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By Veerendra Singh, NILAMADHABA SAHU, ARIJIT BISWAS

Manganese alloys are important raw materials for steelmaking. However, selective mining of high-grade manganese ore resources has resulted in a scarcity of these high-grade Mn ores (Mn: >42; Mn/Fe: >5). The present research work is carried out to explore a new smelting reduction process to produce high-Mn/Fe syntheticMn ore from low-grade ferruginous manganese ores. Representative samples of low-grade ores (Mn: 25–30%; Mn/Fe: ~1) were collected and smelting reduction studies were carried out using variable smelting power (20–30 kWh), carbon rate (10–20% of ore) and slag basicity (0.1–0.3) to produce high-MnO slag and manganese pig iron. Studies have shown that different-grade high-MnO slags (MnO: 38.57–58.24%; Mn/Fe: >15) and manganese pigs (Mn: 5.16–24%) can be produced at optimum process conditions. The high-MnO slag can be used as synthetic ore for the ferroalloy production process. The developed process is capable to effectively segregate the iron and manganese in the metal and slag, respectively. The optimum Mn and Fe separation (>95%) was achieved by smelting of 10 kg Mn ore batch in a 50-kVA electric arc furnace using 30 kWh smelting power and 0.16 kg of coke. The slag basicity was maintained at 0.3 and the optimum slag SiO2 was ~30%. The studies indicated that the upgrading of low-grade ferruginous manganese ores is a promising solution for achieving high-Mn/Fe-ratio synthetic ores for ferroalloy production. It can help the manganese alloy industry to overcome challenges associated with the scarcity of high-Mn/Fe-ratio Mn ores and efficient utilization of low-grade resources.

Aug 3, 2020

By Veerendra Singh, NILAMADHABA SAHU, ARIJIT BISWAS

Manganese (Mn) ferroalloys are chiefly consumed in the steelmaking process as a deoxidizing agent or as an alloying element to produce high-quality steels. These alloys are typically produced in a submerged arc furnace using coke, fluxes and manganese ores of a specific manganese/Fe (Mn/Fe) ratio. Preferred-grade manganese ores should have Mn content greater than 46 percent and Mn/Fe content greater than 5 to produce commercial-grade, high-carbon ferromanganese [1]. Selective mining of high-grade Mn resources has created a scarcity of these resources, which is emerging as a major challenge for the manganese and steel industry. Manganese ore resources are mainly distributed in South Africa, with about 32 percent; Ukraine, with about 17 percent; Australia, with about 17 percent; and Brazil, India, China, Gabon and Mexico, with lesser amounts.

By A. Heriba

Cyanide is highly toxic to humans and other organisms. Concentrations of RCN as low as 0.05 ppm can be lethal to fish (Scott and Ingle', 1981). In wet climates and in colder climates where natural degradation is slow, it is becoming mandatory to destroy cyanides in effluents before they can be discharged. The disposal of spent gold ore as tailings from cyanide heap leach processing facilities is a matter of concern to the public, the mining industry, and regulatory agencies. South Dakota mining laws and regulations require that spent ore be neutralized to a suitable level with respect to cyanide before disposal (Durkin, 1990). To safeguard the environment and protect ground-water and surface-water supplies adequately, a reliable test is needed to determine the amount of cyanide in the solid spent ore.

Jan 1, 1993

By H. Singh

Principal source of rhenium is molybdenite. Depending on the mineral processing route, rhenium can be recovered by one of the several alternative solvent extraction processes. Extensive experimental work has been carried out on the development of tertiary amine extraction process for treating very dilute highly impure scrub solutions obtained during scrubbing flue-gases of molybdenite oxidative roasting. Equilibrium data has been obtained under various process conditions by tracer analysis using radioactive Re-186. Extraction with 1% solution of a high molecular weight tertiary amine in kerosene, followed by scrubbing of organic extract with a solution of sulphuric acid and stripping with ammoniacal ammonium sulphate yields high recovery, concentration, and purification.

Jan 1, 1982

By N. Sauret-Szczepanski, G. Patry, S. Gauthier, G. Potvin, C. Munger

Adsorption/thermal desorption with sorbent cartridges and analytical method using gas chromatography coupled to mass spectrometry (GC/MS) was developed for the determination of tetrafluoromethane (CF4) and hexafluoroethane (C2F6) emitted from primary aluminum smelters. A customized cartridge was built like a packed column with a stainless steel tube filled with a specific resin. The optimization of adsorption and desorption parameters was carried out to support the PFC sampling for all aluminum production technologies. The proposed method showed good linearity for concentrations ranging from 10 to 500 ppbv for CF4 and from 5 to 500 ppbv for C2F6 with correlation coefficients above 0.999. In certain conditions, the detection limits of the analytical method reached 0.3 ppbv for CF4 and 0.15 ppbv for C2F6- Using this methodology, a field campaign was carried out using a sequential sampler allowing the simultaneous sampling of PFC with cartridges and sampling bags. The results showed no significant difference (t-test) between the two sampling technologies and no breakthrough was observed from the cartridges .

Jan 1, 2006

The New Zealand Steel Ironsand Slurry Pipeline was successfully commissioned in February 1986. The project includes 18 km of high pressure, polyurethane lined buried pipe. McConnell Dowell Constructors Limited has developed a coupling which has allowed this pipeline to be fully welded. The design and development of the coupling and its application on this project is discussed.

Jan 1, 1986

By H. B. Sahu, N. M. Mishra, D. C. Panigrahi

The paper presents the development of a spontaneous heating liability index (SHLI) of coal based on a mathematical approach. The parameters for the calculation of this index have been determined by differential scanning calorimetric studies. Thirty-one coal samples representing both fiery and non-fiery coal seams of different ranks have been collected from different Indian coalfields and their SHLI values have been determined. In addition, the susceptibility of these samples to spontaneous combustion has been ascertained by standard crossing-point temperature measurement. The moisture percentage of all the samples has been obtained by proximate analysis. A comparative study between SHLI and crossing-point temperature, along with moisture percentage, indicates that SHLI predicts the proneness of coal to spontaneous heating more accurately.

Jan 1, 2008

By Georges Houlachi, Akram Alfantazi, Michael Mahon, Maysam Mohammadi

Corrosion resistance of the lead-based anodes directly influences the purity of the final product in the zinc electrowinning process. The anodic MnO2 layer that is electrodeposited on the anodes during this process can protect the anodes against corrosion. Sand-blasted anodes generate a uniform, adherent and shiny MnO2 layer, which gradually blisters and eventually sloughs off after several weeks. In this study, we attempted to develop a new method to stabilize the MnO2 protective layer on the anodes during the electrowinning process by providing suitable nucleation sites for electrodeposition of this layer. MnO2 particles (P80=40µm) were used as seed material for this purpose. Different techniques of galvanostatic and cyclic voltammetry polarizations, scanning electron microscopy (SEM) and atomic absorption spectroscopy (AAS) were employed to investigate the performances of the MnO2-seeded lead anodes. The experimental results showed that growth of the MnO2 layer is influenced by the MnO2 seed particles on the anode surface. The MnO2 layers electrodeposited on the MnO2-seeded lead anodes were uniform and strongly adherent to the substrate. This layer was more stable than those formed on the PbAg anode without MnO2 seeding. This could provide the anode with a higher level of corrosion protection. Moreover, formation of undesirable MnO2 mud in the electrolyte and the rate of manganese consumption were decreased when the MnO2-seeded lead anodes were polarized. These observations could be attributed to the different properties of the electrodeposited MnO2 layer on this anode in comparison with that formed on the PbAg anode.

Jan 1, 2016

By P. J. Noakes

Remote and isolated, located in a frigid, hostile environment, the Black Angel mine in Greenland had to create a warm social environment which would help attract and retain a stable work force of miners and support staff. The high cost of personnel turnover plagues many mines and, when the mine is inside the Arctic Circle, accessible by helicopters which are highly vulnerable to unpredictable weather conditions during the long, dark winters, the potential costs of personnel turnover become critical factors in the success or failure of the mining venture. Manpower planning should start from the date the engineers begin the technical design of the new mine. The plan should include provisions not only to ensure an adequate, skilled work force, but also to ensure a stable work force of people who are happy enough in the mining environment to want to remain, take their vacation and return to work at the mine. The skilled work force was assured with training courses of four months, designed to produce highly specialized underground workers from unskilled Danes and Greenlanders supported by trained Swedish and other Scandinavian miners. The stable social unit was assured by plans the primary attribute of which had to be flexibility. The accommodation changed from shared accommodation with communal washroom facilities to single accommodation with private washroom facilities. A recreational director was hired to help the workers make use of elaborate recreational facilities. A closed-circuit TV and radio system was installed to operate as a private broadcasting system using taped programs originally broadcast on European TV networks or developed by the mine personnel themselves. The liquor rules were changed and the mine manager became a licensed innkeeper responsible for the orderly operation of the Black Angel Bar in accordance with the Danish laws governing the services of a public bar. The result is a relatively stable work force. Some 35% of the people have more than two years' service with the company, Greenex A/S, and some 62% complete 10 months of service.

Jan 1, 1978

By Wang Chen

COREX process is briefly introduced. A static model combining a set of mass and heat balance equations has been developed. Taking the specified inputs from the graphical user interfaces, the model is capable of calculating the consumption of raw materials and fluxes, the volume and composition of the slag and the volume and composition of the generator gas. The model enables the examination of the changes of materials and energy flows induced by the variations of operational parameters and raw materials chemical analysis. The model allows a detailed process analysis and adjustment of the plant operation and can thus be used to improve plant operation.

Jan 1, 2008

By Swayn G. P, Floyd J. M

BHAS, together with the G.K. Williams Laboratory, and Ausmelt Pty. Ltd., has examined a number of possible alternatives to conventional silver cupellation in gas fired reverberatory furnaces. Of these alternatives, a Sirosmelt furnace was preferred for both technical and economic reasons. Small scale work on Sirosmelt processes was carried out at the G.K. Williams Laboratory at Melbourne University in 1985/86. Pilot scale work was carried out at the Ausmelt plant in Melbourne in July 1987. Board approval for construction of a full size plant was received in October, 1988, and construction of the plant is currently underway. The plant is expected to provide significant savings in operating costs and silver inventory. Hygiene around the furnace should also be greatly improved. An increase in cupellation rate of at least ten times is expected, compared with the conventional reverberatory furnace.

Jan 1, 1989

By Syd S. Peng

A total of 209 cases of subsidence data over longwall panels in 16 US coal seems have been collected and built into a subsidence database. The database is developed under MS Windows environment. It uses a very user-friendly menu driven system. The empirical formulae for a number of commonly used subsidence parameters have been derived from those collected subsidence data.

Jan 1, 1995

By J. R. D. Gravel, D. A. Poland

"The induration of iron ore pellets has always utilized prefired pellets to protect the pallet cars from the environment of the induration furnace. This paper presents the process used to obtain superior upper sidewalls. These heat resistant castings are used on induration pallet cars, and their life improvements by as much as 400% is a significant step towards the reduction of the prefired (or hearth layer pellets.) The benefit to the industry in the removal of the hearth layer is improved overall productivity. IntroductionThe Iron Ore Company of Canada (IOC) operates with production facilities located in Labrador City, Newfoundland and Sept Iles, Quebec. It has recently been acquired by North Limited, an Australian based resource oriented company. Prior to its acquisition, IOC has examined several methods of operational cost reductions. One of these was an examination of indurrating pallets. Pallets are composed of numerous assemblies and sub-assemblies. The examination of the upper sidewalls began as an intent to increase the operational life of the component. The anticipated net effect was to be a reduction in the overall pallet maintenance cost. All of the components and assemblies have undergone a severe scrutiny. IOC has found that the success of the project has depended upon not only the technical competency of all parties involved, but also upon the ability to share risk, to be innovative, and to find a partner with whom the development can proceed without fear and yet with accountability. IOC has found in Cast Steel Products (CSP) such a partner in the field of pallet development. This paper will undertake to explore the progression into the arena of partnering between IOC and CSP. CSP and IOC met in the fall of 1994. The work of re-engineering the pallets began with an initial order for 36 pallets in March, 1995. The work on the upper sidewalls involved segregation of the effect of alloy development versus physical geometry development. The nature of partnering between the two companies allocated alloy development to IOC and physical geometry development to CSP, yet no advancements were made in either area without the close co-operation or the involvement of both partners."

Jan 1, 1999

By C. Pieper, J. B. Pateiro Fernandez, S. Möllerherm

"Since the United Nations conference on "environment and development" in Rio de Janeiro in 1992, the term "sustainable development" or short "sustainability" is used more and more in social-political discussions. Agenda 21 calls on the countries on national level as well as governmental and non-governmental organisations on international level to develop a concept of sustainability indicators to measure the progress towards sustainability. This paper deals with the development of an evaluation system for sustainability in the minerals extraction. By their application, aspects of sustainable development in the raw minerals industry are to be systematically conceived and assessed. This project has been carried out on behalf of the German Federal Ministry of Economics and Labour."

Jan 1, 2005

By M John

The Kwinana Industrial Area (KIA) is by far the largest and most diverse industrial processing region (with supporting industries) in Western Australia. As with elsewhere in Australia (and globally), the KIA is facing sustainability challenges on various fronts, such as increasing water and energy scarcity, climate change, an aging workforce, and growing community expectations. Through the Kwinana Industries Council (KIC) the industries within Kwinana are working closely on common issues in the KIA, including the sustainable development of the region. Over the past decade, significant progress has been made by the industries towards the improvement of the sustainability performance at the company and regional level. Given the ever increasing sustainability pressures, there is strong desire to address sustainability challenges in the KIA, through a pro-active and collaborative industry approach. A sustainability roadmap is being developed to assist the KIC and its industry members with strategic decision making on the long-term sustainability of there. At the heart of the roadmap is a set of key performance indicators for each of seven priority themes or focus areas (water use, by-products produced, greenhouse gas emissions and energy use, economic performance, environment, community impacts and sustainable workforce). Aspirational targets and subsequent strategies are being developed for those activities where the KIC has an influence and can make a positive impact. The indicators and their targets enable constructive stakeholder discussions (eg with government and community) on emerging local issues and possible future directions for the KIA. The paper will report on the development process and the preliminary results of the sustainability roadmap for the KIA, including a historical perspective on milestones achieved so far and future aspirations.

Jan 1, 2009

By P. Personnet, D. Wheaton, E. Couzinie, V. Demetriou, Brooks. W., G. Girault, M. Meyer, L. Charbonnel

A common problem in Gas Treatment Centers (GTC) from primary aluminium smelters is the temperature of the gas to be treated : above a threshold, filtering media are irreversibly damaged. The traditional way of dealing with high gas temperature is to dilute with fresh air, which implies over sizing - and therefore higher cost for - the GTC in order to have the capacity to treat this dilution air without compromising on pot suction. A system was developed which decreases gas temperature without having to use dilution air. This system is based on water pulverization in gas collectors. The water vaporization leads to a temperature decrease of the gas. A pilot system was trialed in our R&D unit. Satisfactory results led to the development of an industrial system based on Envirocare equipment (partnership), which was trialed in our production plant in Tomago (NSW, Australia). This patented system was then generalized in this plant, which is now using it with success during austral summer.

Jan 1, 2006

By S. Page, R. Bhaskar

The development is described of a real-time tracer gas sensing system for use in fell-scale laboratory studies of air flow behavior around mining machines. A semiconductor sintered tin-dioxide gas sensor is used for gas analyses. A data acquisition and analyses software specific to the sensor characteristics was also developed as part of the system. The system permits the study of transient behavior and assists in obtaining a better understanding of the movement of air around mining machines and in the study of the effect of potential airflow modification devices on the dust exposure of face personnel. It seeks to replace the current method of using a centralized infrared gas analyzer that polls several sampling points using an array of solenoid valves and gas line purgers. The polling results in a significant time lapse between the first and the last set of readings. The system described in this paper has the advantages of real-time sampling and safe operation.

Jan 1, 1992

To solve the mining safety and health needs of the future, access to, and sharing of, timely and relevant information will be crucial. The next generation of the Web will provide tools (RDF, OWL, SPARQL, etc) to define and link content for more effective discovery, integration, and reuse across applications and organisations. A recent Gartner Research Report (Finding and exploiting value in Semantic Web technologies on the web, May 2007) predicts these technologies will begin to coalesce in ten years. Implementing this Semantic Web requires structured web content described via metadata (information about information). If an industry or enterprise bases its metadata on a common vocabulary, it becomes possible to share and reuse information. The National Institute for Occupational Safety and HealthÆs (NIOSH) Mining web site provides access to more than 1500 NIOSH-developed publications, products, and topic pages on issues as diverse as ground control, respiratory diseases, and mine emergency management. As the site has grown, locating content has become increasingly difficult. To improve the searching process, a panel of internal experts representing all major research programs was established to develop a controlled vocabulary for indexing that content. The outcome is the NIOSH Mining Safety and Health Thesaurus, a faceted, hierarchical thesaurus containing hundreds of mining safety and health terms organised into 20 facets (eg diseases, injuries and disorders; hazardous events and exposures, equipment, engineering and administrative controls). One immediate goal of this project is to reduce the complexity of locating information on the NIOSH Mining web site by implementing metadata and faceted information retrieval techniques. Another goal is to stimulate discussion in the international mining community regarding developing metadata standards so the industry is ready to adopt future Semantic Web technologies to improve access to mining safety and health information.

Jan 1, 2008

Heap leaching of copper sulphide and oxide ores' has been conducted at Rum Jungle since the end of 1965.A review of operations was made and this led to an examination of some theoretical aspects of copper sulphide heap leaching. Ox,ygen diffusion was indicated to be the factor controlling copper leaching rate at Rum Jungle and in other similar operations. Suggestions are made for measuring the heap leaching rate. Prediction of full scale operational results from pilot scale testwork are discussed.

Jan 1, 1969

By Marie-Aline Van Ende, In-ho Jung

A thermodynamic database for the oxyfluoride system CaO-MgO-Al2O3-SiO2-Na2O-K2O-Li2OMnO- FeO-F has been developed based on the critical evaluation and optimization of all available experimental thermodynamic and phase diagram data. The developed database can be used for phase diagram and equilibrium solidification calculations for multicomponent systems and for understanding the solidification behavior of mold fluxes. Based on this thermodynamic database, a simple kinetic model was developed to simulate the interactions between the mold flux and molten steel using effective equilibrium reaction volumes combined with the thermodynamic database.

Jan 1, 2014