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By Leandro Voisin

A new pyrometallurgical treatment alternative is proposed for cleaning complex copper matte with high content of impurities in the copper smelting process, thus, in a suitable furnace, a given amount of pig iron will be added to the liquid complex matte with a matte grade between 65 and 75 % Cu under reducing condition and will produce three liquid phases of matte, copper-rich alloy and iron-rich alloy. Hence, in this study, firstly, a mass balance calculation was made on the basis of the reported data for the distribution ratios of the components among the three phases to define the optimum condition where most of the arsenic can be fixed in the less valuable liquid iron-rich alloy. By taking advantage of the high concentration of arsenic in the iron-rich alloy, the small volume alloy may be disposed in a yard, while the precious elements may be recovered effectively in the liquid copper-rich alloy and/or in the liquid matte. Secondly, laboratory-scale experiments were conducted to apply the proposed process to the matte produced from the slag-cleaning electrical furnace and the Teniente Converter of the Codelco-Norte smelter. The obtained results indicate that the proposed process for cleaning complex matte is promising.

Jan 1, 2006

By T. McCallum, B. Wellbrook, T. Ratnaweera

Leaching of copper (Cu) concentrates produces elevated concentrations of Cu and acid, which makes solvent extraction (SX) processing more challenging. Maintaining extraction targets can be more difficult with higher pregnant leach solution (PLS) grades, and variability of PLS Cu and acid can lead to increased chemical iron transfer. Diluting concentrate leach feeds with an existing heap leach inventory makes SX processing easier. However, considerations about how much to dilute and where to distribute the flow into the SX configuration must be carefully evaluated, given their impact on metallurgical performance. In this paper, characteristics of a concentrate leach feed are discussed, along with considerations for processing by SX. Also reviewed are pilot plant results of concentrate leach distribution into SX and plans for commercial testing. INTRODUCTION Hydrometallurgical processing of copper concentrates continues to gain interest from the industry. Treatment by smelting and electrorefining continues to dominate, accounting for ~80% of global copper production, but is faced with its own challenges (Li et al, 2017). The case for increased hydrometallurgical processing has been discussed as high grade ore deposits are diminishing, capital costs for smelting are high, and the environmental aspects present challenges for sustainable practice. The hydromet copper industry is also turning a corner as easily leachable copper oxide deposits are depleting, and excess SX-EW capacity exists in certain regions. The transition to hydrometallurgical processing of copper concentrates will take a bit of effort as leaching of copper sulfides is difficult and byproduct credits must be considered. Various POX leaching processes have been studied and proposed to the industry as viable practices. Of the many processes, commercial use has been practiced with the Mount Gordon Copper Process, total and partial pressure oxidation by Freeport-McMoRan at their Bagdad and Morenci, Arizona complexes, the Sepon Copper Process in Laos, and the bioleach BIOCOP™ process in Chile (Dreisinger, 2016).

Jan 1, 2019

By Kanau JL, Kilgour I

This paper describes the metallurgical processes at the 80 000tpd Ok Tedi Mining Limited concentrator, which treats copper- gold ore by single-stage crushing, SAG and ball milling and flotation to produce over 500 000tpa of concentrate. Plant and process developments, including installation of column cells, reduction of fluorine in concentrate, use of sulphidisation and process control improve- ments are also discussed.

Jan 1, 1991

By La Brooy S R, Fenton K

A low grade copper flotation tailing from Telfer containing 1.2% Cu as chalcocite and cuprite and 5 gt-t Au was leached with ammonia, cyanide and ammonia-cyanide mixtures to extract copper and/or gold. Direct cyanidation extracted both copper and gold but consumed about 30 kgt 1 NaCN. Pre-leaching the tailing with an aerated ammonia solution containing 28 kgt 1NH3 and 17 kgtl(NHa)2S0a at pH 10 readily extracted up to 95% Cu in about 6 hours under optimum conditions. However pH and total ammonia concentration were critical factors. Subsequent cyanidation ex- tracted 80% Au using 6 kgt NNaCN. Ammonia-cyanide mixtures werefound to selectively leach gold over copper depending on the concentration and relative proportion of NH3 and CN. The best composition for leaching up to 80% Au from Teller tailing was 1.6 kgt t NaCN and 1.1 kgf 1 NH3 in the presence of 0.3 kgt t Cue+. Such a mixture left only 50 mgL-1Cu in the final solution after precipitation of some of the initially dissolved copper.

Jan 1, 1991

By George D. Coumoulos

The following aspects of diasporic bauxite are discussed: The importance of world reserves of diasporic bauxites; the geological, chemical and mineralogical characteristics of the Greek diasporic bauxite; the uniformity of bauxite deliveries; the significance of the absence of organics; the excellent settling properties of the red mud; the production of sandy alumina from diasporic bauxites; the advantages of applying tube digestion systems in processing diasporic bauxites; the conditions for introducing diasporic bauxite in the existing European refineries.

Jan 1, 1984

By L. D. Muller, C. P. Sayles

When minerals are mined in arid or semiarid areas where water is at a premium, dry processing is a natural route to take for concentrating or classifying the values. Until recently though, dry processing technique were limited by the lack of suitable equipment. With the advent of the pneumatic pinched sluice at Warren Spring Laboratory, Stevenage, Hertfordshire, England, a new tool emerged to fill this gap and it has the potential of providing industry with a high output concentrator or preconcentrator for dry natural ores and secondary materials. The pneumatic pinched sluice gives every indication of fulfilling these requirements with the added advantage that with homogeneous materials-such as crushed limestone or quartzose sands-it may alternatively operate as a high throughput dry classifier or sizing device. An industrial version of the equipment is now being manufactured by Dryflow Separators Ltd., as sole licensee for the National Re- search Development Corporation.

Jan 1, 1971

By D. L. Schweyer, W. A. Munson, R. H. Hanewald

Discussed is the INMETCO processing of electric arc furnace (EAF) baghouse dusts from the specialty-steel and low-alloy industries. In addition, the INMETCO process has been modified to recover nickel, chromium and iron from many other waste materials including: •pickling solutions or filter cakes, •spent nickel and chromium plating baths, •carbon refractories from pickling tanks, and •superalloy wastes including baghouse bags. INMETCO is the only North American company presently capable of recycling nickel-cadmium batteries by high-temperature metals recovery. This process and the details of INMETCO's best demonstrated available technology (BDAT) test program are discussed.

Jan 1, 1993

By R. H. Hanewald

The processing of EAF baghouse dusts from both the specialty steel industry and low alloy producers will be reviewed. In addition, the INMETCO process has been modified so as to recover nickel, chromium and iron from many other waste materials such as pickling solutions or filter cakes, spent nickel and chromium plating baths, carbon refractories from pickling tanks, and super alloy wastes including baghouse bags. INMETCO is the only North American company presently capable of recycling nickel-cadmium batteries by high temperature metals recovery. This, along with the details of INMETCO's BDAT Test Program and results performed to pre-agreed standards with the EPA will be discussed.

Jan 1, 1992

By Bret Boster

Facilities at Amax Gold's Sleeper Mine process some 330 kt of high grade ore and 4100 kt of low grade ore annually to produce 6.8 t of gold and 7.8 t of silver. High grade ore is processed in a conventional milling facility employing gravity concentration, CIC and CIP unit operations for gold and silver recovery. Low grade ore is processed using heap leaching and carbon adsorption methods.. Presented are the evolution and descriptions of the Sleeper processing facilities and discussions of selected' operating results.

Jan 1, 1989

By M. Ghiani, P. Carbini, R. Ciccu, C. Del Fà

"This paper is concerned with the problems inherent in the efficient and economical processing of the fine fractions of a coal from the Sulcis basin (Sardinia, Italy) whose characteristics are typical of low-rank coals occurring in the Mediterranean region. Three different techniques, based upon surface properties, are examined. Flotation can be very efficient from both a technical and economic point of view, provided care is taken in the modulation of the flotation pulp. Interesting results have been obtained with oil agglomeration and this method could be economically feasible. Finally, electrical separation has proven a viable technique, although it entails preliminary drying.Besides discussing the problems encountered in the experimental research, some significant results of general validity are also given. They demonstrate that cleaned products can be obtained with fairly interesting recoveries, thus opening the way to advanced research aimed at setting up the most suitable technique for industrial application. IntroductionAs a result of the oil crisis, which caused a major upset in world energy supplies, the last ten years have seen a revolution in the energy policies adopted.In particular, the status of coal, which seemed destined to decline in view of the availability of liquid fuel, has had to be re-examined. The need to meet energy demands under improved reliability conditions and controlled prices through a broader and more flexible diversification of sources of supply has evoked, especially in highly industrialized countries, a renewed interest in coal. The result has been a consistent increase in demand and production as well as investments in new mines and the reinforcement of the infrastructure.This turn of events has also lead to a re-evaluation of young low-rank coals, hitherto considered uneconomical and thus neglected, because of their low heat value. In fact these coals, which have a high ash content, may also be relatively highly contaminated with sulphur. The above drawbacks, which still today preclude the widespread use of these coals, are bound to create even greater problems in the future as increasingly restrictive environmental control imposes, without exception, recourse to cleaner fuels."

Jan 1, 1986

By Arthur F. Colombo, David M. Hopstock

The Lake Superior region contains extensive deposits of potential iron ore in the form of fine-grained oxidized taconite. To help assure utilization of this resource in an environmentally sound manner, the U.S. Department of the Interior, Bureau of Mines, is conducting bench- and pilot-scale research using wet high-intensity magnetic (WHIM) separation. The advantages and disadvantages of WHIM separation in comparison with other feasible beneficiation methods are discussed. Pilot plant results are given for a flowsheet in which WHIM scavenging is used in conjunction with selective flocculation and flotation. A mathematical model for use in process optimization is given. Practical aspects of matrix selection and separator design for WHIM separation of fine particles are discussed.

Jan 1, 1980

By Dean D. Turner

Exploration geochemistry requires computer processing for quick and efficient reduction and interpretation. An easy to use microcomputer based geologic workstation fulfills this need and allows the geologist to independently process geochemical data. Functions necessary for geochemical data processing are: 1)Digitizing; 2)Communications; 3)Data base management; 4)Statistical analysis; 5)Mapping analysis; and 6)General purpose applications (ie: word processing). A geologic workstation that can perform these tasks will yield significant advantages in processing and interpreting geochemical data.

Jan 1, 1987

By E. J. Hammer

Crushing and grinding of gypsum demands con- trolled processing to a fineness suitable for further treatment of the mineral into end products, and into various sizes of material which are themselves saleable products. The majority of gypsum tonnage ultimately ends up in stucco for wallboard. Therefore, mineral reduction is normally designed toward this end, but it is done in a manner that permits drawing off intermediate products to meet various customer requirements. This forces companies into compromises at times in equipment installations. Normally, 5 to 6 different sizes intermediate to the end product are marketed and these are generally the fineness of material to be used as stucco for wallboard. These sizes are produced by controlled crushing, grinding and sizing. How Ore Characteristics Guide Processing First, gypsum as a mineral (CaS0;2H,O) is number two on the Mohs scale two of hardness; only talc is softer, Despite being soft, gypsum is tough, a factor which is of critical importance when developing equipment specifications. In addition, of the increasing volumes of rock handled, the associated and included impurities such as anhydrite, silica or lime- stones are found to be relatively abrasive.

Jan 1, 1970

By B. R. Conard

Occupational epidemiology of the nickel-producing industry has found that inhalation exposures to certain nickel-containing substances are linked to respiratory cancers and to nonmalignant respiratory endpoints. Establishing such a linkage, however, is complicated by the fact that some diseases occur long after exposure to a causal agent (i.e., some diseases have long latencies). Furthermore, most chemical agents (especially nickel substances) vary significantly in their toxicological properties and their concentrations in workplace air have varied over processing history. Because of these complications, it is critical to understand historical exposures to specific nickel substances. To assist in this effort, the author focuses on the history of smelting and its related processes at Vale Canada’s (Inco’s) Ontario operations in the first half of the 20th century.

Jan 1, 2012

ABSTRACT Inco’s Iron Ore Recovery Plant was operated by Inco from 1955 to 1980 near Sudbury, Ontario. As exposures to specific nickel substances have been associated with adverse respiratory endpoints it is important to understand processes giving rise to such substances. This manuscript discusses the process and equipment, the propensity for aerosol formation, and operational procedures used by Inco in roasting a pyrrhotite concentrate, reducing the nickel in the formed oxide, leaching the nickel in ammoniacal solution, purifying the resulting solution, making green or black NiO, and producing iron oxide pellets. Industrial hygiene measurements are also reported.

Jan 1, 2013

ABSTRACT It is critical that historical processes and concomitant exposures to specific nickel substances be understood because some diseases linked to inhalation of certain nickel-containing substances have a long latency between first exposure and disease onset, and because nickel substances vary significantly in their toxicological properties. A discussion of the smelting history and related processes at Vale Canada’s (Inco’s) Copper Cliff, Ontario, smelter is integral to the understanding of these processes. The post-1950 processing history, equipment, propensity for aerosol formation, operational procedures, and ventilation controls used by Vale Canada in roasting, smelting, converting, and copper-nickel separation is discussed.

Jan 1, 2013

By K. Lascelles

ABSTRACT Nickel compounds vary significantly in their toxicological properties, so it is critical that continuing studies to accurately quantify worker exposures consider the processing that accompanies refining nickel-containing materials. The Clydach nickel refinery, which has operated for more than 100 years, was the first nickel-producing facility to show a high risk for lung and nasal-sinus cancers among workers employed since it opened in 1902. Process chemistry and equipment have changed dramatically over Clydach’s history. This paper describes the processing evolution at Clydach with a focus on the propensity for aerosol formation and the forms of nickel in airborne dusts.

Jan 1, 2013

By Thomas J. DeMull

Amax Gold's Sleeper Mine was brought to production as an open pit mining, cyanidation milling operation in March 1986. The Sleeper deposit is unique in that it contains zones of very high grade gold ore. Despite blending of ore, mill head grades have varied over a broad range. These grade variations were anticipated during mill design and affected, in particular, the sizing and selection of equipment for the CIP circuit. When grades proved to be even higher than anticipated, design operating parameters were adjusted shortly after start-up to accommodate the higher grades. Operating results have been excellent: during the first 18 months of operations the Sleeper mill has processed 375,600 tons of ore and produced 229,000 ounces of gold.

Jan 1, 1998

By George H. Edwards

Most cullets consumed in large-volume glass manufacturing processes receive little processing beyond crushing. But lead-glass cullets for specialty glasses such as industrial lighting refractors or cathode-ray tubes are combined with metals and various coatings that prohibit their direct recycling into the glass-melting processes that created them. In many cases, the contained lead renders these cullets hazardous. At present, virtually all industrial processes to separate one cullet from another depend on hand sorting, and thus are necessarily costly per unit weight. Lead-glass cullets of differing lead content are of interest because they offer the possibility of separating one glass composition from another by high-speed, automated processes at low cost. A potential process for comminution, cleaning, and separation of lead-glass cullets would involve primary and secondary crushing, magnetic and other metals separation, attrition scrubbing in water, separation of glass types by gravity techniques, drying if necessary, sampling, and preparation for transport to the point of use. Process water would be filtered to remove finely divided coating materials and glass, and reused. If carried out on a scale similar to a specialty industrial mineral processing plant, the cost per unit weight of such processing should be substantially less than the raw material value of the cullet in specialty glass production. The added value of avoiding waste disposal costs makes this process economically attractive.

Jan 1, 1994

By Francois Mignard

With a limited global steel production growth, automotive application market shows interesting volumes and trends especially in emerging countries. The recent period has again enabled Siemens VAI to confirm a position amongst leading suppliers of new plants serving high-end steel production in particular for unexposed and exposed automotive material. With a series of recent plant references in operation and under construction, relevant answers to such sustained level of performances are highlighted along the downstream processes. Designed for a wide range of applications, Siemens VAI processing lines includes advanced technological and state-of–the art equipment, among them, Solid state laser welder, Pickling Tunnel tanks, Skin pass mill and Tension leveller, Side trimmer with dynamic width adjustment, and new generation of Automatic surface inspection systems. With a continuous aim of driving improvements, Siemens VAI has also developed Global Quality Monitoring solutions notably through advanced software which provide just-in-time warnings and assist steel makers in the daily operation of their lines. As lifecycle partner, Siemens VAI offers solutions and services in metallurgical expertise from metallurgical modelling, through physical simulation on rolling, annealing and galvanizing processes, and enables Siemens to accompany our customers along with their project definition till fulfilment of highest market requirements.

Jul 30, 2018