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By X. Xie

The dissolution behavior of palladium powder in thiourea solutions has been studied. The variables studied included temperature, stirring speed, and concentrations of thiourea, acid and ferric ion. Palladium was found to be soluble in thiourea solutions in the presence of an oxidant such as ferric ion. The dissolution of palladium in thiourea solutions was found to be chemical reaction controlled with an apparent activation energy of about 2S.3 kJ/mol.

Jan 1, 1995

By Xinghui Meng

The leaching behavior of platinum powder in .iodide solutions under oxygen pressure in an autoclave was investigated. Ammonium salts were added to the leaching solution at neutral pH as a key lixiviant for platinum. The effect of temperature, partial pressure of oxygen, concentration of iodide and of arttmonium salts on the dissolution rate of platinum was examined. Under experimental conditions, the leaching behavior of platinum powder exhibited a complex reaction mechanism. A precipitate was found during the leaching process and was identified to be platinum ammine iodide, Pt(NH3hI4. The dissolution rate was controlled by a series of chemical reactions, the equilibrium concentration of the platinum ammine iodide being responsible for the ultimate limit to the recovery.

Jan 1, 1996

By D. Hong

The leaching behavior of rhenium in ammonium iodide solutions with iodine as oxidant has been studied. Experiments were carried out in an autoclave. The effect of stirring speed, temperature, pH of the solution, iodine and iodide concentrations on the dissolution of rhenium was investigated. It was found that high temperature and high pH of the solutions were essential for the efficient leaching of rhenium. The dissolution rate was found to be dependent upon the concentration of iodine and iodide. It was concluded that the dissolution of rhenium under the conditions studied was controlled by mass transfer of iodine with an apparent activation energy of 15.77 kJ/mole.

Jan 1, 1997

By S. J. Ma

To look into the ionic release laws of the sulphide tailings in some copper mine, the effects of the soaking period, temperature, oscillating speed, and pH of the solution on the heavy metals ionic re-lease were investigated through static soaking leaching experiments. The results show that Cu2+, Zn2+, Pb2+, Cr3+ are of different leaching behaviors with soaking period. The ionic concentration in soaking solution for four ions has a great gap. Zn2+ is more easily released out of sulfide tailings than Cu2+, Pb2+, Cr3+ , and the ion release concentrations are not proportion to their contents in the tailings. The time for each ion to reach its maximum concentration are different. The minimum concentration do not occur at the first day. Each ion concentration shows different fluctuation characteristic during soaking process. Solution pH, oscillating speed, and temperature affect the releases of Cu2+, Zn2+, Pb2+, Cr3+ out of the tailings to different extent. The effect of pH value on ion re-lease for the four ions ranks as Zn2+>Cu2+>Pb2+>Cr3+, the oscillating speed ranks as Pb2+>Zn2+>Cu2+>Cr3+, and the temperature ranks as Cr3+>Pb2+>Zn2+>Cu2+.

Jan 1, 2014

By Y. C. Guan

The leaching kinetics of chalcopyrite in ammonium iodide solutions with iodine has been studied using rotating disc. The variables studied J include the concentrations of lixiviants, rotation speed, pH of the solution, reaction temperature, and reaction product layer. The leaching rate was found to be independent with the disc rotating speed. The apparent activation energy was measured to be about 50 kJ/mole from 15°C to 35°C, and 30.3 kJ/mole from 35°C to 60°C. Experimental findings were described by a kinetic model, and the overall rate was found to be: (formula)

Jan 1, 1997

By D. L. Jones

The leaching of natural chalcopyrite was studied in both ferric sulfate and ferric chloride solutions. The chemistry of the two reactions is quite different, with substantial sulfur oxidation occurring only in sulfate solutions. Ferric chloride is a more effective reagent, for the leaching rate is greatly increased with finer particles and higher (Fe+++), and unaffected by high (Fe++); none of these advantages are found with ferric sulfate. In addition, the morphology of leaching appears to be different, with ferric sulfate leaching preferentially along fissures or grain boundaries. The kinetics were found to be linear over an extended period, rather than parabolic as reported elsewhere. An explanation of the observed phenanena is proposed using the electrochemical theory of leaching, and experimental measurement of the mixed potential of the mineral during leaching.

Jan 1, 1976

By I. H. Warren

Hydrometallurgy has a well-known and established role in the production of manganese metal (1) and manganese compounds, including battery grade manganese dioxide (2). Also, several leaching processes have been developed and applied at various times for the recovery of manganese from low grade ores (3). Recently, interest in the hydrometallurgy of manganese has been stimulated by the problems presented in the processing of sea nodules (4). Fumes and dusts from the ferro-manganese furnaces also offer a potential field for the application of manganese leaching techniques (5). In treating low grade manganese ores a major requirement of the leaching process is that it should dissolve manganese from a mixture of manganese and iron oxides. The most selective reagent for this purpose is ammonium carbamate applied after preliminary pyrometallurgical reduction of the ore (6). Since soluble carbamate complexes of the postulated type (7) are formed by both manganous and ferrous, but by neither manganic nor ferric, ions, selectivety of manganese leaching is achieved by control of the reduction operation to yield, essentially MnO and Fe304? A potential improvement to this two step process would be to simultaneously reduce and selectively leach the manganese in one hydrometallurgical operation. This possibility has been experimentally studied and the results are described below. During the preliminary study of the stability of solutions of ammonium, ferrous and manganous carbamates at elevated temperatures, it was observed, contrary to the observation of Welsh (8) at lower temperatures, that

Jan 1, 1971

By R. Menge, N. Basin, M. Sibony, J. Lecadet, S. Schmidt

In 1996, Metaleurop replaced its conventional sintering and blast furnace lead smelting activity in Nordenham, Germany by Sirosmelt/Ausmelt technology. Following some alterations to the process and the equipment, the bath smelting plant reached its design capacity for the treatment of lead concentrates, lead sulphate paste from spent batteries, secondaries and internal by-products. A reliable metallurgical process has been established, and thus higher process stability has been achieved, increasing simultaneously the refractory life. Nevertheless, improvements are needed to control the process with a better automation system and reliable expert-systems, because of the intensity of the smelting process. The introduction of the Sirosmelt process for the pyrometallurgical production of lead instead of the prior conventional process has also demonstrated the following advantages: reduced emissions of heavy metals and gaseous compounds, reduction of the specific energy consumption, minimization of residues and a reduction of staff and maintenance costs. The environmental performance of the plant meets the requirements of the German regulations.

Jan 1, 2000

By Wm. E. Milligan

LEAD stocks at the beginning of 1943 were comfortable when compared with those of other base metals such as copper, zinc and tin. This situation was early recognized by W.P.B. and other Governmental agencies and every effort was made to encourage the substitution of lead for these latter metals in all essential uses. Despite this apparently healthy condition, lead was not denied participation in the various measures inaugurated by the Government to relieve metal shortages. Thus in the Mexican trade agreement, effective Jan. 20, the tariff on two important classes of lead importss was halved. Similarly, in the setting up of B quota premiums, a B base was allotted to lead, with all pro¬duction above this figure receiving an additional payment of 2.75c. per lb., or a total payment of 11.75c. per lb. At about the same time it was announced that all quota transactions would be based upon the lead content as shown by the smelter settlement sheets. This basis was 86 percent of the lead content for all ores shipped to custom milling plants and 95 per cent for ores and concentrates shipped to custom smelting plants. The importance of this action can be appreciated when in the Coeur d'Alene it was estimated as equivalent to a 5 per cent increase compared to the previous base.

Jan 1, 1944

By R. A. Perry

DURING 1943, supplies of lead, like those of most base metals, moved from a position of scarcity to one of ample supply for all possible war requirements. The principal worry in the market, as 1944 began, was that surplus stocks might increase too rapidly to maintain price stability. The problem of postwar stockpiling had definitely entered the picture. The end of the year finds the lead industry having met all use demands, but not without depleting stocks to a critical low in spite of heavy importations. The principal reason for this dangerously reduced stock position is lack of adequate man power, which, without question, has become the lead industry's number one problem. This condition became obvious about the middle of the year, after Selective Service placed in effect orders that no deferments would be given employees under 26 years of age, and to a complacent attitude toward the industry assumed by the War Manpower Commission. It has become progressively worse since then. The WPB continued its policy, started during 1943, of easing restrictions on materials to be used for maintenance, repairs, and operating supplies. The policy of premium payments established by the Metals Reserve Co. was continued and, in spite of expressions to the contrary, has proved quite satisfactory. In short, the Government continued its program of stimulating the lead industry in practically all

Jan 1, 1945

By L. D. Anderson

IN STUDYING Utah as a lead producing state one is immediately confronted by the fact that few, if any, of the ores of the state are valued for their lead contents alone. More correctly the ores from which this metal is recovered are characterized as silver lead. Even then the whole story is not told for many of these ores carry also gold, copper, zinc, bismuth, antimony, arsenic, tellurium, and other metals. It becomes apparent, therefore, that the production of lead i11 Utah is influenced by many factors. For example, i11 the early part of 1923 there was a marked increase in the production of the lead by reason of the efforts made by silver mines to produce as much silver as possible before the termination of purchases under the Pittinan Act in June, 1923. As nearly all silver ores carried more or less lead the production of that metal was increased with the increase in silver production. Very few, if any, ores of the State are mined for their lead contents alone. Important as Utah's contribution to the lead output of the country is nevertheless it is bound up to some extent with the production of gold, silver and copper.

Jan 1, 1925

By R. S. Dean

THE first attempt to establish an equilibrium diagram of the lead-antimony series was made by Roland-Gosselin1 in 1896. This investigation classified the system as a purely eutectiferous one, with the eutectic at 12.5 per cent. antimony and 228° C. In the next year, Stead2 placed the eutectic temperature at 247° C. The error in temperature made by Roland-Gosselin, however, has been perpetuated in the literature with a remarkable degree of persistency; this value was accepted by Campbell (1902), and Ewen (1910),3 and will be found in the last edition of Desch's3 Metallography (1922). Gonterman's investigation, made in 1907, was the most complete one available at the time the present investigation was started. He concluded' that the system was a simple eutectiferous one and placed the eutectic at 13 per cent. antimony and 247°C. Other investigations by Tammann (1907),5 Garbow (1909),6 Rudolfi (1910),7 Loebe (1911),8 and Leroux (1913)9 added little, if any-thing, to Gonterman's diagram. A number of investigations have been made of physical properties of the alloys. The electrical conductivity of the series was studied by Matthiessen (1860)10 and by A. W. Smith (1921);" the thermoforce by Rudolfi (1910),12 and Pelabon (1923);13 the specific heat by Durrer

Jan 2, 1926

By J. D. Little

"THE SALMO PROPERTIES of Canadian Exploration, Limited comprise forty-one Crown-granted mineral claims situated on Iron mountain between Sheep creek (on the north) and Lost creek, some eight miles southward from Salmo, in the Nelson mining division (see Figure 1). On these claims there are at present four operating mines. These are, from north to south, the Dodger, Feeney, and Emerald, all tungsten mines, and the Jersey, a lead-zinc mine, about 7,000 feet south of the Dodger. About midway between the Dodger and the Jersey is a fifth mine, the Emerald lead-zinc mine, which was the first producer in the area but has been inactive since 1926. The locations of the mines are shown in Figure 2.Records of prospecting and claim staking on Iron mountain -which owes its name to the presence of large iron-stained outcrops -go back to 1895. The first recorded owner of the claims that form the old Emerald lead-zinc mine was John Waldbeser who, in 1908, did considerable work and produced 426 tons of lead ore valued, at the then price of lead, at $7,000. This ore was chiefly lead carbonate and was taken from the surface outcrops of two bands of ore that form the Emerald orebodies. In 1909, the Emerald was the largest lead producer in the Nelson mining district."

Jan 1, 1953

By David B. Brooks

I gratefully acknowledge the help of a number of American and Canadian geologists, in both federal surveys and in private firms, who took the time to discuss this problem with me. Hans Landsberg and Bruce Netschert also followed the study with interest and encouragement. In their 1961 monograph, THE FUTURE SUPPLY OF THE MAJOR METALS, Bruce Netschert and Hans Landsberg noted that identified potential resources (that is, known but submarginal resources) of lead and zinc were much lower relative to reserves (that is, known and supermarginal resources) than was the same ratio for other metals.1/ Put another way, it seemed that for such metals as iron, manganese, copper, and aluminum, slightly more favorable economic conditions or modest advances in technology would greatly increase reserves by permitting the exploitation of vest quantities of leaner or deeper or otherwise less valuable mineral deposits. But for lead and zinc, Netschert and Landsberg concluded that either: "(1) there is relatively little material below present cutoff grades; [or] (2) such material exists, but for some reason there are no data.? 2/ This situation, which they called "the lead-zinc anomaly" has been subsequently discussed by other authors. The purpose of this paper is to carry the discussion further by examining the evidence in favor of (1) and (2) and by advancing a third alternative.

Jan 1, 1967

By Neil Campbell

"The gently-dipping Devonian dolomite beds south of Great Slave lake in northern Canada are nearly every-where concealed by a cover of glacial drift and muskeg. Nevertheless, in 1898 or earlier, four small outcropping areas of dolomite, richly mineralized with lead and zinc sulphides, were discovered. Exploration work performed here up to the end of 1930, included intensive trenching and drilling of the showings, together with mapping and wide-spaced drilling in the surrounding region. This work proved that the discoveries are isolated pockets of mineralization much too small to be commercially valuable by themselves. No evidence of orebodies elsewhere was reported.Meanwhile, mapping by the G.S.C. in the Shield far to the east disclosed major Precambrian faults, some of which can be projected southwesterly (under a cover of Paleozoic sediments) to the vicinity of Pine Point. During the period from 1940 to 1947, consideration was given, by The Consolidated Mining and Smelting Company Ltd., to evidence of a theoretical possibility that, although apparently dormant in Paleozoic times, these faults may have provided a structural control and a source of ore-bearing solutions in some post-Devonian period. From this, it was postulated that the breaks might have created, in the overlying dolomite, a linear array of orebodies concealed by overburden but lying in a belt of considerable length and in a position predictable within practical limits. A program of drilling designed to test and exploit this specific concept was conducted from 1948 to 1955.he drilling within the new, theoretically-defined search area resulted in the discovery of many lead-zinc ore-bodies, none of which was exposed at the surface. Some of these are large and (as indicated by 1965 production records) very rich. They are situated 1 to several miles distant from, and apparently not connected to, the earlier-known surface discoveries. The drilling also disclosed that the ore, which consists of disseminated sphalerite and galena replacements together with colloform sphalerite and coarse galena cavity fillings, occurs mainly at certain stratigraphic horizons within a large, coarsely-recrystallized dolomite barrier reef. Considerable fracturing and folding was found. It has been suggested that reef development was influenced by post-Precambrian tectonic movements associated with the old faults in the basement complex. The ore may have been deposited by solutions moving from distant sources to favourable structural and chemical environments in or related to the reef.In more recent exploration performed in the course of preparing for mining production, the rate of ore discovery within the same general geological context has been greatly accelerated by the use of new geophysical techniques and drilling equipment. Reserves of 21.5 million tons, averaging 4 per cent lead and 7.2 per cent zinc, were reported in 1965, and production from open pits at the rate of approximately 248,000 tons of concentrates per year is in progress"

Jan 1, 1966

The common notion that the Box Hole Bore mineralization represents a variant of the Mississippi Valley type, has not been supported by the present investigation. Most of the common characteristics of Mississippi Valley type, namely 1. saturated saline brines; 2. low temperature domain; 3. mineralization in intraformational breccias and collapsed anticlinal structures; 4. hydrocarbon-rich or foetid carbonates, and 5. very simple geochemistry seem not to be applicable. The Box Hole Bore mineralization features: 1. moderately saline brines (18% NaCl); 2. very high temperature (495¦-520¦C) and low density brines, of critical vapour:water ratio and low pressure of formation (700 bars); 3. mineralization confined by faults and ex- tending laterally into carbonates of high pore volume such as stromatolitic dolo- mites; 4. ore environment characterized by oxidizing conditions, such as ferruginous carbonate and silica sands of high energy environment (heavy mineral banding) and 5. more complex geochemistry than is normal for Mississippi Valley type deposits (copper sulphosalts, and appreciable silver content). Additionally, the ore has un- usual textures formed by the replacement of carbonates and barite by large idiomorphic galena crystals. The pressure and temperature domains of the Box Hole Bore mineralization indicate post- Devonian emplacement and local high heat flow, possibly related to the Alice Springs Orogeny. Because of high lead and zinc trace element con- tents (100-600 ppm) of the carbonates, even out- side mineralized areas, it is possible that the mineralizing fluids have derived their metal con- tent from a local source, possibly aided by evap- oritic concentrations of the tidal to supratidal sequences. The new model for Box Hole Bore gives treater importance to the confining faults.

Jan 1, 1984

By Frank Schrama

Steelmakers worldwide agree that the most efficient and cost-effective solution in BOF steelmaking is to desulfurize the hot metal between the blast furnace and converter. Various methods are currently in use, among which the Kanbara Reactor (KR, using only lime as a reagent), Magnesium mono-injection (MMI, using only magnesium; also known as the Ukraina-Desmag process) and co-injection (using magnesium and lime/CaC2) are leading. These three hot metal desulfurization methods are compared based on metallurgy, efficiency, costs and overall performance. Both available data from literature and experience from Danieli Corus engineers is used for this study. The KR process is able to reach low sulfur concentrations (> 10 ppm) in hot metal and has lower reagent costs. However, due to higher Fe-loss and heavy wear the KR process has the highest operational costs. The Magnesium mono-injection process is very fast due to the use of the reactive magnesium as reagent. Major problems with resulfurization (sulfur levels below 50 ppm cannot be reached) and the violence of the process made that this process could never get a firm foothold in the western steel industry. The co-injection process with magnesium and lime proves to be able to combine the best of both worlds. It can reach low sulfur concentrations and desulfurize fast. Co-injection is also the most flexible and cost effective.

Aug 16, 2017

By R. H. McCorkell

Measurements of radon in air and aqueous solutions can be affected by leakage from vessels in which samples and standards are kept and by absorption and later release of radon by the materials of these vessels. The author had received various oral communications concerning the se processes : e.g ., that natural rubber and greases absorb large amounts of radon, whereas silicone rubber and grease do not; and that radon is readily lost from polyethylene bottles and that inverting glass bottles containing aqueous samples reduced radon loss from them . However, the results of actual tests and quantitative data showing these effects were not available. For this reason, it was necessary to make numerous measurements of the leakage and absorption of radon in the course of designing apparatus and methods for measuring radium and radon concentrations. It was thought that the data obtained might be of use to others, and consequently they are compiled in the present note .

Jan 1, 1980

By John Greenhalgh, Benoit De Rivaz

"1.INTRODUCTIONThis paper is based on the Lee Tunnel project, which is part of the Thames Water’s Tideway Project.The client Thames Water has employed a Joint Venture of Morgan Sindall/Vinci Grand Projets and Bachy Soletanche to undertake the design and construction of the project under the management of CH2M Hill at a value in excess of £635 million ($990 million). The 3 main elements of the tunnel project are the permanent lining to the shafts, the precast segmental lining, and the secondary tunnel lining. All 3 are reinforced with different types of Dramix steel wire fibers and each element will be described in this paper. This paper will explain the basic structural design of FRC (Fiber reinforced concrete) based on the post cracking residual strength and will describe all the steps of this project, the testing program realized to support innovative design and the main technical learning point. 2.BASIC CONCEPT OF STRUCTURAL DESIGN OF FRCStructural design of FRC elements is based on the post-cracking residual strength provided by fiberreinforcement. Other cases, like early age crack-control or fire resistance, are considered non-structural use of FRC. For structural use, a minimum mechanical performance of FRC must be guaranteed. Fibers can be used to improve the behavior at SLS (Service Limit State) since they can reduce crack spacing and crack width, thereby improving durability and they can be used to improve the behavior at ULS (Ultimate Limit State) where they can partially or totally substitute conventional reinforcement in most conditions. In the design process, the definition of the performance expected from the material is a key factor and the mix-design of the material has to be optimized for the required structural performance.2.1 Testing Method In order to ascertain the structural requirements requested for the FRC segments, preliminary testing on samples will be required and the effectiveness of the proposed solution will also be assured by the testing of full scale specimens. Structural design of FRC elements is based on the post-cracking residual strength provided by fiber reinforcement. For structural use, a minimum mechanical performance of FRC must be guaranteed. Nominal values of the material properties can be determined by performing a 3-point bending test on a notched beam according to EN14651 (figure 1) or by performing the ASTM C1609 beam test:"

Jan 1, 2016

By B W. Ham

The legacy of underground coal mining may be a land surface which, in parts, may be unstable in the long term. A case study analysis has been undertaken to explain some of the hazards and how the risk may be assessed and managed.The Ipswich Coal Measures were extensively mined with shallow underground workings, which now underlie a number of suburbs in the eastern side of the city of Ipswich in south eastern Queensland. The area was subject to underground mining from the 1840s to 1997. In general, the mines were small, family-owned operations that were restricted by complex geology, interactions with neighbouring operations and ownership of surface facilities. The oldest available mine plans date back to the late 1890s.The residents in these mining areas have a long history of unexpected mining subsidence events. A level of risk management for property owners has been implemented by the Ipswich City Council, which requires a mining subsidence risk assessment to be submitted as part of building applications for property development in the areas suspected of having mining subsidence risk. This discussion examines a series of generic subsidence events and how the risk may be assessed and managed and the hazard controlled.CITATION:Ham, B?W, 2014. The legacy of underground coal mining – mine subsidence: Ipswich coal measures case study, in Proceedings Life-of-Mine 2014 , pp 113–120 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014