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By C. E. Schmidt

Condensate waters from the Bureau of Mines Synthane process for coal gasification have been investigated by mass spectrometric methods to determine the organic contaminants. Waters from the gasification of six coals were extracted with methylene chloride, yielding 0.6 to 2.4 weight-percent extractable material. Using high-resolution mass spectrometry (HRMS), combined gas chromatography-mass spectrometry (GC-MS), and low-voltage mass spectrometry, 60 to 80 percent of the extract was found to be phenolic. About 20 organic contaminants have been identified and are present in the condensate waters from each coal gasified. The relative distribution of contaminants in the condensate water was nearly the same for the six coals gasified under various conditions; phenolic compounds were the most abundant in all cases.

Jan 1, 1974

By V. L. Stolyarova

The high-temperature Knudsen effusion method was used to study partial pressures of vapour species, activities of components and the Gibbs free energies in the DyF3-Dy2O3 system at the temperature (1357±5) K. Partial pressures of vapour species were obtained by the ion current comparison method, with the DyF3 partial vapour pressure over pure DyF3 as a standard. The equilibrium constant of the gaseous reaction DyF3 + DyOF = Dy2OF4 is evaluated. Thermodynamic data obtained are in a agreement with the available phase diagram of the DyF3-Dy2O3 system. Results of the present study illustrate the negative deviations from the ideal behaviour in the system.

Jan 1, 1997

By Kumar M. Lyer

The channel reactor for ferrous and nonferrous processing has been modeled as a combination of ideal reactors. Cold model studies simulated the counter-current flow of slag and matte (or metal) with high-strength submerged gas injection. A composite model has been developed which describes the mass transfer between the two liquid phases, including the transfer of minor elements. The residence time for the matte droplets in the matte/slag emulsion is compared with the settling rates for the matte droplets in the slag to determine their relative importance in the mass transfer between matte and slag. The governing equations for mass transfer have been developed using correlations for the mass-transfer coefficients in the continuous and dispersed phases. An application of this scheme to a typical copper smelting system is presented.

Jan 1, 1993

By J. K. Brimacombe, F. D. Richardson

Studies have been made of interfacial turbulence occurring in reactions in which indium, zinc and cadmium, dissolved in amalgams, are oxidised into aqueous phases by ferric or mercurous ions. It has been found that this turbulence occurs when the concentrations of oxidising ions in the aqueous phase become sufficiently great. These concentrations are the same as those at which the mass-transfer coefficients in the aqueous phase increase sharply when both phases are stirred by gas bubbles rising through them. The effects of gas flow rate on the mass-transfer coefficients for zinc in mercury have been established, and the oxidation of pure mercury has been investigated. The relevance of the work to processes involving liquid metals is discussed

Dec 1, 1971

By E. S. Vargas, T. W. Chapman, Samuel W-S Tse

Models for interphase mass transfer rates in the solvent extraction of metals are developed for zinc and copper chlorides being extracted by trilsooctylamine and for copper extraction by LIX 64N from ammonia solution. The approach is to adopt a stagnant film model on which film thicknesses are known and to derive the interfacial metal fluxes for the case where all reversible reactions are fast and locally equilibrated. A growing drop mass transfer cell is used to measure extraction rates. It is found that for the cases studied the transfer rates are mass-transfer limited On the other hand, copper extraction by LIX from acidic solution exhibits slow reaction kinetics, and earlier kinetics models are confirmed. Interactions that cause varying selectivity in the simultaneous extraction of copper and zinc chlorides are demonstrated.

Jan 1, 1981

By E. Barsky

"Theoretical notions of mass transfer processes in cascade separation of bulk materials have not been adequately developed as yet (Barsky M.D. 1980). In this paper we have derived linear difference equation of the second order for a cascade with initial feeding top any stage proceeding from mass exchange regularities. The solution of these equations has allowed us to determine quantitative dependences of the material distribution over the cascade stages, which serve the basis of the method of predictive estimate of the process results. We have also examined the model of the material distribution coefficient formation at individual cascade stages.We have checked the adequacy of this model to experimental data. It is noteworthy that the obtained theoretical results are phenomenological, i.e. they can be applied to the processes of separation of different physical nature, e.g. of isotopes, liquid media, gases, etc.INTRODUCTIONRecently, the processes of cascade separation of bulk materials have found broad application in various industries. They ensure a high separation efficiency and high-quality composition of final products. Although specialized literature gives serious attention to cascade processes [1], their theory is not sufficiently developed yet. To achieve optimal organization of this process, we examine mass transfer in a cascade gravitational classifier with stages of identical design."

Jan 1, 2016

By K. H. Bech, S. T. Johansen

"The mass transfer at fluid-fluid interfaces due to turbulent agitation is investigated theoretically. In particular a theory is derived for interface stresses due to interface energy and surface renewal. This theory indicates that surface renewal may take place if the geometry is sufficiently large and if surface tension is sufficiently low.By using a model for a typical turbulent structure we compute the interface mass transfer for a stressless interface and a fully interface. Results for the general situation is not presently available. The computed results are used to derive analytical expressions for the mass transfer based on turbulent kinetic energy and free stream turbulent length scales.One important application of the theory is the mass transfer at the electrolyte side of the bath-metal interface in the Hall-Heroult process. For this process we show that mass transfer should be expected to be of the rigid surface type."

Jan 1, 1999

By G. S. Gupta

To predict the iron oxide concentration a mass transfer model has been developed for an Induction Smelting Process (ISP) in which self-fluxed composite pellets (made of iron ore, brown coal and lime) are melted in a single phase induction furnace in conjunction with top blown oxygen. Transient mass balance equation with complex boundary conditions has been worked out by adopting a relatively new approach known as the cell model approach. These equations have been solved numerically using finite difference technique to obtain the iron oxide concentration profile in the ISP. Numerical and experimental results obtained for iron oxide concentration show a reasonable agreement with each other.

Jan 1, 1991

By A. Kar

A mathematical model is presented for pure titaqium deposition from titanium tetrabromide on a stainless-steel (SS 304) substrate. Five three-dimensional, transient, and nonlinear partial differential equations are used to account for the diffusion of various species inside the deposition chamber and the thermal decomposition of titanium tetrabromide, titanium dibromide, and titanium monobromide at the surface of the substrate in order to determine the thickness of the titanium film deposited on the substrate. The effects of various process parameters on the deposition and shape of titanium films are examined, and under certain conditions, the deposited titanium films are found to have volcanic profiles.

Jan 1, 1992

By Ramani R. V

There are many important physical phenomena in mine ventilation which involve transient mass and heat transfer processes. These processes have been modeled using differential equations often solved with close form solution. Within the last two decades, many numerical schemes have been devised to solve these mass-transfer problems. Much of this effort has focused on variants of the finite element and finite difference methods. In this paper, the solution of mass transfer models in mine ventilation by finite difference technique is discussed. Specifically, the computational effort and the accuracy of the solution are presented.

Jan 1, 1988

By Dan Adams

A number of gas-liquid processes require high intensity agitation systems to provide uniform blending and dispersion of reactants in order to achieve desired end products. Processes such as hydrogenation, fermentation, and minerals processing have used conventional down pumping or radial agitation systems with some success. In 1996, LIGHTNIN introduced the concept of Up-Pumping to the industrial marketplace as an improved mixing technology for these applications. For processes requiring gas-liquid mass transfer, such as those listed above, conventional mixing technology requires the use of gas introduction devices (sparges) below impellers. These devices can be a maintenance concern due to plugging and erosion in the presence of solids. Up-Pumping impeller systems are able to draw in a significant amount of gas from the headspace, much more so than conventional vortexing impellers designed for headspace gas incorporation. This paper will demonstrate the effectiveness of Up-Pumping impeller systems that have the potential to eliminate need for sparge devices entirely. It demonstrates the ability of Up-Pumpers to re-entrain gas for higher utilization compared with conventional impeller technology. This is significant in applications using costly gases such as enriched oxygen or hydrogen, reducing overall operating costs of production.

Jan 1, 2003

By H R. C Pratt, G W. Stevens

Hydrodynamic and mass transfer performance are presented for a 72.5 mm diameter pulsed disc and doughnut column of the type used by Western Mining Corporation, Olympic Dam Operation, for the extraction of uranium from sulphate media using Alamine 336 as extractant. For the present purpose, 4.0 g/L sulphuric acid was used as solute. The mass transfer data were interpreted in terms of the diffusion model, thus accounting for continuous phase axial dispersion. The results indicated that an efficiency corresponding to approximately one transfer unit over the 1.0 m height of the column was obtained. This efficiency is comparable to that observed by Gottliebsen (1997) for a pulsed perforated plate column using 173 gm/L sulphuric acid.

Jan 1, 2000

By V. E. Ross

A model has been developed that describes the behavior of mineral particles and water in the cleaning zone of flotation columns. The possible detachment of particles from their sites of attachment at the bubble surfaces is related to the flux of bubble surface area with increasing distance from the interface between the collection and cleaning zones and the late at which floated particles are transported into the cleaning zone. The drainage velocities of floated and entrained particles are calculated from the drainage velocity of water and the properties of the particles. The effects of wash water and inhibited drainage in the froth are also explicitly accounted for.

Jan 1, 1988

By R. Hogg

The mathematical description of solids transport in mills is an important aspect of the development of comprehensive models for the analysis, simulation and control of grinding systems. The basic mechanisms of particle transport and mixing, including gravity flow, carrier fluid transport, and "diffusion", are reviewed and their relative importance in wet and dry ball mills is discussed. Specific models for transport and mixing in dry, grate-discharge and wet, overflow ball mills are described. The limitations of the models, parameter estimation problems, scale-up criteria etc. are discussed and the conditions which lead to particle size dependent transport, and hence to internal classification in the mill, are described in detail.

Jan 1, 1984

By Thomas P. Kwiatkowski, John S. Anderson

The Massachusetts Bay Transportation Authority (MBTA) has undertaken an under-ground transit project to extend public transportation service from downtown Boston to the South Boston Piers area. This new system, known as the Transit way, will connect existing subway lines to this area which is comprised of approximately 300 acres, in light of the potential for 21 million square feet of development by 2010. This system includes construction of a concrete immersed tube tunnel crossing of Fort Point Channel. The crossing will be accomplished in the highly congested setting of down-town Boston and will be located just to the north of the famous Boston Tea Party ship exhibit and amid major Central Artery Construction activity. The most recent concrete tube constructed in the United States was in 1962. The Fort Point Channel Crossing will employ current design and construction methods commonly utilized in the Netherlands, Australia, Hong Kong and elsewhere. This paper will present the design philosophy, planning, and evaluation of alternative crossing methods which led to the selection of the concrete immersed tube tunnel and construction techniques envisioned for this particular application.

Jan 1, 1997

By David E. Thompson, Edward S. Plotkin

The Massachusetts Bay Transportation Authority (MBTA) Red Line Extension Northwest is nearing the final stages of construction. The 3. 1 mile extension of the Red Line from the existing Harvard Square Station in Cambridge, Massachusetts to Alewife Brook Parkway in Cambridge, includes a large, near surface, hard rock, rapid transit chamber at Porter Square in Cambridge (Figure 1).

Jan 1, 1983

By Nancy J. Wheatley

I. INTRODUCTION The Massachusetts Water Resources Authority (MWRA) is a regional water and sewerage authority which provides wholesale water and sewer services to the Metropolitan Boston area. The MWRA was created by the Massachusetts Legislature as an independent authority in 1985 following the filing of a lawsuit in federal court to correct the pollution of Boston Harbor resulting from inadequate and inadequately maintained sewerage facilities. Immediately upon its creation, the MWRA began to tackle treatment plant issues, including addressing the need for a secondary treatment plant, planning for ceasing ocean discharging of sludge, and making interim repairs to the existing, antiquated treatment plants. The MWRA's initial activities led to a court-ordered schedule for construction of a single new primary and secondary treatment facility, for development of sludge management plan focussed principally on reuse, and for completion of a short term program of repairs to existing facilities. Once a schedule for completing these activities had been negotiated, the U.S. Environmental Protection Agency (EPA), a plaintiff in the federal court case, asked that the MWRA take "responsibility" for controlling discharges from combined sewer overflows (CSOs) within its service area. Combined sewers (sewers in which both sanitary sewage and storm water runoff are carried in a single pipe) presently discharge over 10 billion gallons of untreated wastewater into Boston Harbor and its [ ]

Jan 1, 1991

By James M. Baylor

Ladies and geltlemen, it is indeed a privilege and a pleasure to be here in Denver with you. I want you to know too I'm not a stranger out here. Golden, Colorado is the headquarters of A. T. Massey Coal Company's Western Division, headed by Vice President, Gregory H. Hoyl. I also have a very close friend and fraternity brother who works and lives in Denver so I could talk on and on about this area and our western coal properties, but it's Massey's coal terminal business I'm to focus in on today, and that's a horse of a different color. So on to the subject of my address: MASSEY COAL TERMINAL INVOLVEMENT As I have stated on other occasions, A. T. Massey Coal Company, for better or for worse, is in the coal terminal business.

Jan 1, 1981

By Sergio Segovia Parra, Victor Hernan Sheen Uriol

This contribution of the concept of mass blasting both closing and production allows breaking paradigms, to limit the number of tons to thunder. The areas of geotechnical different mining large mining companies worldwide and especially from the National Copper Corporation (CODELCO, Chile) has been declining volumes closing blasting and production, with the misconception to protect the end walls of the pit, before any geotechnical risks caused by various types of faults; especially the circular faults. A blasting of small tonnage can do more damage to a wall when it is not properly sequenced, leading to the coupling of the wave train and therefore the exponential damage in/s (peak particle velocity, PPV) on the wall of the Tagus. Blasting closing mass production and contribute technically and operationally in the dynamics of the following operations: loading, hauling, crushing, processing and preparation of the final product; eliminating delays to return to thunder small volumes where one must stop all mine equipment, incurring high costs and especially losing valuable time in the continuity of the following unit activities.

Jan 1, 2015

The unique characteristics of the Target orebody and modernistic approach to mining present significant challenges and a concomitant high potential for new opportunities. The break-away from the traditional labour intensive mining methods improves both safety and productivity significantly. The intention of the paper is to illustrate the application of well known mining methods to the particular requirements of a complex orebody at depth. The evolutionary process followed to establish the final mining method design provides insight behind the finished product, and the modern approach to the planning and service principles equips the reader with a suite of mining engineering ideas.

Jan 1, 2000