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By M. Menegaki

Restoration of abandoned mine sites is still one of the weak points of mining practice. The latter stands especially for the case of the surface coal and lignite exploitations, where the extended size of the disturbed land and the drastic changes to the geomorphologic features do not facilitate the implementation of a cost effective and environmentally sound reclamation plan. The paper examines the parameters involved towards the legal requirements for the reclamation of the first lignite exploitation in Greece, namely the ?Plakes? mine, located at Euboea, due to the particularities of the site. Then an integrated redesign procedure is presented, aiming at minimizing aesthetic degradation, confronting technical difficulties and preparing the site to accept new uses.

Jan 1, 2005

By N. Novikov, M. Jastrzebski, N. Kryzhanovskaya, D. Shevchenko, I. Kapran, N. V. Novikov, T. Koehler, B. Zaporozhets

"The PFK FeNi Smelter was re-commissioned by Solway Resources in 2002, ending a long period of economic decline in the adjacent town. In 2009 Hatch was retained to design, supply and install a custom furnace crucible that would accommodate a capacity increase from 34 MW to 40 MW and increase campaign life through binding and cooling technologies, as part of ongoing improvement efforts. The involvement of PFK personnel was critical to the successful integration of the new furnace technology with the existing process and operational practice. The furnace upgrade project was completed in 18 months during 2010 – 2011. Since start-up, the furnace has exceeded production expectations, operating successfully at 42 MW.INTRODUCTIONAfter ceasing operations in the 1990’s, the Pobuzhsky Ferronickel Combine (PFK), located in central Ukraine, was stripped of useful equipment and deteriorated while dormant. The surrounding town experienced a period of economic decline throughout the 1990’s. Solway Industries purchased the complex in 2002 and began a systematic incremental program to re-commission the smelter using both local expertise and specialists from other parts of the former Soviet Union. This led to the re-birth of PFK as a successful toll-smelting complex, and a renaissance for the surrounding economy.As part of the continuing improvement program, PFK approached Hatch in 2009 to study the possibility of a capacity expansion from 34 MW to 40 MW. It was decided, based on the results of the study, to design and install a custom furnace crucible integrating the unique PFK FeNi process with modern Hatch furnace technology. This novel approach had many benefits, including: maximum re-use of existing furnace components (off-gas, feed equipment and transformers), minimal impact on upstream and downstream equipment and building structure, and the retention of a familiar operating regime. The latter was a key factor in the success of the project, as it allowed the extensive operating expertise of the PFK staff to remain highly relevant to the upgraded furnace. This led to minimized capital investment, a rapid start-up and no significant operational challenges switching over to the new equipment incorporating Hatch furnace technology."

Jan 1, 2012

By Barry K. McMahon

Following minor slope failures at the commencement of mining the west wall of the Kanmantoo Mine was redesigned from an overall slope between haul roads of 55° to 46°. This decision was based on a probabilistic analysis which indicated that 46° was the optimum economic slope.

Jan 1, 1983

By D. J. Goodwill

BHP Copper operates a 3,400 tpd dry concentrate, single burner, Outokumpu flash smelting furnace (FSF) at their San Manuel copper smelter in Arizona. The very fine (-325 mesh), dry concentrate is fed to the burner from a 550 metric ton (nominal) capacity furnace feed bin via two drag chain feeders. During the 10-year history of the furnace, operations have been plagued by serious flooding problems. The fine concentrate sometimes becomes aerated during discharge from the bin and flows like a fluid at very high uncontrollable rates to the burner. This results in upset conditions at the concentrate burner leading to poor furnace metallurgy. This paper will examine the problems of uncontrolled feed from the furnace bin (i.e. flooding), and' instantaneously feeding a flash smelting burner. It will show that a drag chain is a poor choice of feeder when high rates are needed, and that drag chains always produce a funnel flow pattern in a bin. BHP's drag chains cause narrow diameter, high velocity flow channels within the stored material. Consequently, there is insufficient residence: time for the concentrate to fully de-aerate before discharge, hence flooding occurs. In addition to the flooding problem, drag chains create a pulsating flow to the concentrate burner due to the tendency for material to slough off in discrete chunks at the discharge end of the slow moving chain conveyor. During the scheduled FSF rebuild in May 1999, BHP intends to remove the drag chains, modify the bin to a mass flow design and to use STAMET® multi-disc feeders to accurately and instantaneously control the rate of discharge from the bins. Air slides will be used' to convey the concentrate to the burner.

Jan 1, 1999

By L. Li

To accommodate the large payloads and harsh operating conditions associated with heavy vehicles in the mining industry, off-the-road (OTR) tires are typically used with heavy mining vehicles. These tires have increased abrasion and wear resistance due to their thicker tread, sidewall and bead thicknesses. Given these features, OTR tires are much stiffer than conventional passenger vehicle tires and cannot be mounted to a single-piece rim without damaging the structural integrity of the tire during the mounting process. Therefore, multi-piece wheels are used with OTR tires to facilitate mounting. While these assemblies are necessary, several instances of their failure have been reported to result in injuries or fatalities within the mining workplace. Many of these failures were specifically reported to be caused by the disengagement of the wheel lock ring - a component used to securely engage the assembly during operation. In this study, a threaded-connection locking mechanism has been proposed in place of the traditional lock ring design. The performance of this threaded-connection was numerically evaluated in a pull-out test against a conventional five-piece wheel assembly. The pull-out test was devised as a means of quantifying the engagement ability of each wheel?s locking mechanism. A high degree of modelling accuracy was maintained throughout the analysis by validating the vertical and horizontal static loaddeflection behaviour of the rim model of the five-piece wheel assembly against experimental data. Through validation, the model data were found to be within 10.5 and 4.80 %, for vertical and lateral loaddeflection behaviour, respectively. Results from the pull-out analysis found that the threaded-connection demonstrated a 113 % increase in the force required for disengagement to occur relative to the conventional five-piece design - a force of 9,550 kN in total.

Aug 1, 2013

By Greg Stokkermans, Jim Hansen, Mary Kate Dempsey, Mark Reinders

The City of Toronto is reshaping and revitalizing its waterfront in the largest ongoing urban redevelopment project in North America. The redevelopment includes naturalizing the mouth of the Don River, which has become a source of flooding as the city has been built around it. Constructing a new river valley to alleviate this bottleneck involves multi-staged excavations up to 7 meters below Lake Ontario in permeable alluvial sands. In order to place a protective environmental barrier, these excavations need to be dewatered and require cantilevered earth retention over 6 meters high. This paper highlights the rapid design and construction of a 1.1-kilometer-long, up to 45-meter-deep secant pile cutoff wall that was constructed to support the first phase of excavation and dewatering of the new river valley. The paper discusses the geotechnical investigation and seepage analysis, selection of wall type, verticality criteria requirements, and construction challenges associated with the deep secant pile cutoff wall. Data collected during construction confirmed that the cutoff wall met critical design objectives and allowed for successful construction of the new river valley.

Oct 31, 2023

By J Samosir, L A. Snyman

Northparkes is located 27 km north of the township of Parkes in central New South Wales, Australia. The operations consist of underground block cave mines and an ore processing plant that produces high-grade copper and gold concentrate. Production is currently sourced from the E48 Lift 1 block cave mine and open cut stockpiles. Mining commenced at Northparkes in 1994 as an open cut operation. Underground block cave mining began in 1997. Northparkes was the first mine in Australia to use the highly efficient block cave mining method, which relies on gravity and natural rock stresses to fragment the ore.An issue affecting production in 2011 was the stability of the E48 mine. A small portion of the drives on the extraction level began to deteriorate as the ground support system failed. The problem was temporarily fixed by stopping production in three extraction drives and tight filling selected areas within these drives (and drawpoints) with low-strength concrete. This action provided immediate support and stability whilst allowing time to investigate potential ground support remedies. From these investigations it was decided to use resin injection technology and additional ground support to stabilise the rock in the aforementioned extraction drives as the concrete plug was excavated in a controlled advance and sequence. This made the area safe and ensured the ongoing safe operation of the E48 mine. The redevelopment of one of these drives began late in 2011, with the remainder being progressively redeveloped over the next two years in order to maintain the extraction level stability.This paper looks at the strategies employed to safely re-open previously converged drawpoints and associated extraction drives that were subject to high abutment loading that was possibly associated with premature cave breakthrough.CITATION:Samosir, J and Snyman, L A, 2014. Redevelopment at Northparkes following significant drive closure, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 87–92 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

The Carnilya Hill Mine, a joint venture project between Western Mining Corporation Limited (WMC) and The Broken Hill Proprietary Company (BHP), is a nickel sulphide deposit being developed by the Kambalda Nickel Operations (KNO) of Western Mining Corporation. Seven months elapsed from the time a decision to proceed with the project was taken until the first ore production. During the first month of operation a new KNO record for decline development was set. Equipment used includes an electro- hydraulic drill jumbo, 4 cubic metre front end loaders, and 35 tonne haulage trucks.

Jan 1, 1981

Morning Star Gold aims to enter the ranks of Australia's gold producers, revitalising the Eastern Victorian Goldfi elds in the second half of 2010 - the fi rst gold production in around 50 years from the Morning Star Gold mine, which was once Australia's largest under WMC. This presentation will outline the redevelopment of the Morning Star Gold Mine from exploration to production. Morning Star Gold NL's (MCO) key project area is centred at the historic mining town of Woods Point and nearby Matlock (to the southeast) and Gaffney's Creek (to the northwest), all of which are located in the lower part of the Victorian Alps roughly 60 kms south of Mansfield. Morning Star has literally numerous historic mines and gold bearing 'dykes' on its tenements, many with a rich production history of high-grade gold from quartz reefs and alluvial sources. The area encompassing the Woods Point goldfi eld and the multiple high-grade gold bearing dyke structures located north towards Jamieson and south towards Walhalla formed one of the most significant mining fields in Australian history. Historical gold production was at least 155 t or around six million ounces of over a century of mining with an average production grade exceeding 27 g per tonne. The bulk of this recorded production came from just a handful of mines and of those only three were mined to any great depth. One of the key historical production hubs in this area was the famous 'Morning Star' mine, which is situated adjacent to Woods Point township. The Morning Star mine produced almost one million ounces at 27 grams per tonne, operating fairly continuously between 1861 and 1959 with a break after Jan 1939 due to the devastating 'Black Friday' bush fi res across eastern Victoria. During the early 1940s, the Morning Star was Australia's biggest gold mine. The Morning Star mine along with Walhalla ensured that this goldfield was third behind Bendigo and Ballarat as Victoria's biggest hardrock gold production centre. Morning Star Gold has rebuilt its 100 per cent owned 'Morning Star' mine with a view to producing gold in the second half of 2010. Morning Star is exploring its regional dykes in order to estimate an overall gold endowment and rank local production sources to feed its proposed mill at the Morning Star mine site. Key initial targets (all within 11 kms of the Morning Star mine) are the Waverly, All Nations, Rose of Denmark, Hunts, Wallaby and Loch Fyne dykes, all of which historically produced high grade gold, much of it gained from only shallow workings above the water table in the weathered zone of rocks. Historically the Morning Star mine was developed over 24 levels to a depth of 940 m via one large vertical shaft and a smaller, deeper inclined shaft at the 1900 feet level underground. At present MCO has dewatered and completely refurbished all infrastructure to the ten level (~310 m below surface). MCO knows there are a number of substantially under-explored and undeveloped or partially developed but not stoped areas within the Morning Star mine. As a result, MCO has been carrying out extensive channel sampling and an underground diamond drilling program targeting areas of the mine that were largely unexplored and undeveloped by the last operators of the mine - Western Mining Corp Ltd (Gold Mines of Australia). Four thousand, fi ve hundred pages of archival WMC records have helped the cause significantly. The shaft refurbishment and reconstruction stage is complete. This has been a program that originally commenced back in 1993 and has cost around $22 M. This refurbishment paved the way for the extensive underground resource focused diamond drilling program, which MCO completed in 2008 with two company-owned and operated drill rigs from drill cuddies on level 9 (900 feet underground) of the mine. This drilling, which encountered some stunning grades intersections and multiple visible gold hits, has outlined further production opportunities including 0.4 m @ 1392 g/t Au (MS 410). Metallurgical testing conducted by Gekko Systems of samples obtained from the exploration program found gravity concentration and a leach circuit gave recoveries of ~95 per cent to 99 per cent, or ~92 per cent from gravity alone at a coarse crush (300 ¦m). Currently, the plan is to use gravity to fi rstly produce dore bars on-site from the free milling gold and secondly a saleable concentrate for CIL processing off-site. A purpose built 10 t/h (~80 000 t/a) gravity treatment plant was subsequently ordered from Gekko and is expected to be installed onsite and commissioned in the Q3 2010. The plant features fi ne crushing with a vertical shaft impactor, followed by gold concentration by inline pressure jig, inline spinner and Wilfley table. This is an ABSTRACT ONLY. No paper was prepared for this presentation.

Aug 1, 2010

By Cary E. Ronan, Tyler Toledo, Justin Ray

The Oyster Point development is located near the San Francisco Bay margins in South San Francisco, just north of the San Francisco International Airport. The eastern peninsula of Oyster Point was formerly operated as a municipal landfill from about 1956 until it stopped accepting waste in 1970. The Oyster Point Landfill is currently being redeveloped in phases, in cooperation with the City of South San Francisco, as a combination of public open space, life science campus (laboratory/research facilities, amenities buildings, parking garage), and a hotel. This paper focuses on Phases 1 and 2 of the life science campus development. The site conditions vary drastically across the site with a portion of the site underlain by shallow bedrock and a portion of the site underlain by up to 40 feet of municipal refuse over 50 feet of soft, compressible clay (Bay Mud) and up to 80 feet of alluvial deposits, with bedrock at a depth of about 150 feet. The varying subsurface conditions below the planned buildings led to a foundation system consisting of a combination of shallow and deep foundations. Deep foundations consist of driven steel HP-piles for Phase 1 and augered cast-in-place (ACIP) piles for Phase 2. Because of a steeply sloping site, over 20 feet of fill was placed in some areas to create a level building pad, resulting in over 5 feet of long-term estimated settlement. This paper will discuss the challenges and lessons learned during redevelopment of the Oyster Point Landfill. Specifically, we will discuss the design of piles and utilities to account for longterm settlement and corrosion, pile load test results, and interpretation of load test data. We will also compare and contrast the use of steel HP-piles and ACIP piles installed for building support through the landfill within Phases 1 and 2 of the development.

Oct 31, 2023

By Juan Villanueva, Otto Sandoval

Antapite, en periodos anteriores (2001-2012), fue explotada con métodos de explotación subterráneos convencionales; sin embargo, este diseño tradicional era insuficiente para plantear un modelo económico sostenible sobre los escasos recursos geológicos, lo que motivó a la compañía Sierra Antapite a repensar el contenido del yacimiento que adquirió en el 2015. En el año 2017, Sierra Antapite empezó la rehabilitación de labores, con la finalidad de explotar vetas in situ, por el método de corte y relleno convencional. Asimismo, planea recuperar rellenos (para vetas explotadas anteriormente) por el método de taladros largos mecanizado.

Sep 20, 2019

By Gresham J. J

The rapid and successful development by Western Mining Corporation Limited (WMC) of a gold mining industry based on the deposits of the Kambalda-St Ives group, was the final chapter in a story that started some 85 years earlier. Although the exploration work that led to the development of the current mining operation took place in the 1970s and 1980s, the successes had their roots in the 1890s and it took three gold rushes, and separate uranium and nickel exploration booms to make the discoveries Possible.

Jan 1, 1991

By Kurt Stock

The war caused a demand for enormous quantities of high-grade zinc, which were not available and could not be produced from pure ores in sufficient amounts and in the time required. Redistillation of virgin spelter on a large scale was practiced to supply this demand; this paper gives a full description of the process used by the Oklahoma smelters of the Bartlesville Zinc Co. As the redistillation of zinc has become of historical interest only, having been superseded by the electrolytic process, it was deemed advisable to give expression to this phase of the metallurgy of zinc that, in the past, had never gone beyond laboratory experimentation. THE grades of spelter demanded by the consuming industries were not definitely established until the American Society for Testing Materials undertook to fix specifications, based on the varying percentages of the common impurities (lead, iron, and cadmium) as follows: TOTAL, NOT LEAD, IRON, CADMIUM, OVER. PER PER CENT. PER CENT. PER CENT. CENT. A. High grade 0.07 0.03 0.05 0.10 B. Intermediate 0.20 0.03 0.50 0.50 C. Brass special 0.75 0.04 0.75 1.20 D. Prime western 1.50 0.08 The question which grade was the best for certain purposes and why was left unanswered. The conservatism of the zinc-smelting industry and the unwillingness of the spelter-consuming industries to engage in research work prevented the full benefits being obtained that such standardization promised. The custom smelters, producing spelter in pigs or plates, found it impossible to adhere closely to the established limits on account of the variety of ores treated; and the smelters with long-established and known brands, or those manufacturing their metal into marketable products, like sheet zinc, did not have to abide by the newly established grades based on chemical percentages.

Jan 7, 1924

Reduce rockfall fatalities and injuries by using innovative blasting practices to reduce damage to the rock at the excavation limits with little or no increase in cost. The Problem Falls of highwall have been a leading cause of fatalities, injuries, and equipment damage in the surface mining industry. Although the number of highwall falls is not great, when such an incident does occur it is about 14 times more likely to be fatal or result in severe injury and damage to equipment than other types of surface mine accidents. Overbreak or damage to the rock from poor or improper blasting practices is a major factor contributing to rock falls. Presplitting or cushion blasting is the technique most often recommended for improved wall control. This type of blasting however, adds to drilling and blasting costs and is not universally accepted by the industry. Air gap presplitting techniques, also called air decks, are currently being used in some mines as a less costly alternative to conventional presplitting. Approach Blasting can cause highwall damage, but proper blasting techniques have been shown to reduce the magnitude of rockfall problems. In preventing rock falls, it is important to maintain the natural strength of the rock structure to the greatest extent possible. Improved blasting practices have three main advantages: 1) they are preventive rather than corrective in nature; 2) they are cost effective; and 3) they have a very low impact on the mining operation when properly implemented. New ways of evaluating highwall integrity, such as seismic refraction tomography, were investigated.

Jan 1, 1991

By Douglas L. Gerner

In the early 1950's fishermen and their families around Minamata Bay in Japan were stricken with a mysterious neurological illness. The Minamata disease, as it came to be called, produced progressive weakening of the muscles, loss of vision, impairment of other cerebral functions, eventual paralysis and in some cases coma and death. The victims suffered structural injury to the brain. Minamata seabirds and household cats which, like the fishermen, subsist mainly on fish, showed signs of the same disease. This led to the discovery of high concentrations of mercury compounds in fish and shellfish taken from the bay, and the source of the mercury was traced to the effluent from a factory. Since then there have been other alarming incidents. In 1956 and 1960 outbreaks of mercurial poisoning involving hundreds of persons took place in Iraq, where farmers who had received grain seed treated with mercurial fungicides ate the seed instead of planting it. Similar outbreaks occurred in Pakistan and in Guatemala. In Sweden, game birds and other wildlife, apparently poisoned by mercury-treated seeds, began to be noticed in 1960. The Swedish Medical Board in 1967 banned the sale of fish from 40 lakes and rivers after it was found that fish caught in those waters contained high concentrations of methyl mercury. In 1970 alarm rose in North America. Following the discovery of mercury concentrations in fish in Lake Saint Clair by an investigator working in Canada, restrictions on fishing and the sale of fish were imposed in many areas in the U.S. and Canada. Government agencies in both countries began to take action to control the discharge of mercury-containing wastes into lakes and streams.

Jan 6, 1973

Solution transport of gold and silver has occurred as a result of the chemical weathering of many Western Australian epigenetic gold deposits. Evidence for the remobilization of gold exists in the form of small crystalline octahedra, mustard gold, flake gold, and coatings on iron-oxide. This "secondary" gold is of high purity (low silver content). It is believed that the high chloride content of laterite profiles combined with the acid produced by the oxidation and hydrolysis (ferrolysis) of iron has caused dissolution of Au/Ag and Au/Te alloys. Gold, and less frequently silver, is subsequently reprecipitated in the profile nearby.Pyrite, which is a ubiquitous accessory of gold in vein or lode systems, is probably an important source of iron for the development of acidity. Where carbonate is abundant in the primary assemblage, neutralization directs the oxidation of sulphide to a path which produces thiosulphate, and an alternative type of Au/Ag oxidation process. Sulphide/carbonate ratios in the vein system, and adjacent wallrock are seen as important in determining the course and extent of remobilization in the oxidized zone of gold deposits.

Jan 1, 1984

By Rodney Hundermark, July Ndlovu, Lloyd Nelson, Phillimon Mukumbe, Paul van Manen, Whitey Seyanund, Bart Pieterse, Bertus de Villiers, Diale Mokwena

The 2003 redoubling in power to 68MW on the Polokwane Smelter furnace represented a significant intensification in platinum group metal (PGM) smelting. Combined with onerous ‘green’ PGM concentrate smelting requirements, this yielded conditions unusually corrosive to copper coolers and refractories. This presented unexpected operational and design challenges to reliable crucible operation and maintenance. Combined with specific operational control intervention, development of protective coatings has led to the life of water-cooled copper components improving from 9 to 40 months. The furnace matte endwall was extended in 2010 to address accelerated wear of refractories and the potential risk for contact of copper components by superheated matte. An 18 month planned endwall rebuild cycle has been demonstrated (versus catastrophic failure within 9 months). Finally, benefits including lower energy consumption, improved metal recoveries and higher productivity resulting from operational and in-house design developments will be described, that justify “Celebrating the Mega-scale” in PGM smelting.

Jan 1, 2014

By Issa S. AI-Kharusy

Oxidation/reduction (REDOX) alloy media, as used in wastewater treatment, is founded on the exchange of electrons. Because of this electron exchange, many contaminants are converted to harmless components which require no further treatment. Other types of contaminants are removed from the waste stream by electrochemically bonding to the alloy medium. This paper discusses the REDOX reactions, the role of the alloy medium in various treatment processes, and describes specific applications of REDOX alloy media for the removal and minimization of waste. The characteristics and handling of spent treatment media is also reviewed as a further consideration in waste minimization.

Jan 1, 1996

By S. Fletcher, C. Calle, K. Constanti-Carey, R. Ruzbacky, M. D. Horne

Laboratory test-work has established that two classes of redox catalysts based on anthraquinone and bipyridinium derivatives are effective in accelerating the rate of removal of metallic iron from reduced ilmenite (RI) in the aeration step of the Becher process. Two water-soluble anthraquinone derivatives are efficient: 9,10-anthraquinone-2,6-disulfonicacid, disodium salt (catalyst AQ-2,6) and 9,10-anthraquinone-2-sulfonic acid, monosodium salt(catalyst AQ-2). When 0.2 per cent w/v of either was added during aeration the rate of metalliciron removal was accelerated by two to three times. Furthermore, the addition of either compound resulted in magnetite (Fe3O4), the iron oxide phase preferred in commercial practice, being formed. However, both AQ-2,6 and AQ-2 were rapidly lost from solution during aeration although their catalytic activities persisted even when their concentrations in solution were low(<0.05 per cent w/v). The negatively charged anthraquinones were lost from solution most probably by adsorption onto the magnetite that has a net positive charge at the pH values encountered during aeration. To address this problem, the catalytic activities of positively charged bipryridinium derivatives were tested. Two water-soluble bipyridinium compounds, paraquat (1,1’-dimethyl-4,4’-bipyridinium dichloride) and diquat (6,7 dihydrodipyrido [1,2-a:2’,1’-c] pyrazinediiumdibromide), were found to significantly accelerate the rate of removal of metallic iron from reduced ilmenite, and both gave magnetite as the oxide product in the laboratory tests. Moreover, recycle tests showed they were not lost from solution as quickly as were the anthraquinone derivatives. Results in larger scale plant laboratory reactors also showed a significant increase in aerationrates when diquat was added and magnetite was again the oxide formed. However, the oxygensupply to the reactors was insufficient to achieve the maximum effect of the catalysts on theaeration rates. The limited supply of oxygen in a full scale aerator may prevent the application ofthe catalysts in a commercial Becher operation. Keywords: Becher process, aeration, anthraquinone, bipyridinium, redox catalyst, reduced ilmenite

Jan 1, 2003

By W. K. Tolley

The U.S. Bureau of Mines (USBM) is currently investigating improved technology for mineral flotation. A variable often neglected in flotation control is redox potential. The use of redox control is illustrated by the separation of molybdenite from chalcopyrite. Laboratory testing showed that redox potential had a greater effect on product quality than collector addition. A significant need in froth flotation is greater reliability of the sensors used in measuring and controlling redox potential in mineral slurries. The USBM has developed an automated method for removing scale and reconditioning gold redox-sensing electrodes. Fouled electrodes are anodically polarized to 1.2 V versus the AglAgCI reference potential to remove scale. The electrodes then are conditioned by a brief potentiodynamic treatment to re-establish electrochemical equilibrium. In laboratory tests, this technique removed calcarious deposits from gold electrodes and reconditioned them for useful service in approximately 10 min. In plant practice, this technique would obviate the need for plant operators to manually polish electrodes, and also should result in greater reliability in redox measurements. Inexpensive, automated equipment to condition electrodes in a plant setting is described.

Jan 1, 1995