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By K. T. Valsaraj

The separation process called solvent sublation for the removal of two hydrophobic compounds (penta-and tri-chlorophenols) from the aqueous phase is discussed. A steady state mathematical model for the process is discussed. The process was conducted in a continuous countercurrent mode. The underlying mechanisms, theory and experimental details on the effects of process variables on removal efficiency are reported.

Jan 1, 1992

By K. T. Valsaraj, L. J. Thibodeaux

Solvent sublation, the separation process for the removal of two hydrophobic compounds (penta- and trichlorophenols) from the aqueous phase, is discussed, as is a steady-state mathematical model for fire process. Solvent Sublation "'as conducted in a continuous countercurrent mode. The underlying mechanisms, theory and experimental details on the effects of process variables on removal efficiency are reported.

Jan 1, 1994

By Simon D. Strauss

The world appetite for minerals in the, third quarter of this century grew at a higher rate than had been anticipated. To illustrate, consider the experience of four, commodities. Excluding the Communist bloc, sometimes referred to as the centrally planned economies, demand for aluminum increased at a compound rate of 8.6% between 1950 and 1975,; copper rose by 4.4%; iron ore by 5.5%; and tin, the laggard in the group, by 2%. Except for tin, the figures are substantially greater than growth rates anticipated in 1950 in the Paley Commission report and other studies. The growth rate was not evenly distributed in geographical areas. Professor Wilfred Malenbaum of the University of Pennsylvania did an interesting study breaking these figures down as among three principal sources of demand -- the United States, other industrialized nations (which he referred to as the "rich lands"), and the developing world (which he referred to as the "poor lands").

Jan 1, 1982

By Walter R. Jr. Hibbard, William A. Vogely

INTRODUCTION Volatile markets and pricing, increasing imports, constraining but effective laws related to the environment, health and safety and price controls lead to concerns which generated pious laws stating non-fuel policy and authorizing studies but resulting in ineffective implementation. Several commissions, reports by the Secretary of Interior and even the President have led to many recommendations but little or no action. No single comprehensive policy could solve problems which are diverse, commodity specific and not categorizable (Landsberg 1982, 1983). Thirteen laws administered by 27 agencies regulate or affect minerals and materials. Political instability created by communist regimes in Southern and Central Africa jeopardized sources of critical imported materials. This situation led to a Resource War mentality. It was feared that the U.S.S.R. was seeking to control this area and exclude the United States from resources (Vogely, 1980). The success of the Organization of Petroleum Exporting Countries with a petroleum cartel led to fears of an Organization of Minerals Exporting Countries which might create more cartels and/or make the existing ones more effective. Economic needs of developing countries required export to maintain employment and balance of payments have led to world surpluses, weak markets, low prices, and large loans from the World Bank which have under- mined U.S. industry (Landsberg, 1982a). Un- cooperative environmental laws, obsolete facilities and non-competitive costs have led to shipping U .S. ores to other countries for processing into ingot and bars which are imported back to the United States. Yet massive internal turmoil has interrupted supplies, and led to un- certain availability and higher prices. This situation could happen again. Included in this category of critical materials with uncertain sources are metals required in the manufacture of military aircraft, which has led to concern regarding the defense industry base (Morgan 1983). Remedies have been proposed which include: updated stock piles, material substitution, international cooperation and coordination, foreign policy aimed at resolving racial and national stresses in South and Central Africa, relaxing U.S. environmental and public land regulations and action under the Defense Production Act (Goth 1982). The President's report (1983) to Congress has stated a national materials policy which recognizes: that materials play a critical role in our economy, defense, and standard of living; that public lands contain a vast untapped mineral wealth; that the role of government is to identify mineral issues and act on them; and that there is a need for long term high potential pay off research (Bureau of Mines 1983). There is a serious question as to whether or not a comprehensive national mining, minerals, and materials policy is feasible let alone necessary. One solution is to abandon the attempt at comprehensiveness and to target specific is- sues with realistic policies (Comptroller General 1979). In the following sections, the major studies of the 1970s will be reviewed, major issues yet to be faced will be identified, the principles involved in these resolutions will be reviewed,

Jan 1, 1985

By Jack Eloranta

Building on previous work, this paper expands the template for modeling the economic relationship between blasting and grinding. The actual efficacy of various blasting enhancements is not addressed, however, placing costs and potential benefits in proper context should aid in designing mine/mill optimization trials.

Jan 1, 2014

By Paulo Couceiro

Highly non-ideal explosives usually tend to react expressively below their ideal detonation velocities. In these cases, dimensional effects and product heterogeneities become important to proper model the detonation state. Although Direct Numerical Simulation (DNS) techniques can provide a complete and exact solution for this problem, its actual computation cost is still not practical for industrial applications. In order to minimize these constrains, a simplified two-dimensional steady non-ideal detonation model for cylindrical stick explosives is developed. Based on an ellipsoidal shock shape approach, the proposed model uses the quasi-one dimensional theory for the axial flow solution and combine the post-shock sonic flow criteria with some limiting conditions for the explosives’ unconfined radius determination. Due to its attractive fitting capability for unconfined detonation experimental data, the model offers the possibility to predict the non-ideal detonation state for any diameter, resulting in a full mapping of the diameter-effect curve of the explosive. Thus, the proposed engineering approach is used to model the main properties of some of the most common ammonium nitrate-based explosives used in mining and quarrying industries, including the complete axial flow solution.

By Paulo Couceiro

Highly non-ideal explosives usually tend to react expressively below their ideal detonation velocities. In these cases, dimensional effects and product heterogeneities become important to proper model the detonation state. Although Direct Numerical Simulation (DNS) techniques can provide a complete and exact solution for this problem, its actual computation cost is still not practical for industrial applications. In order to minimize these constrains, a simplified two-dimensional steady non-ideal detonation model for cylindrical stick explosives is developed.

Feb 1, 2020

By Minchinton A

CPeX is a non-ideal explosive performance prediction model. The model takes into account the rate of energy release, the extent of chemical reac- tion and the effect of confinement on energy release. The model resolves the explosive energy into `shock' and `heave' com- ponents as a function of explosive type, hole diameter and rock type. The predictions of the model are compared for a bulk emulsion, and a prill-doped bulk emulsion in soft rock. The predictions, based on calibra- tion of the model with simple unconfined detonation velocity measure- ments, show the significant effect of non-ideality on explosive Performance.

Jan 1, 1988

By K G. Fleetwood

This paper proposes an approach to determine the influence of non-ideal detonation characteristics related to the charge diameter, explosive type and confinement conditions on the available shock energy of ANFO and a representative chemically-sensitised (gassed) emulsion. The proposed degrees of non-ideality of the two different blasting agents are indicated by the Gurney ratios, determined from existing cylinder expansion testing data. The influence of the non-ideal detonation properties on blast design and performance are also compared using a series of theoretical, equal powder factor open pit blasting patterns with hole diameters ranging from 102 mm to 270 mm. The non-ideal shock energy factor (NSEF), which is the available shock energy per tonne of blasted material (MJ/t), is used to compare the different blasting patterns as charged with either ANFO or the gassed emulsion of equal charge density (0.85 g/cm3). The intended purpose of this investigation is to provide explosive users with an approach to compare different explosive types or charge diameters in the absence of dedicated non-ideal detonation modelling, which is generally not available to explosives users.The results of the comparisons suggest that at low charge densities, the example gassed emulsion displays a higher velocity of detonation (VOD) than ANFO in smaller charge diameters but similar degrees of non-ideality (based on proposed Gurney ratios). The results also suggest that the confined, non-ideal gassed emulsion VOD at hole diameters greater than 270 mm can be less than ANFO due to the low density effects on the emulsion matrix. The differences in non-ideal detonation properties and Gurney ratios between the ANFO and gassed emulsion resulted in gassed emulsion NSEF values ranging from 15 per cent lower to 65 per cent higher than ANFO for equal powder-factor patterns in blasthole diameters from 102 mm to 270 mm.

Nov 8, 2011

By C. J. Bise

Continuous mining accounts for about 69% of the nation's underground coal production. This level is not expected to change much in the near future. This is because continuous mining represents the primary means of under- ground coal production. It is also the primary means of driving development entries for underground coal mines, including longwall mines. The continuous miner worksite contains many characteristics that can lead to personnel accidents. It continues to be an area of concern for mine managers, safety engineers, and training coordinators. In an effort to assist mine management in attempts to reduce the number of accidents and injuries sustained in this area, this paper presents a loss-control-based, non-intrusive strategy for conducting safety evaluations at continuous miner worksites.

Jan 1, 1991

By K. E. Livo, D. H. Knepper

Modern remote sensing provides a means for locating and characterizing exposed mineralized systems in many parts of the world. These capabilities are non-invasive and help target specific areas for more detailed exploration. An example of how remote sensing technology can be used is evident from a study of the Questa Mining District, New Mexico. Analysis of low spectral resolution data from the Landsat Thematic Mapper satellite system clearly shows the region-al distribution of two broad mineral groups often associated with mineralized systems: clay-carbonate-sulfate and iron oxides-iron hydroxides. Analysis of high spectral resolution data from the Airborne Visible and Infrared Imaging System (AVIRIS) shows the occurrence and distribution of many individual mineral species that characterize the pattern of hydrothermally altered rocks in the district.

Jan 1, 2004

By Warfield Garson

Few, if any, of the non-ionizing radiation health hazards to be found in either surface or underground coal mining are uniquely different because of their being found in the work environment. Hence, they can be considered generally for their bio-effects on the worker when found in the mining work environment. The same may not be said, however, for the lack of non-ionizing radiation and its bio-effects, particularly as it relates to underground coal mining. The term "non-ionizing radiation" refers to various forms of electromagnetic radiation of wavelengths longer than those of ionizing radiation. As the wavelength gets longer the energy of electromagnetic radiation decreases. Therefore, all non-ionizing forms of radiation have less energy than cosmic, gamma, and X-radiation. In order of increasing wavelength, non-ionizing radiation includes ultraviolet, visible light, infrared, microwave, and radiofrequency radiations. The energy frequency and wavelength range of both the ionizing and non-ionizing electromagnetic forces are shown in Table I. To convert the wavelengths of various radiations to Ångström units, one multiplies millimicrons by ten. In a vacuum, all electromagnetic radiation has the same velocity, namely 3 x 1010 centimeters per second. The natural source of radiant energy here on earth is our sun which emits radiation continuously over a wide spectrum. This radiation on average reaching earth ranges from 290 nm in the ultraviolet range to over 2,000 nm in the infrared range with a maximum intensity of about 480 nm in the visual range. You will note this falls into the visible blue wavelength and accounts for our blue sky and blue ocean and deep water effects. We are all familiar with the fact that the passage of solar radiation through the atmosphere to the earth changes the spectrum considerably because the atmosphere absorbs and scatters many of the sun's rays. The ozone in the upper atmosphere absorbs the shorter ultraviolet wavelengths and water vapor absorbs some of the infrared wavelengths. Smoke, dust particles, gas molecules and water droplets scatter the rays, especially those of shorter wavelengths. In addition to the sun, every gas, liquid or solid object at a temperature above absolute 0° radiates energy. Solid objects emit almost continuous spectra. At low temperatures only radiation of the longer wavelengths in the infrared range is emitted, but as the temperature of the object is increased, more and more of the shorter wavelengths are added. This fact is most readily demonstrated by heating a piece of steel. When a piece of steel reaches a temperature of about 1,700° Fahrenheit, it gives off radiation at the red end of the visible spectrum and appears dull red. As the temperature is further increased, the shorter rays are also emitted, until at about 2,100°F, the metal appears white, due to the emission of wavelengths throughout the entire visible range. Gasses, on the other hand, when heated emit radiant energy only at certain wavelengths, which are characteristic of their chemical structure. This latter fact is of importance in underground coal mining as high intensity gas and vapor lamps are becoming more and more utilized for illumination in underground coal mining. The biologic effect of non-ionizing radiation exposure depends upon the type and duration of exposure and on the amount of absorption by the miner. The effects of this radiant energy on the miner fall into four distinct types: (1) the heating effect of infrared radiation, (2) the effect on the eye of visible radiation, (3) the effects of ultraviolet radiation, and (4) the growing potential effects of the misuse of microwave radiation. Each non-ionizing type of radiation will be considered individually. ULTRAVIOLET RADIATION The sun is the major source of ultraviolet radiation, which is of concern in open pit and surface mining at certain seasons and in certain climes necessitating protection for the surface miners under those conditions; nonetheless, there are some man-made sources such as electric arc lights, welding arcs, plasma jets, and special ultraviolet bulbs for illumination underground that demand surveillance in the underground environment to be aware of whether the miners are at risk above the threshold limit values allowable. Since ultraviolet radiation has little penetrating power, the organs that are affected are the skin and the eyes. Ultraviolet radiation is strongly absorbed by nucleic acids and proteins, and the effects in man are largely chemical rather than thermal. Short-term effects on miners include acute changes in the skin. These are of four types: (a) darkening of pigment, (b) erythema (sunburn), (c) increase in pigmentation (tanning) and (d) changes in cell growth. Ultraviolet radiation also causes acute effects on the tissues of the eye. Overexposure can lead to keratitis, inflammation of the cornea, and conjunctivitis. Long-term effects of ultraviolet exposure include an increase in the rate of ageing of the skin with degeneration of skin tissue and a decrease in elasticity. Late effects of ultraviolet on the eye include the development of cataracts. The most serious chronic effect of ultraviolet exposure is skin cancer. Ultraviolet radiation effects are increased by some industrial materials and drugs. After exposure to such compounds as cresols, the skin is exceptionally sensitive to ultraviolet radiation. Photosensitivity reactions occur after exposure to a variety of other chemicals and drugs including dyes, phenothiazines, sulfonamides, and sulfanylureas. On the other hand, we must remember that ultraviolet radiation has an important role in the prevention of rickets. Vitamin D is produced by the action of

Jan 1, 1981

By Zhang Jianliang, Xu, Zuo, Runsheng, Haibin, Kexin, Jiao

Full oxygen blast furnace iron-making is one of the new technologies, which is most likely to realize large-scale application. In this paper, based on the technology of full oxygen blast furnace, the reduction behavior of pellets is studied systematically by using the analytic method of non-isothermal dynamics on the different atmosphere(CO,H2) and the dynamics model of gas-solid reduction reaction is constructed, which lay the foundation of reduction model establishment of full oxygen blast furnace burden. The result shows that the time of pellets which began to react is delayed with the increase of the content of H2. When the temperature is between 650 'C and 1050 'C, the content of H2 in the reduction atmosphere is larger, and the rate of the reduction pellets is larger. The reduction rate changes at 780 'C, and a certain amount of H2 in the reducing atmosphere will significantly improve the reduction reaction when the temperature is above 780 'C. Non-isothermal reduction behavior is controlled by interfacial chemical reaction and internal diffusion under high reduction potential. H2 ratio in reducing atmosphere increased from 0% to 100%. The reduction reaction of the apparent activation energy decreased from 49.03kJ-mor1 to 33.74kJ·mor1.

Jan 1, 2013

By J. Lobel, M. Bourassa, J. A. Kozinski, B. Peng

Non-isothermal kinetics studies of the reduction phenomenon of electric arc furnace (EAF) dust generated in stainless steelmaking have been carried out. The dust was mixed with carbon as a reducing agent and dolomite as a binder to form pellets. A Thermo-Gravimetric Analyzer (TGA) was used to determine the weight loss of pellets heated at an average rate of 40 K/min. up to a temperature of 1500°C. The degree of metal reduction was calculated by considering the pellet weight loss, and evaporation of moisture, dust, zinc and lead at high temperature. The reduction process was divided into three different steps. The first covers the 300°C to 760°C temperature range (from 7 to 18 min.), the second step ranges between 760°C and 980°C (18 to 24 min.), and the third covers temperatures above 980°C. Each step is characterized by different chemical reactions. Non-isothermal reduction kinetics equations were set up to describe each step. The kinetics parameters such as apparent activation energies and frequency factors were established. It was found that the first step was chemically controlled, while the second step was diffusion-controlled. Reduction behaviour in the third step was strongly dependent on the initial carbon content in the pellet. Chromium oxide (CrO) could only be reduced in this last step. High temperatures and higher initial carbon content favoured the reduction of CrO.

Jan 1, 2001

By Kim Fagerlund

A novel apparatus for studying refractory infiltration and dissolution/degradation under a temperature gradient was developed. To supersede conventional isothermal refractory testing, a new temperature gradient technique, based on a crucible equipped with a cooling element, has been developed to provide practical information on the penetration and dissolution of refractory materials under cooled conditions. This technique was adopted and applied to several refractory-slag systems. Commercially available magnesia chrome refractory bricks against a copper-containing calcium ferrite type of slag were tested and compared using both a conventional crucible test and the new temperature gradient method. The experiments were conducted at 1300-1420°C under a controlled atmosphere of nitrogen or air. It was noticed that the type of porosity has a significant effect on infiltration of magnesia chrome refractories. Furthemore, the copper-containing calcium ferrite slag caused a severe slag attack and refractory failure in some cases, due to its fluidity and corrosive nature.

Jan 1, 2002

By S. Hardy

The paper describes state of the art non-linear analyses of the pile groups that were employed during the raising of the 133m high triumphal arch which forms the centre piece of the new Wembley stadium in North London. The deformation behaviour of these piles groups was critical during the lifting process, due to the slendemess of the arch structure. The issue was made more critical by the high profile nature of the project. The results of Class A (Lambe (1973)) predictions of the pile group movements are compared with observed displacements and rotations which were accurately measured on site. To illustrate the importance of soil non-linearity on pile group behaviour, comparison is also made with pile group analyses which assume a linear soil stiffness.

Jan 1, 2006

By Vasileios A. Drosos

The response of pile foundations to lateral loads is an important factor for the successful performance of several critical structures. A new numerical code for the analysis of single piles under lateral load is outlined. The code can simulate (through appropriately chosen parameter values) not only the non-linear behavior of soil, but also the inelastic structural response of the pile itself under lateral load. Emphasis is given on the calibration of model parameters and the verification of the code. For the calibration of the parameters, data is used (a) from the well documented in the literature p-y curves, and (b) from experiments conducted either in full scale or in the centrifuge. Results are compared to those of well known published codes for inelastic analysis of single piles under lateral load.

Jan 1, 2006

By F. Castelli

A simplified non-linear method to predict the behaviour of a single pile and/or pile group under horizontal loads is presented in the paper. The evaluation of the non-linear lateral deflection is based on a procedure taking into account the decrease of the model stiffness with the increasing of the applied load. The solution derived firstly for the single pile, was extended to the case of a pile group introducing the p-multiplier (fm) concept proposed by Brown et al. (1988).

Jan 1, 2006

By K G. van den Boogaart, S Konsulke, R Tolosana Delgado

Adaptive mineral processing has to rely on spatially predicted information on primary geometallurgical parameters, like phase composition, size and shape distributions of grains from various phases, portions of value elements in different grain types. Naively, one would predict these parameters geostatistically and select an optimal processing for the predicted structure. This is suboptimal, due to various kinds of non-linearities in the problem. First, some primary geometallurgical quantities themselves are measured in non-real scales, like compositional or stereologically distorted geometric information. Standard geostatistics has to be replaced by compositional and geometric geostatistics, involving complex transforms and restrictions. Further, only partial and uncertain information is available, introducing a stochastic character to the optimisation problem. Moreover, many response variables leading to costs, outcomes and eventual effects of later processing depend non-linearly on the primary geometallurgical parameters, which implies that the final monetary value is not estimated unbiasedly by kriging. Finally unbiased linear prediction (such as kriging) is not the best method of prediction for decision making. The conditional expectation of the monetary values is needed instead. The impact of these problems is explained in this paper, with simplified examples, and a first approach to a general solution is proposed. CITATION:van den Boogaart, K G, Konsulke, S and Tolosana Delgado, R, 2013. Non-linear geostatistics for geometallurgical optimisation, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 253-258 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

Paper written on project work carried out in partial fulfilment of B.Sc. Eng. (Extractive Metallurgy)degree The concepts behind support vector machines are very interesting both in theory and in practice, as they are based on a universal constructive learning procedure derived from the statistical learning theory developed by Vapnik. In this paper, their application to time series modelling is considered by means of simulated data from an autocatalytic reactor. In particular, reconstruction methods from non-linear dynamics are used to define a state space model for the process. Multivariate embedding techniques are compared to scalar embedding with respect to modelling. Keywords: System identification, Support vector machines, Multilayer perceptrons, Non-linear dynamics

Jan 1, 2003