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By E. Gervais

Modern life in inconceivable without zinc. Zinc provides the most cost-effective and environmentally efficient method of protecting steel from corrosion. Zinc is also used to power electric vehicles and computers, to make brass, automotive equipment, household appliances, fittings, tools and toys, and to support the building and construction industries. It is also used in pharmaceuticals and cosmetics, in rubber, in fertilisers and in animal feeds. The links between properties, applications and performance, as well as zinc demand and market dynamics, will be reviewed along with market development opportunities and successes. The presentation will also include a progress report on the five-year plan of the International Zinc Association to increase the global market for zinc, over and above the natural growth, by 500,000 tonnes/year by 2002.

Jan 1, 2000

By D. Ducharme, J. Lenz

Operation of the Kidd electrolytic zinc plant commenced in 1972 with a cellhouse capacity of 105,000 tonnes of zinc cathode. The original cellhouse layout consisted of 42 parallel rows for a total of 588 cells. As leaching capacity increased, the cellhouse was expanded to 630 cells. Zinc cathode was manually stripped from plant start-up until the development of a mobile automated stripping system in 1994. Machine development continued until a second unit was placed in production in 1996, from which point, 60 % of the cellhouse was being stripped with the automated system. The final phase of the project was implemented in 1999 with the commissioning of two more automated strippers. This paper describes the implementation of the automated stripping system and its impact on cellhouse productivity.

Jan 1, 2000

By Jr. Koch

Since 1882, world zinc production has increased. In contrast, United States zinc production rose until about 1915, but since then has remained nearly constant, with a slight tendency to decrease. Production from the Tri-State district, the largest early source of zinc in the United States, has gone down steadily; this decline has been balanced by a growth in the rate of other districts. These changes in United States production are due to economic, not geological, factors. Recent exploration has located large mineable ore bodies; additional deposits will undoubtedly be found in the strata-bound carbonate rock and volcanogenic environments. A statistical analysis of the exploration effort in the Middle Tennessee district indicates that new discoveries can be expected there. Thus, the United States is in an early stage of the production cycle for zinc. Of major mining districts in the United States, only the Tri-State is exhausted under current economic conditions; large zinc resources of low-grade material, which would repay mining at higher prices or improved technology, are known to exist in that district.

Jan 1, 1980

By George S. Koch

Since 1882, world zinc production has increased. In contrast, US zinc production rose until about 1915, but since then has remained nearly constant, with a slight tendency to decrease. Production from the Tri-State district, the largest early source of zinc in the US, has gone down steadily; this decline has been balanced by a growth in the rate of other districts. These changes in US production are due to economic, not geological, factors. Recent exploration has located large minable ore bodies: additional deposits will undoubtedly be found in the stratabound carbonate rock and volcanogenic environments. A statistical analysis of the exploration effort in the Middle Tennessee district indicates that new discoveries can be expected there. Thus, the US is in an early stage of the production cycle for zinc. Of major mining districts in the US, only the Tri-State is exhausted under current economic conditions; large zinc resources of low-grade material, which would repay mining at higher prices or improved technology, are known to exist in that district .

Jan 1, 1982

By W. R. Ingalls

THE manufacture of zinc oxide directly from the ore is one of the most important contributions that America has made to the metallurgy of zinc. Heretofore, this has been clone chiefly for the production of zinc and zinc-lead pigments, and the method has been known as the Wetherill process. While that term may properly be applied to the process for pigment manufacture, it must be recognized that the principles of the process are of far wider application; and that there is going to be wider application in the immediate future is more than an expectation. I have in mind the use of the process as a method of igneous concentration. Igneous concentration is broader in its scope than the Wetherill process, for it may be done in the blast smelting furnace, or in the reverberatory, or by other means. Igneous concentration is a rather clumsy term, and I prefer to introduce the new generic expression of "zinc burning," which is convenient, readily understood and precise, for in all cases the zinc oxide is reduced to metallic form, is volatilized and is then burned to zinc oxide, the latter happening, however, after the zinc has been separated from the residue of the ore. As previously indicated, zinc burning may be done either in blast or reverberatory smelting, the gangue of the ore being scorified and drawn off as slag, while other metallic minerals are reduced to matte or metal. Such processes have heretofore been practised on fairly large scales. Thus, F. L. Bartlett smelted zinc ores at Canyon City, Colo., in specially designed blast furnaces, wherein the smelting column was only about 18 in. high. Such a limitation was necessary in order to prevent zinky accretions in the shaft of the furnace, which in course of time would have interfered with its operation. In running the Bartlett furnaces it was easy to bar them off, indeed, to poke right down into the smelting zone, and keep things going freely. Some iron blast furnaces in Virginia and the spiegeleisen furnaces of the New Jersey Zinc Co. afford other examples of zinc burning in blast-furnace smelting, although in their cases the happening is incidental rather than a primary purpose.

Jan 9, 1917

THE CHAIRMAN (G. C. STONE, New York, N. Y.).-It is a matter of history that the smelting of zinc ore in, a reverberatory furnace was the first process used in this country for making oxide of zinc, and it was abandoned for three reasons: it was very expensive, the recovery was, very poor, and the color of the oxide was worse. It is probable, however, that the Anaconda company is working in a totally different way. While Mr. Ingalls does not say so, my own suspicion is that they are using coal-dust firing, very much as they do in the copper furnaces, and by that method there is much more chance of getting good recovery.

Jan 1, 1918

By S. M. Javad Koleini

The aim of this research is to extract zinc from complex lead and zinc ore containing carbo- silicate lead and zinc minerals using sulphuric acid. Samples, taken from Dareh Zanjireh mine located in central of Iran, were subjected to leaching tests after calcination process. Experiments were planed according to the Taguchi statistical method. The calcinated samples contain 13.98% zinc and the constituting minerals being dolomite and zincate. Various parameters such as speed of mixing, temperature, time, solid to liquid ratio and pH were studied. A solid to liquid ratio of 1:6 gr/mL at 60°C and 800 rpm speed of mixing for 30 minutes resulted in a product with 85.96% zinc recoveries.

Jan 1, 2014

By G. X. Wang, J. O. Marsden, M. C. Fuerstenau

Zinc cementation of high-temperature carbon eluates is now used extensively in gold processing to replace electrowinning. Under these conditions, zinc consumption is high. In this paper, zinc solubility is press rated us functions of temperature, cyanide concentration and pH in the presence of gold, silver and mercury cyanides (both individually and in combined solutions). Based on the experimental results, cementation of these metals is characterized and discussed. The importance of cyanide concentration in cementation efficiency and the effect of mercury and its co-precipitation onto zinc are also discussed.

Jan 1, 1997

By Paul M. Keyser

Flotation columns continue to offer improved metallurgical and economic advantages over other flotation methods. Pilot testing at Ozark-Mahoning Co. in Rosiclare, IL led to installation of one 2.3-m-diam (7.5-ft-diam) column for zinc roughing and one 1.1-m-diam (3.5-ft-diam) column for zinc cleaning. This circuit replaced one stage of mechanical roughing-scavenging followed by two stages of cleaner flotation. General Column flotation continues to make inroads into applications traditionally dominated by mechanical flotation cells. For example, columns are becoming more visible as rougher flotation devices. At Royal Mountain King Mine in California, two 2.9-m-diam (9.5-ftdiam) columns are used for rougher flotation of carbon from a gold ore (Orlich et al., 1992). In addition, work performed at BRGM in France demonstrated the superiority of column flotation over mechanical flotation with respect to design of new plants (Morizot et al., 1991). The primary reasons for this acceptance of columns are a general improvement in design, scale-up and operation, as well as improvements in sparger design and performance. With these advances, the full benefits of column flotation can be realized. The benefits of properly designed, aerated and operated flotation columns include lower capital costs, reduced operating costs, fewer processing stages and improved metallurgical performance.

Jan 1, 1993

By P. M. Keyser

Column flotation continues to make inroads into applications traditionally dominated by mechanical flotation cells. For example, columns are becoming more visible as rougher flotation devices. At Royal Mountain King Mine in California, two 2.9 m (9.5 ft) diameter columns are used for rougher flotation of carbon from a gold ore (Orlich et al, 1992). In addition, work performed at BRGM in France demonstrated the superiority of column flotation over mechanical flotation with respect to design of new plants (Morizot et al, 1991). With the mounting evidence, columns can succeed in any flotation application. The primary reasons for this acceptance of columns are a general improvement in design, scale-up and operation as well as improvements in sparger design and performance. With these advances, the full benefits of column flotation can be realized. The benefits of properly designed, aerated and operated flotation columns include: ? Lower Capital Costs ? Reduced Operating Costs ? Fewer Processing Stages ? Improved Metallurgical Performance

Jan 1, 1993

By W. Geo. Waring

THE growing need of better methods for the recovery of zinc and other elements from complex sulfide ores has suggested an inquiry respecting a possible group separation of the elements by the aid of volatilization at more or less elevated temperatures. It 'is evident that if the zinc content of such ores can be completely separated, for instance, as pure oxide, by a volatilization 'method, there should be no difficulty in recovering the other elements by smelting and refining. Zinc burning" as applied to zinkiferous ores has advanced but little in practice since the invention of the wetherill grate-furnace process in 1852, as may be seen by reference to papers on the subject.' In other words the thermochemical reaction employed in effecting the volatilization of the zinc is essentially one of reduction by means of carbon, whether the ores treated contain their zinc in an oxidized form, or as the sulfide. The zinc vapors, liberated from the ores at a temperature above that required for the reduction of ZnO by C (about ,1100° C.) or for the volatilization of ZnS per se, (about' 1300°-1400° C.) are subsequently burned to ZnO or to ZnO + SOz, by contact with' atmospheric ,oxygen in the upper or posterior parts of the furnace chamber, or in a so-called "combustion chamber" after leaving the .furnace proper.

Jan 1, 1925

Zinc concentrates from the newer mines and from proposed developments provide both opportunities and processing challenges to the conventional roast-leach electrowin smelters. These concentrates are often characterised by low iron, elevated silica, possibly high manganese, and levels of elements such as germanium which may cause concern. In addition, environmental constraints on residue disposal are forcing significant changes to some smelter practices. Iron in concentrate, and the resulting environmental impact of residue disposal are now major questions. However, normal concentrate tariff structure provides a disincentive against smelters taking high grade concentrate and oxide fume. Processing technology to cope with these changes is reviewed, as is de-watering and materials handling of ultra-fine concentrate. Within a few years, such fine concentrates will account for up to 1 000 000 t/y of contained zinc. New processing technologies including novel transport methods, siliceous leach circuits, manganese removal cells and front-end smelting will become significant in zinc smelting.

Jan 1, 1993

By C. Barnett

"The mill at Noranda Mines Limited, Geco Division in Manitouwadge, Ontario went into production in 1957 treating 3,500 tons per day of copper, zinc, silver, lead ore. It was not until 1964, however, that the zinc concentrate drying plant was constructed. In 1970, milling capacity was increased from 4,000 to 5,000 tons per day. The zinc content of the ore is quite variable so that the tonnage of zinc concentrate dried varies from 200 to 650 tons per day.The drying plant was designed to dry 25 tons of zinc concentrate, dry basis, per hour from an initial moisture of 8.5% to a final moisture of 2%. Major components were selected so that capacity could be increased to 35 tons per hour with minor modifications.The rotary dryer is a Hardinge type ""XH-12"" with a diameter of 80"" and a length of 50 feet. The all welded construction shell is 1/2 inch thick mild steel plate with 3/4"" thick reinforcing bands under the tires arranged for operation at a slope of 1/2 inch to the foot. The 3/8"" x 12"" radial flights are welded to the shell. There are no flights in the last ten feet of the shell in order to reduce dusting. This unit is driven by a 50 HP motor through a Hamilton type CD250 double reduction helical gear speed reducer. The shell speed is 5.8 RPM.The standard Peabody horizontal air heater has a rated capacity of 10,000,000 B.T.U. 's/Hr. The combustion chamber is lined with high temperature refractory brick and is air cooled. The conical outlet section of the air heater is lined with insulating fire-brick. The burner is a type AT wide range mechanical atomizer fired by a type ""CR"" gas-electric ignitor.The Bunker ""C"" fuel is supplied by a Compower duplex pumping, heating and straining unit, including tank hotwell, Powertronic oil line heating system with a 550/24 volt transformer."

Jan 1, 1972

By F. K. Letowski

Leaching of zinc sulphide concentrate by nitric acid which is simultaneously regenerated by oxygen in the reactive froth has been investigated. The reactive froth was formed by a recycled zinc sulphate electrolyte containing nitric acid, a mixture of gaseous 02 and NOx, entrapped in the foam and particles of the zinc concentrate suspended in the foam. In the reactive froth the multiple regeneration of nitric acid proceeded owing to the encapsulated oxygen and amount of nitric acid used can be considerably lower than in the continuous liquid phase. 93 to 97% of zinc was extracted to a solution containing 30 to 409/1 HNO, during 40 to 60 min of leaching in a batch reactor without regeneration of nitric acid. 50 to 100% of the consumed nitric acid was regenerated during continuous leaching in froth carried out in the ‘flotation column’-type reactor at 80 to 90°C and under pressure of 100 to 200kPa. The rate of HNO, regeneration in the froth was proportional to oxygen pressure and inversely proportional to nitric acid concentration in the froth. A two-stage process flowsheet is proposed. In the first, the reduction stage, removal of nitric acid from the leach solution directed to standard purification and electrolysis is carried out by its reduction to nitric oxide using fresh concentrate in the froth. In the second, the oxidation stage, nitric acid is continuously regenerated by oxygen in the froth.

Jan 1, 1995

The problem of applying instrument control of variables associated with lead-zinc ore treatment has been under investigation for several years at The Zinc Corp. facilities in Broken Hill, Australia. In 1959 it was decided that there was sufficient knowledge of the problem to enable specifications to be drawn up for a system to automatically control at set conditions the roll crushing, ball milling, lead flotation and zinc flotation sections. In choosing between electrical and pneumatic control systems the broad principle was adopted that if the sensing system was pneumatic the transmission and control would also be pneumatic, whereas if electrical sensing was employed, electrical transmission and control would apply. In general. pneumatic systems were preferred owing to lack of experience with, and standardization of, the electrical systems offered at the time the specification was prepared.

Jan 12, 1964

By P. E. Auger, J. E. Gill

"The zinc deposits to be described are in Lemieux township a few miles south of the Tabletop mountains, in the central part of Gaspe peninsula, Quebec. Although they have not been worked, they constitute a potential source of zinc and lead and structurally are of considerable interest.GENERAL CHARACTER OF THE OCCURRENCEThe deposits are in sharp-walled quartz-carbonate veins and breccia zones carrying locally, and in varying amounts, sphalerite, galena, pyrite, marcasite, chalcopyrite, and specularite. Those so far investigated strike generally north-south, have steep dips, and cut through sediments of Lower Devonian age, mostly calcareous argillites or siltstones. Wall-rock alteration is negligible.BROADER STRUCTURAL FEATURESThe principal known occurrences are in the south-central part of a dome structure measuring 6 by 5 miles. The argillaceous sediments are overlain, on the flanks of the dome, by sandstones and lavas. These have been stripped from the central part of the dome, revealing the veins in the argillites beneath. The veins formed after the volcanics, but the fractures and breccia zones in which the deposits formed are confined mainly to the argillite series, presumably because of the greater strength of the lavas.The argillite series is cut by dykes, sills, and small stocks of diorite and acidic 'porphyries' that are older than the veins.THE FEDERAL HILL AREAThe distribution of known veins is shown in Fig. 1. The characteristic features of the veins are well illustrated by the Federal Hill area shown in Figs. 2, 3, and 4, and described below."

Jan 1, 1954

By U. C. Tainton

THE world-wide continuation of low prices for zinc in 1934 has militated against any striking changes in the position of the metal. The price of zinc in London at the end of the year, about £11 5/8 per long ton, or 2.5c per pound at the existing rate of exchange, is more than 25 per cent below the average price for last year. In these circumstances probably the most significant event of the year was the putting into operation of the new electrolytic plant of the Giesches company at Magdeburg, Germany. This plant is designed to have an initial capacity of 20,000 long tons per year, and it is planned to increase this to 40,000 tons annually. This development is significant not only as indicating a continued swing of zinc metallurgy towards electrolytic methods, but also because it will make Germany virtually independent of foreign sources of zinc. This will mean that the zinc tonnage normally exported to Germany from Belgium and Poland will. become available for other markets, and it is feared may lead to lower prices unless the production of Bel-

Jan 1, 1935

By A. D. Smigelskas, E. O. Kirkendall

THIS is the third paper in a series on the diffusion of zinc in alpha brass.1 At the time of the first-paper it was accepted that diffusion in a substitutional type of solid solution depended upon an equal interchange of solute and solvent atoms across the diffusion interface (or past a given lattice reference point). Discrepancies in the size of the areas under the diffusion curves on each side of the interface, if observed, were explained on some other basis than the fact that the solute atoms might cross the diffusion interface without an equal number of solvent atoms diffusing across the interface in the opposite direction. The second paper presented evidence indicating that zinc atoms in alpha brass diffuse across the interface more rapidly in one direction than the copper atoms diffuse across the interface in the opposite direction. This phenomenon forced the interface to move in the opposite direction of the diffusion of zinc atoms to provide space for the additional zinc atoms dissolved in the alpha brass. That the interface and columnar grain structure on one side would remain intact during this mass movement was not expected; however, it is gratifying that they did. While the evidence was sufficiently satisfying to the author, it was decided that additional experiments were in order to prove that zinc diffuses more rapidly than copper in alpha brass. It is the purpose of this paper to present the results of these experiments. PROCEDURE A bar of 70-30 wrought brass was selected, to avoid the relatively large volume change in going from beta to alpha brass as in the previous investigation. A bar 7 in. (18-cm.)* long and about ¾ in. (1.9 cm.) wide was surface ground and polished with abrasive paper on plate glass to 0.4184 ± .0002 in. (1.0625 ± 0.0005 cm.) thick. Six 0.005-in. (0.013-cm.) diameter molybdenum wires, chosen because of their very low solubility in copper and alpha brass, were stretched lengthwise along each of the two plane surfaces. Glass tubes placed at right angles to the wires every ½ in. held the wires tightly against the brass. The sample was then emersed in an acid copper sulphate plating bath and electroplated to a depth of about 0.020 in. (0.050 cm.) copper on all sides. The glass tubes were no longer necessary to hold the molybdenum wires in place and were removed. The sample was then electroplated to a depth of

Jan 1, 1946

By W. J. Sharwood

IN the cyanide process, gold and silver are dissolved from crushed ore as double alkali-metal cyanides, from which they may he precipitated by such positive metals as sodium (amalgam), aluminum, or zinc, or by electrolysis. Two extreme conditions may he noted. Some works, especially slime plants practising decantation, use a relatively large volume of solution-possibly 4 or 5 tons per ton of ore-nearly all of which may require precipitation, so that the solutions handled are of much lower value per ton than the ore. On the other hand, in some leaching plants it is possible to extract with very little solution, and to percolate some of this more than once through the charge before precipitation, so that the solution to be precipitated may he much less than half the weight of ore, and proportionally richer. Solution intended for further use need not have all its precious metal removed, but any that has to be thrown away should be impoverished as far as is economically possible. In spite of certain advantages possessed by other precipitants, zinc in some form has been almost universally used. In some of the first attempts to utilize cyanides as gold solvents, a "piece or plate of zinc" was suggested as a precipitant, but extension of surface was early recognized as a desideratum. Macarthur and the Forrests adopted a "metallurgical filter" of zinc shaving, turned from disks or rolled sheets. They had previously experimented on other forms of zinc, and Macarthur records having tried zinc dust, which had of course been long known as a general reducing agent. It had also been known and used as a precipitant of precious metal from plating and photographic solutions, and comminuted zinc had been patented for recovering copper, etc., from ore leaches. Other inventors proposed the virtual making of zinc powder by the attrition of balls of zinc, and by similar means, during the passage of a stream of gold-bearing solution.

Jan 9, 1917

By M. Moats, J. A. Gonzalez

A review of operating practices in zinc electrowinning plants is presented in this paper. Surveys were sent to several zinc electrowinning plants and data provided by some of these plants was compiled in a database. Information about anodes and cathodes, electrolyte composition, stripping methods, cells, electrical systems, and additives was compiled and analyzed. From the data analysis, correlations between operating variables are presented. Recent trends in operational practices are also highlighted.

Jan 1, 2008