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By C. M. Loeb, T. E. Norman

THE use of ball, rod and tube mills for grinding ore, cement and other materials has grown so rapidly during the past forty years that the world's annual consumption of ferrous grinding media for these mills is now estimated to be between one half million and one million tons per year. Ferrous grinding balls constitute the major portion of this tonnage. Obviously they represent sufficient value to justify thorough studies' of the factor sgoverning their performance. The selection of grinding balls is governed principally by: I. Quality (wear resistance, impact resistance, soundness, and the like). 2. Sources of supply and delivered cost. 3. Grinding characteristics or efficiency in the ball mill. This paper deals principally with the quality of ferrous grinding balls. In the study of these factors certain data relative to the fundamental nature of ball wear in ball mills have been obtained. These data are also presented and discussed briefly. THE DEVELOPMENT OF A SUITABLE WEAR TEST A study of the fundamental factors governing the quality of grinding balls has been hampered seriously by the fact that a competent test has, in the past, involved the purchase of several hundred tons of balls of a specific type which were then run in one or more ball mills for a period ranging from several months to several years' duration. Often, during the period of test, it became necessary to change operating conditions or the character of the ore fed, to the test mill with the result that the rate of ball consumption changed and the test figures became of little value. Under such circumstances, progress in the development of better grinding balls, has been necessarily slow. Economic factors and variations in the quality of balls produced by different sources of supply generally make it necessary for each mill operator to determine for himself the most suitable type of balls for his mills. In our own ball mill grinding operations at Climax, Colo., we were faced with this problem. After we had run a few large scale wear tests at considerable expense we decided to investigate the possibilities of a small scale wear test which would be capable of testing numerous types of balls within a relatively short time. The most important requirement of any test is, of course, that it give results which can be used to predict accurately the wear in full scale operations. It was known that Ellis and his associates1,2 had developed a method of testing grinding balls by small scale tests run at the Ontario Research Foundation. Ellis' method of testing was used as a starting point in our investigations. In the course of our tests a number of modifications of the original method were found to be desirable so that, by an evolutionary procedure, a method of small scale

Jan 1, 1947

By C. M. Loeb, T. E. Norman

THE use of ball, rod and tube mills for grinding ore, cement and other materials has grown so rapidly during the past forty years that the world's annual consumption of ferrous grinding media for these mills is now estimated to be between one half million and one million tons per year. Ferrous grinding balls constitute the major portion of this tonnage. Obviously they represent sufficient value to justify thorough studies of the factor sgoverning their performance. The selection of grinding balls is governed principally by: I. Quality (wear resistance, impact resistance, soundness, and the like). 2. Sources of supply and delivered cost. 3. Grinding characteristics or efficiency in the ball mill. This paper deals principally with the quality of ferrous grinding balls. In the study of these factors certain data relative to the fundamental nature of ball wear in ball mills have been obtained. These data are also presented and discussed briefly. THE DEVELOPMENT OF A SUITABLE WEAR TEST A study of the fundamental factors governing the quality of grinding balls has been hampered seriously by the fact that a competent test has, in the past, involved the purchase of several hundred tons of balls of a specific type which were then run in one or more ball mills for a period ranging from several months to several years' duration. Often, during the period of test, it became necessary to change operating conditions or the character of the ore fed to the test mill with the result that the rate of ball consumption changed and the test figures became of little value. Under such circumstances, progress in the development of better grinding balls, has been necessarily slow. Economic factors and variations in the quality of balls produced by different sources of supply generally make it necessary for each mill operator to determine for himself the most suitable type of balls for his mills. In our own ball mill grinding operations at Climax, Colo., we were faced with this problem. After we had run a few large scale wear tests at considerable expense we decided to investigate the possibilities of a small scale wear test which would be capable of testing numerous types of balls within a relatively short time. The most important requirement of any test is, of course, that it give results which can be used to predict accurately the wear in full scale operations. It was. known that Ellis and his associates1.2 had developed a method of testing grinding balls by small scale tests run at the Ontario Research Foundation. Ellis' method of testing was used as a starting point in our investigations. In the course of our tests a number of modifications of the original method were found to be desirable so that, by an evolutionary procedure, a method of small scale

Jan 1, 1948

By S. Constantinescu

The alloys mainly used for short (or segmented) chip material cutting (cast iron, porcelain, etc) are alloys of the WC-Co type; in some cases with small additions of other carbons. The same alloys but of different granulometric classes are also used for pieces exposed to wear (wire drawing, moulds) The higher performance of the WC-Co alloys in chip machining applications is accounted for by their very good heat conductivity, which is 2-3 times higher than that of fast steels. The hard-alloys producers can resort to a wide range of possibilities to achieve variation of properties of a WC-Co composition and thus they can adapt their products to the particular type of tools they may choose to manufacture. The present metallography technique allows for a correct identification and evaluation of hard sintered carbons structures. The metallography approach is an indispensable method of investigation and control in the industry.

Jan 1, 2008

By G. J. Wright, M. J. Neale

As machines become more complex and vital to our way of life, any disturbance or failure of their proper functioning tends to have serious consequences. To prevent such failures, increasing attention is being paid to techniques for the monitoring of machinery condition or 'health'. Of the many methods available, examination of the lubricant and any particles it contains forms a basis for interpretation of the conditions of operation, and the rate and severity of degradation of the moving parts, in a machine. Many techniques of wear-debris analysis, such as spectrographic oil analysis and ferography, are available indicate the composition, shape, size, and concentration of contaminants in a lubricant. This paper reviews the important aspects of wear-debris analysis as an integral component of machinery condition monitoring, and gives an insight into the selection of appropriate techniques and the information that can be obtained from each.

Jan 1, 1987

By C. E. Berry

NATURAL stone or manufactured porcelain pebbles are used as the grinding elements in pebble mills and the mills are lined with stone or porcelain blocks. Steel balls usually form the grinding medium in ball mills, and the mills may he lined with steel. Pebble mills are used to avoid contamination by metal of the material being ground, to avoid rapid wear due to corrosion, and for other specialized reasons. Belgian silex (silica) blocks formerly were used widely for lining pebble mills, because of their good resistance to wear, light color, and low cost, but the importation of these blocks was suspended early in the war. The stocks of Belgian silex diminished so rapidly that it was found desirable to compare the properties of a number of domestic substitutes for use in critical operations. Accordingly, a study was made to determine the best substitutes for fine grinding of white pigment and for certain heavy-chemical process work such as the disintegration of phosphate rock in weak phosphoric acid solution. A comprehensive survey of substitute lining materials was not contemplated. It was stipulated at the beginning of the investigation that only materials on the market, available in large quantities, would be tested and that these should be reasonable substitutes from a wear-resistance viewpoint as determined from known physical characteristics. Marble and limestone, for example, could be eliminated immediately. Quartzite, granite and porcelain were selected as likely substitutes for Belgian silex and were subjected to quality tests. MATERIALS TESTED I. Belgian Silex.-Sample blocks of a standard grade were taken from crates in which they had been imported. The stone was light gray in color and contained inclusions of small clusters of quartz crystals as well as light colored portions that might be calcite. This was a siliceous rock which appeared to be of igneous origin. 2. Quartzite.-Samples of quartzite were obtained from a quarry in Minnesota. The blocks exhibited a crystalline fracture. The stone was pink in color and composed of fine quartz crystals bound together with a siliceous cement. 3. Granite A was a fine-grained granite quarried in South Carolina. 4. Granite B was coarse-grained granite quarried in South Carolina. 5. Granite C was a coarse-grained granite quarried in North Carolina. 6. Porcelain A.-Sample blocks of the pebble-mill lining material were obtained direct from the manufacturer. It was white in color and of lower specific gravity than the natural materials. It did not have a crystalline structure. 7. Porcelain B.-Sample pebble-mill lining blocks of the porcelain were received direct from the manufacturer. It was white

Jan 1, 1946

By M. X. Yao, C. D. Opris, P. C. Patnaik, R. Liu, X. J. Wu

Two cobalt-based superalloys, Stellite 694 and Stellite 712, were functionally graded with reinforcement of titanium-carbide particle for high-temperature wear/corrosion applications. The designed composite specimens were fabricated using powder metallurgy (P/M) technique, combined with hot isostatic pressing (HIP). Calorimetric effects of the alloy powders were investigated using the differential scanning calorimetry (DSC) technique, which provided the basis of the sintering cycles designed. The phases present in the microstructures of the materials were analyzed using SEM and X-ray diffraction. The wear resistance of the materials was evaluated on a pin-on-disc tribometer. It was demonstrated that adding titanium-carbide particles to the alloys has increased significantly their wear resistance. It was also found that the HIP process had improved the density of the sintered specimens and thus enhanced their wear resistance.

Jan 1, 2004

By Jupneek Singh, Zachary A. Kiehl, Leila Safazadeh, Gareth Kennedy, Eleonora Widzyk-Capehart, Jeremy W. Ward

Mine workers are continuously exposed to a host of nonfatal stressors and potentially fatal hazards: noise exposure, excessive vibration, poor air quality, toxicant exposure, ignition of combustible gases, equipment-related accidents, and thermal heat stress. Wearable or portable sensors and contextual analytics provide a platform to unobtrusively collect and fuse multimodal health and safety data in real time to compute both acute safety and longitudinal health insights. This paper presents preliminary trial results, conducted by Simtars, VigiLife, Inc., and Queensland Mines Rescue Service, of the application of wearable sensors to monitor heat stress and other vital biometrics for mines rescue personnel.

Feb 1, 2024

By Danny Chan, Shahram Tafazoli, Nicholas Himmelman, Edmond Chow

"While wearable technology has been garnering attention in the consumer market, enterprise and industry have just begun exploring its potential applications. Since February 2014, Motion Metrics International has been working in collaboration with Vandrico Solutions Inc. to apply wearable technology to improve productivity and safety in the mining industry.This article discusses the value proposition of using wearable technology to deliver critical notifications in mining. The advantages and disadvantages of various form factors are explored. The challenges, both specific to mining and in general to wearable technology, are defined. Finally, the concept of MetricsGear, the first wearable technology platform developed for mining by Motion Metrics International in collaboration with Vandrico Solutions Inc., is described. MetricsGear is designed to notify the user with minimal distraction to keep the user focused on his or her primary task and aware of mission-critical events. This focus and awareness allows the user to work more efficiently and safely. The mining process consists of a series of intricate stages, where certain events or conditions in one stage can have a huge impact on other stages. The notification of these critical events or conditions is vital for ensuring the overall efficiency of the mining process. Critical notifications can be classified as two types: timecritical events and contextual information. Time-critical events are situations where a timely response from a responder can have a significant impact on seizing an opportunity or mitigating cost. Some human-computer interaction (HCI) experts classify notification types based on the interruption, reaction and comprehension (IRC) framework. Time-critical events are classified to have high interruption, high reaction and low comprehension due to their urgency. The responder should have just enough information to identify the crisis and react as soon as possible (Chow, 2014). For example, when a tooth is lost during shovel operation, it is necessary to recover the missing tooth before it jams the primary crusher. The consequence of missing this critical time period is a jammed crusher that can cause the mine to be out of production until the jammed tooth is extracted (Baumann, 2013). In this case, the responder only needs to see an image to confirm if the tooth is missing and information to identify which equipment and when the tooth went missing (Fig. 1)."

Jan 1, 2014

By S. Tafazoli, N. Himmelman, D. Chan, E. Chow

"While Wearable Technology has been garnering attention in the consumer market, enterprise and industry have just begun exploring its potential applications. Since February 2014, Motion Metrics International has been working in collaboration with Vandrico Solutions Inc. to apply Wearable Technology to improve productivity and safety in the mining industry. This paper discusses the value proposition of using Wearable Technology to deliver critical notifications in mining. The advantages and disadvantages of various form factors are explored. The challenges, both specific to mining and in general to Wearable Technology, are defined. Finally, the concept of MetricsGear™, the first Wearable Technology platform developed for mining by Motion Metrics International in collaboration with Vandrico Solutions Inc., is described. MetricsGear™ is designed to notify the user with minimal distraction to keep the user focused on their primary task, and aware of mission-critical events. This focus and awareness allows the user to work more efficiently and safely. INTRODUCTION The mining process consists of a series of intricate stages, where certain events or conditions in one stage can have a huge impact on other stages. The notification of these critical events or conditions is vital for ensuring the overall efficiency of the mining process. Critical notifications can be classified as two types: time-critical events and contextual information. Time-critical events are situations where a timely response from a responder can have a significant impact on seizing an opportunity or mitigating cost. Some Human-Computer Interaction (HCI) experts classify notification types based on the Interruption, Reaction, and Comprehension (IRC) framework. Time-critical events are classified to have high interruption, high reaction, and low comprehension due to their urgency. The responder should have just enough information to identify the crisis and react as soon as possible (Chow, E. 2014). For example, when a tooth is lost during shovel operation, it is necessary to recover the missing tooth before it jams the primary crusher. The consequence of missing this critical time period is a jammed crusher that can cause the mine to be out of production until the jammed tooth is extracted (Baumann, M. 2013). In this case, the responder only needs to see an image to confirm if the tooth is missing, and information to identify which equipment and when the tooth went missing (see Figure 1). Contextual information is relevant information that is valuable for the receiver to be aware of as it can present an opportunity to improve efficiency or save cost. According to the IRC framework, contextual information is classified as low interruption, low reaction, and high comprehension. They are not as urgent as time-critical events, but provides more detailed and informative information to assist the receiver. For example, when a shovel’s worn tooth is predicted to require replacement soon, a notification to a GET technician can help him or her schedule a pre-emptive replacement of the tooth in an already planned maintenance to prevent having to reactively schedule another one when the tooth is critically worn. This helps reduce the amount of equipment downtime to maximize production (Baumann, M. 2013). In this case, the receiver will look at the information when he has a moment to spare to get a quick forecast, and make use of this information as needed (see Figure 2)."

Jan 1, 2015

By T. Richard Davies

This paper primarily deals with the application of wearfacing materials and their role within a well-established preventive maintenance welding program. Some examples are shown, as well as a synopsis of possible benefits and a compendium of methods and materials.

Jan 1, 1979

By Jack Eloranta

Transmission of sound through the atmosphere is affected by local conditions. Anecdotal accounts of the sound of cannon fire traveling great distances go back to the Civil War. The Royal Society published a paper near the turn of the century concerning the reports from the cannons fired in London at the funeral of Queen Victoria. Early computers were used by the U.S. Army at Aberdeen in Maryland in the 1950’s to model airblast problems during munitions demolition. Today’s blaster has to have access to weather information beyond a simple local forecast. Surface winds, winds aloft and temperature profiles have a dominant role in neighbors reaction to blasting. Many ground vibration complaints are really airblast complaints. Blasters who maintain ground velocities under . 1 inches/ second are often perplexed by complaints from distant neighbors, even when local monitoring shows airblast to be under 110 dB. This paper will help the blaster identify warning signs of high airblast conditions.

Jan 1, 2000

By Kot F. Unrug

The shale response to moisture changes and the major finding of the appropriate research concerning this subject are briefly reported in this paper. Also described are mine ambient atmospheric conditions which are responsible for moisture changes in mines. The need for a quantitative measure of the weathering potential of roof. rock is demonstrated in relation to its influence on safety and the potential for increasing the cost of mine operations. The weatherability test presented in this paper has been developed and used in many mines. It imitates the natural process in a mine by subjecting the rock sample to alternating wet and dry cycles. The natural changes are thus accelerated, but are similar to the natural conditions to which the surrounding excavation rock will be exposed. The measure of the weatherability index is the percentage of the initial sample mass remaining after the test as the largest fragment of the sample. Thus, the index changes, from 100% for rock affected by moisture changes which disintegrates completely, to 0% for rock totally unaffected. In this paper, the apparatus and testing procedures are described. Also presented are examples of test results. with a discussion of the design implication to he considered by mine planners.

Jan 1, 1997

By Erkan Bozkurtoglu

The most important difference between weathering and alteration, which are the definition of the change in rocks that occur with the help of physical and chemical effects, is a new product is formed as a result of alteration. Although atmospherical conditions are the most important factor during rock change, geothermal fields play a large role in the developing of alteration phenomenon. Because every geothermal system shows different characteristics including the chemistry of geothermal fluids and their potential applications, alteration on the field is important for the studies to find geothermal energy sources and to obtain the thermal fluids. The development of weathering and alteration which is the mark of interaction , between the physical and chemical properties of geothermal fluids and gases with the reservoir and wall rock, gives out important data about the hydrogeology, hydrology, reservoir conditions and characteristics of reservoir rocks of the geothermal field. Therefore defining the development of weathering and alteration phenomenon in a geothermal field and modeling the change in rocks, is very important for the benefication of the geothermal field economically. In this study 70 km2 that reside between Kösedere plains, Uzunburun, Çamtepe, Centirler villages in Çanakkale - Ayvacik - Tuzla geothermal field were studied and subsurface travel of saline thermal fluids and their interaction with the rocks and development of weathering and alteration phenomenon in the field were investigated. For this purpose geological mapping of the field were done and observations and measurements as well as rock sampling were carried in locations more than 220. As the result of petrographical investigations of rock samples development of weathering and alteration phenomenon were defined and 16 rock samples out of 220 that represent the field in general were chosen to be chemically analized and after that geochemical comments on the Tuzla geothermal field were made. Also hydrothermal alteration zones that are located in Tuzla Tepe, on which weathering and alteration phenomenon is observed as widespread and thermal water discharge locations in the near perimeter of Tuzla Tepe were mapped and from these data rock change in Tuzla geothermal field were modeled.

Jan 1, 2005

By K. J. Aglias, M. Jeffery, J. V. Simmons, J. A. Johnston, S. G. Fityus

"Shales and mudrocks undergo weathering in the near-surface geological environment, and degradation when directly exposed at the surface. Despite having superficially similar appearances, many shales have very different degradation behaviours. For example, some shales break down readily upon exposure whilst others remain more or less intact. Further, for those shales which break down, the style of degradation can vary greatly. A phenomenon is described where fresh shale blocks that are exposed at the surface undergo rapid breakdown to a fragmented texture which then persists for relatively long times, without further breakdown to finer soil particles. This is illustrated for some coal mine waste rocks. Furthermore, this metastable fragmented texture seems to be particular to each particular type of shale. The paper presents a conceptual model for this physical breakdown of shales which accounts for the differences in fragmental texture that are observed. The importance of several factors including strength, permeability and expansive clay content are identified for their contribution to the degradation behaviour of different shales.INTRODUCTIONShales and MudrocksThe term shale is applied widely to a class of mudrocks having a range of distinctive but gradational appearances and mechanical behaviours. Mudrocks are sedimentary rocks primarily composed of silt and clay sized particles (Tucker 1982). Mudrocks form in low to very low energy environments such as flood plains, lakes and deltaic environments, where the finest detrital particles are able to settle out of suspension (Reeves et al., 2006; Stow, 2005; Tucker, 2001).Unlike coarser siliciclastic sedimentary rocks, mudrocks do not present with a wide variety of sedimentary structures and textures. The most common texture is a preferred orientation of clays and micas parallel to the bedding plane. This textural component is related to the property of fissility or the ability for such textured mudrocks to split along smooth planes that are parallel to the bedding. Another common structure is lamination, formed by variations of grain sizes and types during deposition, Massive texture describes the situation where no sedimentary structures or textures are apparent (Boggs Jr., 2009; Tucker, 2001). The term shale varies between sources and contexts, with Reeves et al. (2006) stating that a shale is a fissile mudrock, where “fissility is a property that has developed at a certain stage of weathering”."

Jan 1, 2015

By Valérie J. Bertrand, Richard W. Lawrence, Marcos G. Monroy

Two cemented paste backfill (CPB) formulations containing pyritic tailings were leached in deionized water in flooded and alternating air-flooded environments and in a simulated acid rock drainage-type (ARD) solution. Scanning Electron Microscopy (SEM), solid phase chemistry and acid-base accounting measurements documented the weathering characteristics of the CPB samples. Short-term exposures of the portland-CPB samples preferentially dissolved the cement binder to a greater extent than slag-Portland CPB mistures. In all cases, the added neutralizing potential provided to backfill by cement was short-lived and insufficient to neutralize the acid generating potential of the mixture.

Jan 1, 2000

By S. Devasahayam

Acid production or acid drainage is a major environmental issue that also has negative implications on the aquifer system surrounding the mine tailings area. The approach to controlling acid mine drainage involves physical and geochemical characterization that affect acid production. The material permeability determines the availability of oxygen, which is paramount in acid production in coal rejects, and varies with depth. In this paper the author presents the variation in oxidized pyrite/acid production with depth in black coal mine washery wastes. Chemical kinetic parameters and the diffusive parameters have been used to obtain the variation in oxygen content and the oxidized pyrite content with respect to the depth and time. Its dependence on porosity and moisture content is illustrated.

Jan 1, 2007

The weathering of different types of base metal deposits in the semi-arid environment of the Lachlan Fold Belt of western New South Wales affects the geochemistry of outcropping ironstones (gossans) and derived soils. W eathering of the pyrite- and pyrrhotite-rich mineralisation at the Elura Zn-Pb-Ag deposit leads to highly acidic conditions and strong depletion of Cd and Zn throughout the profile. There are local attainments of high concentrations of Ag, As, Ba, Cu, Hg, Pb, Sb and Sn in the profile and As, Ba, Pb and Sb are still highly anomalous in surficial material (ironstone and soil). However, at Parkers Hill, in the Mineral Hill Field, the primary Zn-Pb mineralisation is pyrite-poor and so weathering is not as acidic as at Elura. Thus, although Ag, As, Cd, Cu, Sb and Zn may be concentrated at various levels in the Parkers Hill weathering profile, Cu and Zn (as well as As, Pb and Sb) are retained in surficial ironstones in essentially the same abundances as in primary mineralisation. Thus, variations in the suite of geochemical indicators present in ironstones and residual soils are likely to reflect differences in the original mineralogy and the degree of acidity produced during the weathering of base metal mineralisation. Hence, an understanding of weathering processes is necessary to fully interpret exploration geochemical data.

Jan 1, 2004

By Rolf B. Pedersen, Ana Filipa Marques, Ingunn H. Thorseth, Ingeborg Okland

"Deep sea mining of polymetallic sulphides will change the physical and chemical conditions at the seafloor by creating scars when sulphides are removed, and potentially also by deposition of mine tailings at the seafloor. These changes will impact the existing ecosystems at the seafloor in and around the mined areas. Seafloor Massive Sulphide deposits that have been exposed to oxic seawater weather into Fe-metal-oxyhydroxides. However, the rates of weathering and release of heavy metals and other toxic compounds to the environment from freshly exposed sulphides in a deep-sea environment are not well studied.During a cruise to the Arctic Mid-Ocean Ridge in the Norwegian-Greenland Sea in July 2014 we will initiate in-situ experiments investigating the microbiological and geochemical processes involved in the weathering of freshly exposed massive sulphides deposits in a natural environment. This will be done by creating scars in naturally occurring sulphide deposits and by deploying weathering experiments at the seafloor. The sites will be revisited and re-sampled in 2015. The mobility and fate of heavy metals will be one of the main concerns of the study as well as constraining the time it will take for exposed sulphides to return to the chemical state present prior to mining. In this presentation we will present the experimental framework and the preliminary results from the July 2014 cruise. This project is part of the EU funded MIDAS (Managing impacts of deep sea resource exploitation) project."

Sep 1, 2014

By Rolf B. Pedersen, Ingunn H. Thorseth, Håkon Dahle, Ingeborg E. Øklandm, Linn M. B. Olsen

Weathering of sulfides and the generation of acid mine drainage (AMD) is a well- known environmental issue in on-land mining. The process can release potentially toxic compounds and heavy metals to the environment and is highly influenced by microbial activity. However, the weathering of sulfides in deep-sea environments is not well studied. In 2014 we therefore deployed two titanium incubators filled with freshly ground pyrite grains into an inactive part of the hydrothermal sulfide mound of Loki´s Castle vent field, aiming to study the in-situ seafloor weathering of the freshly exposed sulfides. Each incubator had five chambers placed in a depth profile, where the upper chamber was exposed to the bottom seawater. After one year of exposure, one incubator was collected and analyzed for weathering features and microbial colonization and community composition. In addition, one sediment core (25 cm deep) was collected from the sulfide mound in close vicinity to the incubators, and another core (45 cm deep) was collected from the (hemi)pelagic sediment just outside the sulfide mound. The cores were analyzed for geochemical composition of the solid material and porewater, and the microbial community composition aiming to define the redox zoning and dominating geomicrobiological processes in the natural deposits, and to unravel how these processes influence the mobility of heavy metals during sulfide weathering. Scanning electron microscopy (SEM) revealed development of Fe-oxyhydroxide weathering rims on the pyrite grains in the incubator chambers. Spalling of the rims on the most weathered grains, exposing fresh pyrite surfaces to oxidation, was commonly observed. The SEM investigation also revealed a positive correlation between weathering degree and microbial community density. Preliminary results from the microbial community analysis show a high relative abundance of putative sulfide oxidizers, suggesting that the community is governing the degradation of pyrite.

Jan 1, 2018

Builders have been very familiar with iron since ancient times, but because of its weathering characteristics it was relegated to use as a fastening material in unexposed places and bronze became the popular metal for exposed applications. It is of interest that iron nails buried deeply about A.D. 87 at a Roman fortress and carefully covered with clean beaten earth under conditions practically excluding oxygen were found to be almost unrusted 1870 years later. (1) Today, weathering steels, which contain less than 2% of alloying additions, can be used in exposed situations without protection and without experiencing continuous wastage. As we all know the steady access of atmospheric oxygen to the surface of plain steel causes continuous corrosion. Weathering steels, on the other hand, due to their alloying additions develop their own impervious surface layer which limits the access of atmospheric oxygen and effectively limits corrosion. Table 1 shows the chemical composition of a plain carbon steel and a typical weathering steel. Fig. 1 shows what we refer to as direct corrosion - time curves in which corrosion loss is plotted against time of exposure in an strial environment. The weathering steel has a high rate initially which then decreases steadily for about three years, as the stable rust film builds up. This is followed by a practically linear relation where the very low corrosion rate, according to one school (2), is due to a blocking of the rust pores by insoluble complex salts formed from interaction of the oxidation products of the separate alloying elements. The start of the linear region represents a total corrosion loss of only about 2 thousandths of an inch.

Jan 1, 1970