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By J. M. D. Wilson

The literature relating to binders in iron ore pelletizing is reviewed from the point of view of their established or proposed bonding mechanisms in green and dry pellets.

Jan 1, 1981

Blasting is known to be both an important and an easily quantified cost factor in rock breaking operations. However, the indirect costs and benefits of the blasting operation are not easily determined due to the irreversibility of the mechanisms involved and the multiplicity of influencing factors. A general conceptual model showing the relationship between blasting and mining costs is well known, but serious attempts to address the critical real relationships have all floundered on the fact that not enough is yet known about either detonation physics or blasting effects. This can only be remedied to the extent that blasting instrumentation enables researchers to pin down not only the relationship between the detonation process and its impact on a particular environment, but also the downhill costs of handling the rock, repairing any damage and building in "Safety Factors" to provide for imponderables. It is vital to standaraize on specifications for instrumentation and measurement techniques and there is a need to review what has been achieved in blasting expertise so as to focus on the most fruitful paths for future work.

Jan 1, 1990

By Vladislava A. Ignatkina, Victor D. Samyguin

"Within the limits of two-phase approach, considering mass transfer with pulp and air streams was shown that each bubble appears to be an elementary carrier, transporting particles from the collection zone into the froth. The kinetics of flotation was described by the exponential equation in which first order flotation speed constant has to be replaced with two-phased coefficient of a mass transfer. Criteria of selectivity of two ore fractions separation, based on determination of optimum time at which maximum difference between extractions and components content in separated fractions were offered. An interrelation between optimum time of pulp residence in a flowing chamber of a flotation machine, time of bubbles mineralization and an optimum airflow has been ascertained. Cumulative criterion of mass transfer efficiency of flotation process has been ascertained to be a form of the spectrum and its position on axis of three-phase coefficient of a mass transfer.INTRODUCTIONRegularities of a mass transfer of three bearing streams: pulp stream, air stream and froth stream underlie theory of mineral complexes flotation (Samygin, Filippov, & Shekhirev, 2003)However, only description of mass transfer in pulp stream by means of kinetic equations that were simple and convenient for practical use, has gained a full distribution (Tykhonov, 2009;Rubinstein&Filippov, 1980; Saleh, 2010).Within the limits of a single-phase approach, the role of gas stream in increase of speed and selectivity of flotation, was associated with an improvement of hydrodynamic mode. An influence of particles and bubbles sizes (Rubinstein&Filippov, 1980; Rubinstein&Samygin, 1998, Samygin et al., 2003; Dai, Fornasiero,& Ralston, 2000), of pulpflow and airflow (Finch& Dobby, 1990) and turbulent energy intensity (Shubert, 1979; Massinaei, 2007) on the flotation process has been studied. It was stated that flotation selectivity is increasing by means of gradual airflow increase from first to final cameras of the impeller flotation machine (Aslan&Boz,2010; Finch, 2011) and by means of using a multizone flotation machine (Samyguin, Filippov, Matinin, Lekhatinov, &Tertyshnikov, 2013)."

Jan 1, 2016

By E. Allen Wendt

It is both a great pleasure and something of a challenge for me to have this opportunity to address a gathering encompassing such a wealth of expertise in the minerals field, It is particularly challenging because I have been asked to turn your attention from the relatively glamorous subjects of gold and money to the more mundane questions of our International commodity policy and the place of buffer stocks in that policy. However, these questions may be of more immediate importance for our economic interests at home and Abroad. I can testify that the problems affecting international commodity markets and the possibility of international action To resolve those problems are matters of real concern to Washington as well as to your industries,

Jan 1, 1978

By M. L. Free

Several studies of the fluorite/oleate flotation system have shown that under certain conditions calcium dioleate is formed at or transported to the fluorite surface. Adsorption of significant amounts of calcium dioleate is generally observed above oleate concentrations of -6 -5 between 4 x 10 and 4 x 10 M, yet little explanation of the onset of calcium dioleate adsorption is provided. In this study in-situ and ex-situ FTIR/IRS experiments have been performed in connection with thermodynamic solution phase analysis to better understand oleate adsorption as well as the onset of calcium dioleate formation. Results from this study are analyzed and compared to industrial practice.

Jan 1, 1995

By J. S. Ross

The significance and role of industrial minerals in Canada differ from those in the United States, The smaller Canadian industry has recently become well diversified and self-sufficient in most commodities, However, it depends on exports, principally to the United States, for much of its market, Imports are small, but imports of several basic products manufactured from industrial minerals are large. This nation is a leading world producer of asbestos, gypsum, sulphur, nepheline syenite, titania slag, potash and barite. It has reserves in asbestos for at least 30 years enough potash to supply the current world's needs for 2,000 years and sulphur reserves for 40 years of current world demand, One of the ilmenite deposits contains enough titania to supply the current world demand for at least, 25 years.

Jan 1, 1964

By Gerald L. Colborne

The major role of financial institutions in the free world in the development of mineral resources is to provide the necessary capital in the form of loans to underwrite the development of these resources by the industry on a stable and continuous basis. This capital provided by the depositors to the bank must be invested in sound projects where the degree of risk is relatively small, the return on the investment is reasonable and the time to retire the loan is of short duration. Money is, therefore, one of the important ingredients along with technology, manpower and an exploitable resource that will provide a sound economic base in this region of development. Canadian banks are similar to banks of other western nations, although each country has some differences in their banking systems. The basic difference between the American and Canadian systems is that the former employs unit banking while the Canadian utilizes the more mobile branch system, which is prohibited or restricted in the United States and some other countries. Canadian banks are the subject of this paper, so, subsequent material will relate to Canadian banks unless indicated otherwise. It will be realized by everyone that the mineral industry is only one area of the economy in which the banks are interested and to cover the subject matter in the time allowed, the topic is restricted to mineral resource development. In Canada this is a vital sector of our economy and before we outline some of the details of financing and services involved in various aspects of mineral development, a review of the Canadian mineral industry is a necessary part of the sequence of presentation. The writer presents this material as a resource engineer advising a major bank in mineral matters, so the presentation may relate more to the financial problems of the developer

Jan 1, 1972

By K. M. Wild, C. D. Martin, F. Amann

Peak laboratory strength data obtained from low permeability clay shales/rocks often display a bilinear or non-linear failure envelope. In many of these tests pore pressures are not measured because of issues associated with back-saturation prior to confined compressive loading. In such tests the effective state of stress at failure remains unknown and provides room for speculation. The non-linear shape of the failure envelope may have several reasons including the influence of capillary forces or the tendency of a saturated clay shale to dilate as the confining stress is changed. The former stems from sample preservation, preparation or core unloading effects and represents a partly saturated state (i.e., not representative for the in-situ state); the latter represents the response of a saturated material. This contribution discusses these issues based on a data set obtained from Opalinus Clay specimens, and concludes that without a careful back-saturation processes knowledge of the underpinning reasons for the non-linear failure envelope cannot be obtained.

Jan 1, 2015

By N. Sahin, K. Baris, A. Ozarslan

This paper aims to assess the current and future role of coal in energy strategy of Turkey and evaluates the compatibility of the policies to the EU energy policy and strategy. The Turkish government set targets to utilize more coal reserves of the country in next decades. However, the country is also in the process of becoming an EU Member State, hence, it is expected that the energy policies have to comply with the EU. Moreover, Turkey ratified Kyoto Protocol, thus the country should limit greenhouse gas emissions. Clean Coal, Carbon Capture and Storage (CCS) technologies are expected to become an important instrument for the mid-term reduction of CO2 emissions from coal-fired power plants. An alternative technique to the conventional CCS methods is CO2 sequestration by mineral carbonation. Turkey has significant resources of magnesium silicate minerals (olivine, serpentine) deposits which can be utilised in CO2 sequestration by mineral carbonation method.

Jan 1, 2011

By N. V. Mel'nikov

This paper discusses the reserves of oil, natural gas and coal in the USSR, with particular attention to the future role to be played by coal in supplying the energy fuel resources of the country.

Jan 1, 1972

By O. E. Humeniuk, A. I. A. Salama, M. W. Mikhail

"Performance testing of prepartion plants is referred to as plant audit. It evaluates plant performance under normal operating conditions and is aimed at improving yield through knowledge of actual process performance and interactions between different processes in a plant.This paper describes the program to evaluate the performance of several Canadian preparation plants. The performance test requires the planning of a sampling campaign that would include all circuits in the plant. Samples are analyzed to determine washing characteristics (screen and float-sink), ash and per cent solids of feed and products of separation units in the plant. Performance characteristics are established based on analysis and material balance. Specific recommendations can then be made to improve recovery, and identify and explain potential causes of apparent deficiencies.The objectives of the program are to reduce the cost of production by improving recovery of clean coal and, in tum, to reduce disposed tailings, establish baseline information on coal preparation plants performance in Canada, and define R&D work needed to optimize plant operation."

Jan 1, 1993

By C. L. Jiang

The role of iron ions (Fe2+ and Fe3+) in the flotation of both ore-and coal-pyrite with ethyl xanthate was comparatively investigated. The complete/partial depression of ore-and coal-pyrite in neutral to weakly alkaline solution is due to the formation of ferric dihydroxy ethyl xanthate between xanthate and the oxidation products of pyrite, ferric and ferrous ions. With xanthate as collector, coal-pyrite was found to be nonfloatable above pH6. In the presence of iron ions and between pH6-9.5, the flotation of ore-pyrite was significantly depressed. Ferrous ions have a stronger effect on pyrite flotation than ferric ions in neutral to weakly alkaline solutions.

Jan 1, 1996

By Wenying Liu, Marek Pawlik

Long-chain ionic surfactants, with fatty acids and amines as the most important representatives, are widely used as collectors in froth flotation. These surfactants, generally referred to as weak electrolyte collectors, frequently form solid insoluble precipitates within a certain pH range. However, the action and behavior of these colloidal precipitates in froth flotation systems are not well understood and has not been well decoupled from those of dissolved forms. The objective of this study was to understand and compare the role of colloidal precipitates with that of the dissolved forms at gas-liquid and gas-liquid-solid interfaces. Using primary amine as the model surfactant, experiments were carried out to measure: the maximum volume of bubbles generated in the presence of dissolved and precipitated forms of the surfactant; surface tension for both forms of the surfactant using the drop shape and maximum bubble pressure methods; and contact angle using the sessile drop method. The experimental results showed that: in the presence of the precipitate, bubble volume was smaller, which was correlated with the lower surface tension and higher contact angle measured; the surface tension of solutions containing surfactant precipitate was affected by the surface age of liquid droplets. This study enhances understanding of the interfacial behavior of long-chain ionic surfactants under different conditions, which would help improve the efficiency of reagent utilization in froth flotation.

Jan 1, 2014

By de Vaux. Deryck, Natalie J. Shackleton, Vratislav Malysiak Cyril T. O. Connor

"The major losses of PGM and base metals in the beneficiation of platinum group deposits occur during the separation of gangue from the value minerals by selective flotation. A number of studies have shown that this negative impact on flotation is due to surface passivation, caused by various ions that may originate from the external water supply or, as is likely in the majority of cases, from the oxidation of the mineral surfaces and the grinding media. This investigation aimed at reducing surface passivation of pentlandite and inadvertent activation of pyroxene, thereby improving ultimate valuable mineral recovery and selectivity. Both synthetic minerals and plant ores were studied in order to determine the effect surface passivation and inadvertent activation have on mineral surface alteration and floatability. Zeta potential determinations, microflotation, ToF-SIMS (Time of Flight Secondary Ion Mass Spectrometry) analyses, laboratory batch flotation tests and continuous flotation testwork were used as tools to study the surface alteration and/or floatability.Zeta potential determinations and ToF-SIMS analyses showed that copper adsorption is non-selective. Both pentlandite and pyroxene become copper (II)-activated in the presence of copper sulphate and subsequently, in the presence of xanthate, adsorption of the collector will occur onto copper activated mineral surfaces. Zeta potential determinations also showed an alteration of the surface charge in the presence of polyphosphate, thereby inhibiting surface passivation of sulphides by slime coatings due to surface repulsion.The addition of diethylenetriamine (DETA) reduces the copper concentration on both minerals, predominantly on the pyroxene surfaces and polyphosphate further enhances the selectivity at pH 6.The microflotation and batch flotation data obtained has shown a significant improvement in the ultimate flotation response of valuable mineral recovery and concentrate grade compared to the standard reagent regime, while the continuous flotation results significantly improved the selectivity, however, at a similar ultimate recovery."

Jan 1, 2003

By Natalie J. Shackleton, Deryck de Vaux, Cyril T. O’Connor, Vratislav Malysiak

"The major losses of PGM and base metals in the beneficiation of platinum group deposits occur during the separation of gangue from the value minerals by selective flotation. A number of studies have shown that this negative impact on flotation is due to surface passivation, caused by various ions that may originate from the external water supply or, as is likely in the majority of cases, from the oxidation of the mineral surfaces and the grinding media. The objective of the study was to investigate the effect surface passivation and inadvertent activation have on flotation and how this can be managed so as to increase the separation of pentlandite and pyroxene. The aim was to minimise the percentage pyroxene reporting to the concentrate and simultaneously maximise the pentlandite recovery. The testwork incorporates the addition of an activator (copper sulphate), a complexing agent, such as DETA (diethylenetriamine) and a dispersant (polyphosphate) at pH 6 and pH 9 in an attempt to alleviate the surface passivation of pentlandite and inadvertent activation of pyroxene. Both synthetic minerals and plant ores were studied in order to determine the effect surface passivation and inadvertent activation have on mineral surface alteration and floatability. Zeta potential determinations, microflotation, ToF-SIMS (Time of Flight Secondary Ion Mass Spectrometry) analyses, laboratory batch flotation tests and continuous flotation testwork were used as tools to study the surface alteration and/or floatability.Zeta potential determinations and ToF-SIMS analyses showed that copper adsorption is non-selective. Both pentlandite and pyroxene become copper (II)-activated in the presence of copper sulphate and subsequently, in the presence of xanthate, adsorption of the collector will occur onto copper activated mineral surfaces. Zeta potential determinations also showed an alteration of the surface charge in the presence of polyphosphate, thereby inhibiting surface passivation of sulphides by slime coatings due to surface repulsion."

Jan 1, 2003

By K. L. Riemer

The West Wits Line first began yielding gold in the mid-1930s and is among South Africa's leading gold-producing areas. Gold mining operations are carried out amidst the occurrence of seismic events which cause both damage to underground excavations and injury and loss of life to production personnel. The feasibility of establishing a system to minotor the seismicity on all the Gold Fields mines was investigated during the early 1980s. This led to the establishment of a centralized seismic network in 1981. The system was structured around three major objectives. It uses Perkin Elmer (now Concurrent Computer Corporation) 16 and 32 bit mini-computers. The hardware in use at both the central and remote sites is outlined, giving a good insight into the role of computers in the system. The system software reveals the fast flow of data through the network; it can be divided into three categories: (1) data logging and transmission - remote sites, (2) data capture and communications - central site, (3) applications and research - central site. Several examples are given which show how the system is measuring up to its objectives. These case studies also indicate how the computers are effective in representing the seismic data collected. It is concluded that the use of computers enables the pin-pointing of seismic events on the West Wits Line within about 3 -4 minutes of their occurrence. The choice of hardware is largely dependent on the objectives of system, and the Gold Fields Network has chosen mini-computers because of the speed of communication and the large amount of data and storage required for research applications.

Jan 1, 1987

The effect of conditioning energy input on the metallurgical results of an emulsion flotation process has beenattributed by previous authors to a detergency process.This paper shows that such a process does not explain the data and that an attrition mechanism is more appropriate.

Jan 1, 1970

By D. B. Dreisinger, V. van der Pas

Zinc sulphate electrolyte used for zinc electrowinning must be purified for cObalt ions. The cobalt is removed in a cementation stage by the addition of zinc dust. Copper arid antimony are frequently used additives which enhance the cementation of cobalt. This paper aims at a better understanding of how copper and antimony promote the removal of cobalt. Initial experiments were done in a batch cementation reactor. Copper and antimony precipitated in the early stages of cementation indicating that a preferential substrate was formed. The individual role of copper and antimony was further investigated in an electrochemical cell. On a microsca1e, the , growth process, morphology and the composition of the precipitates were examined with SEM and XRD. It was found that cobalt could not be deposited in its pure form but as a cobalt-zinc alloy with zinc as the prime constituent. Copper increases the cathodic surface area of zinc dust by precipitating as numerous dendrites. Antimony acts as a cathodic surface onto which a cobalt-zinc alloy with an increased cobalt content is deposited.

Jan 1, 1997

By T. K. Dichmann, J. A. Finch

"Microflotation, laboratory batch, and in-plant minicell continuous tests were conducted to determine if copper ions not only activate sphalerite but also depress pyrite when the minerals are together. Microflotation tests showed that pyrite recovery increased with addition of copper ions in the pH range of 5-10 when alone, but decreased when sphalerite was also present. Batch flotation tests (Red Dog ore) showed that upon addition of copper, pyrite recovery decreased significantly. The continuous tests (Louvicourt Mine) confirmed this and indicated that with excess copper pyrite recovery can increase. The results suggest there is competition for copper and xanthate in favour of sphalerite. To take advantage of this competition it may be necessary to control the sequence and rate of copper, collector, and lime addition. INTRODUCTIONFlotation, in common with all physical separations, is an imperfect process that results in misplacement of minerals. One source of this imperfection is accidental activation by contaminating metal ions. An important practical example is the misplacement of pyrite to zinc concentrates. Flotation of sphalerite generally requires activation by copper ions, added as copper sulphate. Copper ions are also used to activate pyrite [l] hence there is the suspicion that accidental activation contributes to the recovery of pyrite (Py) with the sphalerite (Sp). However, recent literature has shown that copper ions may make Py less floatable if Sp is also present. Xu et al. [2] conducted continuous minicell tests in-plant at Kidd Creek Operations (division of Falconbridge Ltd.) and showed that while the addition of copper sulphate improved zinc/iron selectivity, it did so as much by reducing the recovery of pyrite as increasing zinc recovery (Figure 1)."

Jan 1, 2000

By Jean-Paul Simoes

The development of the blast furnace over the last years lead to a substantial increase in production capacity and productivity. This development triggered an evolution of the cooling systems in order to cope with the raising heat loads. The excellent protection of the shell by copper staves allowed blast furnace operators to achieve campaign lifetimes of more than 20 years. However in recent years some blast furnaces have experienced severe wear of the copper staves due to abrasion. The influences of the blast furnace design as well as of the operation conditions on this premature wear have been analysed and the mechanisms leading to the wear will be explained. New developments in the copper stave technology are part of the solution for avoiding premature wear during periods with less favourable conditions. The protection mechanisms made available by the new design extend the inherent protection mechanisms of copper staves to these periods. BFXpert® system is the ideal tool for the monitoring of the process data, the process models and the recommendations given by Sachem® support the operator in choosing efficient operation points. The charging with a Bell Less Top® (BLT) allows an accurate controlling of the blast furnace with regard to the optimization of the gas distribution. High performance operation together with long campaign lifetimes are thus made possible.

Aug 1, 2018