Search Documents

By L. Tong

"The oxidation of Quebracho was evaluated by acid-butanol assay, which indicates depolymerization of Quebracho. Anthocyanidin, an oxidation product of Quebracho, is stable at 95?C for up to 2 h. The ionization, complexation, and oxidation properties of Quebracho were discussed. Complexation of metal-Quebracho occurs at ambient temperature. The formation of complex precipitates is influenced by the acidity of the solution. Temperature is another important parameter that influences the oxidation and the complexation of Quebracho. Quebracho-ferric complex precipitate forms at 90?C, 0.1 mol/L H2SO4. The formation of Quebracho-metal complex in the leach solution is a possible reason for the consumption of Quebracho. Quebracho molecules adsorption on the mineral surface is reduced by consumption of Quebracho, resulting in poor sulfur dispersing effect in the leaching process. INTRODUCTIONQuebracho is used as a sulfur dispersing agent (SDA) in the pressure leaching of zinc concentrate as stated in U.S. Patent No. 3,867,268 (1975). It prevents the zinc sulfide particles from being coated with molten sulfur, thus preventing the inhibition of the zinc leaching reaction. Recently, the sulfur dispersing effect of Quebracho was investigated in the oxygen pressure leaching of nickel concentrate. The oxygen pressure leaching of pentlandite can be represented by reactions 1-3."

Jan 1, 2012

By M. SIDDARAJU, Rameshwar Sah, T. Umadevi, K. S. SRIDHARA, B. D. Ganesh Shetty, M. RAJU

The production of high strength iron ore sinter for blast furnace iron making unit was developed by optimizing the granulometry of less than − 0.150 mm fines in sinter base mix which consists of iron ore fines (− 10 mm size with 0.150 mm: 41%), beneficiation plant jig concentrate, i.e., washed ore (− 3 + 0.150 mm size with − 0.150 mm 3 to 9%), beneficiation plant concentrate (− 0.150 mm size 97%), limestone, dolomite, coke breeze, lime, sinter return fines, direct reduced iron (DRI plant) fines, and micropellets produced from steel plant waste. The sintering process consists of preparation of base mix, mixing, and production of nodules using mixing and nodulizing drum by maintaining the optimum moisture, transferring of nodules to the sintering machine, and firing of sinter by applying optimum suction pressure. To optimize the < 0.150 mm fines in sinter base mix, the − 10-mm size iron ore fines was replaced with washed ore. The size analysis, granulation index (G index), and optimization of moisture w.r.t. sinter bed permeability were carried out by varying the washed ore addition from 0 to 55% in sinter base mix to vary the − 0.150 mm fine size. With decrease in washed ore addition from 55 to 0% in sinter base mix the finer fraction, i.e., − 0.150 mm in sinter base mix increased from 9.4 to 26.7%. Granulation (G) index increased from 1.46 to 3.10, sinter bed permeability increased from 33 to 53 Japanese Permeability Unit (JPU), and balling index increased from 1.4 to 3.0. With increase in − 0.150 mm fines in the sinter base mix from 9.4 to 26.7%, the sinter tumbler index (T.I) increased and sinter reduction degradation index (RDI) decreased. Increase in sinter strength and decrease in sinter RDI was due to increase in formation of Silico ferrite of calcium and aluminium (SFCA) phase and decrease in pore phase. The SFCA is the main bonding phase in iron ore sinter, and it provides strength to sinter. Sinter base mix with − 0.150 mm fines 18.9% (washed ore addition 25%) achieved desired sinter properties with moisture 8.0%, G index 2.44, balling index 2.3, and sinter bed permeability > 45JPU. Decreased the sinter properties with washed ore addition in sinter base mix beyond 25% due to decrease in − 0.150 mm fines in sinter base mix. Further, to improve the sinter properties with washed ore 30 to 45%, 3 to 10% beneficiation plant concentrate, i.e., − 0.150 mm fines was added to maintain the 18.9% of − 0.150 mm fines in sinter base mix. From the laboratory sintering studies, it was found that minimum 18.9% (range from 18.9 to 26.7%) − 0.150 mm fines should be maintained in the sinter base mix to achieve desired sinter properties.

Oct 16, 2021

By Giuseppe Gaspari, Xiangrong Wang

The pandemic emergency is forcing transit agencies to define strategies allowing social distancing, which are more challenging in underground interchange stations in crowded downtown cores. Toronto Transit Commission’s (TTC’s) Bloor-Yonge Station Capacity Improvement Project in Toronto was approved to meet increasing demand and represents an opportunity to fight COVID-19. This paper discusses cost-effective solutions in expanding the cut-and-cover station box over the existing Toronto Subway Line 2 and connecting it through ventilation openings in the cast-iron tunnel liner. Potential uplift risks and structural damage due to minimal vertical clearance were analyzed via three-dimensional finite element analyses with advanced constitutive laws to simulate the multi-stage construction process. Based on the simulation results, a series of countermeasures, including excavation support systems, king posts, ground-consolidations, and liner reinforcements were integrated into comprehensive design options to ensure the serviceability and structural integrity of the subway tunnels.

Jun 13, 2021

Coal waste materials inhibit direct vegetation establishment due to adverse physical and chemical properties, particularly low water retention and high potential acidity. The Moss # I coal refuse pile is located in Dickenson County, Virginia, and was idled in the late 1980&apos;s with little topsoil resource available for final closure. The refuse was acidic (Total-S = .. 38%; pH = 3.6), black, high (70%) in coarse fragments, and had a low water holding capacity (4.5% in < 2.0 mm fraction). A small plot experiment was established on the refuse pile to evaluate the influence of liming rates (50% and 100% of lime req.) and topsoil thickness (15, 30 and 60 cm) on vegetative growth and leachate quality. Liming and topsoil amendment increased the surface soil pH from < 4.0 to > 6.0 over a two-year period, which resulted in greater vegetative cover and biomass than the control plots. All topsoil treatments resulted in greater vegetative cover and biomass than plots treated with lime only due to improved surface soil physical and chemical properties. A topsoil treatment of 60 cm gave the thickest vegetative cover and biomass yield. Such a treatment, however, would be cost-prohibitive at this location. Application of 27 Mg ha-1 of lime to the refuse surface along with 15 cm of topsoil produced acceptable two-year vegetative cover and biomass, and appeared to be the optimal treatment for this particular situation. Both liming and topsoil had no affect on leachate pH and the electrical conductivity in leachates collected below the plots. This suggests that surface revegetation will have little effect on the quality of water draining through the pile, so long term water treatment requirements may not be reduced by successfully revegetating the pile surface.

Jan 1, 1999

By Peter Zhang, Daniel Su, Heather Dougherty, Jack Trackemas

"Longwall mining has a significant influence on gas wells located within longwall chain pillars. Subsurface subsidence and abutment pressure induced by longwall mining can cause excessive stresses and deformations in gas well casings. If the gas well casings are compromised or ruptured, natural gas could migrate into the mine workings, potentially causing a fire or explosion. By the current safety regulations, the gas wells in the chain pillars have to be either plugged or protected by adequate coal pillars. The current regulations for the gas well pillar design are based on the 1957 Pennsylvania gas well pillar study. The study provided guidelines for gas well pillars by considering their support area and overburden depth as well as the location of the gas wells within the pillars. As the guidelines were developed for room-and-pillar mining under shallow cover, they are no longer applicable to modern longwall mining, particularly under deep cover. Gas well casing failures have occurred even though the chain pillars for the gas wells met the requirements by the 1957 study.This study presents seven cases of conventional gas wells penetrating through longwall chain pillars in the Pittsburgh coal seam. The study indicates that overburden depth and pillar size are not the only determining factors for gas well stability. The other important factors also include subsurface ground movement, overburden geology, and weak floor, as well as the construction of gas wells. Numerical modeling was used to model abutment pressure, subsurface deformations, and the response of gas well casings. The study demonstrated that numerical models are able to predict with reasonable accuracy the subsurface deformations in the overburden above, within, and below the chain pillars, and the potential location and modes of gas well failures, therefore providing a more quantifiable approach to assess the stability of the gas wells in longwall chain pillars.INTRODUCTIONIn the eastern United States, abundant gas wells have been drilled through coal seams that are being actively mined by longwall mining. The existence of gas wells in the U.S. coal fields, whether active or abandoned, have caused many issues for longwall mining. First of all, any gas well in the mining area has to be located by all possible means. Secondly, the gas wells within longwall panels have to be plugged, as cutting through gas wells will allow natural gas to flow into the active longwall mines. On the other hand, the gas wells within longwall chain pillars or barrier pillars can be left in place if the wells are protected by properly designed pillars."

Jan 1, 2019

By Micheal McCarter, Biswadeep Saha, Meenakshisundaram Ramanathan, Chai Ren, Sivaraman Guruswamy

"Three-point bend test was used to study the effect of electrochemically charged hydrogen and magnetic field on the embrittlement behavior of AISI 4340 steel in this work. Acoustic emission signals were collected during the test and analyzed to gain an understanding of the crack growth process. Cathodic hydrogen charging in AISI 4340 steel resulted in drastic reduction of ductility and strength. Hydrogen embrittlement was characterized by a change in fracture surface from dimpled ductile surface to quasi cleavage type fracture. No significant effect was observed in the presence of magnetic field. The acoustic emission signals collected during the test provided an indication of the extent of energy released during the crack growth process.*Support of this work by NSF through the award DMR-0854166 is gratefully acknowledgedIntroductionGrowing interest in hydrogen as a clean fuel and use of steel and other iron based alloys for storage and transport of hydrogen has led to extensive study of the influence of hydrogen on the mechanical properties of these alloys. Hydrogen interaction with materials may result in degradation of mechanical properties. Embrittlement, either ductile or brittle, can be described as a condition which decreases the toughness of the material or increases the ease of crack growth. Hydrogen present even in few parts per million is sufficient to embrittle steels at room temperature [1]. In most cases, hydrogen exposure is through an electrochemical process in aqueous corroding environments. In such cases, they are prone to be exposed simultaneously to electrically induced magnetic fields, which are also believed to affect the hydrogen embrittlement susceptibility of these alloys. So it is also important to study the effect of magnetic field on the hydrogen embrittlement susceptibility. Hydrogen solubility by electrochemical process in aqueous solution is proportional to square root of current density for iron. [2,3]"

Jan 1, 2012

By Anup Tiwari, Khanindra Pathak, BIBHUTI BHUSAN MANDAL

Failure of in-pit overburden dumps in open-pit coal mines causes debris to flow toward the active working face, threatening the safety of people and equipment. The evaluation of the potential mobility of failing mass will aid in hazard mitigation associated with unwarranted dump failure. The potential mobility is shown by mobility ratio (ratio of total drop between debris flow's initial and final deposition points to total travel distance) and runout characteristics. In light of above, a laboratoryscale debris flow flume was developed to investigate the effect of material gradation and slope angle on runout characteristics and mobility ratio. The total mass of experimental debris mix (Q) is fixed at 30 kg with 20% water content. Experiments at three different slope angles (30°, 35°, and 40°) demonstrate that increasing the proportion of fines in the experimental mix increases runout characteristics while decreasing the mobility ratio. The length and area of the runout decrease as the slope angle increases, while the mobility ratio increases. There is a positive correlation between d50 and runout characteristics at a fines content of 0.1Q, but a negative correlation at a fines content of 0.2Q and 0.3Q. Conversely, there is a negative correlation between d50 and mobility ratio for fines content of 0.1Q, but a positive correlation exists for fines content of 0.2Q and 0.3Q. A new index called the fine-to-coarse (F/C) ratio is used to identify the critical value of fines and coarse proportion that causes a transition from dry granular flow to fluidized debris flow.

May 29, 2023

By L. T. Matthews, C. E. Loo, R. P. Williams

The behaviour of iron ores and fluxes in the high temperature zone of a sintering bed is extremely complex. Following a review of current knowledge, an attempt is made to define relevant terminology to describe the processes that occur in this part of the bed. A deformation temperature is used to quantify the initial formation of melt, which is produced predominantly by reactions between fine particles in the sinter mix. The subsequent assimilation of larger particles is considered to depend on the reactivity of the melt and the assimilation resistance of these particles. Novel laboratory experimental techniques are used to quantify these parameters. Results demonstrate that the properties of the raw materials used have an extremely important influence on the initial processes of melt formation and assimilation and also on the nature of the sintering reactions and sinter-bonding phases.

Jan 4, 1992

By S. Mohanta, B. C. Melkap

"SynopsisDry beneficiation of coal by air dense medium fluidized bed is an emerging trend. It is widely believed that the particle size of the medium has a significant effect on the separation efficiency. This investigation demonstrates that medium particle size has a major effect on separation efficiency. Experimental results show that different size fractions of the same feed respond differently to the same size fraction of medium solids. Furthermore, a particular size fraction of feed coal responds differently with different size fractions of medium solids. The Ep values and overall metallurgical performance parameters, obtained from experimental results, clearly indicate the superior performance of an air dense medium fluidized bed separator when using –150+106 µm magnetite powder as the fluidizing medium. These observations reinforce the importance of sizing the medium particle size for the air dense medium fluidized bed.IntroductionIn an air dense medium fluidized bed (ADMFB), a fluidizing bed of a particular density is created by suspending solid particles in an upward air flow. A feed containing coal particles of different densities is introduced into this fluidizing bed. The particles with relative density less than the bed density float on the top of the bed, while particles denser than the bed density sink through it. Since there is a general correlation between ash content and density of coal particles, it is possible to remove ash-forming impurities from a raw coal to the required level by regulating the density of the fluidizing bed. Recently, the ADMFB process has received significant attention world-wide for its specific advantages of low operating cost and less restrictive for small capacities (Luo and Chen, 2001; Houwelingen and de Jong, 2004; Dwari and Hanumantha Rao, 2007; Sahu et al., 2009; Mohanta et al., 2012). This process is not recognized as a well-established industrial practice because of the availability of efficient wet processing technology. However, with the revival of interest in dry beneficiation of coal in general, and ADMFB in particular, there is a concerted effort to improve the efficiency of the ADMFB process, and successive improvements have made the process a competitive and viable option for beneficiating coal."

Jan 1, 2015

By Mahmud Esad Uluer, Aaron Noble

Respirable coal mine dust (RCMD) is one of the biggest occupational health hazards for underground coal miners. Coal extraction is a main source of RCMD. To prevent challenges related to RCMD from developing, it is vitally important to limit airborne RCMD and stay within the regulatory limitations for mine operators. The flooded-bed dust scrubber (FBS), mounted on a continuous miner, is one of the most widely used dust mitigation technologies in room-and-pillar mining, but it is limited by technical challenges, the most notably being the potential to clog. In this study, the impact of mesh design and surface modification on system efficiency is examined using different vibrating, liquid-coated, stainlesssteel mesh panels in a laboratory-scale FBS.

Sep 1, 2024

By Shunhong Huang

Thirty-five soils were sampled from three sites at different distances from chromium slag heap of a Iron-alloy factory, namely, nine from site A located under the chromium slag and eighteen from Site B in the vicinity of the factory and eight from site C far from the factory. The contents of total Cr in these soils from site A, B and C were 1666.0±1310.9 mg? kg - 1,1136.2±1844.6 mg? kg - 1 ,300.4 ±165.1 mg? kg ? 1, respectively. The contents of water soluble Cr were 59.3±77.57 mg? kg ? 1,0.6 ±0.3 mg? kg - 1 ,0.5±0.3 mg? kg - 1 , respectively. In order to evaluate soil health, the activities of four soil enzymes (catalase, polyphenol oxidase, dehydrogenase, alkaline phosphatases) were analyzed. The results have shown that dehydrogenase activity was greatly depressed by conditions in the heavy chromium-contaminated sites. Negative correlation was observed between dehydrogenase activity and the distance from the chromium slag heap, however, the activities of catalase, polyphenol oxidase, alkaline phosphatases in soils from the three sampling sites mentioned above did not differ significantly. The result imply that of dehydrogenase activity could be used as an indicator for the chromium pollution level in the area of Iron-Alloy factory and for the stability level of the soil ecosystem.

Jan 1, 2008

By Jorge Madias

O trabalho está baseado na análise de dados de perto de 200 fornos elétricos a arco de diferente design: convencional, de corrente contínua, de carcaças gémeas, com preaquecimento de sucata no transportador ou em shaft, etc. Incluem-se fornos que processam principalmente sucata, e fornos com carregamento parcial de gusa sólido ou líquido, ferro briquetado a quente (HBI) ou ferro esponja (DRI) a frio ou a quente. São avaliados os consumos de energia elétrica, oxigênio, gás natural e materiais carbonosos; os tempos entre vazamentos, com forno ligado e com forno desligado, assim como a produtividade horária. Com os dados obtidos, se analisa a influência dos metálicos (e seu estado térmico ao momento do carregamento), e o design do forno, sobre os consumos específicos mencionados e a produtividade.

Oct 30, 2017

By Adriane Lopes Mougo

Super duplex stainless steel presents a biphasic structure composed by ferrite and austenite with different characteristics and properties. In the micromilling process the cutting edge radius has similar dimensions to the grain size. The biphasic structure found in this material could influence on the cutting tool life and the surface integrity of the workpiece. Due to its low machinability, caused by high hardening level and low thermal conductivity, the process can produce built-up edge and high surface roughness (Ra). In this work it is performed an experimental study of the micromilling of super duplex UNS 32750 and the influence of the cutting speed (Vc) and feed per tooth (fz) on the surface integrity and tool wear. The design of experiments considered two levels and three replicates. Results indicate the increase of roughness for bigger feed per tooth, small influence of the cutting parameters on the burr formation. The tool presented flank wear after the experiments.

Aug 8, 2018

By B. Kenney

For SOFCs, composite cathodes comprising an electronically conducting electro¬catalyst (e.g. LSM) and an conically conducting electrolyte material (e.g. YSZ) are considered to improve the electrochemical performance by extending the active reaction zone to regions beyond the electrolyte-electrode interface, as in the case of conventional cathodes. Interpretation of experimental data for composite cathodes, however, is complicated by the mixed conducting behaviour which results in local overpotential distributions throughout the composite cathode. These local overpotentials depend on many factors, such as the composition, particle size, porosity and thickness of the cathode. Reliable experimental data obtained from composite cathodes requires carefully crafted microstructural parameters in order to minimize the overpotential variations. A mathematical model of a composite cathode was developed using coupled differential equations describing transport and consumption of chemical species, oxygen ion and electrons. Simulations under various oxygen concentrations were used to obtain the reaction order of the oxygen reduction reaction. An apparent po2 dependency was then extracted from the predicted Rp vs P02 data. It was found that this p02 dependency can be significantly influenced by the micro-structural parameters of a composite cathode, primarily due to local overpotential distributions.

Jan 1, 2005

By L. M. Demers, D. C. Kuhn

It has been suggested that radicals on the surface of dust particles are key chemical factors in the pathophysiology that results from the occupational inhalation of coal and silica dust. In addition, oxygenated derivatives of arachidonic acid (eicosanoidsJ have been implicated as important biochemical mediator5 of mineral dust-induced lung disease through their role in bronchial and vascular smooth muscle reactivity, inflammation, and fibrosis. Therefore, we assessed eicosanoid production by the rat alveolar macrophage (AM) exposed in vitro to mineral dusts with varying surface chemical characteristics in order to determine if radicals associated with the mineral dust could influence the production of proinflammatory mediators in the lung environment. Primary cultures of rat AM were exposed to freshly fractured or "stale" bituminous coal dust, as well as untreated silica or silica calcined to 500 and 1100°C. Prostaglandin E1 (PGE;V, thromboxane Ai (T}(Ay, and leukotriene 84 (LTB; levels in incubation medium were determined by specific radioimmunoassay. When AM were exposed to freshly fractured coal dust, PGE2 production was markedly increased. In contrast, exposure of AM to "stale" dust significantly reduced PGE1 production. Exposure of AM to freshly fractured coal dust resulted in a significant increase in production by AM, while exposure to stale coal dust did not influence AM TXA1 production. Neither "fresh" nor "stale" coal dust had any effect on LTB4 production. In vitro exposure of AM to untreated silica resulted in a significant increase in TXA1 PGE.,, TXA; and LTB4 production compared with control. However, exposure of AM to silica calcined to 11oo•c resulted in eicosanoid levels that were not significantly different from control. These effects were still apparent 8 wk after calcination of the silica particles. Silica was a more potent activator of AM eicosanoid production than was coal, and amorphous fumed silica was a more potent activator of AM eicosanoid production than was crystalline silica. These findings suggest that radicals associated with respirable coal and silica particles may play a key role in the ability of mineral dust to activate AM eicosanoid production and therefore may be important in the pathophysiological consequences of occupational mineral dust inhalation.

Mar 1, 1992

By Sheng-li Wu, Guo-liang Zhang, Bo Su

The mineralogical characteristics of iron ores can influence their high temperature sintering performance. In this study, eight iron ore samples from Brazil, Australia, and South Africa were characterized by their chemical composition, mineral types, particle morphology, and gangue dispersity. Meanwhile the influence rules between the mineralogical characteristics and the high temperature characteristics were evaluated and analyzed. The results showed that the effect of SiO2 on assimilation characteristic of iron ores was relatively complex, Al2O3 and LOI of iron ores had negative correlation with assimilation temperature of iron ores, the dense slab-flaky mineral granule restrained to the assimilation characteristics of iron ores; liquid phase of iron ores with high SiO2 content and low Al2O3 content had high fluidity, and the higher dispersity of gangue minerals in iron ores was good to the fluidity of liquid phase.

Jan 1, 2015

By and Heather E. Lawson, Mark K. Larson, Gabriel Walton

In this study, we evaluated the effects of different shapes and distribution densities of mineral grains in coal on failure mechanics using the numerical software 3DEC. The main aim of this study was to identify possible failure mechanisms influenced by mineral habit and frequency in coal. Exploring differences in failure mechanics associated with the mineral grains helped to determine the role of mineral character as a possible contributor to characterize burst-prone coals. To achieve the goal of this study, a series of numerical specimens were prepared in the 3DEC model as follows: first, the 3DEC modeling in conjunction with the DFNs (Discrete Fracture Networks) technique was performed to explicitly generate the discontinuities (i.e., cleats and bedding planes) in the numerical specimens based on the results of laboratory analyses. Then, the different realizations of mineral grains were embedded in the 3DEC model to simulate an unconfined compressive strength (UCS) test to assess the influence of the mineralogical characteristics on the UCS.

By Xun Hu, Jian Pan, Hongbin Yu, Deqing Zhu, Yanhong Luo

Lump ores are one kind of important burdens for blast furnace (BF), their metallurgical properties have significant influence on BF performance. In this paper, the relationships between the mineralogy of five natural lump ores and the metallurgical performance have been studied. The mineralogy study includes mineral compositions, microstructure and porosity, and the metallurgical performance covers reducibility index (RI), low-temperature reduction degradation index (RDI) and decrepitation index (DI). The results show that the complex lump containing hematite, and goethite has better overall metallurgical performance. For single lump, the RI of goetihte ores is higher, the RDI and the DI is strongly influenced by porosity. The hematite and magnetite ores have good anti-decrepitation and anti-RDI, but generally the RI is lower due to lower porosity, and the RI is related to the grain size, the smaller grain size is, the better reduction will be.

Jan 1, 2015

By Guanghui Li, Xuling Chen, Zhiyun Ji, Min Gan, Tao Jiang, Xiaohui Fan, Zhiyuan Yu

With the increase of proportion of biochar(without modified) replacing coke breeze, the physical strength of sinter decreases due to the faster burning speed of biochar. An investigation upon passivating biochar with boric acid was then conducted to strengthen sintering in this paper. A layer of thin film of B2O3 distributed in the surface of biochar was observed, which could reduce the contact between reaction gas and biochar. So the burning speed of biochar was decreased properly after passivation, and the combustion efficiency increased due to the inhibition of carbon gasification. The comprehensive effects of above changes could increase the maximum temperature of sintering bed, which facilitated to the mineralization of sintering mixtures. Eventually sintering indices got reinforced. Thus the indices of sinter as applying 40% passivated biochar were comparable with that of 100% coke breeze.

Jan 1, 2015

By B. Tougas

Recycling of titanium represents an important economic activity due to high cost of the material and the amount of returns of machined parts which represent the bulk of finished titanium products (typical "buy to fly" of 10 in the aeronautic industry). In the present work, the metallurgical quality of 76 mm in diameter and 20 cm ingots poured in coated graphite mold will be assessed against the nature and condition of application of 4 coatings namely aluminum oxide, yttrium oxide, zirconium oxide and zirconium oxide with 4% aluminum oxide. The metallurgical quality has been evaluated in terms of alpha case thickness, microstructure and composition. Microhardness from surface will be assessed against casting conditions. Least square regression analysis have been use to optimize casting conditions.

Jan 1, 2011