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By Irina Melekestseva

The Cu-Zn massive sulfides from the basalt-hosted Semenov-2 hydrothermal field (13°31.13´ N, 44°59.03´ W, MAR) are enriched in Au (22?188 ppm) and Ag (127?1787 ppm) [Ivanov et al., 2008] and elevated contents (ppm) of Se (269?289), Sn (123?125), and Sb (72?75). These may indicate heterogeneous substrate rocks and possible ultramafic rocks. Based on phase analysis, 70% of the gold in the massive sulfides is free. LA-ICPMS analysis has shown that the main carrier of the invisible gold is covellite (22.51? 226.64 ppm). Covellite is also characterized by elevated contents of Se, Mo, Sn, Te, Au, Bi, As, Ag, Sb, Tl, and Pb relative to the primary sulfides.

Sep 14, 2011

By Jean E. Tilden

An investigation of several trace elements distributed among sulfide minerals from deposits located in the southeastern United States was conducted. The deposits investigated are distributed within both the Blue Ridge Province and the Piedmont Province, which are contiguous geographic provinces. Twenty five deposits were examined;' eleven in the Blue Ridge Province and fourteen in the Piedmont Province. Figure 1 shows the locations of deposits investigated. In the deposits investigated, the mineral phases examined were pyrite, pyrrhotite, chalcopyrite, and sphalerite. These phases were chosen because of their relatively widespread occurrence, although no pyrrhotite was seen in the Piedmont Province. A total of 116 polished surfaces of ores were prepared, and mineral phases were collected from these surfaces for analysis. Samples were analyzed for cobalt, nickel, manganese, lead, tin, chromium, molybdenum, and gold. A total of 372 analyses were made. Trace elements were determined by atomic absorption spectrophotometry following standard procedures. In this study, trace elements are defined as those elements which are present in the mineral but which do not affect the chemical formula for that mineral. Lead is considered as a trace element only in ores where little or no lead sulfide could be identified as a distinct mineral phase.

Jan 1, 1972

By Henry S. Brown, Jean E. Tilden

Pyrite, pyrrhotite, chalcopyrite, and sphalerite from deposits distributed within the Piedmont and Blue Ridge provinces of North Carolina and adjacent areas were examined by atomic absorption spectrophotometry for cobalt, nickel, manganese, lead, tin, chromium, molybdenum, and gold. The ore samples were also examined petrographically. Cobalt and nickel, in general, enter pyrite and pyrrhotite rather than chalcopyrite and sphalerite. Manganese generally enters sphalerite rather than the other phases where an alternative is possible. The presence of tin in sulfide minerals was noted in a group of deposits east of the known occurrences of tin oxide (cassiterite) in the Kings Mountain belt, which may indicate the presence of a more extensive tin belt in the southeastern Piedmont than was previously recognized. Pyrrhotite from a group of four deposits in Jackson and Clay Counties, North Carolina, differs from pyrrhotite from other Ducktown-type deposits in having cobalt/ nickel ratios less than one, finer grain sizes, and colloform texture. These differences suggest that that this group of deposits has had a history different from that of the other Ducktown-type deposits studied. No significant conclusions could be made based on the distribution of lead, chromium, molybdenum, or gold.

Jan 1, 1975

By Niko Hellstén

To capture efficiently the valuable trace metals from nickel slag using electric furnace, it is important to study their distributions between the slag and metallic phases in the furnace. It is impossible to calculate accurately these distributions without experimental measurements. Therefore, in this work, selected trace metal distributions and phase equilibria between K2O containing iron-silicate slags and a metallic Ni-Fe-Cu alloy in nickel slag cleaning furnace conditions were studied. The experimental method developed and applied during the work, involved a modified quenching technique that included equilibration of the samples in semi-sealed quartz ampoules in an inert atmosphere and metallic Fe saturation. The use of the semi-sealed quartz ampoule prevents the escape of volatile elements from the sample during equilibration. Chemical compositions of the phases and the trace elements were analysed by EPMA. From the measured compositions, the trace metal distribution coefficients between the molten Ni-Fe-Cu alloy and slag were calculated.

By Jean Scott, G. A. Collins, G. W. Hodgson

WHILE it is well known that trace metals in crude •oils and distillates have been a matter of deep concern to refining engineers because of the damage done .by the metals to cracking catalysts and refractories (8, 5), the trace metals in crude oils may be of great benefit in correlation studies and in origin studies. During the geological processes in which the oil is formed from •animal and vegetable life, the hydrocarbons are subjected to a host of inter-related reactions, both physical and chemical. It has been well demonstrated that the lighter materials, certainly the short-chain paraffin hydrocarbons, are degradation products of the heavier molecules, and it might be concluded that for correlation studies it would be advisable to direct attention as much as possible not to the degradation products of the large molecules but to the large molecules themselves. Be this as it may, the methods at •hand to conduct the study are not particularly precise and, in the past, attention has centred on the simpler small molecules, as evidenced by the great mass of work involving distillation and chromatography with painstaking separation of the simpler 'front-end' hydrocarbons.

Jan 1, 1954

By ANGELA NAIR AVELAR, Reiner Neumann, PAULO R. G. BRANDÃO

Three types of apatite were identified by means of cathodoluminescence (CL) images in flotation concentrate and tailing samples from the Catalão Mine in Brazil. They are predominantly blue apatite, followed by green apatite and, less frequently, yellow apatite. The chemical compositions of these types of apatite were determined by electron microprobe analysis and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). Blue and green apatite responded well to the process, thus remaining in the concentrate, while yellow apatite remained in the tailings. Yellow apatite has the lowest phosphorus pentoxide (P2O5 ) content and largest anionic and cationic sites substitution, followed by green apatite, whereas blue apatite is the most homogeneous, with highest phosphorus (P) and calcium (Ca) grades and lowest substitution level.

By C. J. A. Mcewan, C. M. Rice

The Rosita Hills contain rich, vein- and breccia pipe-hosted precious metal deposits. Volcanic activity occurred in two cycles - an early, mainly andesitic cone-building phase that terminated in the formation of a caldera and breccia pipes and a later phase characterised by trachytic lavas and dykes, rhyolite domes and lamprophyre dykes. Alteration consists of weak propylitic and argillic and, locally, intense advanced argillic, K-feldspar sericitic and silicic types. Marked trace-element depletions (Rb, Sr, Zn, Mn) are associated with K-feldspar-sericitic alteration and with advanced argillic alterations, whereas enrichments (Pb, Ag) are associated with K-feldspar-sericitic alteration. Gold distribution is highly localised and is controlled by breccia pipes and a caldera ring fault; it is not related to district scale alteration. In general, the geochemical and alteration patterns are complex, but they are clearly influenced by linear structures, the caldera ring fault and breccia pipes. Pipe-hosted Au-Ag and vein-hosted Ag mineralisation are associated, respectively, with early andesitic and late, post-caldera rhyolitic activity. The pipe-hosted and, especially, the vein-hosted mineralisation show affinities with adularia-sericite-type epithermal deposits

Jan 1, 1991

By A Grant, H Thomas, C Clarke, B Fuller

Native seed and plants are often a core input into the rehabilitation process of mine closure. Native plant establishment rate and performance is a function of many input elements including seed quality (purity and germination percentage), processing, treatment, storage, supply chain handling, application and ongoing management. Traditionally native seed has been supplied with very limited supporting information which in some cases has led to establishment failures, repeated attempts at successful plantings, and biosecurity issues, leading to increased rehabilitation costs for mining companies. Product procurement scrutiny, and sustainability credential requirements, in all supply chains is increasing the need for transparent, accurate, verified, and certified information. This collectively continues to evolve towards a social license to operate in all industries, including mining. The Australian Seeds Authority (ASA), in partnership with native seed supplier AustraHort, traceability software company Trust Provenance and supporting partners including Transport for NSW and Queensland Transport and Main Roads (TMR), were recipients of a DAWE National Traceability Grant. The project team has developed a framework and traceability software platform currently being piloted within the Australian native seed industry. The framework and platform allow for all critical-tracking-events along the journey of a native seed batch to be easily captured utilising a smart phone application (APP) and the global standard for data capture. The platform provides a unique identification for each batch of seed and critical tracking event. The batch ID belongs to that batch and all supply chain stakeholders can contribute to batch traceability by providing more information/data to increase information integrity. This gives the end user, and other stakeholders, increased levels of trust in the product to support value, increase efficiency and reduce costs. For mining companies these efficiencies and cost reductions are in the form of information availability across site/company, potentially improved vegetation establishment, less rework and efficient monitoring. Ultimately this contributes to safe, stable and sustainable rehabilitation. By capturing data on harvest, logistics, storage (including temperature and humidity), aggregation/blending, treatment, application and ongoing management, the native seed industry and end utilisers of native seed have a greater level of product integrity, brand integrity and information integrity.

Aug 2, 2023

By Carlos Neto

Traceability is the capacity to recover background, application or localization of an item, through a single, standard and registered identification. It is the identification process necessary to follow all events, occurrences, handlings and movements of a product. Generally speaking, companies and governments in the world are seeking ways for tracing the distribution of controlled products, such as food, medicines, firearms and explosives, within the supply chain as to increase safety of its consumers and the environment (ISO 14000).

Jan 1, 2007

By Daniel J. Kennedy, George W. Klinowski

A significant portion of each mine is ventilated with the help of auxiliary fans delivering fresh air to the faces of its developing headings via flexible or rigid ducts. Quality and volumes of air delivered to the blind working faces are essential for creation of safe and acceptable conditions for employed crews. Well designed and properly maintained delivery systems are necessary in each mine. The Cape Breton Coal Research Laboratory, part of the Canada Centre for Mineral and Energy Technology located in Sydney, Nova Scotia, Canada, developed a tracer gas based technique which provides fast and accurate evaluation of any auxiliary ventilation system performance. In addition, important information about the system's behaviour is gathered which can be used for designing a similar system in comparable conditions.

Jan 1, 1989

By K. Sasaki

Ventilation measurements were carried out in a shallow underground-quarry space with relatively large internal volume of 14,600 m3 in order to evaluate its effective ventilation characteristics. Based on air velocity measurements with an ultrasonic anemometer in the exhaust airway connected to the space, it was found that the space was ventilated by natural ventilation airflow with intermittent changes in direction. It was difficult to measure the ventilation flow with typical methods of flow measurement provided from the intake portal and throughout the mine, because the cross-sectional area and volume of the openings were too large and the flow was variable. In the present study, a tracer gas method was applied to evaluate the effective ventilation airflow rate in the space. A photo-acoustic infra-red gas monitor, highly sensitive to SF6 gas used as a tracer gas, was set in the space to determine air exchange rates from gas concentration-time decay curves. The seasonal variations of airflow and thermal environment in the space were investigated through 13 sets of measurements taken over 15 months. Airborne rock dust concentrations were also measured at same time in the opening. The correlations between the effective ventilation airflow rate, thermal environment and dust concentrations in the opening space were analyzed and are discussed based on the presented measurements taken during year. It is concluded that seasonal variations in effective ventilation flow and the dust concentration are mainly due to differences in air temperature in the space, as affected by the rock?s surface temperature and atmospheric temperature. In summertime, the air temperature and associated air density difference generated lower natural ventilation flows resulting in higher dust concentrations.

Aug 1, 2013

By S. J. Schatzel, J. D. Addis, V. Gangrade, L. L. Chasko, C. A. Hollerich

"A ventilation study using tracer gas was conducted at a western US coal mine. The objective of the study was to evaluate the movement of longwall face air exchanges between the face and worked-out area and to document the presence or absence of face airflow pathways between these locations. The mine operator uses a bleederless longwall ventilation system with a back return and a blowing mine ventilation system. The study was conducted on an active panel and included both underground and surface monitoring sites. The study used sulfur hexafluoride (SF6) released as a slug on the longwall face and in the front of the gob inby the face. The velocity of the tracer gas movement in the gob was 0.019 m/s (3.7 fpm). The rate of movement for the overall tracer gas slug averaged about 0.0091 m/s (1.8 fpm). A separate tracer gas test initiated with the release of SF6 into the legs of the first shield showed the existence of more than one pathway of face air in the general direction from the headgate towards the tailgate corner. Maintaining adequate ventilation air on longwall faces is important for worker safety and for the dilution of methane emitted from the face and caved gob. A more detailed characterization of longwall system air and gas movement allows a mine to better assess its ventilation design for controlling gas on the face and in the gob. INTRODUCTION During a series of stakeholder meetings, a near unanimous concern was expressed related to maintenance of effective ventilation airflow on longwall faces. There was a strong interest expressed regarding the impacts of face length and caving characteristics on the ability to maintain adequate face airflow levels. This study seeks to understand and improve a mine operator’s ability to monitor and control ventilation and methane concentrations across the longwall face by assessing airflow variations in terms of roof caving characteristics and face length. National Institute for Occupational Safety and Health (NIOSH) researchers seek to identify flow paths of ventilation airflow on longwall panels with variations in roof caving characteristics and longwall face lengths. The project research aims to develop an understanding of the role of gas dynamics in variable broken rock, interactions with ventilation airflow and methane concentrations across the longwall face area. The research also addresses continuous ventilation monitoring along the shield line to provide early detection of gas exchanges between face and gob, and thus improve a mine operator’s ability to monitor and control ventilation and methane concentrations around the face. In the context of this paper, the longwall gob refers to the pillared area behind the shields. This work reports on results from one project task to conduct field based research using a tracer gas to describe face air and gob area gas movement in a bleederless longwall ventilation system that incorporated a back return."

Jan 1, 2017

By G. W. Bonnell, D. A. Young, D. G. Genter

Through 1996 and 1997, CANMET and the Cape Breton Development Corporation (CBDC) conducted a project to study the Phalen Mine’s 7 East longwall ventilation network to help determine methane emission patterns that were having a negative impact on coal production. Increased methane emissions were primarily related to mining depth and were also affected by the influence of a large sandstone body located above the worked seam. The research included the installation of tube bundle systems to monitor waste (gob) methane and pressure differentials. The focus of this paper is on the novel use of tracer gas techniques that helped shed light on the performance of the ventilation system and in determining the methane migration paths in the waste.

Jan 1, 2001

By D. J. Kennedy, W. G. Klinowski

Over the past few years the Cape Breton Coal Research Laboratory's staff designed, built, tested and proved the necessary hardware, software and methodology of tracer gas based surveying techniques applied in the field of mine ventilation. These methods are now used routinely in a variety of applications where traditional anemometric methods do not provide the required accuracies or cannot be effectively employed. Irregular or highly turbulent flows, leakages, geometrically complicated or highly obstructed airways are just a few examples where traditional anemometry can produce unacceptable errors in calculated ventilation parameters. Tracer gas based ventilation techniques have been used in many problematic situations where the standard ventilation methods are inadequate. One such problem, faced by many mine operators, is the emergency imposed by the ever present threat of a mine fire. An understanding of the propagation of smoke contaminants and the demonstrated integrity of appointed escape routes can save lives and property during a fire. That knowledge can be gained quickly and inexpensively by the application of tracer gas smoke simulation methods. The concept of controlled air recirculation has recently gained considerable attention in the mining industry. While mathematical models can be used to predict performance, the ultimate proof of a ventilation system's performance can best be provided by a tracer gas based simulation of contaminant levels. Fan performance tests and assessment of auxiliary ventilation systems are highly dependent on accurate definition of airflows; precise data can be easily obtained by tracer gas based volumetric surveys. This paper contains a brief description of the equipment and the methodology of tracer gas based ventilation techniques and presents typical examples of their use

Jan 1, 1991

By R. W. Hyde, B. S. Old, S. E. Eaton

INTRODUCTION ONE of the most important problems facing the steel industry at the present time is that of maintaining at a minimum the sulphur content of many grades of steel where sulphur is known to have harmful effects on both quality and yield. The present outlook in this struggle to reduce the amount of sulphur in steel is rather gloomy since the sulphur content of the raw materials available in the United States is gradually rising, with little relief in sight. A flow sheet of sulphur in the steel process is shown in Fig I. The values used here were obtained by averaging coke oven and blast furnace data at No. 5 furnace in Cleveland and are considered typical for high top pressure practice. The sulphur evolved in the blast furnace top gas was obtained by difference and since the amount is relatively small, little significance should be attached to this particular value. From Fig I it is apparent, however, that coals used in the production of metallurgical coke represent by far the largest single source of sulphur in steelmaking. As an indication of the decrease in quality of these coals as regards sulphur content the weighed average annual sulphur analysis of the coals supplied to two different steel plants, since 1925, is plotted in Fig 2.1 The sharp rise since 1940 is strikingly apparent. Another indication of this trend is found in estimates of coking coal reserves. Thus in the case of Pittsburgh seam coals available in Allegheny, Fayette, Greene, Washington, and Westmoreland Counties in Pa. as of Jan. 1937 only 25 pct of the coal reserves would contain less than 1.50 pct sulphur after washing.2,3 Many of these lower sulphur reserves have been seriously depleted in recent years because of accelerated war demands. Still another demonstration of the increasing sulphur content of coals on a country-wide basis is found in a report by the Bureau of Mines4 which shows a steady increase in the sulphur content of coke made in the United States, It should be noted that this increase continues in spite of the wider use of coal washing in recent years. Sulphur occurs in coal in three forms, pyritic (FeS2), organic sulphur, and a small amount of sulphate sulphur (CaSO4), The sulphur is subsequently found in the coke in combination with carbonaceous material of unknown composition and as calcium and iron sulphides: In considering the general problem of sulphur elimination, the Republic Steel Corp. was interested in determining which, if either, of the two major forms of sulphur in coal contributes the greater portion of sulphur to the coke, Since the ratio of pyritic to organic sulphur varies widely in different coals, it was thought that if it could be shown definitely that the major part of the sulphur occurring in coke originates from one of the two major forms of sulphur in the coal, it would then be possible to select with confidence coal which, although high in total sulphur, would yield coke of fairly low sulphur content, Using the new

Jan 1, 1948

By M Wortley, R Morrison, T Rivett

The tracking of ore through process hold-ups such as stockpiles has been traditionally been difficult to achieve. The inability to pinpoint the exact source in the mine of material that is feeding a processing plant has led to inefficient mine-mill reconciliation processes. In addition, a lack of understanding of the behaviour of ore in process hold-ups such as bins and stockpiles often leads to poor predictions of plant performance and to poor reconciliation of this to the orebody.This paper reports on two short case studies. One case study addresses tracking ore from various parts of two mines to the concentrator. The other follows synthetic particles through the coarse ore stockpile. Both studies use radio-frequency identification (RFID) tracer technology. The paper concludes by discussing general strategies for implementation of such concepts into mine-mill metal accounting and reconciliation systems. As shown in this paper, reliable ore tracking systems will allow much more effective mine-mill reconciliations as well as the ability to model process hold-ups with regard to size by residence time distributions. This should, in turn, allow metallurgists to have a better understanding of the size and grade of material that will report to the plant at different process hold-up (eg stockpile) conditions.

Jan 1, 2009

By Carlos Collado, Oscar Jimenez, Francisco Diaz, Rodrigo Bernal, Carmen Salinas

Water is a strategic resource for the mining industry. The rising cost has forced the industry to become more efficient in their use, reduce and recycle waste as much as possible. The importance of having a reliable water balance is increasingly urgent, because the resource is scarce and vital to the sustainability of human life, animal and ecosystem. Conventional flowmeters can suffer disruptions or failures by corrosion, fouling, presence of elements in the water as acids, salts and suspended solids. Use of radiotracers is advantageous to determine fluid velocities that are transported through pipes, as they are detectable by means of the radiation emitted, the same way for surface flows, such as natural watercourses and drainage from tailings dams, fluorescent tracers are those with the best advantages. For velocity measurements in pipelines a Iodine-131 tracer solution, around 5 mCi was injected into the suction of the pumps. The technique used is the transit time between detectors at known distances and determining the time of passage of the radiotracer. For measurements of surface fluxes using the fluorescent tracer Rhodamine WT by tracer dilution technique, injecting the tracer at a constant rate and measuring it known concentration diluted downstream. This work has been performed in Minera Los Pelambres, located in the IV Region of Chile, measuring the flow rate pumped from 12 pools with 1-7 pumps operating, obtaining speeds of 0.56 to 2.62 m/s. In pumping wells three facilities have been measured at speeds of 0.111-0.223 m/s, plus six surface flows with flow rates of 8.45 to 357.2 L/s.

Jan 1, 2014

By Roy J. Greenfield

A highly undesirable side effect of the mining of coal is the release of acid forming chemicals into the ground water system. The disturbance of the ground during mining allows water to flow through the coal bearing strata and mine refuge where it absorbs iron and sulfide ions and thus becomes highly acidic. The highly acid mine water can then contaminate water supplies and can destroy many of the recreational uses of Pennsylvania's waterways. A great deal of effort has been expended to develop methods of controlling groundwater pollution from mine drainage. At the Pennsylvania State University there has been an ongoing effort to under- stand the chemistry of acid mine water formation and the hydrologic environment in which the acidic water migrates from the mine source into the ground water system. As a support to the hydrologic studies, geophysical studies have been used to help determine the geologic structure of the areas under study which are contaminated by acid water. In addition, the geophysical work has been used to define the type of information geophysical methods can give to determine which geophysical methods are most useful and to develop geophysical field procedures.

Jan 1, 1973

By A. Dreimans

Tracing of 'float' against the latest ice-flow directions ha!' led to or assisted in discoveries of several mineral deposits in Canada at lP.ast since 1891, e.g., fluorite and corundum in eastern ?Ontario, Steeprock and Josephine iron ore in western Ontario, Malartic, Fisher-Quebec, and Lamaque gold ore, and Vendome zinc ore, in western Quebec, Sullivan zinc and lead sulphides in British Columbia, Orvan Brook or New Calumet sulphide deposit in New Brunswick, Lynn Lake nickel sulphide de-posit in Manitoba, etc. Pebbles or ore boulders whose source has not yet been found include diamonds in the Great Lakes region and ?sulphides in several localities in Ontario and Quebec. Complexity of transport of ore boulders, including non-glacial transport, may be the explanation. Tracing of ore boulders requires knowledge of the Pleistocene history of each particular area (ice flow directions, their ?changes during glacial oscillations, existence of pre-glacial lakes with ice-rafted boulders, later interference by streams, lakes, mass movements). Important also is distinction of till from similar non-glacial deposits and knowledge of the bed-rock geology. Quantitative methods, e.g., pebble counts, maybe applied while tracing magnetite, hematite, or goethite. Fragments of sulphide ores are less abundant in indicator trains, and quantitative methods are less suit-able for tracing them. Heavy-miner-al investigations may give good results for minerals resistant to weathering. Geochemical methods are of value only in the vicinity of ore deposits.

Jan 1, 1958

By L. M. English, K. A. El-Nagdy

The mine characteristic curve represents the relation between the airflow in a system and the pressure drop across the system. In a single fan system, this relation can be easily drawn by assuming different values of the airflow and calculating the corresponding pressure drop according to Atkinson’s law. In a multiple-fan system this cannot be done for each fan simultaneously. However, an alternative mathematical method for plotting subsystem characteristic curves on subsystem quantity coordinates is outlined here that achieves this objective. The Hardy Cross algorithm has been combined with a switching-parameters technique and has been used to trace subsystem characteristic curves. An example using four fans in a complex network is presented here. This example illustrates the nature of the problem and the difficulty of detecting unstable conditions in this type of network.

Jan 1, 2001