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By C. Brown, N. Rayyan, T. H. Dubaniewicz

Lithium-Ion batteries (LIBs) have the potential to go into thermal runaway which introduces a new ignition source in hazardous environments such as gassy underground mines that may contain methane in the surrounding air. Researchers from the National Institute for Occupational Safety and Health (NIOSH) used an accelerating rate calorimeter (ARC) to induce thermal runaway in individual lithium-titanium-oxide (LTO) and lithium-nickel-cobalt-aluminum-oxide (NCA) LIB cells within a sealed enclosure with either no methane, a lean, a stoichiometric, or a rich methane-air mixture in the surrounding canister to determine if these LIB types would ignite the methane, causing an additive effect on overpressures. Canister pressures and maximum temperatures reached by the cells, surrounding air, and exhausted gases were measured in this study and remained consistent with varying methane concentrations.

Feb 1, 2023

By Richard A. Thomas, Connor B. Brown, Thomas H. Dubaniewicz, Teresa Barone

Electric vehicles powered by lithium-ion (Li-ion) batteries are being developed by mining vehicle manufacturers as a replacement for diesel-powered vehicles. Explosion-proof (XP) enclosures are frequently employed to enclose electrical ignition sources in gaseous underground mines to prevent the spread of an internal methane-air explosion to a nearby explosive atmosphere. Due to thermal runaway (TR), Li-ion batteries have the potential to cause pressurized explosions in an enclosed structure. Past research has shown the potential for well-confined Li-ion cell TR to drive pressures beyond the conventional pressure specification for XP enclosures. Researchers at the National Institute for Occupational Safety and Health (NIOSH) used an Accelerating Rate Calorimeter (ARC) to induce thermal runaway of Lithium Titanate or Lithium Titanium Oxide (LTO) type 18650 cells enclosed within containers with various volumes and found an inverse power relationship between the TR pressure and available free space. The results were similar in magnitude to that of lithium iron phosphate (LFP) cells, which were used in prior testing. Temperatures, gas amounts, and TR pressure-rise rates were also recorded. The data indicate that with enough free space, the pressures can be lowered below the conventional pressure specification for XP enclosures.

Feb 1, 2024

By Liming Yuan, Isaac Zlochower, RICHARD THOMAS, Thomas H. Dubaniewicz, Teresa Barone

Mining vehicle manufacturers are developing lithium-ion (Li-ion) battery electric vehicles as an alternative to diesel-powered vehicles. In gassy underground mines, explosion-proof (XP) enclosures are commonly used to enclose electrical ignition sources to prevent propagation of an internal methane (CH4) air explosion to a surrounding explosive atmosphere. Li-ion batteries can create pressurized explosions within sealed enclosures due to thermal runaway (TR). Researchers at the National Institute for Occupational Safety and Health (NIOSH) measured TR pressures of lithiumiron phosphate (LFP) cells as a function of free space within sealed enclosures and observed an inverse power relationship. A well-confined cell produced 294 bar (4260 psia) of pressure during a TR, far exceeding minimum pressure containment specifications for conventional XP enclosures. Results indicate that adding enough free space surrounding LFP cells can reduce TR pressures to levels below that expected for CH4-air ignitions. Measured TR temperatures were below the minimum autoignition temperature of CH4-air.

Nov 6, 2020

By Patrik Yrjas, Daniel Lindberg, Emil Vainio

Recovery of trace elements from different industrial waste streams is important in realizing the goals of the circular economy. Ash streams from waste combustion can contain high levels of both toxic and valuable trace elements. These elements can be separated during the combustion process based on volatilization and condensation, as well as being separated in post-combustion processes, through thermal or leaching treatment. In this study, an overview is given of the thermal methods for recovery of valuable elements from ash fractions derived from waste incineration. In addition, a case study is presented of the behaviour of ash-forming elements in combustion of MSW and demolition wood, with special focus on the elements Co, Cu, and Sb. In conclusion, it is shown that thermodynamic modeling of high temperature processes can be a useful tool to predict ash behavior both during combustion and in the post combustion treatment of the ash.

Mar 1, 2018

By H. B. Jensen

STUDY of the thermal-solution process was begun by treating crushed oil shale in a small autoclave at temperatures of 700° to 950° F. The effect of temperature, reaction time, type of solvent, and richness of shale upon the amount of organic matter that was removed from the oil shale was thus determined. Following this orientation work a semicontinuous, bench-scale apparatus was built so that heated solvent could be pumped through a bed of shale under elevated pressure, thus removing the converted organic matter from the spent shale. After some operating experience had been gained, a continuous unit was constructed. This permitted treating a slurry of shale oil and pulverized oil shale at about 300 p. s. i. and temperatures of 750° to 850° F. for various retention times. Considerable cracking and polymerization of the shale oil were found to take place during the process. In an attempt to prevent this, a study was made of extraction of the shale in batch-type autoclaves under high partial pressures of hydrogen at total gas pressures of as much as 4,300 p. s. i. at 850° F. The thermal-solution process was found to convert over 90 percent of the organic matter in oil shale to oil and gas. The highest yields of gas and oil obtained without hydrogen pressure were equivalent to 119 weight-percent of those obtained from the same shale by Fischer assay. With a high partial pressure of hydrogen, yields equivalent to 126 weight-percent of Fischer assay were obtained. However, the oil produced by thermal solution has a higher boiling range than that obtained by other retorting methods, particularly so if the thermal-solution process is used without a high partial pressure of hydrogen. Nondistillable oil (all benzene-soluble material that would not distill under 2 mm. Hg absolute pressure without cracking) equivalent to over 100 percent of the organic matter in the shale was obtained without hydrogen pressure in the system. When the process was carried out under hydrogen pressure, the yield of nondistillable oil amounted to 60 to 70 weight-percent of the organic matter. Part of this heavy material is formed partly by polymerization and condensation of the shale-oil solvent used. These reactions, as well as cracking of the solvent to form gas and a carbonaceous deposit on the shale, are unfavorable features of the process.

Jan 1, 1953

By R. Edward Williams

The Spa1lation Process Because of the low thermal conductivity of many hard rocks, rapid heating of these rocks produces a thin surface layer in which the temperatures attain high values. Thermal expansion of this surface layer is constrained by the reminder of the still cool rock, and when stresses within the surface rock become high enough, the surface rock breaks away from the cooler rock behind it and flies or falls off as a thin flake called a spall. Then the next, newly exposed surface is heated, and the process continues. This process is the basis of spallation drilling. The hot gases from a jet burner provide the heat for spallation to occur, and their high velocity provides a scouring action that transfers heat to the rock and removes the spalls as rapidly as they form. Spallation is a process which works in very hard rock. It is dependent upon the thermal expansion coefficient and the thermal diffusivity of the rock but is also affected by any discontinuities in the rock. To date the efforts which have been made to evaluate the various rock according to their spallability has been minimal. As the success of this process is dependent upon the characteristics of rock it is expected that the study of rock mechanics will prove to be of greater value to this program than to the other mechanism for drilling and excavating rock. Commercial Uses of SPALLATION In the 19408s, the Linde Air Products Division of Union Carbide (UC 1 began developing spallation for use in mining taconite ore, which is presently the chief source of iron in the United States. In this work UC developed a jet-piercing tool that burned fuel oil with oxygen to produce spallation and contained mechanical cutters to remove rock that was not amenable to spallation. The UC jet-piercing machines have since produced about 40 million feet of shallow blast holes used for emplacing explosives in the taconite mines. During this work it was found that hole diameters could be increased by merely reducing the advance rate of the burners and that existing holes could be enlarged by making another pass through the hole with the same burner. The Browning Engineering Go. of Hanover, N.H., has developed a hand-held spallation burner to cut slots in granite. It has been used for a quarter of a century and is now standard equipment for quarrying granite throughout the world. This burner, which resembles a small jet engine oriented with its exhaust pointed downward, is the forerunner of a flame jet burner used to spall experimental holes in granite at maximum rates in excess of 100 ft/hr when operating in hard, competent granite. It uses No. 2 fuel oil, which is burned with compressed air. The system uses water to cool the burner and the exhaust gases. These gases, along with the steam produced from the cooling water, blow the spalls from the hole. Experimental Work Theoretical and experimental work has been accomplished by the Massachusetts Institute of Technology and the Los Alamos National Laboratory. This work is reported in Refs. (3) and (4). To verify the experimental results of this work laboratory scaled down field tests were conducted using two we1 1 characterized granites from quarries in Barre, VT and Westerby, RI, under defined heating conditions. In the laboratory tests a propane - oxygen heating torch was used to direct a flame at the granite surface and the spal 1 ing process was examined at various heating rates with a high-speed video taping system operated at 200 frame per second. This produced a time-lapse sequence where the onset of the spallation process was easily distinguished. Also the heat flux from the torch to a flat surface at various stand off distances and flows was measured. A similar set of tests was conducted using the more easily quantified and uniform heat source of a 1.5 kw GO2 laser. This allowed accurate

Jan 1, 1986

By Thomas C. Ruhe

The Pittsburgh Research Laboratory of NIOSH conducted research to determine the safe operating conditions for using recycled (used) lubricating oil from mining equipment as a partial replacement for diesel fuel to make ANFO-type blasting agents. The use of recycled oil (RO) conserves energy, reduces oil imports, and reduces mining costs. Since RO has a variable composition, there was concern that the additives/impurities it contains may cause ANFO made with RO to be unstable (as compared to regular ANFO) at high summer ambient storage temperatures. Reactivity of RO with zinc was also a concern. Thermal stability tests were conducted to help quantify and resolve these issues. ANFO mixtures (0.66 lb/300 g) were put into sample containers made of steel, stainless steel, and galvanized (zinc coated) steel pipe fittings, which were heated in isothermal ovens. The experimental parameters were temperature settings of 140° F (60° C) and 176° F (80° C), four sample container (pipe fitting) metal combinations, and nominal heating periods of one and three days. The ANFO samples contained 6% each of the following twelve different oils/oil mixtures: No. 1 was diesel fuel, Nos. 2 thru 6 were five candidate oils (2 thru 5 were used oils and 6 was a new synthetic oil), No. 7 was 5% diesel fuel + 1 % graphite, and Nos. 8 thru 12 were 3% diesel fuel + 3% each of the five candidate oils. All samples showed no reactivity when heated at 140° F (60°C). All samples (except No. 7) reacted at 176° F (80° C) in a steel pipe with galvanized caps as follows: No. I reacted most, Nos. 8-12 reacted moderately, and Nos. 2-6 reacted least. All ANFO samples were tested and found not to be cap sensitive.

By Zhijing Zhang

Long-term thermal stability of ionic liquids is essential for reliable performance of ionic liquids in any engineering applications. TGA studies were carried out on a series of ionic liquids with different cations and anions such as 1-butyl-3-methylimidazolium chloride ([C4mim]Cl), 1-hexyl-3-methylimidazolium chloride ([C6mim]Cl), 1-hexyl-3¬methylimidazolium tetrafluoborate ([C6mim]BF4), 1-hexyl-3-methylimidazolium hexafluorophosphate ([C6mim]PF6), 1-octyl-3-methylimidazolium hexafluorophosphate ([Csmim]PF6), and 1-butyl-3-methylimidazolium bis(trifluromethanesulflonyl)imide ([C4mim][Tf2N]). The short-term thermal stability of ionic liquids was evaluated by measuring the onset temperature of decomposition of ionic liquids, and the long-term thermal stability of ionic liquids was also evaluated by weight loss of ionic liquids over a long period of time at various temperatures. The experimental results showed that the long-term thermal stability of ionic liquids decreased with increasing temperature and was significantly lower than the onset temperature of decomposition of ionic liquids.

Jan 1, 2002

By T. Wang

A new generated NaNO3 ? NaNO2 ? KNO3 ternary thermal energy storage system which has low melting point as 124°C and high specific heat capacity was studied for the short and long?term thermal stability by using the Thermogravimetric Analyzer (TGA). Based on the actual working condition of molten salt in solar two, the simulated cyclic thermal stability measurement was also conducted. The ternary system demonstrates excellent short ? term thermal stability and thermal reliability after cyclic heating and cooling processes. However, in the long ? term as well as the simulated cyclic stability measurement, large amount of weight loss was observed. Moreover, the stepwise long ? term isothermal study reveals that below 440°C the weight change is minimal and this temperature is viewed as the upper limit temperature of thermal stability for this ternary system. To determine the lost phases at high temperature above the upper thermal stability limit, techniques such as XRD and SEM are used to compare the condition of the salt mixture before and after the long ? term thermal stability study. On the basis of the comparison, it can be concluded that the major weight loss was due to the decomposition of sodium nitrite.

Jan 1, 2012

By Alicia Esther Ares

This study was conducted to investigate the directional solidification of Zn-20%A1 and Zn20% A1-1O%Si-3o/oCu alloys under different conditions of heat transfer at the metal/mould interface. The type of structure obtained in both cases was analyzed and related to the solidification thermal parameters such as cooling rate, growth rate, thermal gradient and recalescence which were determined from the temperature versus time curves. These parameters were correlated with the structure-like length of columnar grains and size of equiaxed grains. The metallographic analyses were done performing quantitative metallography and composition analysis of the different alloying elements along the cast samples by SEM (Scanning Electron Microscopy) and EDXA (Energy Dispersive X-Ray Analysis). Correlations between properties, structures and thermal parameters were found.

Jan 1, 2008

By S. K. Samal, B. Mishra, M. K. Mohanty, S. C. Mishra

Steelmaking industries consume the majority of chromium and manganese ferroalloys to impart several properties in steel and also for other purposes. The quality of ore governs the process kinetics as well as the process economy of the ferroalloy industry. The present study demonstrates the thermal transformation behavior of chromite and manganese ores with varying compositions. Simultaneous thermal analysis (DTA/TG) is employed for such ore samples where the transformation of mineral phases is correlated with the thermogram characteristics and quantified. Phase, microstructure, and compositional analysis results of individual ores corroborated with thermal analysis are in good agreement. Chromite samples are ferruginous with goethite and gibbsite contents, whereas manganese ores vary in composition and also exhibit multiple and/or overlapping transformations.

Jan 21, 2021

By SUMANT KUMAR SAMAL, BHAGIRATHA MISHRA, MANOJA KUMAR MOHANTY, SUBASH CHANDRA MISHRA

Steelmaking consumes the majority of chromium and manganese ferroalloys for purposes such as to impart various properties to steel. The quality of ore governs the process kinetics as well as the process economy of the ferroalloy industry. The present study demonstrates the thermal transformation behavior of chromite and manganese ores with varying compositions. Simultaneous thermal analysis (differential thermal analysis/thermogravimetry, DTA/TG) was conducted on these ore samples, where the transformation of mineral phases was correlated with the thermogram characteristics and quantified. Phase, microstructure and compositional analysis results of individual ores corroborated with thermal analysis are in good agreement. Chromite samples are ferruginous with goethite and gibbsite contents, whereas manganese ores vary in composition and also exhibit multiple and/or overlapping transformations.

By E. Nurminen

Thermal transport properties of copper flash smelting flue dust have been investigated. Such values of the dust are needed to correctly model the process and to optimize its heat recovery performance. Dust accretions on heat recovery boiler walls may have a significant influence on the boilers heat transfer efficiency. Measurements of the thermal transport properties have been made for industrial flue dust and for pure sulphate components. The measurements have been conducted at temperatures up to 400 °C and the effect of porosity on these properties has also been investigated. The results indicate that the flue dust and the sulphate components are effective thermal insulators and the dust build-up on the boiler walls is likely to greatly decrease the heat transfer efficiency of the boiler.

Jan 1, 2007

By S M. J Koleini, F Hedjazi

The purpose of this research was to study the calcination of lead-zinc flotation tailings from the Angouran lead and zinc flotation plant in Iran as a pre-concentration step prior to hydrometallurgical processing of the oxidised tailings. There is an abundance of these tailings in the Angouran region and making use of these tailings would help preserve national wealth and also reduce the serious problems of environmental pollution caused by the tailings. At the optimal conditions of calcining at 750 - 800¦C for 45 minutes, the sample showed a mass loss of about 19 per cent. Mineralogical analyses showed that under these conditions the carbonate minerals including smithsonite (ZnCO3), calcite (CaCO3) and dolomite (Ca Mg (CO3)2) decomposed to their respective oxides. Hemimorphite (Zn4Si2O7 (OH)2.H2O) converted into willemite (Zn2SiO4) and this transformation postponed the formation of silica gel in the leach solution. The grade of zinc increased from 22.20 per cent to 29 per cent. These mineralogical changes resulted in desirable reactions in the acid leach process.

Jan 1, 2004

By I. Gaballah

Jarosite contains up to 15 % of heavy metal compounds 'HMC'. The current waste disposal methods will not be allowed in the near future due to new environmental regulations and pollution risks. For these reasons, thermal treatments of raw or decomposed jarosite, in controlled atmospheres, were investigated. The aim of these treatments is to decontaminate the jarosite and/ or to recover the HMC for recycling. According to physico-chemical characteristics of the samples, the thermal treatments in controlled atmospheres N2, CO+N2 and C12+air lead to the extraction rate that vary from 93 to 98 %. Heavy metal compounds were separated by cooling the gaseous phase. The treatments' residue was almost free from HMC. Between 700 "C and 800 "C, the chlorinating treatment was successful of eliminating more than 97 % of HMC contained in four different samples.

Jan 1, 1999

By K. Chomyn, R. Veenstra, P. Zangeneh, Hatch Ltd., C. Van der Woude, H. Ghorbani

"The furnace is the heart of smelting operations, and therefore the performance, reliability, and campaign life of the furnace are critical considerations. Furnace refractory is exposed to high temperatures and other harsh operating conditions causing brick erosion, crushing, and cracking, typically limiting the furnace campaign life and requiring costly furnace shut-downs for refractory re-lining. Despite extensive study, the in-service thermal / mechanical stresses in these complex refractory systems are not generally well understood. Hatch has developed a thermal-mechanical finite element analysis (FEA) based furnace refractory modeling approach that allows for the quantification of refractory movements, load distribution, and thermal / mechanical stresses.Due to the complexity of the refractory system, a range of models are used to identify and assess damage mechanisms and design improvements, including: 2D models, to capture expansion and movement of individual bricks, changes to load paths, and thermal stresses; and 3D models, to include the effect of differential expansion between bricks in each course, and assess overall load distributions. The 2D and 3D analyses include the effect of nonlinear temperature-dependent properties, thermal expansion, movement of individual bricks with frictional contacts (i.e., gaps can open, bricks can slide), and brick tensile or compressive failure. Both as-built and damaged conditions can be investigated (e.g., after bath zone brick erosion), for circular and rectangular furnaces. 3D models also include papering and brick joint & interface action.Analyses using these models have shown the importance of thermal stresses, papering, and geometry / arrangement of individual bricks. Results have been used to identify and assess damage mechanisms, showing good alignment with furnace autopsy observations. By using this FEA-based approach to quantify the refractory design, the risk of damage can be significantly reduced, low-cost design changes can be identified, and the furnace campaign life can be extended.INTRODUCTIONThe furnace is the heart of smelting operations and therefore the performance, reliability, and campaign life of the furnace are critical to the success of the smelting operation. Furnaces are inherently exposed to high temperatures, often in excess of 1600°C (Holappa, 2004), and furnace operating power has progressively increased over time (Voermann, Gerritsen, Candy, Stober, & Matyas, 2004). The refractory system must withstand high temperature, high heat flux, and other harsh operating conditions. These conditions are particularly significant for the furnace hearth, and can lead to damage including brick erosion due to molten material flows, crushing due to thermal expansion loads, and cracking due to severe thermal gradients within the bricks. Refractory damage typically limits the furnace campaign life, requiring costly furnace shut-downs for refractory re-lining (repair or replacement). In some cases the refractory may lose integrity causing damage to nearby equipment and harm to personnel."

Jan 1, 2016

By Liming Yuan, Isaac Zlochower, RICHARD THOMAS, Thomas H. Dubaniewicz, Teresa Barone

Mining vehicle manufacturers are developing lithium-ion (Li-ion) battery electric vehicles as an alternative to diesel-powered vehicles. In gassy underground mines, explosion-proof enclosures are commonly used to enclose electrical ignition sources to prevent propagation of an internal methane (CH4)-air explosion to a surrounding explosive atmosphere. Li-ion batteries can create pressurized explosions within sealed enclosures due to thermal runaway. Researchers at the U.S. National Institute for Occupational Safety and Health (NIOSH) measured thermal-runaway pressures of lithium iron phosphate (LFP) cells as a function of free space within sealed enclosures and observed an inverse power relationship. A well-confined cell produced 4260 psia (294 bar) of pressure during a thermal runaway, far exceeding minimum pressure containment specifications for conventional explosion-proof enclosures. Results indicate that adding enough free space surrounding LFP cells can reduce thermal-runaway pressures to levels below that expected for CH4-air ignitions. Measured thermal-runaway temperatures were below the minimum autoignition temperature of CH4-air.

By Frederick J. McGarry, Parviz F. Rad

Although tunneling machines have attained very high advance rates in medium-hard rocks, the need for frequent repairs has slowed their use in very hard rocks. Laser- assisted tunneling is expected to improve tunneling machine performance by improving either specific energy or amount and quality of muck. The beneficial effects of lasing are the initiation and growth of microcracks from differential thermal expansion of grains, and overall spalling in the vicinity of the lased area. Using a constant thrust rock cutting device with disk cutters, the effects of cutter geometry, cutter diameter, thrust, and speed variations on specific energy and muck were explored and the improvement in performance of disk cutters caused by lasing was evaluated. It was found that the improvement depends on beam power and density, beam speed, pattern of heating, and cutting pattern and procedure. A focused beam slightly offset from the cutter path gives the most improvement both when cutting on a smooth surface and when cutting in previously cut grooves.

Jan 1, 1971

By Donald P. Tuchman, Robert P. Vinson, Steven J. Page

Researchers at the National Institute for Occupational Safety and Health (NIOSH) have long used stationary tapered element oscillating microbalances (TEOMs®) in laboratory settings. They have served to assess the mass concentration of laboratory-generated particulates in experimental , dust chambers and they provide a reference method for comparison with other particulate- measuring instruments. Current NIOSH research is focused on further adapting TEOM technology as a wearable personal dust monitor (PDM) for coal mining occupations. This investigation's goal is to help identify, quantify, and provide means for resolving certain TEOM- related error. The present research investigated bias caused by thermal effects on filter assemblies. New filters used in the PDM for 8 h tests show an average positive bias of 25.5 pg, while similar tests of equivalent filters used in two 1400A model TEOMs show an average positive bias of 34.3 µg. The derived bias values allow correction of previously collected biased data. Also, pre- heating the filters for 24 h at 46° C shows significant bias reduction, with PDM pre-heated filters subsequently averaging -3.3 µg and 1400A TEOM filters averaging 5.9 µg. On a single-point comparison to gravimetric sampling, a 25.5 µg bias is only significant at low mass loadings. At 2.5 mg, this bias represents a negligible 1 % of the mass measurement. If ordinary linear regression is used, the bias is still insignificant. However, if the more valid weighted linear regression is used, it gives more weight to the smaller dependent variable values, which are more impacted by the bias. Consequently, what is 1% bias on a single high-mass value can translate into a larger bias percentage at high-mass values when performing a weighted regression on data that include a large number of low-mass values.

By Imre Gombköto, Barnabás Csoke

"Raw material management means not only mining and processing of primary raw materials like ores, but means also collecting and processing secondary sources of raw materials. Recycling is one of the most developing field of raw material management in Europe, and its solutions are derived from mineral processing roots and principals. Complexity and challenges of the field of recycling results innovative solutions of material processing- Since European Union identified 20 raw materials as critical (CRM) due to lack of primary sources within the border of the EU, recycling become more recognised as source of different raw materials. WEEE is the waste streams contains many of the critical elements and along them at least 15 different species of plastics of which recycling is delayed by a lack of effective separation technique. Most paper deals with separation methods based on different specific gravity, triboelectric charge or surface properties of plastic species. Plastics however have differences of thermal properties and thermoplastics, duroplasts and elastomers can be recognised. The experiments described in the paper aimed to determine thermo adhesive behaviour of plastic species often identified in WEEE streams for separation purposes. According to the results, some plastic types as PS, PP. PC or PVC and PET pairs are possible to easily separate from each other, however different additives are changing thermo adhesive properties of most of the plastics that makes industrial process difficult to develop. Along thermo adhesive behaviour, combination of physical interaction can be used to enhance separation selectivity.INTRODUCTIONPlastics has a relatively long term of history as a light, multi-functional material in construction, packaging, automotive industry and electric and electronic products. There are a numerous types of plastic species can be used for various applications therefore they amount are growing from year to year. This quantity however become part of the waste stream and while metal recycling has been done for decades due to its economic value - cheap plastic parts are less desirable as secondary products. In 2013 an annual 5% of plastic production growth has been estimated with a base data of 265 million tonnes at 2010 (Guiqing & Zhenming, 2013). Since landfill requirements are increasing while—especially in Europe where actual regulations are trying to deflect waste from landfills - landfill capacities are decreasing, costs are become more and more expensive, Applications like energy production based on plastics as a fuel or recycling are some of the options can be applied. Direct incineration of plastics are applied at many plants - in most cases where waste consist of dangerous substances are incinerated because plastics high calorific value helps correct average mixture composition enable operators reaching high enough temperature for combined power and heat generation while most of substances—like PAH, PCB or dioxins—are destroyed. Another path is using low temperature reductive cracking due to pyrolysis process, however the chance having higher concentrate of carcinogen substances in the products are higher since it applies around 400°C during the process."

Jan 1, 2016