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By Dennis R. Dolinar

In general, the direction of the maximum horizontal stress in the eastern United States is fairly well defined. However, the variation of the magnitudes of the horizontal stresses is not very well understood. Because the horizontal stresses cause severe ground control problems in underground coal and limestone mines throughout the eastern United States a more complete understanding of how the magnitudes vary would be useful for developing mine design strategies to combat horizontal stress related ground control problems. Therefore, in this National Institute for Occupational Safety and Health (NIOSH) study, the variation of the magnitude of the horizon stresses in sedimentary deposits in the eastern and Midwestern United States are examined with respect to two factors, the elastic modulus of the rock and the site depth. Stress measurements from thirty-seven sites are used in the evaluation. Examining the applied excess strains indicates that the eastern United States can be, separated into high and low strain zones. For most of the eastern United States the maximum applied excess or tectonic strain ranges from only 300 to 550 micro strains. However, there is one area, a portion of the Beckley seam in the central Appalachian region where the strains are significantly higher than the other regions. In this higher strain zone, the maximum applied tectonic strains range from 700 to 1,000 micro strains. Regression models for each zone based on the elastic modulus can explain between 83 to 85% of the variation of the maximum horizontal stress. Because one region, the northern Appalachian district, has strains that are about 20% higher than the other regions in the low strain zone, multiple strain models based on geographic regions were developed for the low strain zone that can explain 87 to 91% of the maximum horizontal stress variation with the elastic modulus. Depth was found not to be a significant causal factor in any increase in the horizontal stress even though the site depths ranged from 275 to 2,500 ft. Beyond a theoretical increase, based on Poisson’s effect and gravity, no other increase in the horizontal stress with depth can be justified with this data. The most significant factor controlling the variation of the maximum horizontal stress is the elastic modulus of the rock, not the overburden depth.

By Clarence Zener

THEORETICAL considerations by one of the authors have led1 to the prediction that the dynamic internal friction of annealed metals has a broad maximum at a certain grain size. This prediction they have veri-fied2 for alpha brass. In the present paper the theory is extended to include the precise manner in which the internal friction varies with grain size on either side of the maximum. New experimental data are pre¬sented to test this extended theory. The physical basis for the type of internal friction that is being investi-gated lies in the interplay between stress and temperature. Just as local fluctuations in temperature give rise to local fluctuations in stress, so like-wise fluctuations in stress give rise to fluctuations in temperature. But temperature gradients give rise to necessarily irreversible thermal cur-rents, and hence to internal friction. The theory for this type of internal friction has been developed quantitatively,3 and has been experimentally verified,4,5 for the particularly simple case of the transverse thermal cur-rents accompanying transverse vibrations. Of more fundamental impor-tance are the intercrystalline thermal currents accompanying all types of vibration. The variation in stress across grain boundaries arises from the elastic anisotropy and at least partial random orientation of the individual crystallites. An exact quantitative treatment of the internal friction due to these thermal currents is of course out of the question. However, much information can be obtained from general arguments.1,6 Thus when the frequency of vibration f is low, or when the grain size d is small, adja-cent grains remain nearly in thermal equilibrium, and vibration proceeds isothermally with little internal friction. Again, when the frequency is high, or the grain size large, the heat flow per cycle is small, the vibration proceeds adiabatically with little internal friction. The internal friction will become a maximum in the transition region. The degree of adiabatic-

Jan 1, 1940

By Tatsunori Matsumoto

In order to investigate the variation of the load-displacement relations of piles in a site, vertical load tests were carried out on 25 small diameter steel pipe piles. Out of 25 piles, 15 piles were close-ended pipe piles attached with a blade at the pile toe and 10 piles were open-ended pipe piles. To carry out these load tests in a short period, two types of rapid load test methods, Spring hammer load test and Falling mass load test, were employed. The load tests of all piles were completed in two days with 180 blows in total. In order to estimate a static load-displacement of a pile, non-linear damping method was used. It is shown from the test results that the performance of the pipe piles such as the ultimate pile resistance and the initial pile head stiffness is improved by re-driving.

Jan 1, 2006

By Ross W. Smith

In recent years there has been a considerable amount of research work done relative to the effect of pretreatment and aging in water on the surface properties of both simple metal oxides and more complex oxides such as the silicate minerals 1-6. Of particular interest is the work of Somasundaran6 who states that after preparing minerals by size reduction and washing with dilute acids "... it is essential to treat it (the mineral) with water in order to remove any effects of leaching itself." Somasundaran also states, "... it is advisable to use a solution close to the point of zero charge for conditioning purposes." Parksl notes that, "Dehydration, dehydroxylation, and increased crystallinity can be expected to decrease the PZC. The presence of anionic impurities or of pH-independent potential determining ions will decrease the PZC. Cationic species will increase the PZC." Healy and Jellett4 believe that in the Zn0-water system "the surface charge of Zn0 in water and each pH is determined by the concentration and adsorption of each hydrolyzed (charged and uncharged) Zn(II) species." Finally, according to Parks 2, "The PZC of an unaltered com¬plex oxide in a system devoid of specific electrolytes is approximately the average of the PZC's of its component oxides... Equilibration with water results in loss of mono and divalent cations by exchange with H+, thus a loss of influence on the PZC by those cations, i.e., a shift in the PZC with time in the direction of that remaining oxide. The present paper investigates the change of point of zero charge (PZC) of a number of simple oxides and several complex oxides as a function of aging time in water. In some cases acid pretreatment of minerals was performed. However, in most cases the minerals were not acid pretreated. In several systems pH change as a function of aging time in water was monitored.

Jan 1, 1972

By Ross W. Smith, Nikhil Trivedi

The variation of point of zero charge (PZC) of both simple and complex oxide minerals was studied as a function of aging time in water. In most cases the PZC's of the simple oxides moved toward more basic pH values with aging time. Evidence to date suggests that this phenomenon relates to dissolution of disturbed layers on the mineral's surface accompanied by later readsorption of metal hydroxy species back onto these surfaces. The readsorption takes place after the solution becomes supersaturated with respect to some crystalline phase. The variation of PZC's of complex oxides as a function of aging time in water is apparently related to several different mechanisms. In a few cases PZC shifted toward more basic values with time. This shift could be attributed to much the same mechanism as for simple oxides. In most cases, however, PZC of complex oxides shifted toward more acid values with aging time, probably because of loss to solution of soluble cations whose oxides possess basic PZC's.

Jan 1, 1975

By R. R. Klimpel

Introduction The grinding of coal-water slurries has received increasing industrial attention during the last decade. In particular, there is long-term interest in the use of pulverized coal-water slurries to replace oil in combustion equipment and in the development of coal gasification/liquefaction processes that require coal-water slurries as feed. More specifically, the use of coal-water slurries in gasification requires grinding a high-density slurry containing the smallest amount of water consistent with slurry pumping and spraying. As part of a fundamental engineering research support program aimed at the industrial implementation of dense coal-water slurry grinding, this author has published several papers on how specific rates of breakage vary as a function of slurry rheology (Klimpel, 1982,1982/83). These papers demonstrated that there is a consistent pattern of change in specific rates of breakage of coal in dense slurries with controlled variation in slurry rheology. By matching rheological data with laboratory grinding results, it was possible to identify directly slurry conditions that correspond to: 1) slowing down of breakage rates, 2) the occasional acceleration of breakage of some sizes, and 3) conditions where chemical additives will increase rates of breakage. In brief, these conditions were analyzed using two different criteria: a) the net production rate of material less than some specified size (e.g. kg/min of minus 325 mesh) in a standard batch laboratory mill test as a function of controlled changes in grinding conditions, and b) the use of the one-size-fraction feed method, which consists of following the disappearance of this largest size over grinding time in a batch laboratory mill to arrive at well-known specific rates of breakage (Austin et al., 1984). Detailed references to the methodology used as well as the conclusions are available (Klimpel, 1982, 1982/83) and will not be repeated here. The purpose of this paper is to further demonstrate several additional characteristics of dense coal-water slurry grinding that were shown in a simplified sense in the earlier publications of the author but which have clearly demonstrated themselves as being very important in the industrial simulation and scale-up of such coal-water grinding systems. In particular, this includes the clear and unambiguous demonstration of how the simultaneous acceleration of breakage of some size fractions and slowing down of the breakage of other size fractions is occurring as a function of changes in coal-water slurry density. In the earlier publications (e.g. Klimpel, 1982), it was shown by specially designed experiments that the addition of fine material and/or the use of a chemical thickening agent accelerated the specific rates of breakage of coals of coarser size fractions using the one-size-fraction method. There were also numerous examples given of non first-order breakage (the slowing down of coal breakage rates) using also the one-size-fraction method due to the presence of excessive amounts of fines which corresponded to the development of a rheological yield value. The problem with the simulation and scale-up of any laboratory and/or pilot-scale mill data to an industrial scale using the mechanistic modelling approach involving specific rates of breakage and breakage distribution parameters (e.g. Austin et al., 1984) is the number of assumptions involved in translating the smaller mill breakage parameters to the predicted larger mill breakage parameters. It is apparent, at least to this author, that to accurately simulate and predict larger scale equipment performance from smaller scale data (given that the larger scale data performance is known and hence predictions can be thoroughly checked) requires a better knowledge of breakage parameters than is currently available. More specifically, it was felt that one of the chief problems was the inability of the one-size-fraction method of determining breakage parameters to sufficiently represent the actual magnitude and sometimes even the directions of. the complicated interactions involved with slurry density changes in coal-water slurry grinding. Thus, a special set of experiments was conducted in a somewhat larger batch ball mill (0.457 m diam x 0.610 m length) than the 0.203-m-diam mill used in the original rheology characterization paper (Klimpel, 1982) so as to minimize any unusual effects due to wall-ball interactions (2.54-cm-diam balls used in both mills). More importantly, the measurements of specific rates of breakage were done using a proprietary tracer method on a portion of a given size fraction, which was then remixed into a natural feed size distribution before grinding. The experimental procedure and analysis of subsequent data was done in exactly the same manner as the radioactive tracer technique on coals as originally developed by Gardner (1962). The advantage of such an approach is that it makes no assumptions such as the independence of the specific rate of breakage of any size on the absolute sizes and amounts of other sizes present (both larger and smaller) in the mix of natural feed material. It will be shown that the measured rates of breakage using the direct tracer technique and the one-size fraction method on the same coal are indeed different. In fact, an accurate assessment of what is happening to the rates of breakage as a function of changing slurry density can only he made by measuring particle breakage under grinding conditions approximating the size distributions actually being produced in practice. Experiment procedures and results The pilot mill used was 44 cm diam x 60 cm long with a volume of 91,250 cm3 and was fitted with six 0.5-in. lifter bars.

Jan 1, 1992

By R. R. Klimpel

The grinding of coal-water slurries has received increasing industrial attention during the last decade. In particular, there is long-term interest in the use of pulverized coal-water slurries to replace oil in combustion equipment and the development of coal gasification/liquefaction processes which require coal-water slurries as feed. More specifically, the use of coal-water slurries in gasification requires grinding a high density slurry containing the smallest amount of water consistent with slurry pumping and spraying. As part of a fundamental engineering research support program aimed at the industrial implementation of dense coal-water slurry grinding, this author has published several papers on how specific rates of breakage vary as a function of slurry rheology, Klimpel (1982, 1982/83). These papers demonstrated that there is a consistent pattern of change in specific rates of breakage of coal in dense slurries with controlled variations in slurry rheology. By matching rheological data with laboratory grinding results, it was possible to identify directly slurry conditions that correspond to: (1) slowing down of breakage rates, (2) the occasional acceleration of breakage of some sizes, and (3) conditions where chemical additives will increase rates of breakage.

Jan 1, 1990

A slag-metal equilibrium study of the system SnO-FeO-(Si02+Al2O3)/Sn-Fe was carried out at 1250°C. The distribution coefficient, k =(Sn/Fe)metal X (Fe/Sn)slag was found to range from 246 for an iron contentof 0·53 per cenrt in the metal to 82 for an iron content of 6·4 per cent. The value of the ratio ?SnO/?FeO was calculated and found to be approximately a function of per cent SnO in slag alone in the region (Si02+Al2O3)/ FeO = 0·4 to 1·2. Comparison with other published work suggests that the addition of CaO to slags having (SiO2+Al203)/FeO ratios of about 1·1 raises the value of ?SnO/?FeO...

Jan 1, 1974

By R. J. Good

It is well known that the elimination of impurities such as iron pyrite, shale, clay, silica, etc., from coal, by floatation [Sun, 1954; Aplan, 1983] and selective oil agglomeration [Keller and Burry; 1990] depends on the fact that coal is hydrophobic, and the impurities are hydrophilic. The water contact angle has long been used to evaluate the hydrophobic nature of coal, first by Brady and Gauger (1940), who demonstrated that the contact angle of water on coals increases with rank, and passes through a maximum at about 88% carbon. Brown (1962) found that the contact angle of coal decreased with increasing ash content. Sun, and also Aplan, have reported a direct relationship between values of the contact angle and rank, and have related the contact angle to coal floatability. Horsley and Smith (1951) first demonstrated that the captive bubble contact angle may be used to characterize the hydrophobicity of a coal containing more than 80% carbon DAF, while Parekh and Aplan (1978) have shown that the sessile-drop technique may be used to evaluate the hydrophobicity of coal of any rank.

Jan 1, 1992

By A. Demirci, A. Keçeciler, Y. S. Durutürk

"This paper deals with the results of the variation of thermal conductivity of rocks with pressure on a laboratory scale. For this purpose, the authors have added a pressure-supplying unit to the apparatus developed by Mousset-Jones and McPherson (1986), Önder (1995), Ashworth and Ashworth (1979), and Innaurato and Occella (1989) in order to measure the thermal conductivity under pressure. The values obtained from the tests performed by this new apparatus have been stated using a regression analysis and the related graphs have been drawn. Results have shown that the thermal conductivity of rock varies digressively with pressure. The same results have been obtained in different rocks types. IntroductionOne of the most important tasks of mining engineers is that of establishing, maintaining and sustaining safe and healthy working conditions in underground mines.Heat can have a profound effect on safe and healthy working conditions and is one of the main problems in deep underground mines. In this regard, the temperature of the air passing through the mine openings increases steadily and causes a decrease in the efficiency of workers due to the unwanted physical effects to human bodies in the working area. At the same time, the hot and humid environment resulting from heat and temperature rise causes some important occupational diseases and increases the accident risks in the related openings."

Jan 1, 2002

By Kametani H

Since pyrite is a semiconductor, the relationship between the leaching rate and the semiconducting properties is of interest. In order to investigate this relationship, a pyrite concentrate (95% FeS2) was oxidized at 90¦C (363 K) in an acid solution containing 100 g/dm3 H2SO4 and 1.0 to 25.1 g/dm3 total Fe. The suspension potential (Pt vs. SCE) was maintained at the desired values, within the range 0.40 to 0.70 V, by controlled additions of a KMn04 solution during leaching. The results were analyzed using a simplified kinetic expression. The rate constant was independent of the Fe concentration, while it increased with suspension potential. Partly oxidized samples were then prepared at varying fractions of reaction. After removing the elemental sulphur formed, they underwent thermoelectric power measurements using a packed bed lying in a temperature gradient. The value of thermo- electric power increased from about 0 to 30 pV/K in the early stages of oxidation. The results obtained are compared with those for chalco- pyrite reported in a previous paper.

Jan 1, 1987

By Crook KAW

New sedimentological and biostratigraphic data indicate that the Leron Formation in the Markham Suture Zone, Papua New Guinea (PNG) represented Pleist- ocene alluvial fan-delta deposition in shallow marine to lacustrine environments. The distribution of sedimentary regimes in the Leron Formation indicates that during collision zone evolution, various tectono-sedimentary regimes do not always track the movement of the triple-junction systematically as idealized by Crook's (1989a) model. The migration of various tectono-sedimentary regimes are also controlled and influenced by the effects of second-order geometric features of the convergent margins. Leron Formation in the Markham Valley represents late to post-collisional marine to fluvial molasse. Foraminifera indicate that the collision and concomitant suturing of the Markham valley occurred after 1.32Ma.

Jan 1, 1991

Little knowledge is available that considers the effects of continuous miner position on the possible respirable dust exposure of the remote mining machine operator. Such information could be very useful for increasing the awareness of the remote operator as to those parts of an extended cut that generate higher levels of respirable dust. This data could be used to develop guidelines for positioning the remote operator to reduce his potential exposure. This work details the effects of continuous miner position on dust levels measured on the machine and at the remote continuous miner operator location.

Jan 1, 1998

By Ogden Malin

IN conducting the manufacture of extruded brass rods and brass forgings it has been noticed that there is considerable variation in the physical properties, particularly the machinability of different rods and forgings, even though the composition, working temperatures and method of manufacture remain the same. It is the purpose of this paper to attempt to establish the cause and extent of this variation, and also to determine whether variations in composition within certain defined limits influence hardness and machinability to any marked degree. The writer believes that this variation probably is due to the variation in grain size of the metal, therefore the microstructure of several compositions under various conditions of working were examined in an effort to establish this as a fact.

Jan 1, 1932

By Kristen E. Coose

Concrete is a mixture of a fine aggregate (sand), a coarse aggregate (gravel), cement, and water. Cement itself is the most expensive of the ingredients but generally amounts to only about 10% of the concrete mixture. Cement raw materials include calcium, alumina, iron oxide, silica, and gypsum. They are heated and chemically changed into clinker "minerals," which are then ground and shipped as cement. Each of the four main clinker minerals-tricalcium silicate, dicalcium silicate, tricalcium aluminate, and tetracalcium aluminoferrite-impart specific strength and compositional properties to the final concrete product. During hydration of the cement, chemical changes produce new minerals that include calcium silicate hydrate gel (C-S-H, the main constituent of hydrated cement paste), calcium hydroxide, and calcium, sodium, potassium, and sulfate ions, among others. Two main reactions can occur that may be deleterious to concrete. Normal cement pore solutions, in a hydrated cement, contain sodium hydroxide and potassium hydroxide. If these alkali concentrations are too high, they can react with the siliceous aggregate (alkali-silica reaction, or ASR) to form an alkali-rich calcium silicate hydrate gel (C-N+K-S-H), which, upon prolonged contact with water, can expand to crack the concrete. The other deleterious reaction occurs when the mineral ettringite (Ca6A12(S04)3OH12. 26H20) forms after the concrete is hardened (delayed ettringite formation) and cracks the concrete. Many of the concrete bridges and structures built in New Mexico in the past 20 years are in need of replacement due to deterioration. Many others constructed very early on in the century are still sound. By collecting and analyzing samples of both old and new concrete and good and bad concrete, we compared their differences on both a microscopic and macroscopic scale. Samples taken from concrete sidewalks, parking lots, drainage canals, spillways, and a railroad-trestle foundation have construction dates that range from 1923 to 1997. They were analyzed by electron microprobe and by petrographic microscopy. Cracks, air voids, and aggregate alteration were primary locations for investigation and analysis. Using the electron microprobe, ettringite was found in voids of most of the samples, both in good and bad concrete. This leads us to believe that ettringite formation is not causing distress in the concrete. There was one exception in which ettringite was found lining a crack. In this instance, ettringite may have the ability to further the cracking and cause distress. No alkali-silica gel was identified with the microprobe. Using the petrographic microscope in cross-polarized light, a light-brown material was observed that lined some of the air voids and cracks; however, exact mineralogic identifications were not made. Although many instances of chalcedony and other deleterious quartz phases were found, no clear evidence of ASR-gel deterioration was present in our samples using these methods. However, positive identification of the ASR gel was made on an in-place concrete near one of our sample sites and in several sample cores using a newly developed chemical test for the soluble potassium ions associated with the gel. The chemical used in this test is sodium cobaltinitrite, Na3Co(NO2)6.

Jan 1, 1999

By J. D. Appleton, J. Ridgway, K. B. Greally

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The results suggest that meaningful geochemical maps can be produced from very low-density surveys, and that existing data sets could perhaps be incorporated into such a map series with the use of a system such as Uniras software. There are still many problems to be resolved, however, including the compatibility of data derived from different analytical methods, and the precise methods to be employed will necessarily require international agreement. Sampling densities should be chosen on the basis of the scale of the geochemical and geological features to be distinguished and will vary from region to region. Reanalysis of selected samples from archives to increase the range of elements determined or to unify analytical methods is only likely to be effective if the original survey was at quite a low density

Jul 1, 1991

By W. P. Campbell

THE investigation herein described had its beginning in the chemical laboratory of the Department of the Interior, Calgary. After the transfer of the natural resources to the Province of Alberta in 1930, the laboratory was closed and the investigation discontinued, but in 1933, with the permission of the Director of the Mines Branch, the work was again taken up and brought to completion. OBJECT OF THE INVESTIGATION The object of the investigation as originally planned may be stated as follows : (1) To determine the chemical composition of the limestone formation underlying Turner Valley gas field. (2) To identify 'beds' in the limestone, if such existed, with definitecharacteristics which would mark them from immediately overlying and underlying measures. (3) To relate information acquired on the composition of the limestone to the occurrence of oil and gas in the particular section examined. Definite information was lacking as to the exact chemical composition of the limestone and of its variations in composition at various depths. The formation was generally referred to in the field as the 'dolomitic' limestone, but the depth to which the dolomitized zone extended and the degree to which the limestone generally had become dolomitized were not known. Jn the drilling and logging of wells, the recognition of suitable 'markers' in the various formations is a matter of some importance. Markers are generally relatively small but widespread members of a formation, which have some characteristic property, of colour, composition, or form, by which they may be identified, and with them, consequently, the formation of which they form a part. In the formations above the limestone in Turner Valley, a number of well defined and easily recognized markers are known to geologists, drillers, and others interested in the field. Many of these markers Hand out in sharp contrast to adjoining measures and are therefore easily recognized; in others, the contrast is less sharp, with consequent difficulty in identification.

Jan 1, 1937

In exploiting the ultra-deep, narrow reef ore bodies of the Witwatersrand, the ventilation and cooling systems within the stopes play a critical role because of high concentrations of active workers. This paper examines the heat, ventilation and cooling effects of a number of different stoping layouts for narrow reef mining in ultra-deep operations in very hot rock. The stope ventilation and cooling needs are driven primarily by the difference between the air temperature and that of the rock front being excavated. These needs depend on the face utilization, geometry, face advance (rate and direction), layout, backfill, use of water and machinery1,2,3. Detailed studies of different stoping configurations have been undertaken for mining operations extending to depths of 5000m below surface, where virgin rock temperatures approach 70°C. Extensive work has been completed with regard to evaluating ventilation and cooling requirements to maintain air reject temperatures of 28°C wet-bulb and better. This knowledge is being used to determine overall cooling requirements, reduce operational costs and maximize the efficiency of cooling systems. These issues are important when considering both the local and regional air conditioning systems and the most effective application of in-stope chilled water.

Jan 1, 2001

By Rob Farnfield, Yuill Gavin

The rock blasting industry continues to be under pressure to reduce the level of vibration induced by the use of explosives. In recent years much research and development has been directed to minimizing vibration levels by controlling the delay period between blast holes. The most commonly applied technique is known as Linear Superposition. This technique takes the vibration produced from a single-hole test shot and simulates the vibration that would be produced from a full-scale production blast. The simulation can be run with various delay periods and the optimum delay chosen. The success of the Linear Superposition technique depends to a great extent on having accurate delay detonators and on the single-hole test shot reliably indicating the vibration signal produced from each hole in a production blast. A quarry-based case study is given illustrating how these assumptions are not always valid. In this case the use of electronic detonators has controlled frequency but not vibration level. The paper goes on to describe a series of single-hole test shots in an U.K. limestone quarry. The vibration 2 signals recorded are examined in terms of variations in free-face provision, blast geometry, explosive properties, etc.

Jan 1, 2001

By Eldon C. Pattee

Variations of a very reliable geochemical field test for beryllium developed by Patten and Ward, have been adapted by the U.S. Bureau of Mines to facilitate rapid testing of reconnaissance samples and to aid in rapid examination of known occurrences. Although several qualitative tests for detecting beryllium have been described in the literature,1,2,3, the Patten-Ward4 morin geochemical field method has the advantages of being rapid and being quantitative for minute amounts of beryllium. In addition to the morin field method, Patten, in cooperation with Griffitts, have developed a contact- print method for determining beryllium in hand specimens.5 The semiquantitative method can be used for rapid screening of samples in exploration or reconnaissance work. The use of beads for fusing samples provides a more rapid test, but gives less accurate results than the method developed by Patten and Ward. The semiquantitative method, however, requires less equipment and combines three stock solutions into one reagent for easy application. Estimates of samples in the range from 3 to 1000 ppm varied from about 0.25 to 5 times the actual beryllium content.

Jan 5, 1965