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By R. E. Heithecker, Van A. Mills

"Crude oils are capable of dissolving quantities of gas under pressure. This fact has been known for some time, but questions have arisen as to the effects of gas in solution upon the characteristics of the oil. Previous investigations4 show that gas in solution in an oil affects the viscosity and surface tension of the oil, but the effects on the volume and A. P. I. gravity of the oil have not been known. The results given in this report show that there is a decided change both in volume and in the A. P. I. gravity of the oil due to the solution of the gas in the oil under pressure. As gas is dissolved, the volume of the oil and the A. P. I. gravity increase. The converse of this phenomenon is also true: if the gas is released from a saturated oil, there is a shrinkage in volume and a decrease in A.P.I. gravity due to the release of gas from solution. However, various oils show marked tendencies to retain a portion of the dissolved gas upon releasing the pressure to that of the atmosphere. This retained gas has an appreciable effect on the volume and A. P. I. gravity of the oil because the oil does not resume its initial volume or gravity while it retains dissolved gas. In a sense the oil has been ""freshened"" and will not return to its original or weathered volume until it loses some of the lighter fractions. Wiggins5 has shown that a fresh oil decreases both in volume and in gravity because of the weathering of the lighter fractions while the oil is standing in storage tanks.This paper includes data attained during the determination of volume and gravity correction factors to be applied in the oil recovery investigations of the Bureau of Mines. Three oils having a wide range in gravity were used in determining the correction factors. These oils were from the Bartlesville-Dewey field, Oklahoma, the Seminole field, Oklahoma, and the Inglewood field, California. The same gas that was used in the oil recovery experiments was used throughout this investigation. Determinations were made of the volume and A.P.I. gravity increases resulting from the gas going into solution at 200, 400, 600, 800, and 1,000 pounds pressure; also the increases in the volume and gravity of the oil due to retained gas were determined after the dissolved gas was liberated from solution by releasing the pressure to that of the atmosphere.Samples of residual and liberated gas were taken throughout the investigation in order to study the selective absorption and selective retention by the oil of the various constituents of the gas. The analyses of these gas samples showed that there was selective absorption and selective retention of the constituents of the gas. The tests on Inglewood crude gave the most pronounced example of selective absorption and selective retention of the gas.All of the tests were conducted at a constant temperature of 709F."

Oct 1, 1928

By R. Van A. Mills

Crude oils are capable of dissolving quantities of gas under pressure. This fact has been known for some time, but questions have arisen as to the effects of gas in solution upon the characteristics of the oil. Previous investigations4 show that gas in solution in an oil affects the viscosity and surface tension of the oil, but the effect's on the volume and A. P. I. gravity of the oil have not been known. The results given in this report show that there is a decided change both in volume and in the A. P. I. gravity of the oil due to the solution of the gas in the oil under pressure. As gas is dissolved, the volume of the oil and the A. P. I. gravity increase. The converse of this phenomenon is also true: if the gas is released from a saturated oil, there is a shrinkage in volume and a decrease in A.P.I. gravity due to the release of gas from solution. However, various oils show marked tendencies to retain a portion of the dissolved gas upon releasing the pressure to that of the atmosphere. This retained gas has an appreciable effect on the volume and A. P. I. gravity of the oil because the oil does not resume its initial volume or gravity while it retains dissolved gas. In a sense the oil has been "Freshened" and will not return to its original or weathered volume until it loses some of the lighter fractions. Wiggins5 has shown that a fresh oil decreases both in volume and in gravity because of the weathering of the lighter fractions while the oil is standing in storage tanks.

Jan 1, 1928

By C. C. Furnas

In the course of an investigation3 of the flow of gases through beds of broken solids the author obtained a number of data .on the specific volume of beds of broken solids of variously mixed sizes. A mathematical theory of the limiting conditions has been developed and some generalizations have been made for intermediate cases. A more definite knowledge of the relation between space occupied and size composition would be valuable to all those who are handling large quantities of broken materials. Such knowledge might be advantageously applied to the operation of a coke oven. For example, the output of the oven depends in general upon the number of pounds of coal which can be put in the oven at charging. It is known that the capacity of one battery of ovens was increased several per cent by slightly increasing the proportion of fine material in the charge.

Jan 1, 1928

By R. D. Leitch, W. P. Yant

"In the course of another investigation4 during 1926 and 1927, samples of water collected from a few abandoned coal mines indicated that their drainage was usually lower in acidity than water from active mines in the same locality. In order to determine whether this condition might have a bearing on the advisability of sealing abandoned mines, a number of such mines were visited, samples of drainage were collected, and as much information- as possible was obtained from officials of the mining companies and older residents of the district. The results of this work are the basis of the present report.The authors are indebted to E. W. Robertson, F. F. Spowart, J. H. Nagle, and W. D. Adams of the Northwest Mining & Exchange Co.; E. M. Fasset, Fred Lane, Wm. Humphreys, and Dr. T. A. Hutchison of Brockway, Pa.; C. W. .Faulk of the Shawmut Mining Co.; James Hau of Kersey, Pa., and to others for information received; and to Dr. R. R. Sayers of the Bureau of Mines, under whose direction the work was conducted.The Lower Kittanning is the most important bed in the locality studied. A great many of the abandoned mines examined are in this bed, and nearly all of the present active ones are. The Upper Freeport bed is also mined to some extent, and a number of the abandoned mines formerly worked this bed. As only three active mines are now (1927) working the Upper Freeport, the comparison of acidities is necessarily limited. Of these three, one had been idle since 1922 until shortly before it was sampled.The location of most of the mines was already known from previous work, but some of them had to be located by following up streams known to contain acid waters. A sample of the- outflow was collected in self-sealing bottles known as ""citrate bottles"" for the determination of dissolved oxygen by the Winkler method.5 Another sample was taken for the determination of acidity according to standard methods of water analysis.6 Ferrous iron was determined at the mine or very soon after taking the sample by titrating with a standard solution of potassium permanganate in acid solution. The hydrogen-ion value was determined by a standard double-wedge comparator.7From the total acidity values in each sample, which are the most important values, the total iron was calculated on the assumption that acidity as sulphuric acid was due to dissolved ferrous sulphate. This assumption is commonly made for mine waters, but is inaccurate to the extent that free acid is already present, and some of the iron is present as ferric, rather than ferrous, sulphate. The amount of ferrous sulphate may be a rough measure of the extent to which oxygen is lacking within the mine. The permanganate titrations just mentioned showed what part of this total iron was in combination as ferrous sulphate, and the difference .was assumed to be that in combination as ferric sulphate, after correcting for the amount of free acid already formed as shown by the titration values."

Oct 1, 1928

By R. D. Leitch

In the course of another investigation4 during 1926 and 1927, samples of water collected from a few abandoned coal mines indicated that their drainage was usually lower in acidity than water from active mines in the same locality. In order to determine whether this condition might have a bearing on the advisability of sealing abandoned mines, a number of such mines were visited, samples of drainage were collected, and as much information as possible was obtained from officials of the mining companies and older residents of the district. The results of this work are the basis of the present report. ACKNOWLEDGMENTS The authors are indebted to E. W. Robertson, F. F. Spowart, J. H. Nagle, and W. D. Adams of the Northwest Mining & Exchange Co.; E. M. Fasset, Fred Lane, Wm. Humphreys, and Dr. T. A. Hutchison of Brockway, Pa.; C. W. Faulk of the Shawmut Mining Co.; James Hau of Kersey, Pa., and do others for information received; and to Dr, R. R. Sayers of the Bureau of Mines, under whose direction the work was conducted.

Jan 1, 1928

By C. N. Schuette

"The production of silica and magnesia crucibles in the induction furnace was attempted and achieved in the laboratory of the Pacific Experiment Station of the United States Bureau of Mines. This work was undertaken at the request of other stations for laboratory crucibles of a certain specified wall thickness and capacity.The essential new parts of this work are the development of a technique for the high-frequency furnace production of silica crucibles of greater wall thickness than could be readily fabricated from commercial fused silica, and for heavy-walled magnesia. crucibles of great density and mechanical strength. A considerable bode of patent literature on the Production of fused silica ware in resistor-type furnaces was examined, but it furnished no significant help for the present problem. Similarly sintered magnesia refractories are often made for technical purposes, but for use at temperatures of 2000o C. or over, the material must be sintered at higher temperatures than can be attained by combustion firing, and the very great shrinkage encountered at these temperatures requires special methods. Small crucibles. of magnesia fused in the electric arc have been made by Tritton and Hansen,3 but the practical size of such containers is very limited.Many different methods of making crucibles in the induction furnace were tried before satisfactory results were obtained. The following description covers only the most satisfactory method, which produced crucibles of excellent quality in a reasonable time and with a moderate expenditure of power and materials."

Oct 1, 1929

Heavy liquids have come into use in ore-dressing investigations, as they make possible the separation of an ore into its specific-gravity components. A paper containing a general dissertation on heavy liquids has been written by John D. Sullivan,4 and the practical application of heavy liquids is explained by Box and Crabtree5. Some heavy liquids become discolored after continued use, and the lack of transparency impairs their value. Since they are fairly expensive, reclaiming is desirable. This paper briefly discusses the preparation and care of some of the more common heavy liquids.

Jan 1, 1928

By C. Travis Anderson

"A recent critical study by Ralston3 of the iron system points out the importance of and necessity for work upon the preparation of ferrous oxide. Not only are ferrous oxide samples desired for determination of the important physical and chemical properties, such as specific heats and heats of formation, bat also information on the stability and behavior of this material is of considerable technical importance. Related. problems where the properties of Fe0 are important have to do with desulphurization of iron, the formation and occurrence of magnetite in copper smelter slags, and sulphur elimination in copperFerrous oxide also has valuable catalytic properties, as is demonstrated in nitrogen fixation.Pure ferrous oxide has never been prepared in quantities large enough to furnish adequate physical and chemical data on its properties. Only two or three experiments4 have produced a fraction of a gram in a state approximating purity and have collected evidence that has been sufficient proof of their having done so. Ferrous oxide is stable only above about 570°C., and below that splits into magnetite and iron according to the reactionUp to about 1920, those who had endeavored to prepare FeO made no provision for rapid chilling, so that although their product. may have had the proper iron oxygen ratio for FeO, in reality it-probably did not consist of pure FeO. The above reaction is reversible; above 570oC. magnetite and iron are supposed to recombine almost completely, and if so, should constitute a direct and easy method of preparation. The data, however, were somewhat conflicting, and the extent to which the reaction goes in either direction needed checking. Preliminary experiments on the interaction of molten Fe304 with solid Fe gave Fe0 of about 85 per cent purity, corresponding to. the approximate purity obtained by some previous investigators. The present work is concerned chiefly with the results cf repeated interaction between partly reduced magnetite and iron, and the calculations which may be made from such results. Repeated treatments are necessary, because molten impure ferrous oxide and iron can not be kept in contact for more than short periods of time."

Oct 1, 1928

By Will H. Coghill

The jig men of the Tri-State (Joplin-Miami) zinc district complain about the flakiness of their mill feed. They believe that the flakiness of the composite grains of gangue and mineral are to blame for losses of zinc; that is, that the flaky grains in the jig tailings have higher zinc tenor than the cubical grains. Although the evidence which follows contradicts this belief, no effort is made to give a final and conclusive answer. On the other hand, there is outlined a positive and mechanical method which the operator may use to pursue this and similar investigations. DISCUSSION OF SCREENING METHOD Hand-sorting is obviously not satisfactory for separating cubical grains from flaky grains because the personal influence can not be removed. Screens, however, may be used with success. A set of each of two types of screens is required; namely, the square-hole type and the rectangular (rectang, oblong) type. The square-hole screens must be of the double Tyler scale; that is, the order of the sieves should be after the fourth root of two instead of the customary square root of two; close sizing is important. The size of the rectang screens may be selected by trials so that a part of the material already closely sized on the square-hole screens, will pass the oblong holes. Obviously, the cubical grains will remain on the rectang and the flaky grains will pass through. Hence the mode of operation is to screen first on square-hole screens and then split the products on the oblong-hole screens.

Jan 1, 1928

By F. S. Wartman

The presence of magnetite, either dissolved or suspended as solid crystals, in slags from the copper reverberatory furnace is a frequently mentioned cause of an abnormally high copper content in those slags. The presence of this oxide in the slag is to be expected, since it is present in appreciable amounts in both converter slag and roaster calcine which comprise a considerable proportion of the furnace feed. Magnetite is also a product of some of the furnace reactions. These abnormal losses result in several ways. Magnetite is supposed to favor the formation and retention of copper ferrite, in the slag. Crystals of solid magnetite suspended in the slag are objectionable-because they make the slag less fluid and often entrap globules of matte. Frequently these crystals settle into a layer at the slab-matte interface which may have such mechanical strength as to create a false bottom and interfere with furnace operation by preventing separation of matte from slag. Magnetite may, by crystallizing on the furnace bottom, build the bottom to such a level that the furnace can no longer be operated.

Jan 1, 1928

By F. D. DeVaney

The supply of manganese is a subject of much interest. The idea of obtaining it from rhodochrosite-MnC03 is attractive because the carbonate is supposed not to be so contaminated with impurities as the commonly utilized oxides. Large bodies of rhodochrosite-bearing rock have been known for a long while to exist at Butte, Mont. Hence samples were obtained from that place. In the two samples examined quartz was the chief diluting substance. The leaner sample was about one half quartz; some copper, lead, zinc, and iron sulphides were also present. The rhodochrosite amounted to about 40 per cent, so that the sample had a tenor of about 20 per cent manganese. This sample was the subject of the examination reported herein.

Jan 1, 1928

By W. W. Odell

Engineers interested in the manufactured-gas industry have witnessed p pronounced improvements in gas-generating equipment and marked changes in operating procedure during the past decade. In spite of these changes, however, the trend of development in the near future seems to be doubtful. Uncertainty exists mainly because no one can yet accurately calculate the number of years which will elapse before petroleum products become too expensive for, general use in making gas. Research in this field has been active, and the ultimate results are awaited with interest. Some engineers predict that in the future coking coal will be carbonized on such a large scale that coal gas will be used (straight or modified) for city distribution; others maintain that gas oil will be used in large quantities in the production of base gas; they believe that it will be economical to use oil even at appreciably higher prices. The question involves, among other; factors, consideration of initial and relative costs of equipment, flexibility of operation, salability of coke, cost of distributing different gases, and the relative value of by-products, It is common belief that for many years large quantities of oil will be used in gas-making, particularly in the generation of peak gas or that water gas will be used for the synthetic production of hydrocarbons to enrich additional water gas. In this paper interest centers in a discussion of the practicability of employing synthetic processes in view of reported investigations of the chemistry of the synthetic reactions. For many years it has been known that the chief components of water gas would react chemically under proper conditions to form methane. As long ago as 1903 a patent3 was issued in this country for a gas-making process which included the synthetic production of methane. More recently the studies of numerous investigators here and abroad have shown that besides methane it is possible to produce other paraffins, olefins, and additional, materials adaptable for enriching water gas or for other uses. The question arises: In what manner, if at all, can such processes be incorporated, as a part of the gas-making scheme in a city-gas plant?

Jan 1, 1928

By C. C. Furnas

Despite the fact that a great many industrial processes depend on efficient contact between a gas stream and a bed of broken solids for their operation, the data in the literature are very meager. Several investigations3 have been undertaken, but the work has been limited in scope and application. BUREAU OF MINES PROGRAM OF RESEARCH For the past 10 years the United States Bureau of Mines has been engaged in research with the object of formulating a more or less complete quantitative theory of the workings of the iron blast furnace. Obviously, in order to do this one of the essentials is to have considerable definite information on the laws of gas flow through beds of broken solids. This report in a brief summary of the experimental work on the problem which has been done at the North Central Experiment Station. The complete report with more detailed tabulation of the data and explanations of the experimental procedure is in process of publication in the form of a bulletin.

Jan 1, 1928

By David F. Smith

[The U. S. Bureau of Mines at its Pittsburgh Experiment Station is frequently called upon to determine by laboratory tests the explosibility of suspensions in air of various dusts encountered in mines and elsewhere. Not all dusts which are combustible or contain combustible material will form explosive mixtures with air under ordinary conditions of temperature and pressure. They may not be highly combustible enough. They may contain a considerable amount of inert or non-combustible material or, the dust particles may not, be fine enough to form explosive mixtures. A knowledge off the chemical composition of a dust together with a determination of the size of the particles often gives valuable indications. But in many cases actual explosibility tests are necessary. Such a case is evidently that of powdered soap, whose explosibility hazard the Bureau was recently called upon to determine, Although an explosion which occurred in a soap plant as early as 1890 was attributed4 to powdered soap, it is apparent, due to the great number of inquiries received by the Bureau, that the hazard presented by powdered soap has not been at all generally appreciated. To the writers' knowledge, no extensive investigation of the explosibility of powdered soaps has been made. It is only recently that pure powdered soap has been manufactured on a large scale. The familiar "soap powder" in the past was usually a mixture of soap with a relatively large quantity of sodium carbonate. Often it contained large amounts of moisture and abrasive material. Even a highly combustible dust when mixed with large quantities of inert dust will not form explosive mixtures with air. Pure powdered soap, however, presents a different aspect. Pure soap is formed by combination of alkali (incombustible material) with fatty acid (combustible material). Toilet soap fray also contain a certain amount of glycerin and essential oil winch, being combustible influence the explosibility]

Jan 1, 1928

By B. W. Gandrud

[The meaning of the term "bauxite' has always been somewhat vague and indefinite, and the term has been used in various applications to denote sometimes a rock, sometimes a mineral, but more frequently an ore. It seems logical to think of bauxite as an ore, however, because a very large part (probably at least 85 per cent) of the entire world's production of bauxite is at present being used as a source of aluminum and aluminum chemicals. In the United States there are two districts that, produce bauxite - the Arkansas district and the Alabama-Georgia-Tennessee-Mississippi district. The deposits in Mississippi have been discovered recently and are riot as yet productive but it seems reasonable to consider them as apart of the-district hat includes the deposits of Alabama, Georgia, and Tennessee. The, two districts are often referred to as the Arkansas field and the Appalachian field. Of these two the Arkansas field has been by far the largest producer, and at present over 90 per cent of the bauxite production of they United States comes from the Arkansas field. The bauxite industry in the Appalachian field had its beginning in 1889, and since that time the total production of the states of Alabama, Georgia, and Tennessee has been, nearly a million tons. The production of bauxite in this field has languished in the last five, or six, years, and In 1927 its production was only about 14,000 tons, according to Harder4. The recent decrease in production is due mainly to the fact that many .of the known deposits of commercial-grade ore have become exhausted. There are, however, considerable quantities of low-grade bauxite in the Appalachian field, but these have not been available because there has been no satisfactory way of concentrating low-grade bauxite. The quantity, of low-grade material in the Appalachian field is probably, fully as large as the tonnage of commercial ore which the field has already produced.]

Jan 1, 1928

By W. P. Yant

Public interest in atmospheric pollution by automobile exhaust gas and in the ventilation of vehicular tunnels makes it desirable to ascertain whether the use of modern automobile fuels is tending to change the amount and composition of the products of combustion. The Bureau of Mines, in cooperation with the Ethyl Gasoline corporation4, has completed a series of testis to determine whether any significant difference exists in the carbon monoxide content of the exhaust gas produced by an internal-combustion engine when its fuel is changed from straight gasoline to the same gasoline containing Ethyl fluid whose active ingredient is tetraethyl lead. In the tests data was sought relative to the composition and mount of the gas produced by ordinary comparatively low-compression motors as well as by higher-compression motors in which distinct detonation occurred with straight gasoline, but which operated without detonation when using the same gasoline containing tetraethyl lead.

Jan 1, 1929

By L. C. IlsLey

In January, 1922, a conference relative to trailing cables for use with permissible mining machines was held at the Pittsburgh Experiment Station of the U. S. Bureau of Mines. At this conference it was recommended that the bureau take steps to investigate the rubber-sheathed type of cables and to bring about the establishment of a list of approved cables. Effective until such time as a complete investigation could be made, the bureau asked the several manufacturers holding approvals for mining machines to recommend cables for use with their machines. In general the cables recommended were tentatively approved. Due to the lack of available personnel, no actual tests of cables were made until mid-1927. Meanwhile a field investigation of trailing cables was made at 20 mines of three coal companies in western Pennsylvania, and samples of cables were obtained from the manufacturers for laboratory tests. Twenty-five samples of the concentric-type cable, representing the product of five manufacturers, were obtained for the tests. These cables were of four sizes, as follows: 3 cables of No. 2 B & S gage, 17 cables of No. 3 B & S gage, 3 cables of No. 4 B & S gage, and 2 cables of No. 6 B & S gage.

Jan 1, 1929

By J. R. Thoenen

"The curtailment of imports of foreign potash during the World War directed attention to the necessity of establishing a domestic source of potash for fertilizer, and considerable study has been given to the subject by Government bureaus, research organizations, and private individuals. These studies have covered all known sources of potash, and among them the extensive greensand deposits of New Jersey in which the potash content is found in the mineral glauconite have been investigated.Several hundred patents have been obtained covering processes for the extraction of potash from siliceous minerals, but up to the present time none have proved successful on a large commercial scale.When the investigation of the potash deposits of Texas was started by the Federal Government, the laboratory study of the drill cores was assigned to the Nonmetallic Minerals Experiment Station at New Brunswick, New Jersey, with the object of ascertaining a possible commercial method of utilization.The purpose of this preliminary study was to investigate existing literature and previous investigations to ascertain the extent and availability of the deposits, the extent of commercial success so far attained in potash extraction, the most promising known methods and by-products obtained from them, probable markets, and possibility of competition with foreign potash, and by a study of these data to determine whether further chemical engineering analysis and laboratory investigation were warranted.As the study advanced it became evident that adequate reserves of green-sand were available for many years supply. and that whereas many processes had been patented few had been tried commercially. In collaboration with former private and Government investigators these patents were first divided into two"

Feb 1, 1929

By J. R. Thoenen

During the year 1927 the Bureau of Mines, at the request of a number of quarry operators, undertook to make a study of quarry operating costs in order to determine average costs for certain operating conditions and to suggest a model cost accounting system for quarry operations. A detailed questionnaire was prepared and mailed by the bureau to all quarries on its records as employing ten or more men in 1926.

Jan 1, 1929

By Ralph L. Brown

As a preliminary step in a recent study4 of the phenols present in a low-temperature tar, the writers prepared the hydroxyacetic derivatives of the simpler available members of the phenol series in order to obtain material to assist in fixing the identity of similar derivatives obtained from the phenols of the tar. When comparing the melting points of the pure derivatives we had made with those given in the literature we were unable to find the characteristics of one of the xylenol derivatives which we had prepared--namely the 1, 3 dimethyl-2-phenoxyacetic acid, In the belief that the compound does not appear in the literature we are presenting these notes on its preparation and its melting point. The hydroxyacetic derivatives are easily prepared and in good yield, and are useful in studying mixtures of phenols. The 1, 3 dimethyl-2-phenoxyacetic acid makes the fifth of the six isomeric derivatives to be reported in the literature. Gluud and Breuer report the preparation of the 1, 3, 4, the 1, 4, 2, and the 1, 2, 4 derivatives. A fourth isomer-¬the symmentrical 1, 3, 5--has been reported by Schutz6, although no record of it occurs in the indexes. The remaining derivative--the 1, 2, 8-has not, been found and it is now being synthesized in the Organic Chemistry Laboratory of the. Pittsburgh Experiment Station. It is true, however, that from a phenolic fraction boiling 215.9 to 2180 isolated from natural petroleum, Tanaka and Kobayashi7 obtained a hydroxyacetic derivative melting at 103.3°. They state that this is the 1, 2, dime ethyl-3-phenoxyacetic acid but present no evidence for the assertion. The known derivatives are summarized in Table 1 following;

Jan 1, 1929