to slaking," etc. On the contrary, the position has been taken throughout that while a low lime content is advantageous, the presence of several per cent. of iron oxide (an impurity), is necessary in order to confer the proper bonding and sintering properties in dead-burned grain magnesite to be used for furnace hearths. We cannot subscribe to the view that pure magnesia is no better fitted for a refractory than pure lime,' nor that the pure natural varieties of magnesite; such as Grecian or Washington, must necessarily be burned with silica and oxide of iron to produce a satisfactory material. On a small scale, pure magnesia has been satisfactorily used as a refractory in the form of crucibles. In the production of dead-burned grain magnesite from the Grecian or Washington mineral, iron oxide is added but the addition of silica is neither customary nor desirable. It is possible to manufacture brick of good quality from both the Grecian and the Washington material without adding either silica or iron oxide, providing they are burned at a sufficiently high temperature. This is regularly done on a commercial scale both in America and abroad when brick of. exceptionally high refractoriness or special purity are desired. The following analysis is of an English brick of Grecian magnesite which is extremely low in all impurities.1

Jan 6, 1919

By F. E. Lathe

RECENT events have emphasized with renewed force the well known fact that war greatly intensifies the demand for certain metals, particularly for iron, copper, and zinc. Any increase in the use of iron and steel, whether in war or peace, is also accompanied by increased consumption of those metals which find their chief application as ferro-alloys, such as nickel, chromium, manganese, molybdenum, tungsten, and vanadium. Further, since high temperatures are essential for the production of all these metals, activity in the metal industry is inevitably accompanied by an insistent demand for refractories. For example, in North American practice the consumption of magnesitic hearth refractories is frequently expressed in pounds per ton of steel. This quantity (not including straight dolomite) ranges on individual plants from about 7 to 12 pounds. When the industry is operating at approximately full capacity, the ratio of refractory to steel tends to increase, since the tonnage of steel produced is recognized as of paramount importance, and this leads to the harder driving of furnaces and less regard for the effect on refractories. It should also be observed that the cost of refractories per ton of metal produced is always so low, in comparison with other items, that it may even increase while the cost of metal per ton is being reduced through more continuous operation and the use of higher temperatures. As one prominent Canadian copper metallurgist has tersely expressed it, he is "not in business to save refractories but to smelt ore". The effect of war demands and of general industrial activity upon the production of basic and neutral refractories is clearly shown in Figure 1, which gives the value of chrome ore and magnesitic-dolomite produced in Canada during the period 1907 to 1937. Tonnages have not been shown, as these are not available for the full period; such figures as have been published from time to time are not strictly comparable, since both raw rock and finished products have on occasion been included. The preliminary figures for 1938, which are now available, have been prepared by the Dominion Bureau of Statistics on a different basis from those immediately preceding, and have therefore not been shown.

Jan 1, 1940

By Lv Guozhi, Niu Liping, Liu Yan, Zhao Qiuyue, He Jicheng, Zhang Ting’an, Dou Zhihe

"This paper proposed a new method of Mg and Cl2 circulating for titanium sponge production by direct pyrolysis and thermal reduction process. Effects of pyrolysis temperature, pyrolysis time and partial pressure of oxygen on pyrolysis efficiency were researched, and the crystallite structural transformation of MgO productions at different pyrolysis temperature and time were analyzed by XRD. The experimental results indicates that the pyrolysis temperature and time effects the pyrolysis efficiency obviously, and the reasonable pyrolysis conditions by using MgCl2 in molten state are as follows: the pyrolysis temperature is 1100?, pyrolysis time is 60min and the partial pressure of oxygen is 100%, the pyrolysis efficiency get above 95% at this conditions. The dynamic analysis of molten magnesium chloride pyrolysis reaction shows that, as a chemical reaction process control, the response of the apparent activation energy Ea=70.4 kJ/mol.IntroductionTitanium is a young metal, it is applied in industrial until the Second World War. It is 160 years from the discovery of titanium to the industrial production of ductility titanium by magnesium reduction method in the United States in 1948. As a new kind of metal, titanium and titanium material are better than the traditional metal materials in mechanical properties, heat resistance and thermal conductivity. Titanium is a kind of landmark structure and function material, which is called “space metal”, “Marine metal”, “Intelligent metal” [1-3]. Although the study of new methods of titanium melting get more at present, Kroll method and Hunter method are really applied to industrial production methods for titanium smelting, and Hunter method is already discontinued because of costs at present. The core technology in Kroll method of sponge titanium production process can be ome down to two circulation, namely the cycle of magnesium and chlorine in preparation-process of titanium sponge. In the traditional Kroll method, the cycle is realized through magnesium chloride which is produced by the electrolytic magnesium reduction process in hot molten state. But because investment of equipment for electrolysis method is too high, this method has not been used by most titanium sponge production enterprise in China. At present most titanium sponge production enterprise in China produce titanium sponge by the outsourcing of titanium tetrachloride, but the main disadvantage of this method is that the by-product of magnesium chloride is difficult to deal with."

Jan 1, 2012

By Lv Guozhi, Ren Xiaodong, Liu Yan, Dou Zhihe

"This paper investigated a new desulfurizer, dolomite and ferrosilicon. Magnesium vapor produced by silicothermic reduction of dolomite and ferrosilicon in an immersion tube of molten iron was injected into the molten iron by carrier gas through the underpunch of the tube and desulfurization reaction occurred. In order to explore the desulfurization process of molten iron by the new desulfurizer, the thermodynamics, and experiments of magnesium vapor production and desulfurization have been studied. Through thermodynamic calculation, the reaction temperature of magnesium vapor production by 75ferrosilicon and light-burned dolomite is 1838K in the standard state and decreased with the decreasing partial pressure of magnesium vapor, PMg· When PMg=25kPa, the reaction happens at 1673K. From experiments of magnesium vapor production, reduction efficiency of Mg vapor is about 60 % in 15 minutes at 1673K. From hot metal experiments, the desulfurization efficiency is 89.35%, and the lowest sulfur concentration after desulfurization is 46ppm.IntroductionPretreatment desulfurization of hot metal has become a necessary step in modem optimizing steelmaking process for its cheap cost, which can not only liberate of blast furnace productivity and reduce the burden of produce steel, but also effectively improve overall economic efficiency of the iron and steel system[l-ZJ_ At present, injection magnesium particle is one of the two main methods of desulphurization in hot metal owing to its strong affinity for sulphur, low amount of slag produced, low iron loss in slag skimming and low equipment investment[3l. However, there are still some insufficiencies on the hot iron pretreatment with magnesium particles at present[4-5l"

Jan 1, 2013

By Kenneth G. Arne

INTRODUCTION The real problem is finding the "appropriate" financing sources by matching the risk and reward expectations of the various classes of investors and lenders. Generally, lenders who advance funds temporarily are interested in assuming only limited risk and conversely expect to earn only a limited reward. The equity owners on the other hand, are expected to take most of the risk of the enterprise, but should receive a reward commensurate with that risk. In particular they will receive the benefit of the company's increase in net worth over time. MINE DEVELOPMENT CYCLE Consider the development cycle of a mining project beginning with rank wildcat exploration (Figure 1) [ ] Just as different professionals must be utilized at different stages, so must different funding sources be used at different points in the pipeline. Figure 2 shows the general sources of funding: [ ] This concept can perhaps be better understood if we compare the risk with the capital requirements. Suppose each area within a triangle is proportional to the risk taken (see Figure 3): [ ]

Jan 1, 1985

By W. G. Brown

"Review of prototype testing of two types of three-phase, argon stabilized reactor/furnace indicates specialized advantages for both, as compared with existing metallurgical furnace technology. They are: the direct-arc, plasma-torch furnace (Knipp); and the indirect, plasma extended-arc reactor (PEAR), developed at the University of Toronto.IntroductionA unique type of three-phase AC, plasma extended-arc reactor, (PEAR), shown in Figure la with gravity feed, has been undergoing development at the University of Toronto, during the past fifteen years: argon gas, introduced axially through drilled-holes in ordinary graphite electrodes, increases the length of indirect arcing and improves electrical stability while decreasing electrode consumption as compared with the performance of AC electric arc furnaces (EAF 's). Meanwhile and independently, a three-phase, transferred arc plasma furnace (Fig. 1b) has been developed by the Krupp Research Institute in Germany, using argon-stabilized, water- cooled plasma-torches with thoriated tungsten electrodes.Accordingly, the two types of furnace are similar as to both three phase and stabilized operation, but otherwise they differ in several respects, ranging from indirect versus direct-arcing to principal intended application and current state of practical development. Between them they raise questions: (I) of their present or fore seeable economics in comparison with existing processes they are intended to replace , (see Heinke and Neuschutz, 1986, for a review of the merit s of AC and DC plasma-torch furnaces); and (2) of the state of development and accessibility of their plasma theory-in-common."

Jan 1, 1991

By William H. Mount

INTRODUCTION The requirements of mine ventilation demand the constant attention of the mine operator. Just as the physical mine structure changes with time, the ventilation requirements of a particular mine change considerably from season to season and even from day to day. No ventilation system can remain adequate indefinitely; and all systems require monitoring and adjustments to achieve proper ventilation. Instead of being given fore- thought and planning, mine-ventilation systems too of- ten are erected hastily, merely to correct an already un- healthy situation. The usual result is an inefficient and costly system that, in some instances, may prove in- effective in providing fresh air to the point of need. The ventilation of mines is a combination of both art and science. The fluid that must be moved is in- visible; its properties change drastically with temperature, barometric pressure, and humidity; and the methods of measurement are not precise. In part, ventilation engineering must rely upon the art of good industrial ventilation experience and sometimes even the trial-and- error method. However, the properties of air can be determined with relatively inexpensive equipment; with some care, measurement accuracies within 5% of the actual values can be obtained. Thus the art of ventilation gradually is being supplanted by improved engineering practices. Although the direction of flow and the volume may not be predicted correctly by airflow equations in every situation, it is better to try to predict the behavior of a given ventilation before installation than to proceed blindly with a system design. When used with the discretion that comes from education and experience, the basic laws of ventilation can provide sub-stantial insight into the design of an air-handling system; and they can prevent wasteful or even dangerous designs from being installed. Since the mine operators who read this text will have varying amounts of exposure to ventilation theory, the basic laws of airflow and of mechanical ventilation are presented in the first section. The emphasis has been placed on the interpretation and use of fan characteristic curves that are supplied by fan manufacturers. Considerable information can be obtained from these fan curves, particularly when they are used with a graphic model of the mine, drift, or duct in which the fan or fans are to be installed. A few minutes spent comparing the various characteristic curves can help the designer obtain the correct fan for the job. However, the under- standing of a few fundamentals is necessary; and this text has been prepared to provide ample and understandable information in a "how-to" style. In subsequent sections of this text, more down-to- earth subjects will be covered, including the problems of air recirculation, relative merits of installing fans in series or in parallel, expected maintenance requirements (vibration, lubrication intervals, etc.), fan noise and some remedies, effect of an inlet bell on the fan per- formance, basic air-measurement techniques and equipment, and similar miscellaneous items. Although this text is not intended to be a comprehensive bible of mine ventilation, it has been prepared as a guide that provides some useful information to individuals responsible for the quality of the underground environment. Every person working underground is en- titled to the safest environment that can be provided within the limitations of existing technology and at a reasonable cost. Adequate ventilation is well within both limits, provided that the system is designed intelligently, in conjunction with the mining plan, and not as an after-

Jan 1, 1982

By L. O. Howard

THE practice of using acid-lined converters at the plant of the Old Dominion Copper Mining & Smelting Co. was discontinued early in January, 1913, and they were replaced by basic-lined converters. The new equipment consists of one electrically operated 12-ft. upright converter stand and two basic-lined shells for same. These shells are provided with twenty-four 1 1/4-in. tuyères. The mouths are 5 ft. in diameter. Owing to the fact that there is no bedding system or other large storage capacity between the mine and the smelter, the furnaces must handle as fast as produced ore and concentrates, which may vary considerably from day to day, both in tonnage and copper content. Consequently the converter is often crowded to its utmost capacity by the frequent fluctuations in the daily matte supply. From the foregoing, it will be seen that in no way can the converter be favored by running light charges or by transferring to it from other stands in operation. Neither can it regularly be allowed to cool between blows, and only occasionally can it be run at as low a temperature as might be wished. No copper precipitate or other foreign material high in copper is available to help out the tonnage. Repairs and alterations or the removal of defective tuyères must wait until such time as a slight falling off in the matte supply-allows the converting operations to ease up. These variable conditions all combine to interfere with the systematic operating of the converter.

Jan 7, 1914

Discussion of the paper of L. O. HOWARD, presented at the Salt Lake meeting, August, 1914, and printed in Bulletin No. 91, July, 1914, pp. 1785 to 1790. E. P. MATHEWSON, Anaconda, Mont.-I would like to add a few words of praise on Mr. Howard's work at the Old Dominion. Mr. Howard has given this particular converter shell his personal attention, and the results are shown in the figures given. Similar converter shells, a little different in shape and of about the same size, have been tried in many plants throughout the United States. The results have been highly satisfactory, but there is no shell of the size of the one described by Mr. Howard that has given anything like the results that Mr. Howard's shell has given. I know of larger shells that have given very good service, and are still in operation, and require very little repair. The main thing about the whole process of using the basic lining in copper converting is to keep the temperature within reasonable bounds, particularly not to get the furnace too hot. If it is overheated a little bit, for say half an hour, an entire lining may be ruined. It is very easy to keep the temperature regulated 'if the mass is large. If you have a large mass in your converter you can easily prevent it from getting over-heated, and that is the big argument in favor of the extra large converters. Of course, there is a limit to what a plant can turn out in the way of matte. Very few plants can supply matte sufficient to keep a converter of 20 ft. in diameter in operation constantly, but the 20-ft. converter is very much superior to the 12-ft. converter in easy handling and absolute control of the temperature. I think Mr. Howard is to be congratulated on the excellent showing he has made.

Jan 12, 1914

By Yindong Yang

Despite the importance and usefulness of basicity in metallurgical slags, the optimum quantitative expression of it has remained elusive, partly due to the fact that the precise concept of basicity has not been properly clarified. The two basic approaches to the concept of basicity are the Lux-Flood, which perceives basicity in terms of the activity of the free oxide ion, a O2- , and the Lewis, which perceives basicity in terms of the ability to donate negative charge. The former has been almost universally adopted in the area of metallurgical slags, while the latter has been increasingly accepted in the field of glass chemistry. In this paper, some difficulties of the Lux-Flood approach are pointed out, including the need for indirect measures of a O2- , which have proliferated in recent years. Accordingly, it is suggested that the Lewis approach has a good deal to commend it, and that the quantification of it in terms of optical basicity is the best measure of basicity available, which should therefore be more widely applied in metallurgical slags than it currently is. The fact that there are intrinsic problems in evaluating the optical basicities for the transition metal oxides is acknowledged, and a new scale is recommended. The patterns of iso-optical basicity lines in ternary systems are shown to agree well with the pattern of iso-activity and iso-capacity lines under appropriate conditions. * Originally published in the Proceedings of MINPREX 2000, published by The AusIMM.

Jan 1, 2001

By T. G. Joseph

ABSTRACT: The Canadian oil sands provide some of the harshest mining conditions in the world. Asoperations demand ever bigger tools, the toll on large mobile mining equipment is high, with structural life often half of that expected. Soft ground conditions predominantly lead to fatigue failure scenarios, poor stability, and inconsistent payload evaluations. These challenges are not solely a concern for Canadian oil sands mines; there are far-reaching implications for surface mining equipment in any poor ground-operating environment. This paper focuses on the basics of payload evaluation, motion response, and a simple estimate of structural life for haulers.

Jan 1, 2011

By T. G. Joseph

ABSTRACT: The Canadian oil sands provide some of the harshest mining conditions in the world. Asoperations demand ever bigger tools, the toll on large mobile mining equipment is high, with structurallife often half of that expected. Soft ground conditions predominantly lead to fatigue failure scenarios, poor stability, and inconsistent payload evaluations. These challenges are not solely a concern for Canadian oil sands mines; there are far-reaching implications for surface mining equipment in any poor ground-operating environment. This paper focuses on the basics of payload evaluation, motion response and a simple estimate of structural life for haulers.

Jan 1, 2011

By F. W. Brackebusch

Paste is a high density mixture of water and fine solid particles with a relatively low water content (10-25%) such that the mixture has a consistency as measured by the ASTM slump cone test from slightly greater than zero up to nearly 12 inches (305mm). Particles of different size classes will not segregate or settle when the paste is not being agitated or when it is stationary in a pipeline. Cement may be a component of paste. Larger particles of aggregate can generally be added to a paste without greatly changing the pipeline transport characteristics. A paste may bleed water slightly when it is allowed to be motionless for periods of up to several hours, but the solids do not become so dense that the paste cannot be easily re-fluidized. The dividing line between the definition of a high density slurry and a paste is not sharp. It is a practical matter that must be considered when designing a pipeline transportation system. If the pipeline is very short, there is very little risk of plugging the pipeline with a high density slurry when flow is stopped for short time periods. With longer pipelines the mixture must remain stable without motion for periods as long as several hours to avoid pipeline plugging. The fine particles in a paste mixture can be composed of mine tailings or naturally-occurring clays, silts and fine sands. The mineralogy of the particles thus can have a wide variety from quartz and feldspar to clays, micas and even salts.

Jan 1, 1993

By Anthony J. Konya

"This paper was written during part of the author’s student co-op with Cargill Salt at its Avery Islandunderground salt mine in Louisiana. Blasting salt is a unique type of blasting that is different than blasting other rock types. The plastic nature of salt, along with its large swell factor make salt a challenge to blast. The Cargill salt mines use and have tested a variety of different methods for breaking salt in an efficient manner, however these blasting methods are rarely used in other operations nor talked about today."

Jan 1, 2016

By Gordon J. Hughes

The ldaho Cobalt Belt represents a unique geologic environment containing some of the largest known reserves of cobalt in the United States. Stratabound cobalt-copper-gold deposits formed within a sedimentary basin that was generated by the rifting of an Archean cratonic block. Host rocks for these deposits are the Early to Middle Proterozoic Yellowjacket Formation comprising a suite of clastic sediments, volcaniclastics, and mafic tuffs that accumulated in the intracratonic rift basin about 1.7 b.y. ago. Rifting was probably initiated during a regional heating and doming event that may date back to 1.8 b.y. ago. During this time, other rift basins were likely to have formed in the region. They probably represent the precursors of a much larger depositional environment having characteristics of an Atlantic- type or passive continental margin where younger formations of the Belt Supergroup were deposited. The Yellowjacket Formation has been subdivided in the Idaho Cobalt Belt into three genetic units representing various subenvironments of a deepwater clastic fan complex. A northwest- trending deep-basin structural trough accumulated fine-grained muddy sediments that were periodically interrupted by distal turbidites of the subaqueous fans. Subsequent progradation caused the deposition of coarser-grained clastics of the more proximal portions of the fan complexes. Submarine fan lobes were built across northwest-trending tectonically active basin growth faults. These in-basin structures caused a great deal of penecontemporaneous deformation within the Yellowjacket sequence. Northeast-trending fault zones formed an orthogonal set of fractures that controlled the shape and size of sub-basins, and were also an influence on lateral migration of dominantly fine-grained clastic material. The eruption of mafic tuffs at about 1.7 b.y. ago added a new component to the Yellowjacket sedimentary sequence. Around the Blackbird mine area these tuffs commonly occur either near the base or within some of the sandier sequences. Since most of the sand influxes were largely controlled by basinal tectonism, the tuffs were probably erupted during tectonically active periods of basin development. The dynamic nature of the sedimentary environment probably caused much of the tuffaceous component to be mixed with other clastics and even resedimented as volcaniclastic material. In time, the change to a higher energy sedimentation regime resulted in such a dramatic clastic dilution of the tuffs that they could not survive in the areas of the vents, and, if present, they must have been distributed elsewhere in the basin.

Jan 1, 2013

By R. Salimi

Tricalcium aluminate hexahydrate (TCA) is used as filter-aid for security filtration in the Bayer alumina process. TCA is typically produced on-site by mixing Bayer liquor with slaked lime. Specific properties are required from the TCA to ensure adequate filter throughput, lifetime and importantly effective reduction of solid/colloidal impurities from the solution. The effect of reaction time on morphology and particle size distribution of tricalcium aluminate was studied for a batch experiment at simulated process conditions. It was found that reaction time plays a critical role on the morphology, crystal structure (diameter and crystallinity) and particle size distribution. In the early stages of the reaction, nucleation dominates the crystallization process followed by growth dominated by agglomeration up to a mean particle size of 10 µm. The particle morphology shifted from an irregular shape to more spherical throughout the course of the reaction.

Jan 1, 2014

By N September, R Abate

Bateman Modular (previously Van Eck and Lurie) has been building and supplying the mining industry with modular DMS plants for the last 30 years. These DMS modules range in capacity from 1 tph to 200 tph. The most popular unit produced by Bateman Modular over the years has been the 50 tph module. Development In the last 7 years a need has arisen from the industry to provide Modular DMS plants that can treat higher tonnages (150 to 200 tph). The first DMS provided to the mining industry based on the modular concept was a 150 tph DMS Module to MIBA in the DRC. Since then Bateman Modular has provided some 14 Mega DMS modules over the last 7 years with the latest two orders from Debswana (Damtshaa double up project) and Namdeb. Ever since the first Mega Module was supplied Bateman Modular has been improving the Modules. Implementation The modules can be supplied in different configurations so as to improve the overall availability of the plant. Two off 150 tph DMS modules were supplied for a Transhex operation. This allowed the client to still operate one DMS module while maintenance is being performed on the other DMS module. The client also has the option of choosing a single module. Successes The following list of projects provides the base for the success of the Mega Modules.

Jan 1, 2006

By A. Scheltema Beduin, H. Oterdoom, A. Haaks, C. Kempe, A. Liedtke

The bath level measurement is applied in many furnaces to keep control of the level of slag and metal or matte inside. The BLM is used mainly in bath processes, and has not seen much evolution in its basic functionality. For a closed DC FeCr furnace, special demands based on the furnace design and extreme process conditions were considered for the design of a bath level measurement in order to collect valuable information about the furnace operation. This paper will describe these demands and the solutions for them, followed by some of the uses for the BLM in a closed FeCr furnace. Some of the future developments on the BLM conclude this presentation.

Jan 1, 2015

By Patrik Bloemer

Reliable and accurate furnace bath level data during the melting process is invaluable for good decision making and furnace optimization, while obtaining such information rapidly and safely on a regular basis is of paramount importance. This paper shows how a melting process problem was identified as a concern, how a solution was sought and how a real-time measurement system was tested by simple modification to an existing temperature sampling manipulator. Also how, with furnace power on or off, taking reliable hot heel, fill and running levels could be used to assist melting control, aid decision making and improve safety.

Jul 30, 2018

By L. Paulino, R. A. Camilli, J. Yamamoto, J. C. Araujo

The first paper presented on this work [1], showed how bath ratio was increased from 78% to over 95% using a structured approach to reduce bath chemistry variability. This update will illustrate the steps taken and update the results presented earlier, showing the effects of long power interruptions and several load reductions as well as load increase during the period from 1999 to 2005. Current efficiency was affected by such processes upset; however, bath ratio in range (±0.05) is still higher than 90%, even after an increment of more than 6 kA. This review will explain each of the steps taken to reach stability in this critical smelting parameter.

Jan 1, 2006