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J. W. RICHARDS*(South Bethlehem; Pa.).-The brass industry would find it very profitable to subsidize researches on the purely scientific determination of the thermophysical properties of the brasses. The data we need most in connection with the brasses are the vapor tension of the zinc from the brasses at different temperatures, the heat of combination of zinc With copper to form different kinds of brasses, and the latent heat of fusion of these brasses at the melting temperature.

Jan 1, 1919

By Behram H. Wadia

El presente estudio describe el proceso de volitización de plata-plomo y otros valores metálicos como cloruros en la Cerro de Pasco Corporation. La aplicación de este procedimiento busca recuperar metales como la plata y el oro, así como los metales menores: bismuto, cadmio, teluro, etc., los cuales se perciben en los humos, producto de la volatización de los valores metálicos. En este sentido, el proceso de volatilización de plata y plomo como cloruros aplicado en altas temperatura, es metalúrgicamente fac¡tible, ya que logra una eficacia de plata entre 80 y 84% y no menos de 95% de plomo. Asimismo, el uso de la cama fluidizada como reactor usado en la experimentación, es el más conveniente dado que se puede obtener mayor concentración de valores en los productos de condensación de los cloruros volatilizados.

Nov 20, 1967

By Qian Li, Li-chen Hou, Yong-bin Yang, Tao Jiang, Jian-jun Hu, Bing Xu

Extraction of gold from refractory gold concentrates usually requires an oxidation step to remove arsenides、sulphides and carbonaceous matter. In this investigation, the gold concentrates were two-stage roasted under different atmospheres and temperatures. Results indicated that at the first stage, under neutral atmosphere, the removal rate of arsenic increases as the temperature rises. Under the oxidizing atmosphere, with the increase of temperature, arsenic content in the residued calcine increases, in addition, the volatilization of arsenic is also affected by the oxidation of carbon that generated CO, which is advantageous to the decomposition of arsenate decomposition. At the second stage of roasting, it is the higher temperature and stronger oxidizing atmosphere, the faster sulfur and carbon oxidated rate is, but at the same time, the calcine appears the phenomenon of consolidation because of the phase of silicate compounds generate.

Jan 1, 2015

By Ho-Sang Sohn

Copper concentrate particles of 200 to 300 mesh size were fed from the top of vertical reaction tube of 2.8 cm ID and 2 m long with an O2-N2 gas mixture. The reaction tube was heated to 900 K to 1100 K. The residence time of the particles in the reaction tube was about 1 second. The copper concentrate particles were very rapidly oxidized and melted down during their descent in the reaction tube. The particle temperature were calculated by combining an un-reacted core model, mass transfer between gas and particles, and heat transfer between gas, particles and tube wall. The particle temperature reached its maximum within a distance of 60 cm from the top of reaction tube, and it attained at 2000 K at higher oxygen partial pressure. The most particles were melted at the oxygen partial pressure above 20 kPa. An appreciable amount of As, Sb and Pb in the concentrate particles was eliminated in the upper portion of the reaction tube and the rate of elimination are explained by the rate of mass transfer of volatilized species through the gas film on the particle surface and the variation of particle temperature during the descent.

Jan 1, 2006

By K. Sugawaral, W. Tongampl, K. Hiruta, Takasaki Y., A. Hosoi, T. Katol, A. Shibayamal

Printed circuit boards of discarded personal computers, televisions, mobile phones and so on contain a significant amount of valuable metals. For the recycle of valuable metals contained in the printed circuit board wastes (P CB W), the effect of temperature on chlorination-volatilization of metals under chlorine gas flow was studied. The experimental sample used was powder of two types: crushed PCBW (Sample 1) made from PC and industrial machines, and crushed-combusted PCBW (Sample 2) made from Sample 1. The principal element in Sample 1 and Sample 2 was copper, about 13 wt% and 20 wt% respectively. Sample 1 was composed of pure metals such as copper, tin and lead. In comparison, Sample 2 consisted of oxide metals such as copper oxide, tin dioxide and silicon dioxide. The two samples were heated at predefined temperatures (ranging from 300 °C to 900 °C) in chlorine gas. The chlorine gas flow into the furnace was set at a rate of 100 mL/min. As a result, copper in Sample 1 began to volatilize at 600 °C and completely vaporized at 700 °C. While in Sample 2, copper started to volatilize at 600 °C and reached 100% vaporization at 800 °C. For Sample 1, zinc finished volatilizing at 500 °C, while for Sample 2, zinc volatilization reached only about 80% (maximum). Also, lead, nickel and titanium showed similar results. Consequently the volatilization rate of Sample 1 is higher than Sample 2 and the temperature dependency was verified for copper, lead, zinc, nickel, antimony, titanium and chromium. In fact, the volatilization rate of these metals increased with the temperature. This result reflects the difference between pure metal and metal oxide, as Sample 2 was combusted before the chlorination-volatilization test. Moreover, the chlorination reaction may be accelerated by a reductive atmosphere because Sample 1 contains carbon. In this study, the volatilization behavior of some valuable metals in PCBW by chlorine gas was observed. Further improvement in the rate of volatilization can be achieved by optimizing the experimental conditions.

Jan 1, 2011

By Xu Zhong

The theoretical limit to smelting rate and possibly the size of a smelter is dependent on the rate of heat transfer, and the chemical kinetics of both sulfur removal and minor element volatilization. The fundamental kinetics of volatilization of minor elements such as As, Sb, Bi, and Pb from matte and white metal is being investigated. It has been shown that the molecular form of trace elements in matte depends on the chemical potential of sulfur and the propensity for the minor element to form a sulfide. The impact of the variable molecular form of the minor elements on the volatilization kinetics is unknown and is under investigation in this study. The experimental technique is reviewed and preliminary results are reported in this manuscript.

Jan 1, 1995

By S. Skowronski

PURPOSE OF INVESTIGATION Since cuprous chloride melts at 418° C., boils at 954° C. to 1033° C.,1 and is known to be volatile at a much lower temperature, the presence of chlorine in any form in or on copper to be melted has always been looked upon by copper refiners as a possible source of-serious copper loss. Although this fact has been known for some time, the copper literature contains little or no information regarding it and the field seems .never to have been properly investigated from a metallurgical standpoint. According to Greenawalt,2 cupric chloride, CuCl2, when ignited gives cuprous chloride; therefore cuprous chloride is always formed when copper enters into reaction with chlorine at a high temperature. Cuprous chloride melts somewhat below a dull red heat, and does not volatilize in closed vessels, even if strongly heated, but if heated in the air it goes off as a white vapor. Hofman3 gives the melting point of cuprous chloride

Jan 2, 1919

By Linfeng Zhou, Yuanbo Zhang, Rong Sun, Guanghui Li, Zhiwei Peng

The volatilization behavior of rhenium in the process of oxidative roasting of a molybdenite concentrate with 43.55 wt.% Mo and 321 g/t Re is explored based on identifying the relationship between volatilization of sulfur and rhenium. The results show that rhenium volatizes after sulfur and precise control of operating variables plays an important role in separating rhenium from molybdenite concentrate. When the roasting parameters are optimized as follows: roasting temperature 600 oC, roasting time 2 h, roasting atmosphere air, the volatilization rate of rhenium reaches 89.26%. In the process of solidification roasting, the volatilization rate of rhenium decreased almost to zero when the ratio of slaked lime/molybdenum concentrate was 10% excess to the stoichiometric requirement at 600 oC for 2 h.

Jan 1, 2016

By Edgar Peek

Lixiviant regeneration is by definition a precondition for any hydrometallurgical process. In chloride hydrometallurgy either HCl or Cl2 has to be regenerated in order to establish an economically viable metallurgical process. One such regeneration process is widely used with steel pickling where HC1 is regenerated through the thermal decomposition of ferrous chloride in either spray roasters or fluid bed pyrohydrolyzers. This standard HC1 regeneration process deserves to be considered as a potential separation process, since thermodynamic calculations show that a fluid bed pyrohydrolyzer can function as a ferrous-nonferrous separator. Several nonferrous,metals such as zinc, lead and cadmium can be volatilized as a chloride under ferrous chloride pyrohydrolysis conditions. If such a nonferrous metal volatilization could be achieved in the case of slurry feeding of "contaminated" iron oxides, then this would increase the Fe/H2O ratio of the (process) feed and thus save on fuel per ton of iron, while yielding a marketable iron oxide product. Previous test work on synthetic materials revealed that the near-complete separation of zinc, lead and cadmium from iron oxide was possible in a pyrohydrolytic atmosphere, even if zinc was present as zinc ferrite (more than 99.5%). This investigation, which was carried out in a tube furnace at 1100 K has now been extended to treat synthetic zinc minerals and also franklinite ore. For the latter, it was found that 85% zinc volatilization could be achieved in 4 hours at 1300 K. It is postulated that complete zinc volatilization could not be attained due to the formation and/or presence of gahnite and hardystonite, which might be stable in HCl/H2O atmospheres at 1100 K. The effect of adding small amounts of calcium chloride to react with gahnite and hardystonite to give zinc chloride and both calcium aluminates and silicates is being discussed. Test work on slurry feeding of this complex ore in a recently constructed 4-inch diameter fluid bed pilot unit has been planned for the near future.

Jan 1, 1995

By Finlayson EJ

Epithermal gold is hosted by late Middle Miocene Okiduse Volcanics on Woodlark Island. Dating of associated alteration minerals indicate mineralisation to be broadly contemporaneous with volcanism (12.2 - 12.5 m.y.) and is probably related to subduction of the Solomon Sea plate along the Trobriand Trench. Mineralisation is polymetallic and structurally controlled. Pyrite, sphalerite, galena and minor chalcopyrite occur in steeply dipping fracture zones and/or hydrothermal breccia bodies associated with mixed clay-pyrite alteration envelopes. These envelopes occur within a terrane of regionally propylitised high-K, calc-alkaline andesites and related epizonal subvolcanics. Gangue minerals include quartz, calcite, dolomite and minor anhydrite. High level advanced argillic alteration and siliceous cap rocks are not present but may have been eroded off the top of the system. Fluid inclusion and stable isotope data suggest that the carbonates and paragenetically associated auriferous base metal sulphides probably deposited from an isotopically evolved (+8%. 180) reduced hydrothermal fluid sourced from underlying sedimentary rocks. The fluid was predominantly of low salinity (0-4 wt % NaCl equivalent) and had a temperature of about 270¦C at the time of boiling and mineral deposition.

Jan 1, 1987

By C J. N Wilson

The central Taupo Volcanic Zone is a region of intense Quaternary silicic volcanism accompanying rapid crustal extension. Modem central TVZ is the most frequently active and productive silicic volcanic system on Earth, erupting rhyolite at c.0.28 m3 s-1. The rhyolites show no major compositional changes with time, but the total extent of magma chamber zonation has changed with the advent of rifting and crustal extension at c.0.7 Ma. At least 34 caldera-forming ignimbrite eruptions have formed a complex sequence of relatively short-lived, nested and/or overlapping volcanic centres in central TVZ. Taupo contrasts with other large silicic magmatic systems in the exceptionally high frequency, but small size, of caldera forming eruptions. This contrast reflects the thin, rifted nature of the TVZ crust that precludes the development of long term magmatic cycles at Taupo. Within central TVZ, non-rhyolitic compositions have been erupted apparently irregularly in time and space; in particular there is no evidence for a geographic separation of basalts from andesites. TVZ is a rifted arc, but its segmented nature, high thermal flux and voluminous rhyolitic volcanism make it unique on Earth.

Jan 1, 1995

By Wilson CJN

The central Taupo Volcanic Zone is a region of intense Quaternary silicic volcanism accompanying rapid crustal extension. Modem central TVZ is the most frequently active and productive silicic volcanic system on Earth, erupting rhyolite at c. 0.28 m' s'. The rhyolites show no major compositional changes with time, but the total extent of magma chamber zonation has changed with the advent of rifting and crustal extension at c.0.7 Ma. At least 34 caldera-forming ignimbrite eruptions have formed a complex sequence of relatively short-lived, nested and/or overlapping volcanic centres in central TVZ. Taupo contrasts with other large silicic magmatic systems in the exceptionally high frequency, but small size, of caldera- forming eruptions. This contrast reflects the thin, rifted nature of the TVZ crust, that precludes the development of long- term magmatic cycles at Taupo.Within central TVZ, non-rhyolitic compositions have been erupted apparently irregularly in time and space; in particular there is no evidence for a geographic separation of basalts from andesites. TVZ is a rifted arc, but its segmented nature, high thermal flux and voluminous rhyolitic volcanism make it unique on Earth.

Jan 1, 1995

By Alan J. Wianwright

Introduction ??New world-class Upper Devonian porphyry Cu-Au system located in south Mongolia ??6.5 km NNE-trending mineralized corridor ? 4 discrete deposits ??Southern Oyu deposits: Chalcopyrite, deposits: bornite ??Hugo Dummett: Zone: Hypogene chalcocite in addition to chalcopyrite and bornite ??Total resource exceeds ~2 Gt@ >1% Cu, >0.25 g/t Au (0.6% Cu equivalent cut-off) (Ivanhoe Mines press release, 2005)

May 1, 2006

By A. F. Banfield

"IntroductionELEMENTAL sulphur occurs in three types of deposits: in salt domes in the Gulf Coast region of the United States and Mexico, from which over 90 per cent of world native-sulphur production is obtained; in sedimentary deposits such as those in Sicily, which are thought by some authorities to contain the largest world reserves of elemental sulphur; and as surface deposits, associated now or in the past with some phase of vulcanism, the type which bas the greatest world-wide distribution.Deposits of the volcanic type are the subject of this paper.From antiquity until the successful development of the sulphur-bearing salt domes at the beginning of this century, important sulphur production for local needs was obtained from volcanic deposits in many parts of the world. Due to technical and economic factors, however, producers could not compete in price with sulphur from salt domes. •The result has been that, except in Japan and Chile, little sulphur was produced from volcanic deposits from about 1910 until the start of the Korean war in 1950. Shortly after the outbreak of the Korean war, an acute world sulphur shortage developed and prices skyrocketed in many countries up to several hundred dollars a ton. Interest in volcanic deposits was renewed and exploitation of many was undertaken. Few of these operations have been successful, mostly due to inability of management to solve technical problems.While important volcanic deposits of elemental sulphur have not been reported ( 1) in Canada, and it is doubtful that any will be found, data presented in this paper may be of interest to students of ore genesis.This paper is based on field examination of numerous deposits of the volcanic type in North and South America."

Jan 1, 1954

By John Drew Ridge

Recent work by Haas has made available information on densities and vapor pressures of solutions of differing salinities at temperatures up to 330°C. From these data it is possible to predict the behavior of volcanic exhalations of various degrees of salinity as they approach the sea floor. Particular attention is devoted to solutions of 5.0 weight per cent NaCl and 20 weight per cent NaCl, two fluids that approximate quite closely the salinities of what Roedder termed: (1) normal hydrothermal fluids and (2) fluids typical of stratiform deposits of low-temperature conditions of origin. It is apparent that solutions above 220-230°C. cannot reach a sea floor on which the depth of water is 600 feet or less in the liquid state but will boil at some appreciable depth beneath the sea floor. Such boiling would result in the precipitation of all constituents of the ore fluids of significantly lower vapor pressure than water. The principal such constituent would be salt, and no sulfide deposits, the major constituent of which is salt are known. It follows, therefore, that ore fluids probably never get close to the sea floor of shallow seas at temperatures high enough to permit boiling. Ore fluids significantly above 230°C. can reach the sea floor in the fluid state only if the depth of the sea in the area. in question is well above 600 feet, for example, solutions at temperatures of ±300°C. reach the sea floor in the liquid state only if the depth of sea water is slightly over 3000 feet. Ore fluids reaching the sea floor at such depths may be the parents of such fluids as the Red and Salton Sea brines. On the basis of these data, the Cyprus and Kuroko deposits are discussed.

Jan 1, 1973

By Marie-France Caille, Carl Caumartin

"Audrey Resources' Mobrun Mine is located in Dufresnoy Township some 30 km to the northeast of Rouyn-Noranda. The Mobrun tine deposits consist of two major massive sulphide lenses; the newly discovered 1100 lens located 450 m south of the Main zone, and one ntellite lens, the 850-870-930 complex.The 1100 lens is hosted in a large pyroclastic unit bounded to the mouth by rhyolite and andesite flows and by a thick rhyolite unit to the art h. stratigraphically belon the three lenses. It consists of approximately 15 Mt of massive sulphide, of which 10.4 Mt are of economic ade. The Main lens lies comformably above thick rhyolite flows, ecciated and pyritized by the sulphide horizon, and is overlain by ttercalated ash tuffs and rhyolites which host the over-lying satellite ns. The Main lens consists of 3,3 Mt of massive sulphide, of which 523 000 tgrade0.80% Cu, 2.44%Zn,30.19 g/t Ag, and2.2 g/t Au he richer satellite lens (180 000 t) is part of the same volcanic stem and resulted from a resurgence of hydrothermal activity. ructure played a role in the final geometry of the deposits but did not eatly affect the volcanogenic and stratabound nature of the lens. Total production since the start of operations in 1985 amounts to 58 000 t and is restricted to the Main lens. Production from the 100 will come onstream in 1992 as ore reserves from the Main and e satellite lenses are exhausted.RESUMELa Mine Mobrun de Ressources Audrey inc. est située dans le mton Dufresnoy, a quelque 30 km au nord-est de Rouyn-Noranda. lle comprend deux lentilles de sulfures massifs d’importance majeure ~i sont les lentilles 1100 et Principale, et une lentille satellite qui est complexe 850-870-930.La lentille 1100, la plus ancienne, est contenue dans une épaisse 1ite pyroclastique bordée, au sud, par des coulées de rhyolite et d’andésites, au nord, par une épaisse unité rhyolitique. Cette lentille contient environ 15 Mt de sulfures massifs dont 10,4 Mt à teneur économique. La lentille Principale repose sur d’épaisses coulées rhyolitiques brechifiees et pyritisees à proximité de l’horizon de sulfures; elle est recouverte de tufs a cendres et de rhyolites interlitees qui contiennent la lentille satellite. La lentille Principale est constitute de 3,3 M t de sulfures massifs dont 1 523 000 t sont économiques avec une teneur moyenne de 0,80% Cu, 2,44% Zn, 30,19 g/t Ag, et 2,2 glt Au. Faisant partie de ce second épisode volcanique, la riche lentille satellite (180 000 t) temoigne d’une recrudescence de l’activité hydrothermale. La structure joue un rôle important dans la géométrie finale des dépôts mais ellen' affecte pas, de fa~on significative, la nature volcan génique des lentilles. Depuis le début des opérations, en 1985, la production totale est d’environ 568 000 t, provenant essentiellement de la lentille Principale. La mise en production de la lentille 1100 est prévue pour 1992, alors que les réserves des lentilles Principale et Satellite seront probablement épuisés."

Jan 1, 1990

By P G. Rutherford, A W. McOnie

A volcanic sequence is described from the Golden Cross Mine, Waihi, New Zealand. The sequence includes seven lithostratigraphic units comprising flow and pyroclastic units of Coromandel Group andesite and dacite and overlying Whitianga Group dacite and rhyolite which is intruded by the Golden Cross dacite porphyry and rhyolite dykes. The sequence is mineralised and is unconformably overlain by two post-mineral units, the lacustrine Waitekauri beds and Omahine Subgroup andesite.   Detailed structural analysis of mine data has identified four deformational events (D 1-D4) and related these to the gold-silver mineralising events. Faulting was coeval with the mineralization and directly controlled the development, localisation, style and geometry of the ore shoots. Mineralization developed in competent lithologies where dilation occurred during faulting. The Empire Fault is the master shear which controlled fluid flow. Mineralised veining developed in response to tectonic pulses occurring at slightly different stages as represented by the underground Empire vein complex and the open pit vein array. The mineralising events culminated with the deposition of barren calcite veins. Post-mineral movement along the Western Boundary fault appears to have offset the orebody.

Jan 1, 1995

By John B. Hastings

THE origin of the watery vapors of vulcanism has always been an object of interest and speculation to the seismologist, and as theories of the genetic origin of ore-deposits have of late years been pretty well narrowed down to the expiring forces of plutonic action, the same question has had a lively interest for mining engineers and geologists, as is well shown by the discussions of the subject in our Transactions. The important part taken by volcanic emanations in the origin of pegmatites and quartz-veins, described in my paper, Origin of Pegmatite,1 and their latent power to concentrate into useful deposits such scattered gold as occurs in the Hartsel granite, make a discussion of their derivation but a natural third and final step. It is conceded that enormous amounts of vapor accompany volcanism, though perhaps we are apt to forget that steam has 1,700 times the volume of water, besides which the column seen over Vesuvius and other volcanoes is greatly mixed with air; the immensity of such volumes compared with solids and liquids is shown by the experiment of Gautier, who, by heating dessicated granite to 100° C., evolved from it uses 20 times, and steam 90 times, its own volume. Dana appraised the average amount of water left in ordinary rocks as 2.5 per cent. T. M. Read estimated that the Mississippi river carries to the sea annually 150,000,000 tons of rock material. If these Mississippi sediments, as deposited, contained 20 per cent. of water, it would be 600,000,000 cu. ft., or 4,500,000,000 American gallons, annually. Allowing the vapor suspended over a volcanic cone to be mixed with 80 per cent. of air, this amount of water converted into steam would replenish anew, every 9 min., a column 15,000 ft. high, 2,000 ft. in diameter at the base, and 10,000 ft. at the top. Read's estimate is only half of the amount given in a more recent and probably correct one .2

Jan 5, 1908

The Archean Gossan Hill Group at Golden Grove, Western Australia, hosts two potentially economic volcanogenic massive sulphide deposits. The volcanic-sedimentary succession hosting this mineralisation is composed of a facies association which includes the products of rhyodacitic to,andesitic effusive volcanism, mass-flow sedimentation and concentrated hydrothermal fluid discharge, in a deep subaqueous setting. The Tertiary Kuroko deposits of Japan are widely compared to Archean volcanogenic massive sulphide deposits and a comparison of the facies associations hosting this style of mineralisation, in these two successions separated widely in time, allows a refinement of facies models suitable for exploration in ancient successions. The required deep subaqueous environment for the formation of volcanogenic massive sulphide deposits places constraints on the physical processes that can operate during accumulation of the host stratigraphy. Limitations on the operation of physical processes is reflected by the resultant facies association which can be used to characterize suitable volcanic-sedimentary successions in which volcanogenic massive sulphide mineralisation may be present. The facies association includes: (1) proximal effusive volcanic products - lavas and associated autoclastic breccias (2) distal volcanic products - mass-flow resedimented pyroclastic debris (3) background sedimentation - reworked volcanogenic and terrigenous mass-flow sediments and (4) chemical sediments - exhalites including cherts, sulphides and oxides, with perhaps various carbonates and sulphates. Primary pyroclastic deposits are not expected to be present, other than distal water-lain air-fall deposits, derived from shallow to emergent basin margin explosive volcanic centres, which also provide a source for the resedimented pyroclastic debris.

Jan 1, 1987

Waitemata Tectonic Event(25 Ma ago) created a subduction system from the northeast of Northland, causing: (1) the emplacement of the Northland Allochthon (24-23 Ma) which provided argillaceous limestone and serpentine to Northland, and minor copper to both there and East Cape (located off Northland then); and (2) Northland volcanism (from 22 Ma), which lacked economic mineralisation. The Kiwitahi Tectonic Event (1714 Ma) caused: (1) a realignment of volcanism - from coastal western Northland, to west of the Hauraki Plains (Kiwitahi); (2) a start to the migration southwards from Northland of (a) the Alpine Fault System towards Marlborough today, (b) subduction towards Cook Strait, and (c) volcanism towards Taranaki-to-Bay of Plenty (initially through Coromandel, Kiwitahi, and offshore west coast); and (3) a start to rhyolitic volcanism & associated hydrothermal activity. The latter caused epithermal mineralisation, providing in Coromandel the best known North Island metalliferous deposits. Andesitic volcanism has been active in both of these two contrasting, subequal belts since 22 Ma. Rhyolitic volcanism and hydrothermal activity was wholly restricted to the eastern Marshall Belt, with an abrupt limit to economic mineralisation at the Volcanic Divide (within Hauraki Plains) and a major change there to basaltic volcanism of the western Searle Belt. The Kaimai Tectonic Event (5-1.5 Ma) caused: (1) a temporary reversal in volcanic migration in the Searle Belt, and a duplication of rhyolitic & hydrothermal activity at Waihi (Marshall Belt); (2) the rotational rifting of both the Central Volcanic Region (by 30¦) and the Hauraki Rift (10¦), causing major curvature of the North Island and New Zealand, and the transfer of the offshore subduction system from Coromandel to East Coast; and (3) an effective end to Coromandel mineralisation. Post-Kaimai Volcanism (1.5-0 Ma) included: (1) andesitic volcanism in the Searle Belt, yielding the western coastal titanomagnetite deposits; and (2) andesitic, and rhyolitic & hydrothermal activity in the Marshall Belt - the latter providing geothermal energy, sulphur, and pumice/perlite deposits. Post-Subduction (Intraplate) Volcanism (10-0 Ma) developed in a steadily expanding northwest region of relative tectonic quiescence, as subduction and its volcanism migrated southwards. Intraplate volcanism was predominantly basaltic, providing excellent aggregate; but less common rhyolitic & hydrothermal activity provided geothermal potential and mercury at Ngawha and at Puhipuhi, and halloysitic clays of extreme brightness elsewhere in Northland. This volcanism has reached as far SE as Mayor Island, providing an early New Zealand mineral resource - obsidian.

Jan 1, 1997