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By M. J. Gula, S. S. Xue, E. P. Horwitz, J. T. Harvey

A study has been conducted to control iron in copper electrolyte streams using Eichrom Industries’s new Monophosphonic /sulphonic acid resin. The resin strongly and selectively extracts ferric ion over copper and cobalt from highly acidic copper electrolytes. The resin has a loading capacity of 27 g/L of iron and can be readily regenerated. In addition, the new resin can be easily synthesized using commercially available starting materials. This paper presents the experimental results for iron control in copper electrolyte streams using the new resin and discusses its potential applications to other hydro-metallurgical streams.

Jan 1, 2000

By S. Shairp

The first commercial application of the Dynatec two-stage zinc pressure leach process commenced operation at the metallurgical complex of Hudson Bay Mining and Smelting Co., Limited in Flin Flon, Manitoba in 1993. A key feature of the successful leaching operation is the presence of iron in solution, which facilitates oxygen transfer in the autoclaves and enables rapid oxidation of zinc sulphide minerals. At the same time, the solution from which zinc is recovered must be essentially iron free. Precipitation of iron from the solution starts in the autoclaves and is completed in subsequent atmospheric purification steps. Conveniently, these iron precipitation steps also remove nuisance elements such as arsenic and fluoride from the solution, while producing solids with good liquid-solid separation characteristics. This paper provides an overview of the current operations in Flin Flon, with particular reference to the behaviour and deportment of iron throughout the zinc plant.

Jan 1, 2006

By M. H. Pettibone

During the past decade, the size of grin- ding mills has steadily increased. Mills 11 m in diameter with 9 mW motors have been installed with even larger units on the drawing board. The rising costs of energy and labor have spurred interest in improving efficiency while reducing capital investment and operating labor. Autogenous and semiautogenous grinding have experienced renewed interest as efforts to reduce operating and capital costs have increased.

Jan 1, 1981

By Nozomu Hasegawa

The phase diagrams and microstructures of the slags in the Mitsubishi Continuous Copper Smelting and Converting Process were studied for the prevention of the magnetite troubles such as accretion build-up on furnace hearths and launders, blockages at the melt outlet, slag viscosity increases and so on. According to the results of those studies, the silica and lime contents in the silicate slag at the smelting furnace, and the lime content in the lime-ferrite slag at the converting furnace were changed, resulting in lower and more consistent copper levels in the discard slag, with much less need for operators to clean melt outlets and launders. However, these changes may decrease the desirable amount of accretion-coating inside the furnaces and thereby reduce furnace campaign lives. Therefore, a method of estimating the magnetite level in the melts was developed, and slag compositions and temperatures have been controlled within the appropriate ranges to prolong furnace lives and also prevent magnetite troubles.

Jan 1, 2003

By Pengfu Tan

Converter slag chemistry control has played an important role in optimizing converter operations. A thermodynamic model of copper P-S converter has been developed to predict the behavior of magnetite in the converter slag. Predictions of bath temperature, slag and matte compositions, and magnetite content in the slag have been validated by industrial data. The effects of fluxing strategy, returns and skim charges, oxygen enrichment, and temperature on the magnetite formation in the slag have been predicted and discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2005

By Bratt G. C

When zinc is electrowon from concentrates or residues of high manganese content, the zinc sulphate electrolyte may contain high levels of manganese. The manganese level is usually controlled by removal of manganese at the anode as the dioxide during the zinc electrodeposition stage.By increasing the temperature of an electrolyte containing 8 gll manganese from 35°C to 90°C, decreasing the acidity from 100 gll to 30 gll, reducing the current density from 432.A.m-2 t6 286 A.m-2 and using new lead anodes containing over 0·75 per cent silver, the current efficiency for manganese dioxide removal was .increased from less than 1 per cent to over 20 per cent.At the same time the current efficiency for zinc deposition was maintained above 90 per cent by additions of high molecular weight cationic polyacrylamides to the cell. By utilization of these conditions in a small number of cells, the manganese level in the circuit could be economically concrolled to any desired level.With these conditions the formation of the dioxide changes from an indirect route, via Mn04-, to a direct oxidation of Mn2+ to Mn02.The incorporation of impurities such as Pb, K, NH4, Cu, Ni, or Fe makes the deposit unsatisfactory for direct use in Zn - Mn02 dry cells. The deposit structure changes from cryptomelane at low temperature to y3-Mn02 at high temperature.

Jan 1, 1975

By T. C. Murray

An automatic control system was recently installed to insure the continuity of operation between the ship docking and ore handling facilities and the computerized conveyor-fed sintering plants and blast furnaces. Although the basic concept for material handling has not changed, many innovations including computer control have been implemented.

Jan 1, 1978

By Fred N. Kissell

In This Chapter [Ventilation and methane sampling guidelines for conventional shafts Dealing with restricted spaces where methane can accumulate Ventilation and methane sampling at raise bore drills and Filling shafts at closed coal mines] It is not unusual to encounter methane gas during shaft excavation or shaft-filling operations. Shafts into coalbeds usually produce the most methane, so the information in this chapter applies primarily to shafts at coal mines. Nevertheless, much of the information is relevant for noncoal mines that have methane in the mine or in the overlying strata. METHANE IN SHAFTS EXCAVATED BY CONVENTIONAL MEANS (DRILL, BLAST, MUCK) [ ] Ventilation. Shafts excavated by conventional means are ventilated with a fan on the surface connected to ductwork that extends down into the shaft (Figure 9–1). Shafts into coalbeds should have ventilation systems designed to handle the higher gas flows to be expected as the shaft excavation passes through any over-lying gas-containing strata and nears the coal-bed to be mined. Following are some simple ventilation guidelines for the minimum amount of air required and the selection of the ventilation duct: • Provide enough air to meet the mini-mum OSHA tunnel requirement of 30 ft/min air velocity in the open shaft, as specified in 29 CFR2 1926.800(k)(3). For example, a 20-ft-diam shaft having

Jan 6, 2006

By Fred N. Kissell

In This Chapter [Measuring the gas emission from the coal Methane at the top of the silo Methane at the load-out area and Actions taken after a silo explosion] Methane accumulations in coal silos have resulted in the occasional silo explosion. These can be quite violent and dangerous because coal dust adds to the strength of the blast. However, with the appropriate precautionary measures, methane accumulations in silos can be greatly reduced. Mine Safety and Health Administration (MSHA) regulations at 30 CFR2 77.201 require that the methane content in the air of any coal silo be maintained below 1.0 vol %.3 Also, MSHA requires that methane tests be conducted before any electrical equipment is energized, unless a continuous monitor capable of deenergizing the electrical equipment is used.4 Measuring the gas emission from the coal. The first necessary step in dealing with silo methane issues is to measure the gas emission from the coal going into the silo. Such measure-ments allow one to estimate the silo ventilation needs and permit a comparison with the methane controls used at other mines that have similar gas levels. The gassiness of the coal can be measured by taking conveyor belt grab samples.5 Matta et al. [1978] measured the gas emission from conveyor belt grab samples using a simple desorption test. To conduct the test, they collected several grab samples of coal, weighing a few pounds each, from the conveyor belt entering the silo.6 They then sealed the coal into an airtight sample container that was equipped with a valve and short hose along with a pressure gauge. Every few hours they opened the valve and bled the emitted gas into a water-filled graduated cylinder that had been inverted and placed in a pan of water (Figure 11–1). The results are shown in Figure 11–2.

Jan 6, 2006

By Brian Flintoff

Basic process control is an integral part of most mineral processing plants. It is widely acknowledged to have helped many operations reduce costs and increase productivity and performance. The research community is very active in the development and evaluation of both model based and Al techniques for advanced control applications. Vendors and specialist consulting or engineering firms are in business to help deliver these solutions to the plant floor. It would seem that there is a good balance between business needs and technology, and that the industry should be moving steadily forward in an aggressive pursuit of plant-wide automation. However on closer examination one sees some systemic problems which are sewing to inhibit progress. One of the mist obvious manifestations is the gap which exists between the available technology and current This paper explores the control of mineral processing systems, with a particular emphasis on some of these problem areas.

Jan 1, 1995

By D Gelling

Mineral sands dry plants consist of a large number of repetitive unit operations with significant transport delays, in the form of stream pipes, conveyors and elevators. As part of the P255 mineral sands sponsorship and using the JKMRC developed conductor/non-conductor (CNC) gauges, control loops have been implemented at the multi-duty dry plant of Cable Sands Limited at Bunbury. This paper describes the loops for kV control on a rougher high tension roll machines (HTR). The options available are product grade control and ratio control using the JKMRC CNC gauges, which measure the percent conductors in a stream. The purpose of control is to stabilise the circuit operation against disturbances such as atmospheric and feed disturbances.

Jan 1, 2001

By Ira B. Jorafemon

In the interesting Institute symposium of the preservation of peace by force, through mineral control, one important aspect of the question was not presented. This is the responsibility the United Nations, and particularly the United States, will incur the through limitation of the economic activities of nations that are now friendly to us, as well as of nations that are enemies or are under the control of enemies. After the war all nations, friends as well as enemies will be poor. Hunger and bankruptcy will, will like the sword of Damocles, hang over the heads of all of us on this blundering planet. When the actual fighting is over, there will be a universal attempt to squirm out from under the sword by resuming production of peacetime goods, for trade as well as immediate consumption.

Jan 1, 1944

By I. Iwasaki

The presence of calcium ion in iron ore pulps causes heterocoagulation of montmrillonite on hematite leading to indiscriminate dispersion. Two methods were investigated to control the adverse effect of montmorillonite: chemical method using such complexing agents as EDTA and sodium tripolyphosphate, and mechanical method involving ultrasonic treatment. Their roles in controlling the adverse effect were investigated by zeta potential measurements, starch adsorption tests, and flocculation and selective flocculation tests.

Jan 1, 1986

By J. P. Ramsey

This is a description of the efforts of a research project intended to demonstrate methods of alleviating pollution from coal mine refuse piles and slurry lagoons. These are mainly derelict barren sites. Some are burning and some are vulnerable to wind erosion which causes air pollution. Some occupy valuable land near metropolitan areas. They are an integral part of the landscape of the Appalachian and Midwestern Coal Fields. They are important in the light of growing civic awareness of the great general problem of waste disposal and environmental improvement. In the V-shaped valleys of the Pocahontas Region, they continue to be piled higher and higher. In flatter topography, they tend to form broad, flat ridges. Some contain more metal forms than others and some have a minimum of metal, but weather to a fine talc, which chokes streams with a fine particle suspension. Most are burning or have burned, but burning or weathering, most all are sources of pollution to the atmosphere and to adjacent waterways. This demonstration project is being carried out at an abandoned mine near the town of Du Quoin in southern Illinois. It is jointly sponsored by the Truax-Traer Division of Consolidation Coal Company and by the Federal Water Pollution Control Administration of the Department of the Interior. The site area is a refuse pile and slurry lagoon, each of fifty acres. It is hoped that basic data from this study will be generally applicable to other sites and will provide a basis for rational and efficient engineering design of future reclamation projects. Most refuse piles have extremely long term capabilities to produce highly potent acidogenic oxidation products typifying the more serious aspects of acid mine drainage contamination. Numerous sites remain where the abandoned mine no longer discharges acid waters, but its associated refuse pile continues to generate significant quantities of acid and other oxidation products even after many years.

Jan 1, 1969

By Ernest F. Giovannitti

A couple of years ago, one of the major television networks produced a series on the environment. One episode in the series dealt with the nation's solid waste problem and some of the research being done to solve it. It was interesting to listen to one researcher who was attempting to develop a glass that when broken would dissolve in water. It was said that using this glass would eliminate over 100 million tons of solid wastes each year. At first glance, it would appear that this research-effort would make a significant contribution to environmental pollution control; however, if one pauses to consider the water, he can see that this solution to the solid waste problem may well contribute to a water pollution problem. The dissolved material must either end up in our surface streams or be removed in waste treatment systems. Either alternative may have a more adverse effect on the environment than the original problem. With today's emphasis on the environment, it is important that the effects of our activities be studied in depth. Then, by properly planning the activity, the adverse effects can be minimized. The coal mining industry 100 years ago was in the same boat, as our glass maker, is today. Unfortunately, it too failed to consider all the effects of its activities and as a result, in Pennsylvania, there are over 5000 miles of streams adversely affected by coal mine drainage. The situation is improving, however, because mine operators are beginning to recognize and accept the methods for controlling coal mine drainage. The purpose of this paper is to discuss the measures for the control of coal mine drainage and to set forth the factors that affect these controls.

Jan 1, 1972

By Akira Yazawa

To realize highly efficient process in extractive metallurgy, continuous operation nearly in equilibrium is preferable, but most metallurgical processes consist of plural steps with different chemical potentials. Traditional two-step process of sintering followed by reduction is continuous in each step, but is heterogeneous reaction system far from equilibrium, and the chemical potentials are varied considerably along the distance the charge travels in a reactor. This route will become old-fasioned in next century due to the various inherent problems caused especially by sintering process. To establish reasonable new smelting processes, the important tasks of the metallurgists are how to introduce feed and reacting gas in the reactor, and also how to overcome the difference in chemical potential in the reactor system. Based on the ways to solve theses tasks, recent proposals of new smelting process for copper and lead are classified and discussed with the help of sulfur-oxygen potential diagram. On such potential diagram, each equilibrium step in continuous smelting is expressed at a fixed point, and two reactors with different chemical potentials must be connected by continuous molten flow through launder or partition wall. In the latter case, the reactor is apparently single, but some technical problems must be overcome. While, in a batch smelting like converter, potential variation is successively realized along a path on chemical potential diagram with the time elapsed. To establish immediate equilibrium, continuous steady flow of reactants into well mixed reactor is indispensable. In modern smelting process, the ore is mostly supplied in the form of powder which have huge surface area and fluid character, and consequently injection process must be very attractive. Several examples are discussed for both of copper and lead smelting, and promising future technologies are suggested.

Jan 1, 1988

By John C. Franklin

INTRODUCTION Alpha-emitting radon daughter products are a recognized health hazard contributing to the development of lung cancer in persons exposed to excessive concentrations over an extended period. The primary control technique used by the mining industry is dilution with fresh air. Because the uranium is deposited in porous sandstone in most U.S. mines, the control of this hazard with dilution requires excessive volumes of air. As the mines become larger and deeper, the cost for ventilation becomes a major expenditure for the mining industry Most mines are maintaining levels of radon daughters lower than required by law but to maintain these present levels the mining companies are going to be drilling more vent holes or using other control techniques as the mine expands. These control techniques are being investigated by the U.S. Bureau of Mines to determine their effectiveness, cost, and safety for underground use. [Instrumentation] The Bureau's early research used batch sampling of both radon and radon daughters for determining the concentrations. In both cases it was determined that batch sampling did not give a complete understanding of what was happening to the concentrations. Therefore, continuous monitoring systems were developed for both. A continuous flow-through radon monitor was developed by the Bureau (Franklin, et al.., 1976) using a modified Lucas flask mounted on a photo-multiplier-tube (PMT). The air was filtered twice prior to entering the flask to remove dust, diesel smoke, moisture, and radon daughters. The signal from the PMT was then inverted, shaped, and driven to a data acquisition system (DAS) which accumulated the signals. The DAS has two comparators for setting the scan time and interval, a 24-hour clock with Julian date, a printer, and a perforated paper tape punch. Sampling time is determined by the type of experiment being conducted. Our normal sampling time is one 10-minute scan every 15 minutes, but could be set as low as one scan every minute or as long as a 16-minute scan every 167 minutes. There are two models of the DAS. One is a 10-channel system and the other a 30-channel system. On a 10channel system normally 6 channels are used for radon and radon daughters and the other four channels are used for temperature, absolute pressure, air velocity, and relative humidity as described by McVey (1977). Figure 1 shows a scan of five channels monitoring the radon concentration from intake to exhaust in a stope for a non-work day. If the radon concentration stayed this constant during work days, then continuous monitoring would not be necessary. [ ] Droullard (1977) developed a continuous alpha-beta monitor. This monitor has been modified so that it can be used with the DAS previously mentioned. Control Techniques The U.S. Bureau of Mines has conducted research in controlling airborne radon/radon daughter for 10 years. Major efforts have been conducted in sealing the rock to prevent the release of radon, bulkheading to seal nonproductive areas, backfilling with classified mill tailings, and positive pressure ventilation. Also, tests have been conducted to determine the mining cycles contribution to the radon problem. Surveys One stope with two intakes and one exhaust was continuously monitored to determine the effects of blasting, mucking, and drilling on the airborne radon concentrations (Franklin, et al., 1976). Two other detectors were located inside the stope which were close to the mining activity. In this stope no appreciable change in radon was observed during drilling holes for blasting and roofbolts. This study showed increases up to 40 percent in radon for slushing in the exhaust drift. The radon remained high and very eratic during slushing, as can

Jan 1, 1981

By Friedrich Steinhäusler

RADON SOURCES AND CONTROL MEASURES IN THE MINING ENVIRONMENT Most of the contamination of the mine atmosphere by radon 222 is due to radon emanating from solid or fractured ore surfaces of walls, roof and floor. Also radon gas emanates from broken ore either from storage in backfilled mined-out areas as applied in e.g. shrinkage stopping methods or from ore spillage along intake airways mainly due to the use of trackless haulage. To a lesser extent water itself can represent an additional source of radon, which emanates into air from open drainage ditches or seepages along intake airways. The contribution from water can be controlled effectively by isolating the water from the primary intake air system, e.g. by diverting the water through pipes and/or sealing of seepages by grouting. However, control of radon emanating from rock surfaces creates a major technical problem with significant impact on the economic aspects of mining operations, if adequate radiological conditions must be maintained. Basically this can be achieved by suppressing the emanation process itself, confining already emanated radon or by removal of radon from the mine atmosphere. Extensive research has been carried out on the rate of radon emanation as a function of barometric pressure changes (Pohl-Rüling and Pohl, 1969). It could be shown that the radon supply consists of a permanent and variable component. The former results from the surface of the rock and depends mainly on the emanating fraction of its radium 226 content; the latter originates from within the rocks and is a function of the suction effect of decreasing barometric pressure, rock porosity and fissures. The practical application of this barometric pump effect for depressing the rate of radon emanation, e.g. by pressurizing the mine atmosphere, is limited due to high costs for providing a sink for absorption of radon and air as well as lack of permeability in most uranium ore bodies (Schroeder et al., 1966). Mine air cleaning by removal of radon can be achieved with the use of cryogenic methods, chemical removal, adsorption into charcoal beds, use of a gas centrifuge or general ventilation techniques. Technical problems have so far prevented the application of any of these methods other than ventilation. It is common practice to use the age-of-air concept, i.e. fresh air is delivered to the worker as directly as possible and removed quickly afterwards thereby maintaining the air "young". Engineering principles for quantity distribution of air through underground working areas are straightforward for general mining situations where radon constitutes an environmental contamination problem. However, in cases of high uranium ore content this concept may result in high costs with regard to installation and energy requirements for effecting both frequent air changes as well as sufficient heating of the air in cold seasons. Taking into account that the investment in ventilation systems is a major cofactor for the overall ore production costs this can be a limiting and decisive component in the assessment of the economic feasibility of specific mining operations and mineral reserves in general. Effective control of the radon flux from the rock surface prevents the initial contamination of the mine air with radon directly at the source. A radon diffusion barrier for practical application in mining requirements should fulfill the following requirements: - reduction of radon emanation rate by at least an order of magnitude - high mechanical strength - ease of sealant application onto surface to be coated - water resistant - low fire hazard - resistant to temperature changes encountered in mines - high cost efficiency in relation to exposure reduction achieved (direct and indirect costs) - low degree of maintenance. In the past several materials have been tested as sealants for controlling the emanation of radon from surfaces of rock and building materials. Epoxy paints reduce radon emanation rate only by a factor of 2 to 6 (Auxier et al., 1974; Eichholz et al., 1980; Keith Consulting Engineers, 1980). Although it is possible to prevent the escape of more than 99 % of the radon to the environment with gel seals over 80 mm thick (Bedrosian et al., 1974), practical applicability is very limited. Multilayer coatings of epoxy resins with various additives require meticulous preparation and flawless application of seamless four-layer coatings in four days to impede radon diffusion (Culot et al., 1976), otherwise results from this method have not been totally satisfactory (Leung, 1978). Aluminium foil laminated with polyethylene and paper on each side is under test as radon barrier but results are not available yet (Ericson, 1980). However, this method has the inherent disadvantage that possible malfunctioning electrical installations can cause fire or electrical shock through the sealant. Polyurethane foam coatings have been used on stoppings as very effective sealants. It does, however, represent a potential danger of spontaneous ignition and it is expensive (Rock, 1975). Thus, there is still need for a material which has similar properties as outlined above. In the following results are reported from investigations on the suitability of various materials as radon diffusion barriers.

Jan 1, 1981

By M. F. Gallerneault, V. Fallah, A. Howells, W. M. T. Gallerneault

"The occurrence of recrystallization in cold-worked aluminum sheet during the brazing process leads to loss of strength, an inhomogeneous grain structure and reduced corrosion resistance. AlMgScZr alloys are known for their extraordinary recrystallization resistance due to the influence of Sc and Zr addition on their microstructure. Here, we investigate the effect of alloy composition (i.e. Mn, Mg, Sc, Zr content), cold-roll reduction and pre-aging treatment on the recrystallization behavior of cold-rolled sheets at brazing temperatures typically used during the manufacture of heat exchanger units. The analysis of recrystallization behavior is carried out through microstructural characterization and the results are compared with the behavior of a commercial, AA3xxx-based heat exchanger alloy.INTRODUCTION Control of recrystallization is of critical importance during brazing, which is a widely-used joining technique for aluminum alloys in aircraft structures (Heinz, 2000) and automotive heat exchangers (Miller, 2000; Marshall, 1993). Due to excessive local heat at brazing temperatures, the cold work texture of aluminum alloys in the cold-rolled sheets may undergo a local recrystallization process (Marshall, 1993). This leads to the formation of an inhomogeneous microstructure and thus anisotropic mechanical properties (Miller, 2000) and low corrosion resistance (Marshall, 1993) across the sheet. X800, a commonly-used Al-Mn alloy series for automotive heat exchangers applications, has been developed specifically for a higher strength as well as an enhanced corrosion resistance as opposed to the traditionally-used AA3003 alloy (Marshall, 1993). X800 alloys, however, exhibit a low recrystallization resistance at normal brazing temperatures, i.e. 590°C. In contrast, Al-Sc-Zr alloys have been shown to exhibit an extraordinary recrystallization resistance at such temperatures (Riddle, 2004) while also being corrosion resistant and possessing a high room-temperature strength (Fuller, 2002). This has been shown to be due to the formation of coherent, nanoscale Al3(ScZr) precipitates that effectively impede grain boundaries while also exhibiting very slow coarsening kinetics at high temperatures (Riddle, 2004; Jones, 2003; Ocenasek, 2001). In this study, we analyze the recrystallization behavior of X800 alloys under brazing conditions through introducing Sc and Zr into the system as well as varying the Mn and Mg content. The effect of processing route is also studied by introducing a pre-aging stabilization treatment as well as varying the cold-roll reduction prior to the final brazing anneal."

Jan 1, 2018

By R. A. Pimentel

Complying with reduced dust standards (i.e., less than 2.0 mg/m3) due to quartz levels that exceed 5 percent is presently a critical problem for many continuous mining sections. Results are presented of research which was performed to determine the factors causing high levels of respirable quartz dust and to identify the major contributors to operator exposure. It was found that the significant sources of quartz dust are the drilling of the roof and the mining of the roof, floor and rock bands. Both the miner and the bolter may be on a reduced standard, but compliance is easiest to achieve on the bolter for which improvements in maintenance and operator practices are usually sufficient. At the miner, the problem is more elusive. Research continues to identify operating and mining practices that contribute to the exposure..

Jan 1, 1985