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By E. S. Longfellow, S. H. Katz

Poisonous hydrocyanic acid gas (HCN) is sometimes evolved in dangerous quantities from cyanides used in metallurgical and chemical operations. This gas is much used for fumigating buildings, ships, greenhouses, and such commodities as grain and cotton to destroy rats, mice and insect pests. Wherever cyanide fumes are evolved, thorough ventilation is necessary in order to render the sur- rounding air safe to breathe. Many persons have been killed by entering tanks and fumigated places too soon, and a simple test for this gas would promote safety. In view of the need for an easy method for quantitatively determining HCN in air, the three color reactions used originally for testing HCN in solution tions *** were modified and adapted. The reactions employ (1) picric acid (CH(NO2)3OH) which is yellow but combines with hydrogen cyanide to form a red- purple dye, isopurpuric acid****; (2) phenolphthalin (CH1604), which is a reduc- tian product of the phenolphthalein (CH4) used for acid indicator, this colorless substance is oxidized***** by presence of HCN to pink colored phenolph- thalin; and (3) guaiacum which oxidized from colorless to blue******. Phenolph- thalin and guaiacum require the presence of copper compounds which catalize the color formation by reduction of cupric cyanide. The chemical processes involved *Associate physical organic chemist, Bureau of Mines, Department of the Interior. **Assistant gas chemist, Bureau of Mines, Department of the Interior. 2014 20 *** Kohn-Abrest, E., Notice toxicologique sur les gas: Arnales des Falsifica- tions, vol. 8, 1915, pp. 215-35. (Tested air with picric acid and guaiacum papers). **** Élasiwietz, H., Ueber eine neue Zersetzungsweise der Trinitrophenylsaure: Anal. der Chemie, vol. 110, 1859, pp. 289-303. ***** Weehuizen, F., Phenolphthalin as reagent for HCN: Pharmaceutrisch weekblad, Utrecht, vol. 42, 1905, pp. 271-2. Abstract, Jour. Chem. Soc., vol. 88, part 2, 1905, p. 489. ****** Schonbein, C. F., Ueber den thatigen Zustand der Helfte des in dem Kupfer- oxydenthaltenen Sauerstoffs und ein darauf beruhendes hochst empfindliches Reagens auf die Blausaure und die loslichen Cyanmetalle: Jour. fur. Praktische Chemie, vol. 106, 1869, pp. 263-70.

Jun 1, 1923

By S. H. Katz, J. J. Bloomfield

In studies of mine and tunnel ventilation conducted by engineers of the Bureau of Mines , various smokes are used to determine flow of air , direction of the currents , and the rate of mixing . The instrument for generating streams of sulphur trioxide (SO ) smoke , shown in the drawing herewith, has been found helpful , convenient and practicable for such purposes ; it is also especially useful in some places where fire for generating smokes is not permissible . The apparatus consists simply of a glass tube containing fuming sulphuric acid on granular pumice stone , attached to a rubber syringe bulb . When a squeeze of the bulb blows air through the tube , a stream of dense white smoke evolves, which follows and makes visible the air currents . The tubes after preparation are hermetically sealed to prevent deterioration . When ready for use , they are easily broken open at a file scratch for the purpose on both tips , and inserted into a rubber nipple at the bulb . Sometimes it is of advantage to attach them to a longer rubber tube leading to the bulb . Tubes of the size shown (about 1/2 inch outside diameter by 5 inches long) are usually sufficient for the needs of a day . Thereafter they cease to fume because the acid absorbs moisture from the air and looses its effectiveness . Smaller sizes of tubes and larger have been made , but the size shown has proved most practicable . Immediately after a person has finished using a tube it should be buried or disposed of in a place where it will not be touched by shoes or clothing, or come in contact with wooden floors , furniture , or metals , because the acid , which will eventually leak from the tubes , is highly corrosive . -- Reports of Investigations , Department of the Interior , Bureau of Mines .

Jul 1, 1923

By L. C. IlsLey, H. B. Freeman

In connection with the approval of coal-cutting machines for service in gaseous mines , the engineers of the Bureau of Mines have been somewhat concerned as to the type of trailing cables that could safely be used on permissible outfits . While no final action has been taken on this question ( tentative approvals having been granted pending investigations ) , the Bureau has been endeavoring to collect data and information on this question which would permit a fair , yet safe , ruling to be made . For this purpose cooperative arrangements were made with three coal companies to visit certain of their mines , making inspections inside the mines to observe the cables and cutting machines in operation . In all , twenty mines were visited . A questionnaire covering the operations of trailing cables was filled out at each of these mines . In a few instances no personal inspection was made , the information being supplied by mine officials after conferences with the Bureau's engineer . At other mines the information given by mine officials was supplemented by personal observation inside the mines , usually at a time when the cutting machines were in operation .

Jul 1, 1923

By Mayo D. Hersey

This problem was taken up by the Bureau of Mines as a result of the oxygen explosion at the Jefferson Physical Laboratory of Harvard University , and other similar explosions , in order to supply technical information which would serve as a basis for safety precautions in the future . At the Harvard inquiry the fact was emphasized by the Massachusetts State Chemist , Mr. Walter M. Wedger , that we do not know the limiting pressures and temperatures above which compressed oxygen and lubricating oil are capable of spontaneous explosion . The problem is also of importance to the Army and Navy and to the Bureau of Mines in connection with the hazards incurred in the use of compressed and liquified gases in the repurification of helium. In fact , the risk of fires and explosions due to traces of lubricating oil coming into contact with high pressure oxygen is of serious interest to all concerned with the manufacture and use of oxygen , a commodity which is now being produced and distributed on a rapidly increasing scale . Part of the money expended on this investigation was from Army and Navy funds . The problem was undertaken by the Bureau of Mines at the suggestion of Dr. Charles E. Munroe , Chairman of the Committee on Explosives Investigations of the National Research Council , and referred to the Pittsburgh experiment station of the bureau.

Jul 1, 1923

By L. D. Wyant

That natural gas-gasoline can be used to advantage as a refrigerant is suggested by the fact that the "make" tanks and other parts of the equipment of gasoline plants frequently become coated with frost. The experiments reported in this paper confirm this assumption and indicate that volatile gasoline can be use used to advantage in many refrigerating plants. The Bureau of Mines is making a study of wax distillates in order to find out why satisfactory lubricating oils and waxes can be made easily from certain crude oils and only with difficulty from others. In the commercial distillation of crude petroleum it is customary to separate the distillates into the following groups: (A) Gasolines and naphthas, (B) Kerosenes, (C) Gas oil, and (D) Wax distillate (consisting mostly of light lubricating oil together with small amounts of paraffin Wax).

Jan 1, 1923

By N. F. LeJeune, Earl C. Lane

This is the third of a series of reports on a survey of petroleum prod- ucts manufactured on the Pacific Coast from California crude oils. California crudes differ in many characteristics from the petroleum produced in the other parts of the United States, and the claim has been made that some of the present Federal Specifications for petroleum products tend to discriminate against Cali- fomia products. The purposes of the present survey are to determine what par- ticular specification requirements Califomia petroleum products characteristical ly fail to meet, how widely the products deviate from these requirements, and if possible to show whether the fault lies with the specifications or the products, or along what lines investigation to determine this question should proceed. The first report of the series gave the physical and chemical properties of the samples of gasoline and mineral spirits. A second report**, gave the physical and chemical properties of samples of lubricating oils. The present report deals entirely with burning and fuel oils. The refin ing companies have continued their very cordial and helpful cooperation. Seven samples of kerosene, four samples of Diesel fuel and eight samples of fuel oil were obtained. The methods of analysis used are those adopted by the Interdepartmental Petroleum Specifications Committee, published by the Bureau of Mines in Technical Paper No. 323. The specifications used for corparison are those officially adopted by the Federal Specifications Board for the use of the various Depart- ments and Independent Establishments of the Government, effective February 3, 1923, and published by the Bureau of Mines in Technical Paper No. 323, Part 1. Specific gravity, degrees A.P.I., viscosity and other special tests al- though not required by the specifications have been given for comparison. All temperatures are recorded in degrees Fahrenheit. Tables have been prepared giving data on physical and chemical propertios of the individual samples. Before each table the classification and specifica- tions for the particular class of oil considered in the table are given. Follow- ing each table, brief notes show wherein samples deviate from specification re- quirements.

Aug 1, 1923

By R. T. Stull, G. A. Bole

Previous Work . The Bureau of Mines reported a survey of bond clays for graphite crucibles at the American Mining Congress which met at St. Louis in November , 1919 *** . The report contained information in regard to : (a) tests carried on to determine the effect of substituting Canadian and Alabama graphites for Ceylon graphite in varying proportions . The data indicated that Alabama graphite is superior to Canadian graphite and further , that Alabama can be substituted for Ceylon graphite to a large measure without lowering the quality of the ware . These tests were made on No. 70 size brass melting crucibles and were carried out under foundry practice . (b ) Tests were reported in which an attempt was made to modify the nature of Alabama graphite by heat treatment so as to resemble Ceylon graphite . Little advantage from the treatment was reported . With this general information as a basis , the experimental work proceeded along two lines : A study of bond clays for steel -melting crucibles and for brass -melting crucibles . Twenty- one sets of standard-size crucibles were made up of a body containing Ceylon graphite as standard , bonded with 21 bond clays . These tests were carried out under foundry practice as were the former tests . Three domestic clays proved to be superior to the standard Klingenberg clay formerly used in brass -melting practice while in the steel - melting industry , 13 domestic clays gave service superior to Klingenberg clay .

Aug 1, 1923

By M. H. Rinkenbach, C. A. Taylor

The detonating compound cyanuric triazide was discovered*** and patented**** by Erwin Ott, and on account of his claims, the Bureau of Ordnance, U. S. Navy, desired more complete data, so an investigation was made. The results obtained were such that the Bureau of Crdnance recommended publication thereof for the benefit of the explosives industry. Some of the patent claims regarding cyanuric triazide are as follows: 1. It is not poisonous in contradistinction to fulminating mercury and lead azide. 2. In contradistinction to the hitherto employed priming agents it is fusible, and its fusion point (94°C) is so low that the product melted by a single heating in water or steam bath, can be poured without danger in the capsule shell. It solidifies therein after cooling, and shows the density of 1.5. 3. It has been determined that the cyanuric triazide, in spite of its very much higher priming actions, is much less brisent then ful- minating mercury and lead nitride. 4. The chemically pure cyanuric triazide (C3M2) constitutes colorless crystals melting at 94°0., and is not volatile. It is not affected by cold water, and only slowly saponified by hot water. It is relatively insensitive to friction and not too strong concussion, but explodes by impact or when hea ted to 170°C., or when heated suddenly. It is not more sensitive to friction and shocks then fulminating mercury. 5. The preparation of the triazide is preferably carried out by acting with an excess of sodium azide in an aqueous solution; in the cold, on cyamric chloride gradually suspended in the said solution.

Aug 1, 1923

By A. C. Fieldner

It is estimated that 6,202,235,000 gallons .of- gasoline was produced during the year 1922. The crude light oil- output Burin- the same year is estimated at 111,000,000 gallons, or 1.8 per cent of the gasoline production. In fact, if all the coal mined were coked in by-product ovens, and the light oil recovered therefrom, this product would amount to only 15 to 20 per cent of the quantity of the petroleum gasoline now produced annually. It is obvious therefore, from these figures that the light oils by present coking processes can not assume great importance as a gasoline substitute in a national sense. However, the use of light oil as a motor fuel is of real importance in districts adjacent to by-product coking operations from which a reasonable proportion of the local motor fuel supply may be derived. The certainty of diminution of petroleum resources in the relatively near future demands the utmost utilization of gasoline substitutes from the distillation of coal as well as other sources. Motor benzol is a by-product from the destructive distillation of coal. From 11/2 to 3 gallons of refined motor benzol is obtained per ton of coal carbonized. The light oil vapors are extracted from the by-product coke-oven gas by passing it upward through a series of towers in which these vapors are absorbed in a descending current of "wash" oil (petroleum distillate). The light, oil is recovered from this wash oil by distillation with live steam, the resulting crude light oil consisting of a mixture of benzol, toluol, xylol, solvent naphtha, and a small amount of other substances (unsaturated hydro-carbons, carbon disulphide, and other sulphur compounds, phenols and pyridines) is then transferred to an intermittent still and fractionated into crude motor benzol, which includes the toluol and a part of the xylol or light solvent naphtha. The crude, motor benzol is yellow in color, contains sulphur compounds which corrode copper and brass, and also contains unsaturated bodies which oxidize and polymerize on standing, producing sediment and forming gummy deposits highly objectionable when the benzol is used in motors. These objectionable

Jan 1, 1923

By John H. Thompson

Recent studies ** at the Pittsburgh Experiment Station of the Bureau of Mines have revealed some interesting facts as to the probable behavior of steamed coke in the blast furnace . The literature on the chemistry of the blast furnace was tho roughly reviewed , and with this information in mind , the probable behavior of the coke sulphur in the blast furnace was deduced . Enough small - scale tests were conducted to furnish a check on most of the important deductions , and the conclusions derived therefrom accord with what is already known in regard to the forms of sulphur in coke , and fit in well with the general opinion concerning blast-furnace reactions .

Aug 1, 1923

By RUDULF KUDLICH

Pennsylvania anthracite coal is almost universally recognized to be the solid fuel best suited for domestic use when cleanliness , convenience and cost are considered . At various times and in various localities , however, conditions so affect the supply that it becomes insufficient or is too high in price and recourse must be had to other fuels as substitutes . In practically every district in the United States where anthracite has been the common domestic fuel , some other fuel is available as a substitute . In even the most severe climates such fuels are used either as emergency substitutes for anthracite , or as the ordinary domestic fuel . There may be some drawback to the use of such fuel , such as the need of more frequent attention to the furnace , smoke , soot and dust , in the case of solid fuels lower in price than anthracite , but these inconveniences must be accepted as necessary accompaniments to a decreased fuel bill . The cleanliness and ease of handling anthracite in the house must be considered in the light of a luxury and a higher cost of heating with this fuel must be expected . That a growing number of people are willing to pay for such added convenience is evident from the increasing mumber of heating installations using oil , gas and electricity , all of which are more convenient and usually more expensive even than anthracite .

Aug 1, 1923

By S. P. Kinney, P. H. Royster, T. L. Joseph

An investigation of the production of iron in the blast furnace is obviously not an easy subject for research . Enough is known of the mechanical , thermal and chemical conditions existing inside the furnace to say certainly that they are complicated. Furnace operators have found that the process is sensitive to a number of known and to many unknown operating conditions . In order to form any conclusions of value , it seems necessary to collect a large amount of data taken with considerable care and accuracy. These facts make a blast furnace research difficult but not impossible . The most serious obstacle in attacking the problem comes from the fact that it is useless in the design and operation of the blast furnace to use the method of " trial and error , which has proved valuable in so many other industrial problems . The variables are so interrelated and are so dependent one on the other that the number of experimental combinations to be tried is enormous . There are certainly not less than twenty factors in furnace operation and design that are known to influence the results . This is apparent if it is remembered that a phrase like " size and shape of the furnace" includes height of the furnace , height , diameter and angle of the bosh , inwall batter , stockline diameter , and furnace volume ; and that a phrase like " chemical and physical properties of the fuels charged " includes size and shape of the lumps , density, porosity and strength of the coke , in addition to its chemical analysis . Let us suppose that we need choose for each of twenty factors one of two values , for example , suppose we must say only that the furnace shall be " tall " or " short , " that the bosh angle shall be " flat " OF "steep , that the ore shall be " coarse " or " fine , " or that the blast has to be "hot" or " cold , " the number of resulting combinations is more than one million . In putting twenty pennies on the table , either heads up or tails up, the number of permutations possible is the twentieth power of two , slightly more than one million. It is obvious , therefore , that some sort of mathematical relationship , a set of rules of thumb , laws , curves or the like , are needed . Whether the relationships , curves or formulas are derived from experiment , from theory, or from mere guess -work, makes no difference provided they agree with the known facts . If they do not agree with known facts , they are worthless no matter what their origin or how weighty the " authority" vouching for them. Few such relationships have appeared in blast- furnace literature , and it may be doubted whether such formulas can be discovered .

Sep 1, 1923

By N. F. Le Jeuns

For a number of years the Bureau of Mines has conducted semi-annual surveys to determine the changes in motor gasoline being sold in the United States. It was pointed out in the previous survey that there was an apparent tendency toward greater uniformity in the character of gasoline marketed in the United States. This practically uniform tendency which continued from April, 1917 to January, 1923, has been interrupted in the, present survey, as shown by an examination of the column marked "Difference," as given in Table 1. The figures in this table were obtained by averaging the end points of the least volatile and most volatile samples of gasoline. For example, of 850 samples analyzed in 1919, the 10% ,(85 samples) having the highest end points and the 10% having the lowest end points mere grouped, and the end points of each group averaged. These averages are represented in the table as the "Maximum 10%" and the ?Minimum 10%? respectively. The same process was used on the other surveys.

Jan 1, 1923

By R. D. Leitch, C. A. Taylor

Trinitrotoluene is made by the direct nitration of toluene by a mixture of nitric and sulphuric acids . The exact procedure varies , but the product , where Grade I of TNT is desired , is similar , and consists largely of material that has a melting and setting point of 80.6 °c . The purification consists of draining off the liquid portions , including the acid and liquid nitro compounds . The mass is crushed and washed until the TNT is acid - free . It may still have a low-melting point due to the presence of material of lower nitration. Other isomers also have the same effect . The crystal mass may be washed with a solution of sodium sulphite , thiosulphate , sulphuric acid , or with an organic solvent such as alcohol , benzene , or carbon tetrachloride , Where a very pure product is desired , the TNT is separated by fractional crystallization from solution in organic solvents . The TNT is If it forms In some cases the material is melted during purification . agitated as it cools to prevent solidification in a solid mass . in a solid mass , this is broken up and screened . There has been some question as to the effect of the different methods of purification on the strength and sensitiveness of TNT , although all methods left a product that would give satisfactory tests .

Sep 1, 1923

By G. E. McElroy, A. S. Richardson

"The Bureau of Mines, in cooperation with the Anaconda Copper Mining Co., has conducted a series of experiments an air measurement in fan-pipe installa¬tions in a Butte mine during the fall and winter of 1922-3. The chief purpose was to determine the friction factors for different types and sizes 3f fan piping, but much attention was devoted to methods of air measurement, not only with respect to the methods used for friction factor tests, but also to com¬parison with other methods.The air flow was measured simultaneously at two points 380.6 feet apart in six different fan-pipe installations, each over 500 feet in overall length, in a rock cross cut adjacent to an air shaft,The air pressure was regulated by two sinoco multivane fans, driven by 7 ½ h.p. motors, the fans being connected in tandem so that one discharged into the intake of the other through a short connector and the latter discharged into the line through a straight connection equipped with a honeycomb of 4-inch squares or S radial vanes to prevent spiral flow of air, At each point where it was desired to measure the air flow, measuring sections equipped with piezometer rings pierced for easy insertion of pitot tubes, thermometers, etc. Piezometer static pressures were used in all the tests as standard, and dynamic or total pressures only were obtained with the pitot tubes, except for purposes of comparison.The tubes had special guide blocks, designed especially for underground work. To insure greater accuracy two tubes were used simultaneously, in order to obtain the velocity pressure at the center of the section simultaneously with that nearer the circumference, so that the mean velocity would be determined as accurately as possible. The tubes were held in proper place by means of flat guide boards. Velocity pressures were measured in manometers."

Sep 1, 1923

By L. C. IlsLey

"There are two general classes of accidents that prevail in and about mines, namely - (1) those that through the nature of mining work can only be lessened, and (2) those that by proper precaution can be eliminated altogether. Explosive accidents that ordinarily take place while explosives are being transported in and about mines belong to the second class, that is, by proper care all such accidents can in general be avoided.The following table gives a brief summary of several accidents and disasters that have occurred in the United States and indicates the need of universal preventive measures as a basic part of all State regulations.ACCIDENTS AND DISASTERS OCCURRING WHILE TRANSPORTING EXPLOSIVES.***"

Sep 1, 1923

By H. C. George

This report presents a comprehensive tabulation of lifting cost data collected from oil companies in many different fields. These data were collected during the writer's studies of surface equipment and methods of pumping oil wells, in practically all of the important oil fields in the United States and are based on average operating conditions at 57 groups of properties with a total of 4,497 producing wells. Although lifting cost is only a part of the total cost of producing oil, it nevertheless gives a representative cost figure for purposes of comparison.

Jan 1, 1923

By Ludwig Schmidt

The consumption of gasoline in the United States varies materially with the seasons; during some of the summer months it exceeds the rate of production and in the other seasons the production of gasoline exceeds the consumption, The usual practice of the larger refiners is to store surplus stocks during the winter season in order to meet the heavy demands during the summer months. The following table shows the stocks of gasoline at refineries on the last day of April for the past five years: 1919 593,616,170 gallons 1920 643,5526644 " 1921 747,222,900 " 1922 892,567,766 " 1923 1,336,417.871 "

Jan 1, 1923

By Oliver Bowles

"Conservation of slateWaste slate is a problem of outstanding importance in the slate industry, for a very large proportion of all slate quarried is thrown on the waste heap. While many uses for waste slate have been found, the demand calls for merely a fraction of the present supply of unused material. If the slate industry is to increase in prosperity, the producer's energy must be directed toward the development of ways and means of reducing waste to the lowest possible point. The Bureau of Mines of the Department of the Interior has devoted much study to this problem and a recent bulletin ** contains a detailed discussion of the waste problem.Attention has recently been directed toward an improved method of cutting slate in quarries, a method that promises to reduce greatly the percentage of waste material. The method has been introduced since that bulletin was published, and this supplementary paper covers the details of the process.A reversion in method,In connection with this new mode of operation history is repeating itself in a very interesting way, for the old quarry bar used years ago with steam drills, and later discarded in favor of the channeling machine .and the hammer drill, has been salvaged from the scrap heap, and again put to active use. The occasion for its employment is an attempt to improve quarry methods by the substitution of drilling for channeling or blasting."

Oct 1, 1923

By W. H. Rinkenbach, C. A. Taylor

"Among the recently patented detonating compounds that have been suggested as substitutes for the commonly used fulminate of mercury is the normal lead salt of trinitroresorcin, or styphnic acid. As no data concerning its use or practi¬cability were available, a study of its properties was made in the explosives laboratory at the Bureau of Mines experiment station at Pittsburgh, Pa. This paper embodies the results obtained.Normal lead trinitroresorcinate was first prepared and patented*** by Herz; it probably found some use during the World War, but no record of its performance is available,Preparation of Lead Trinitrpresorcinate.In his patent specifications, Herz states that the normal salt may be obtained in a quantitative way by precipitating a multiple of the equivalent weight of the lead salt of a strong inorganic acid - such as lead nitrate - in the presence of a weak organic acid - such as acetic acid - by heating with a Teak solution of the alkali-metal salts or alkaline-earth salts of trinitroresorcin. Herz gives the following example: 245 grams of dry trinitroresorcinand 290 grams of crystalline sodium carbonate are dissolved in in 18.8 liters of boiling water, to which 77 c.c. of glacial acetic acid is added. The toiling solution is mixed with a boiling solution of 650 grams of lead nitrate in 1.4 liters of water, stirring rapidly; and the mixture is boiled for two minutes, after which it is cooled quickly with constant stirring. The precipitated crystals are then filtered off, washed several times with cold water, and dried."

Oct 1, 1923