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By B D. Sowerby, N G. Cutmore

Improved process control can be achieved through the accurate and reliable on-line measurement of critical process parameters in real time. Over the past few decades on-line analysis techniques have been developed and applied in the mineral and energy industries for the measurement of process stream composition, mineralogy, particle size and flow rates. This has led to increased throughput and product quality while reducing processing costs and minimising emissions. The support of a sustainable mineral processing industry will require the further development of on-line analysis and control technologies. The application of developments in instrumentation combined with improved control strategies will lead to improvements in process efficiency resulting in large economic benefits to the industry, reduced energy usage and lower process emissions. There is a clear convergence of interests in being able to better measure and control minerals processing in terms of the triple bottom line of economic, social and environmental impacts. Technology is increasingly becoming available enabling measurement across the entire spectrum of minerals processing from mining to hydrometallurgy and pyrometallurgy. CSIRO is developing a range of these new technologies. A number of these developments are discussed in the present paper, namely: on-line particle size analysis and acoustic emission methods to enhance the control and optimisation of grinding circuits; on-line mineralogy of dry powders and slurries; on-line bulk elemental analysers for application on conveyor belts and in smelters; and the development of new sensing technologies for sorting base metal ores.

Jan 1, 2002

By S. Ndlovu

To investigate the influence of orientation of crystal lattice on the bacterial leaching of pyrite crystals, single crystals of 100, 111 and110 plane orientations were used for the study. Experiments were carried out in the presence of a Thiobacillus ferrooxidans culture. The different corrosion patterns observed on the surfaces of the bioleached samples suggests a variation in cell-surface interaction from one crystal plane to the other. The surface corrosion patterns generally reflected the influence of the symmetrical arrangement of the atomic planes in the lattice on which they formed. The results indicate that the surface properties of mineral sulphides may control the evolution of corrosion patterns and consequently the initial oxidation process in acid bacterial leaching.

Jan 1, 2004

By Roderick 1. L. Guthrie, Mei Li

"A mathematical model was developed to study the role of orifice shape in the detection of inclusions in LiMCA (Liquid Metal .cleanliness Analyzer) system. The fluid flow field within the ESZ was obtained by solving the Navier-Stokes equations. The trajectories of entrained particles were calculated using the equations for motion of particles. A numerical study of the effect of orifice shape on signal shape generated by inclusions passing through orifice showed that the signals in a parabolic orifice are gaussian in shape, while those in a cylindrical orifice are trapezoidal in shape. This signal shape difference needs to be taken into account when performing particle discrimination. Orifice shape influences also pass-through fraction of inclusions. Finally, a study of the orifice shape on critical conditioning currents suggested that as the polynominal coefficient of the parabolic orifice increases, the critical conditioning current, which is also the maximum operating current, decreases dramatically. These critical conditioning currents also increase as the fluid flow velocity within the ESZ increases. IntroductionThe presence of non-metallic inclusions in metals often leads to impaired mechanical properties such as a reduction in fatigue strength, and to processing problems such as tear-offs in deep drawing and increased breakage rates in wire drawing operations. Similarly, inclusions cause a variety of surface defects in rolled or extruded products.Prior to the development of the LiMCA system (1) at McGill University in the early 1980's, it was not possible to measure inclusions, in situ, in liquid metals. Compared with other techniques, such as sedimentation, filtration and metallography, which require considerable amounts of labor and time, the LiMCA method has the advantage of providing not only information on the volume concentration of inclusions, but also on the size distribution of inclusions immediately and quantitatively."

Jan 1, 2001

By L. Alagha, L. Sanchez-Calderon, M. Silwamba, W. Kirk

Selenium-rich metallurgical waste, also known commercially as “crude selenium,” is a byproduct of the copper (Cu) refining process. This by-product, contains ~ 90% selenium (Se), precious metals, platinum group metals (PGMs), and other critical elements. This study investigated the leaching efficiency of Se from the sludge under alkaline conditions using different oxidizing agents to enrich PGMs and precious metals in the leach solid residue. The effectiveness of each oxidizing agent during leaching was assessed and compared. Additionally, Eh-pH diagram for Se was established under specific experimental conditions and utilized to inform process optimization. Key variables, including leaching time, temperature, and oxidant concentration, were evaluated for their impact on the efficiency and the selectivity of the oxidative alkaline leaching process.

Feb 1, 2025

By C. Carlson, W. Muir

"The oxygen demand of the complex lead-zinc-iron feed at the Cyuro Anvil concentrator was determined denendent on the cyanide ion con-contration of the pulp. By redistribution of the cyanide [ ] the grinding circuit in direct proportion to the amount of surface area created, a more activated flotation feed in obtained.Monitoring the oxygen demand of the flotation feed and grinding mill discharge has proved useful in diagnosing metallurgical problems day to day operation."

Jan 1, 1976

By K. E. Haque

"This paper is a brief overview of the role of oxygen in cyanide leaching of gold feeds (e.g. ore, concentrate). As the majority of gold occurs in the elemental state (Au °), its oxidation is of vital importance for dissolution in the cyanide lixiviant. The cyanidetion at high pH is favourable for the oxidation of Au° with a mild oxidant such as air or oxygen. Beside oxidation of gold, deleterious effects of soluble sulphides, arsenates, antimonates on cyanidation of gold can be alleviated by preaerating the leach slurry with air or oxygen (i.e. preaeration process).If gold is refractory due to its occlusion in sulphides, silicates, tellurides, etc. then gold liberation is possible by roasting in the presence of oxygen or by leaching under oxygen pressure. The data in the recent literature indicate that reactive oxygen supplied by H202, Na202, Ca02 or 03 during cyanidation can accelerate considerably gold oxidation-cyanidation and yield high gold recovery in much shorter leach time. The information compiled in this review leads to the conclusion that oxygen plays a vital role in the dissolution of gold in cyanide lixiviant."

Jan 1, 1992

A study was made to determine the effect of increasing concentrations of dissolved oxygen on the floatability of galena pyrite and chalcopyrite. Adsorption, flotation and contact-angle tests were done in deoxygenated, in air-saturated and in oxygen-saturated solutions. The results showed that the adsorption of collector increased as the concentration of oxygen increased. Adsorption followed the exponential law r = kC'/"• Discontinuities in the curves were observed after the adsorption of several monolayers of collector. Although adsorption increased with increasing oxygen concentration, the floatability of the pyrite minerals did not increase, because oxidation had adverse effects on the floatability of these minerals. The floatability of galena was maximum in oxygen-saturated solutions, pyrite was depressed and chalcopyrite was also slightly depressed. Contact-angle tests proved that a bubble could not be attached to large flat surfaces in deoxygenated solutions, because sufficient surface free energy was not available for adhesion after the deformation of the bubble. In the presene of air, all the minerals yielded the same maximum angle of 72 degrees, characteristic of isopropyl xanthate.

Jan 1, 1970

By J. G. Eacott

This paper reviews the role of oxygen potential and the advances that have been made in the application of tonnage oxygen in copper smelting. Brief reference is made to reaction kinetics before attention is turned to the thermodynamic considerations in copper melting to illustrate the importance of oxygen and. oxygen potential in the component parts of the overall smelting process. The chemical potential diagram for the Cu-Fe-S-O-Si02 system is used to elucidate the difference b etween the conventional matte smelting process and the modern continuous processes. A progressive oxidation scale' is constructed to show the common elements which exist, and the matte grades produced, during the smelting of concentrates to blister copper in commercially available copper smelting processes and those under development. The common route in producing blister copper from molten mattes, regardless of process, is illustrated on the Cu-Fe-S equilibrium phase diagram. The essential features of oxygen enrichment, in terms of its effect on combustion conditions (i.e. oxidation of fuel and sulphide minerals) and the heat balance are outlined. The benefits of oxygen enrichment are listed. The influence of tonnage oxygen and its effect on productivity, fuel savings, gas volume and strength in various copper melting processes are examined as a state-of-the-art review. Reference is made to the economics of tonnage oxygen utilization.

Jan 1, 1983

With some notable exceptions, marine placers located just below, or just above, present sea level, are responsible for much of today's production of detrital ilmenite, rutile, zircon, and other minerals of value. The purpose of this paper is to discuss the paleogeographic and paleo-oceanographic factors which may have determined the location of presently submerged marine placers. These factors include changes in sea level, burial by recent marine sediments, stream capture and other changes in drainage patterns, and recent changes in climate. Selected geologic situations in the Yellow Sea off the coast of Korea, in the Atlantic Ocean off the coast of Portugal, in the Bering Sea off the coast of Alaska, and in the Arabian Sea off the coast of India, will be used to illustrate the author's point of view.

Jan 1, 1971

With some notable exceptions, marine placers located just below, or just above, present sea level, are responsible for much of today's production of detrital ilmenite, rutile, zircon, and other minerals of value. The purpose of this paper is to discuss the paleogeographic and paleo-oceanographic factors which may have determined the location of presently submerged marine placers. These factors-include changes in sea level, burial by recent marine sediments, stream capture and other i changes in drainage patterns, and recent changes in climate. Selected geologic situations in the Yellow Sea off the coast of Korea, in the Atlantic Ocean off the coast of Portugal, in the Bering Sea off the coast of Alaska, and in the Arabian Sea off the coast of India, will be used to illustrate the author's point of view.

Jan 1, 1980

By A. Metzer

When paraffinic gases (ethane, propane, butane) are used as the gas phase in flotation systems, the initial rate of flotation and recovery are generally increased as compared with air. The mechanism of the effect of paraffinic gases in flotation was studied and it was shown that they co-adsorb with the collector ions on the mineral-aqueous solution interface. The effect of this co-adsorption was interpreted in terms of apparent increase of the effective chain length of the collector by the co-adsorbed gas. Adsorption densities, contact angles and flotation behaviour were studied on the following systems: a) Quartz - dodecyl ammonium chloride - ethane and propane b) Calcite - sodium oleate - propane and butane. The positive effect of the co-adsorbed gases is a maximum at low collector concentrations or where critical conditions for flotation with air prevail.

Jan 1, 1974

By James L. Austing, Allen J. Tulis, Ronald Pape, Ronald G. Draftz

In a certain sense, the explosives industry began in the 13th century with the invention of black powder, which is an intimate mixture of sulfur, carbon black or charcoal, and potassium or sodium nitrate. For several centuries thereafter, black powder was the sole general purpose energetic material, serving as an igniter, propelling charge, bursting charge, and blasting agent. By today’s standards, black powder is totally inadequate for the latter three functions, but its use continues as an igniter for propellant charges because of its unique ability to ignite and burn under ambient conditions. The history of the development of black powder was reviewed by Rose (1980).

Jan 1, 1995

By Chamila Jinendra Nanayakkara, Nimila Dushyantha, Amila Sandaruwan Ratnayake, Gayithri Niluka Kuruppu

Rare earth elements (REEs) are key ingredients in many advanced materials used in energy, military, transportation, and communication applications. However, the prevailing geopolitical dynamics and the rising demand for REEs have rendered the reliance on primary REE resources susceptible to future supply disruptions, posing a substantial risk to the availability of these elements for numerous applications. Therefore, it is imperative to undertake substantial initiatives in the extraction of REEs from secondary sources on a large scale to ensure the resilience of the supply chain. Permanent magnets, lighting phosphors, and nickel-metal hydride (NiMH) batteries are among the secondary sources with high potential for sustainable REE extraction. This review assesses the extraction potential of REEs from the aforementioned three secondary sources and their leaching kinetics and thermodynamics aspects. More importantly, state-of-the-art different existing kinetic models employed in rare earth (RE) leaching were well discussed for a better understanding of the REE leaching reactions. Furthermore, the optimized leaching parameters related to this kinetics were described, and various RE recovery methods were comprehensively summarized. These processes facilitate to managing one of the fastest-growing solid waste streams by minimizing environmental impacts and producing critical metals, including REEs via circular economy approaches. The recovery of REEs from secondary sources aligns with numerous United Nations Sustainable Development Goals (SDGs), particularly in the renewable energy sector for climate change mitigation. Consequently, this trash-to-treasure urban mining concept to transforming e-waste into a valuable resource for REE recovery emerges as a pivotal element within the REE industry.

Dec 28, 2023

By Michael A. Krstich

A soil washing pilot plant to treat soils at the U.S. Department of Energy (DOE) owned Fernald Environmental Management Project (FEMP), was designed based on extensive bench-scale testing. The system's design incorporated a combination of physical separation and' chemical extraction processes and was tested on two soils. The textural composition of the two soils was approximately 20 percent sand, 60 percent silt, and 20 percent clay. Since this grain size distribution was not considered optimum for physical separation techniques, thesoil washing pilot plant had to be designed with selected equipment to provide specific soil size fractions during processing operations. A trommel, vibrating screen deck, centrifuge, and attrition scrubber were used in the system to selectively separate specific soil size fractions at 4.75, 2, 0.3, and 0.02 millimeters (mm). The trammel used high pressure water [1000 pounds per square inch (psi)] during the initial step of the process to reduce soil aggregates to single grain composition, separate out greater than 4.75 mm gravel, and dislodge chemical contaminants from the individual soil particles. The vibrating double-screen deck provided 2 - 4.75 and 0.3 - 2 mm soil fractions that, when combined, averaged greater than 75 percent solids for both soils. The centrifuge was designed to take the less than 0.3 mm soil slurry from the screen deck and produce a particle size of 0.02 mm. The centrifuge produced a high solids stream that averaged greater than 70 percent solids for both soils. These 0.02 to 0.3 mm soil solids from the centrifuge were combined with the 0.3 to 4.75 mm soil solids from the screen deck and processed through the attrition scrubber. The data collected from the pilot-plant operation was used to aid in the design of a full-scale system and was instrumental in formulating full-scale process operations and the selection of equipment.

Jan 1, 1995

Several inorganic reagents and organic polymers were tested as depressants in the single mineral flotation of ultrafine iron oxide and hydroxylapatite with Dowfroth 250 as a frother. It was observed that the inorganic reagents and the low molecular weight polymers generally caused dispersion of the ultrafine particles, and consequently their recovery into froth products more or less equaled the recovery of water. On the other hand, the high molecular weight polymers caused different degrees of flocculation of the ultrafine particles, and their recoveries were much lower than the recovery of water. These observations pointed to a need to re-define flotation depressants in fine particle flotation. The traditional definition of a flotation depressant, i.e., to make particle surfaces hydrophilic by forming a hydrophilic film and/or by removing collector and activator coatings, is sufficient for relatively coarse particles. However, to prevent fine and ultrafine particles from floating, a successful depressant should not only make the particles hydrophilic, but also enlarge the particle sizes so that they do not enter the froth product by mechanical entrainment. Polymeric depressants are ideal for these purposes. The different schemes to use polymeric depressants in the selective flotation of fine and ultrafine particles were discussed These schemes involve the integration of the polymeric depressants into other size enlargement processes such as shear flocculation, oil agglomeration, etc., for hydrophobic particles.

Jan 1, 2004

By Zvonimir Ester

The course of motorway tunnel under construction was set only 2 m away from the main motorway. The thickness of the tunnel overburden rock was 9 m. During the tunnel construction the traffic on the motorway was not supposed to be interrupted. The tunneling was carried out by NATM with classical drilling of blastholes and by blasting.

Jan 1, 1998

By James Lett

The role of pre-conditioning in a caving operation has multiple benefits, ranging from assisting with improved caveability, normalising fragmentation and improving draw point hang-up frequency. At Newcrest Mining’s Cadia Operations, both the Ridgeway Deeps block cave the Cadia East Panel Cave have utilised pre-conditioning using hydraulic fracturing. Seismic response data inside and outside the pre-conditioned volume show the benefit of treating the full caving block. Cadia East has further developed pre-conditioning to mitigate developing seismic hazards associated with major structures (fault-slip events) and managing mine-wide seismic hazards in new caving operations where the potential for large damaging seismic events exists due to high stresses and hard competent rockmasses. A case study reviewing the impact of pre-conditioning to mitigate seismic hazard associated with fault slip is presented. Cadia East operation undertook a targeted hydraulic fracturing program and reduced the overall number of large events as an example of the benefits of pre-conditioning. This paper will review the application of Hydraulic Fracturing at Cadia and discuss the geotechnical and seismological parameters of seismic events that occur within and outside of pre-conditioned rockmass volumes to demonstrate the benefits that Hydraulic Fracturing bring to future caving operations.

Apr 26, 2022

By J E. Everett, K Jupp, T J. Howard

Precrusher stockpiles are designed principally as buffers to decouple the mining and processing operations. They are usually paddock dumped or dumped over a face to form fingers by dumping haul truckloads and reclaimed by front-end loader in an ad hoc manner. In addition, they are often not built and reclaimed to completion but continually added to and extracted from. While this design suits the mining process and is operationally simple, there can be little confidence in the grade of the ore that is fed to the crusher. This makes short-term grade control difficult and reconciliation back to the mine face imprecise. Well-designed and operated precrusher stockpiles can overcome these deficiencies.The different types of grade variability in mining are reviewed in this paper. The role of precrusher stockpiles in reducing short-term variability is discussed and their ineffectiveness in addressing long-term variability is highlighted. Their role in removing the serial correlation of the extracted ore is explained.Precrusher stockpiles carry out the four, at times competing, objectives of storing, buffering, blending and grade separation. Their actual design and operation result from a compromise between these four competing roles. These roles are explained in detail along with the advantages and disadvantages of the different types of precrusher stockpiles. The recommended blended-in blended-out stockpile (BIBO) design is discussed in detail. Matched pairs of BIBO stockpiles of limited tonnage built and reclaimed to completion retain the best knowledge of grade and facilitate the reconciliation process.Simulation studies have been carried out on BIBO stockpiles to understand the blending opportunities of the different options for building and reclaiming, and to identify the methods that achieve maximum blending. It was found that laying down rows in one direction and reclaiming across these rows gives the best blending. Matching the width of the reclaim face with the daily crushing requirements is also important. The length of the rows, and building in either one or two layers has little effect on the extent of blending.Appropriate design can provide a reasonable compromise between the four objectives.CITATION:Jupp, K, Howard, T J and Everett, J E, 2013. The role of precrusher stockpiling for grade control in mining, in Proceedings Iron Ore 2013 , pp 203-214 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By Pinakin C. Chaubal

Today?s steel industry is in a vibrant and resurgent mode. This transformation has been in the making for some time now. Over the last few decades, the industry was steadily transforming itself into becoming a high tech industry. New technology was adopted, efficiencies were enhanced, lean manufacturing concepts were brought in and a strong customer focus was developed. Today?s mills employ sophisticated instrumentation, computerized monitoring, on-line smart systems etc. driving processes that are producing at rates of many tons/minute. All this is not possible without judiciously using the latest available technologies in various fields and developing a more sophisticated work force. Prof. Sohn has been a pioneer in driving the concept of process engineering in process metallurgy. In this paper the focus is on some aspects of process engineering ? primarily process modeling - as applied to iron and steelmaking processes. Examples are shown to demonstrate how problems have been addressed. Some thoughts on future directions are presented.

Jan 1, 2006

By Pinakin C. Chaubal

Today?s steel industry is in a vibrant and resurgent mode. This transformation has been in the making for some time now. Over the last few decades, the industry was steadily transforming itself into becoming a high tech industry. New technology was adopted, efficiencies were enhanced, lean manufacturing concepts were brought in and a strong customer focus was developed. Today?s mills employ sophisticated instrumentation, computerized monitoring, on-line smart systems etc. driving processes that are producing at rates of many tons/minute. All this is not possible without judiciously using the latest available technologies in various fields and developing a more sophisticated work force. Prof. Sohn has been a pioneer in driving the concept of process engineering in process metallurgy. In this paper the focus is on some aspects of process engineering ? primarily process modeling - as applied to iron and steelmaking processes. Examples are shown to demonstrate how problems have been addressed. Some thoughts on future directions are presented.

Jan 1, 2006