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"This research aims at improving the beneficiation of coals and minerals in fine and ultrafine size fractions. A widely used method for upgrading fine and ultrafine particles is froth flotation, which is generally classified into mechanical flotation and column flotation. The present work is focussed on column flotation. A flotation column equipped with a conventional bubble diffuser/sparger was used with oscillatory air supply generated using a fast-switching solenoid valve. The flotation tests were carried out for coal particles and mineral particles, respectively, and a comparison in flotation performance was made between oscillatory air supply and steady air supply. It was found that use of oscillatory air supply with a proper valve switching frequency and on/off time ratio to replace steady air supply could lead to increased recovery of coals or minerals by more than 14 percentage points and substantial reagent cost savings. The improved flotation performance was attributed to enhanced gas dispersion and flow conditions. This research offers a simple new approach to improving the beneficiation of fine coals and minerals with using flotation columns.INTRODUCTIONFroth flotation has been widely used for the separation and concentration of fine coals and minerals by exploiting the difference in their affinity to air bubbles in aqueous medium. Froth flotation is an effective method for beneficiation of coal and mineral particles in a certain size range. It remains difficult to upgrade ultrafine mineral particles. One of the reasons for the ineffective flotation of fine particles is the low probability of bubble-particle collision in the collection zone (i.e., the pulp zone). According to Reay and Ratcliff (1973) and Yoon and Luttrell (1989), the probability of collision is significantly affected by bubble size and particle size, and the collection zone recovery can be increased by decreasing the bubble size."

Jan 1, 2018

By S. K. Nicol

The results of column flotation tests conducted on a bulk sample of ultrafines discarded from the fine coal desliming cyclones at the Riverside coal preparation plant of Theiss Dampier Mitsui Coal Limited are presented. A 9% ash concentrate was obtained from a 51% ash ultrafine feed at 75-80% recovery of combustibles in a single stage of column flotation. From this result it is predicted that installation of column flotation at Riverside would lead to the annual recovery of additional coal worth $US5.1M. The operating conditions for coal and copper column flotation are compared and some differences which may result in a variation in column design are noted.

Jan 1, 1987

By R. Harris, M. Misra

Column flotation technology has a demonstrated potential for recovering clean coal from high-ash waste fines. The effect of different variables such as air flow rate, frother addition, depressant addition, percent solids and particle size on the quality of separation are discussed. Results indicate that air flow rate and depressant addition are the important variables which control the selectivity in the flotation of fine coal in a column cell. Separation efficiency achieved with column cells is significantly better than that with conventional flotation cells. Under appropriate experimental conditions with a deep column, more than 80 percent coal can be recovered in the concentrate containing 10 percent ash from waste fines containing over 60 percent ash.

Jan 1, 1988

By Felicia F. Peng

Two modes of collector addition techniques are applied in the column flotation for cleaning ultra fine coal. The collector can be: 1) added directly into the coal slurry through the feed system; and 2) gasified collector and transported in the gas phase through the bubbles. Operating parameters of the column flotation were investigated through three phases of work plans for Pittsburgh No.8 seam coal. In present study, the column flotation using two modes of collector addition techniques were tested and compared. Ninety percent or higher combustible recovery can be achieved by using both methods. However, utilizing the gasified collector addition technique in column flotation has more potential than direct liquid addition technique to obtain the higher recovery at same collector dosage.

Jan 1, 1993

By R. Sharma, S. Svoronos, S. Gupta, N. A. Abdel-Khalek

This paper presents the results of column flotation of a fine feed sample of Florida phosphate. A central composite design is used to study the main and interaction effects of parameters affecting column efficiency. The statistical design is also used to determine the optimum conditions. The results indicate that, depending on the experimental conditions, it is possible to achieve a concentrate of high grade and recovery. A concentration of 15 ppm of non-ionic frother is found to be enough to maximize the recovery at the pH of 9.5.

Jan 1, 1999

This paper presents the results of column flotation of a fine feed sample of Florida phosphate. A central composite design is used to study the main and interaction effects of parameters affecting column efficiency. The statistical design is also used to determine the optimum conditions. The results indicate that, depending on the experimental conditions, it is possible to achieve a concentrate of high grade and recovery. A concentration of 15 ppm of non-ionic frother is found to be enough to maximize the recovery at the pH of 9.5.

Jan 1, 1999

By H Thanasekaran, L Christodoulou, J Kohmuench

"Column flotation has been successfully applied to iron ore concentration since the 1980s with the goal of reducing silica content and allowing for the efficient production of pellet feed. Since then, columns have been widely used in iron ore processing due to: their lower capital and operational costs when compared to conventional cells their ability to generate higher concentrate grades and recoveries.Currently, more than 100 columns have been installed within Brazilian iron ore processing circuits for rougher, cleaner and scavenger duties. Despite it being a well-established approach, several technological advances have improved column design, accessories and performance. This work presents the performance of some iron ore columns in Brazil and the recent technological developments.CITATION:Thanasekaran, H, Kohmuench, J and Christodoulou, L, 2013. Column flotation of iron ore - status and advances, in Proceedings Iron Ore 2013, pp 479-484 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

By J. D. McKay

The Bureau of Mines devised a column flotation technique using either fine or coarse bubbles and compared it with conventional flotation on a Montana chromite ore. On deslimed ore, fine-bubble column flotation produced a 44.7-pct-Cr203-grade rougher concentrate with 87-pct recovery, compared with 43.8- and 43.5-pct-Cr203-grade rougher concentrates with 85- and 77-pct recovery for coarse-bubble column flotation and conventional flotation, respectively. On undeslimed ore, coarse-and fine-bubble column flotation produced rougher concentrates containing approximately 41.5-pct-Cr203 with 95-pct recovery, exceeding conventional flotation which produced 35.6-pct-Cr203-grade concentrates with 87-pct recovery.

Jan 1, 1985

By D. P. Patil, T. C. Rao, J. P. Barnwal

Factorial design of column flotation experiments was used to understand the main and interactional effects of the column parameters. In the experiments, the air flog rate, the wash-water, flow rate and the froth depth were varied at two levels. Analysis of the results showed that an increase in airflow rate had a deleterious effect on the grade of the concentrate, whereas, an increase in froth height increased the grade. The interactions between airflow and wash water and between airflow and froth height were significant with respect to grade of the concentrate. These results demonstrated that, from an ore containing 12.76% P2O5, it is possible in a single-stage flotation column to obtain a concentrate containing 31 % P2O5 (10.6% Si02) with a recovery of 94%, thus reducing the number of cleaning stages that would be required if conventional flotation cells were used.

Jan 1, 1997

By C. N. Bensley, S. K. Nicol, R. Lamb, G. W. Kidd

Flotation circuits in the metalliferous industry recover high value concentrates from very fine (minus 0.lmm), low grade, slow-floating feeds. Flotation columns acting as final cleaners within these circuits offer the benefits of higher grade concentrates, reduced circuit complexity, improved control and reduced power consumption. By contrast, in the coal industry, these benefits have not been realised, principally because columns are not well suited to the treatment of conventional coal flotation feeds (minus 0.5m). However, this does not imply that columns do not have a place within the coal industry, rather that they must be applied in a role where all the unique advantages of column flotation can be of benefit. The development of a commercial scale column to recover discarded ultrafines from the Riverside preparation plant of BHP-Utah Coal Limited is discussed. Particular emphasis is placed on the column design features pertinent to the recovery of ultrafine coal. Pilot and commercial scale column performances are compared. The results of the commercial scale testwork indicate that a full installation at the 5.5 MTPA Riverside plant would annually recover additional coal worth $US 6.6M.

Jan 1, 1988

By Samuel Polinsky, Lawrence W. Bierman, Wayne Perkins

[A column float beneficiation plant using 9, 8.5 foot diameter, cells was constructed by the Simplot Company and the Smoky Canyon Facility in the fall of 1986 and has been in operation since May of 1987. The float beneficiation process was developed jointly by the Simplot Company and the Bureau of Mines (Salt Lake City, Utah) which incorporates the Bureau's bubble generator design and chemistry system based around the reverse float technology, (Albany Bureau of Mines, Application of Carbonate-Silica Flotation Techniques to Western Phosphate Materials, Rule, Dallenbach , Larsen, RI8728, 1982) . This chemistry has been modified by Simplot in both patented and unpatented improvements. The objective of the beneficiation process was to reducethe A1203 content in the overall pipeline concentrate by 0.2 wt z. Therefore, a process stream was identified in the mill circuit which provided an opportunity to isolate and treat 1100 tons per day of poor quality phosphate concentrates The process allows recovery of approximately 15% of the mill concentrates, otherwise unsuitable for fertilizer production. The alternative would have been to waste this ore. Wasting would have resulted in considerable ore loss, increased mining costs and required additional products grinding. ]

Jan 1, 1989

By V. Coffin, T. Cienski

"(Figure 1) Reagentized pulp enters into the column at about 1/4 of the distance from the top. Inside the column it meets with a downward flowing stream of water and with an upward flowing mass of air bubbles. Flotation takes place in this counter current system while at the same time fine gangue particles are washed off the froth before it reaches the overflow lip at the top of the column. The main operating features of the column flotation are as follows:a) No moving parts. Solids are kept in suspention not by an agitating action of a propeller but by settling down against the rising air bubbles.b) Wash water. Spray pipes are installed a few inches below the froth surface and deliver required volume of water. The purpose of this water is twofold:(i) it keeps in balance the flow of material through the column and(ii) it washes rising froth in the froth layer as well as removes unwanted fines attached to the bubbles at the lower flotation section. As a result the concentrate produced is of higher purity than in the conventional flotation. Column is characterized by very high up-grading. However, even temporary disruption of wash water supply results in a drastic drop of concentrate grate.c) Flow balance. (Figure 2) For the correct operation volume of the underflow (tail) is larger than that of the feed. The difference is made up by the wash water. This difference called bias is predetermined and ranges from some 4 to 15 USGPM depending on the size of the unit and process requirements."

Jan 1, 1981

By J. G. Groppo

Eastern U.S. oil shale contains approximately 10 to 12 gallons of oil per ton and 7 to 10 percent pyritic sulfur. Physical beneficiation of these low grade shales using froth flotation provides a high grade material which will make extraction of oil more economically attractive. The Alabama oil shale used in the present study contained 16.46 percent organic carbon and 14.5 gallons of oil per ton as determined by Fischer assay. Liberation size of the kerogen was estimated at 10 /-Lm. 'Ken-Flote' column flotation technology provided a high grade concentrate containing as much as 60 percent organic carbon, however, carbon recovery was about 60 percent. Carbon recovery was improved to 75-85 percent while maintaining concentrate grades in excess of 40 percent carbon by providing longer retention time in the column which facilitated effective bubble-particle collision and attachment.

Jan 1, 1993

By Gerald H. Luttrell, Roe-Hoan Yoon

Flotation columns are becoming increasingly popular due to their ability to improve selectivity and to reduce operating costs. Unfortunately, these advantages are not often realized because of poor operating practices and difficulties associated with design and maintenance. This article provides guidelines for the operation and design of columns. The discussion will focus on designing proper wash water systems for improved selectivity, maximizing throughput by increasing the bubble surface area rate, and minimizing operating and maintenance costs. It is suggested that the design of the air sparging system is the most critical element in column flotation.

Jan 1, 1993

By J. E. Gebhardt, H. Toro, K. Y. Lee

Industrial-scale test results indicate superior metallurgical performance of column flotation compared to conventional cell flotation for copper cleaning. A technical comparison of bubble generation systems for column flotation is made. Two types of bubble generation systems are considered: the filter-cloth type spargers and the Turbo-Air® sparger, which utilizes an air-water mixture fed to the column through injection tubes. Examples of the improved technical performance available with an external sparger system are presented using data from plant tests conducted for specific applications with several different mineral ores. INTRODUCTION Column flotation is now a valuable unit operation which mineral processing engineers employ in the design and operation of flotation circuits in nearly all mineral applications. The acceptance of columns in the mid- 1980s by the minerals industry was paralleled by a rigorous approach to developing a scientific understanding of the design, scale- up, and operation of column flotation units (Finch and Dobby, 1990). Since then, column flotation has become a standard unit of the cleaning stage in many new mineral concentrator projects and has replaced older mechanical cells to improve process efficiency. The size of column cells has continued to grow from the initial 0.9- to 2.1 -meter diameter range, and it is not uncommon to find column cells today being 2.7- to 3.6-meters in diameter. With the success of the smaller units, the scale-up to larger cells has been proven and demonstrated by the performance of the large-diameter cells (Murdock and Wyslouzil. 1991). The use of columns in flotation circuits has also been accompanied by developments in modelling. control, and optimization of column performance (Lee et al, 1991). The bubble generation system is the heart of the operation of column flotation cells. The most common methods for generating bubbles can be divided into two types: the internal and external spargers. Internal spargers are typically a porous material, such as sintered glass, porous rubber or filter-cloth, or maybe a single- or multi-nozzle sparger. External spargers implies that a gas and a liquid (either water or slurry) are brought into contact outside the column and that mixture is then introduced into the column. Several types of external spargers are available today, and innovative designs for externally mounted air sparging systems have been a significant factor in the successful application of columns. Early types of bubble generation systems.

Jan 1, 1993

By Yuliy Rubinstein

"The paper presents a analysis of the history and the trends of development of flotation apparatus. The laws of their evolution are stated and the place and role of column flotation are indicated. It is demonstrate development and different design of column apparatus. The major parameters of column cell such as diameter and height are discussed. Options are proposed on optimization of hydrodynamic characteristics of columns with large-capacity cells. High efficiency of columns with cell height of 4-6 m is shown on examples of coal preparation. A new generation of multi sectional column cells has been developed. In the cells are zones with different aerohydrodynamic parameters: combined in the machine are co-and counter- counter flows of phases. The transition from single-chamber column to multi-sectional apparatus makes it possible to create favourable hydrodynamic and aeration regimes in each section of the column dependent on the pattern of material distribution by floatability. Efficiency of application different designs column apparatus uses shown on the example of enrichment of various non-ferrous metals ores and coal. The principles of mathematical simulation of the flotation process are developed. A scaling-up procedure for column cells was based on flotation macro- and micro- dynamics simulation.INTRODUCTIONColumn flotation is considered to be one of the most significant achievement in the field of mineral processing in the end of last century. We cannot but agree with this statement but would like to understand what underlies this success. History of the flotation column can not be considered in isolation from the development of flotation apparatus on the whole. It can be argued that the first attempt to switch from oil flotation to the use of bubbles during flotation was performed Bessel brothers in 1877 (Berlin patent 42 class 22, July 2) and in 1886 (Berlin patent 39,369 May 12). According to these patents, the crushed ore was mixed with oils , hydrocarbons and water. Then the pulp received in this way was heated up to boiling . Air bubbles and steam formed during boiling facilitate the flotation of ore particles coated with oil (first patent) or bubbles been generated by the reaction of lime with acid (second patent). The evolution in the design of the flotation apparatus incorporates the following key stages. Further development is connected with the Francis Elmore’s idea to use gas bubbles received at water electrolysis (UK, 13578; 1904). This method was not introduced then, but much later, in our time and on the essentially new technical basis it found a use for sewage treatment (electroflotation). Gas bubbling under vacuum patented also by Elmore (UK, 17816; 1904) obtained a practical use. It should be noted that the method did not lose its importance till now. The design of the camera has been surely optimized (Glembotskii etal, 1963). A year later A. Macquisten (UK, 26712) developed pressure (compression) flotation. Thus, the H.Sulman, H.Picard, D. Bell’s (US, 853120, May 29, 1905) basic patent and the adjoining T. Goover’s patent 1910 (US, 953746) formed the basis of the first and most important element of modern flotation: flotation with air bubbles sucked in from the environment. In 1914, J.Callow received a patent for on an apparatus where air was sparged through the porous false bottom of the cell ( US, 1104755). Woolen fabric folded four times was fixed on a perforated metal frame to be used for air sparging (Gaudin, 1932). The following year Durrel created the prototype of the injection (ejector) apparatus. The jet aerator made it possible to significantly reduce the size of the bubbles, in comparison with the filter cloth. An apparatus with slurry pre-aeration in an airlift prior to feeding into separation cell was developed Wagner in 1917 (US, 1235083). And finally, the first column apparatus with a counter-current of slurry and air was developed by M. Towne and S. Flynn in 1919(US, 1,295,817). ("

Jan 1, 2018

By Danfeng Xu

The majority of the world?s nickel (Ni) resources occur as laterite ores, which are exceptionally complex, lower grade (<1.5% Ni) and expensive to treat using conventional smelting and high temperature/pressure autoclave methods. Heap leaching is a promising, less costly, alternative technology for processing low grade nickel laterite ores. However, significant technical challenges remain with Nickel laterite heap leaching, preventing its general adoption. This paper presents some highlights of laboratory column leaching studies undertaken to characterise, evaluate and optimise sulphuric acid leaching behaviour of Nickel laterite agglomerates. They provide basic but valuable information regarding Nickel laterite agglomerate structure stability and leaching performance under industrially-relevant, continuous acid irrigation conditions. In particular, Nickel and other key metals? (e.g. Co, Fe, Al and Mn) extraction rates, free acid concentration, bed slump and structural changes were determined at a given acid percolation rate as a function of time. Potential implications of the findings, for devising strategies for improved Nickel laterite plant heap leach operations are discussed. Keywords: nickel laterite, column leaching, agglomerates, leaching kinetics, acid consumption

Sep 1, 2012

By D. Moradkhani

The heap leaching of oxide copper ores with copper cathode recovery by solvent extraction and electrowinning is now well established as a low-cost method of copper recovery. The main purpose of this study was to extract copper from the copper low-grade oxide ore of Chodarchaei mine using column leaching. The copper oxide ore contained 1.1% Cu and 1.75% Fe. The mineralogical analysis indicated the malachite (Cu2(OH)2CO3) was mainly composed of oxidized phases. The sulfuric acid leaching experiments were performed under the laboratory conditions. The influence of several parameters on the course of the reaction such as particle size, acid concentration, flow rate, and time was examined. The optimum collective extraction of copper and iron was obtained at a particle size of +10-15 mm for a leaching duration of 3 days with sulfuric acid concentration of 100 gpl and using a flow rate of 2.5 cc/min. Under these conditions, the recovery of copper and iron were 98.54% and 41.99%, respectively. Keywords: column leaching, copper, iron, working diagram.

Sep 1, 2012

By P. A. Schmitz

The characteristics of gold leaching from carbonaceous matter by sodium cyanide, and sorption of gold cyanide to carbonaceous matter in autoclaved and non -autoclaved gold ore from Barrick Goldstrike Mines Inc. (BGMI), Nevada, was investigated. Much greater gold cyanide complex sorption was observed for the carbonaceous matter in high preg-robbing ores relative to the low preg-robbing ores. This observation corroborates previous reports that have attributed observed preg-robbing behavior to the carbon in the ore. Gold cyanide complex sorption was found to be reversible for carbonaceous matter from low preg-robbing ore, but was irreversible for carbonaceous matter from high preg-robbing ores. Autoclaving the ore appeared to enhance the sorptive behavior of the carbonaceous matter from both high and low preg-robbing ores.

Jan 1, 1999

By Alicia E. Ares

316 L Stainless Steel samples were solidified directionally under conditions which produced the columnar to equiaxed transition. The position of the transition was located in each sample and the distance from the bottom of the ingot was measured. During solidification the distribution of temperatures were measured by means of thermocouples located strategically. From the measured temperatures the following parameters were derived; the local temperature gradient, the cooling rate and the velocities of the liquid and solidus fronts. Comparing the location of the transition and the values of these parameters it was found that the temperature gradient reaches negative values of as low as -13.44 "C/cm, and velocities of the fronts of around 0.1 cm/s. Also, a supercooling of 5.81°C were measured which was associated with the supercooling for the nucleation and growth of the equiaxed grains ahead of the columnar front. In addition the primary and secondary dendritic spacing was measured in both regions. The spacing was compared with the predictions from available models. The results are presented and discussed in the frame of the results obtained for other alloys

Jan 1, 2002