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By R. A. Friedel

THE IMPORTANCE of infrared and ultraviolet-visible spectrometry in studies of the structure of coal and similar substances is described. Special experimental techniques have been developed for these studies. Thin sections of coal are preferred, but halide pellets are easier to prepare. Information obtained from infrared spectra on chemical functional groups has been discussed; the importance of both intensities and wavelengths of absorption bands has been emphasized. Functional groups assigned include aliphatic and aromatic CH, methylene and methyl groups, hydrogen-bonded hydroxyls, hydrogen-bonded and chelated carbonyls, phenolic structures, minerals, and aromatic structures that are benzenoid or polynuclear. Infrared studies of structures of coal extracts, distillates, and reaction products of various processes, both chemical and physical, are discussed. Coallike infrared spectra of chars of model compounds have been utilized extensively in studies of coal structure. Ultraviolet-visible absorption spectra of coals show a lack of fine structure and low spectral intensities. These results have been applied to the questions of the chemical and physical structure of coal, particularly the question of polynuclear aromaticity of coals. The color of coal is also treated. The physical-chemical origin of the color of coal may be due to free radicals, as interesting correlations of ultraviolet-visible spectra with electron paramagnetic resonance have been obtained. The optical color of coal has been explained and simulation of the color changes observed in thin sections has been carried out, The spectra and structure of coal derivatives and other carbonaceous materials are also discussed. Possible sources of error in absorption spectral measurements are pointed out. Limited measurements of the ultraviolet-visible reflectance spectra of coal are described.

Jan 1, 1967

By D. Krippner, C. Nexhip, D. George-Kennedy, P. Gebski, R. Kaur, W. L. Ying

ABSTRACT Water-Cooled Tapblocks Are Essential Components Of Modern Smelting Furnaces. Uninterrupted Operation Of A Tapblock Is Critical For The Optimal Operation Of A Furnace. This Critical Function, Together With Exposure To Extreme Conditions, Drives The Need For An Efficient And Reliable Means For Tapblock Monitoring. The Main Objective Of Tapblock Monitoring Is To Help Optimize The Life Of The Tapblocks By Better Scheduling Inner Refractory Relining And Protecting Operators By Preventing Sudden Deterioration Of The Tapblock. A Taphole Acoustic Monitoring (TAM) System Was Developed To Meet The Above Requirements. This Paper Describes The Principles Of The TAM System And Selected Case Studies.

Jan 1, 2013

By G Gibson, B Bessen

In coal preparation, large dense medium cyclones (DMC) at low pressure heads (typically 9D where D = cyclone diameter) are the norm. This contrasts with high density mineral applications where, largely for historical reasons, smaller cyclones at high heads are the standard. There are advantages in preferring large diameter cyclones at low heads, assuming that metallurgical performance does not suffer significantly. These include simpler plant layouts, easier maintenance, smaller spares inventories, reduced wear, reduced medium pumping demands, smaller buildings and overall lower capital and operating costs. In 2008, therefore, Xstrata Zinc decided to trial a single DSM-design 800 mm cyclone in one of its four DMC lines at Mt Isa, replacing the four 400 mm cyclones previously installed. Circumstances allowed a low head of 9.5 D to be trialled, compared with the existing 400 mm head of 21.5 D. This paper describes the trial, including tests using painted ore particles as tracers, estimates of yield and metal recovery, and wear monitoring. The larger unit performed well. There was no evidence that metallurgical performance in terms of metal recovery and waste reject rate suffered, and there was some evidence that it may have improved. Cyclone life increased, and preliminary data suggest that the replacement cost of the 800 mm cyclones is less than half that of the 400 mm units, and this is expected to improve. The plant layout and operability have also improved significantly. Xstrata has therefore decided to convert the whole plant to four low head 800 mm units, replacing the original 16 high head 400 mm units. The paper includes an explanation of the effect of static head on DMC separating force. It also reviews earlier research on diamond applications, and applies a general DMC process model to the Xstrata case, both of which confirm that large, low head cyclones are appropriate in mineral applications, contrary to conventional practice. Such units could significantly reduce both the capital and operating costs of DMC plants in mineral applications.

Jan 1, 2009

By H Rossiter, C Simpson, J Market, P Jeanneau

Downhole Assay tools are a geophysical method to collect an instigated response from the material surrounding a drill hole and deliver a multielement proxy-assay. They were first tested in the Pilbara at the turn of this century, however since 2011 they have seen a more focused testing and implementation regime with multiple companies across multiple Pilbara mine sites. The increase in the volume of data has led to advances in the measurements and significant improvements to the efficiency of the calibration process. Pulsed Fast and Thermal Neutron Activation Analysis (PFTNA) downhole assay tools collect gamma photon spectra which are characteristic of elemental signatures. One of the key components of the technique is calibrating the spectral signatures to lab assays. Each tool is slightly different due to the organic nature of the crystal detector and therefore responds slightly differently. Environment and hole conditions as well as ore characteristics are among other external influencing factors. Thus, a unique calibration is required for each tool. In addition, not all elements are measured directly, but some are actually characterised by proxy, meaning that if the signal-to-noise ratio for an element is small, it may be easier to identify the mineral or geology in which that element is found and thus infer the concentration of the element. These proxies may differ for each site or geology type within a site. There is a large advantage to build a unique calibration per tool at each site rather than a universal one to be used across the whole province. This then delivers the accuracy and precision of measurements that mining companies require for modern operations. Early work with the tool required several thousand metres of calibration data and several weeks of analysis to build each calibration. This process has now been streamlined to significantly reduce the amount of data required and the analysis time to make it much easier to introduce new tools to a site with an existing model or to create new models. This paper details the calibration process, illustrating the increasing accuracy of the models as training data are acquired as well as the methods for transferring a calibration from one tool to another.

Nov 8, 2021

By Mohammed Ali Shah, Martin Waller

The mining industry depends to a large extent on the availability of high performance equipment. For drilling this means a requirement for well engineered, reliable machines with mechanised handling and widespread utilisation of automatic control. Such machines enable performance optimisation of drilling operations and integration into a high productivity mining system. A review is presented of the current status of drilling technology as applied to the mining and minerals industry. This covers developments in: drill bit materials and design; drilling techniques; machine design; mechanisation; automation; and drilling control. It also covers the ways in which current and future mining methods and practices will influence the applications and demands placed on drilling activities. The probable impact of current research on the industry is discussed.

Jan 12, 1992

By F. S. Knoll

Electrostatic separation is one of the most misunderstood physical processes used to beneficiate minerals. Nonetheless, millions of tons of titanium ores, iron ores and other minerals are processed every year economically, efficiently and safely. Over the past ten years major advances in electrostatic separation and its application have occurred. New processes include dewatering clay slurries, separating halite and sylvite, and shape separation of vermiculite and gangue minerals. Electrostatic separation techniques are based on one of two methods, electrophoresis or dieleccrophoresis -- processes involving charged and uncharged particles respectively. In some cases, the combination of these two techniques has proven quite useful. The purpose of this paper is to provide a basic understanding of the physical processes collectively called "electro- static separation" in order to enhance one's ability to define and consider new possibilities in mineral processing and other fields.

Jan 1, 1984

Flotation works very well for particles that are typically in the range 20 to 150 µmin diameter, for base metal ores. In this range, it is possible to get quite high recoveries in conventional flotation machines. Outside this range, the recoveries decline progressively, whether it be with the very fine or the coarse end of the size spectrum. In this paper, the reasons for the drop-off in recovery are briefly reviewed, together with strategies for future work. Recent progress in the author's laboratory will be described. These include the Concorde Cell, which takes advantage of the high dissipation rates in the shock wave created when a gas-liquid mixture reaches supersonic velocities. The environment thus created is very beneficial for the flotation of ultrafines. For coarse particles, the reasons for the drop-off in recovery can be related to the highly turbulent nature of the pulp in a conventional flotation cell. To improve recovery, it is necessary to find a way of bringing particles and bubbles into contact in a quiescent environment. A new process for coarse particle flotation will be described, in which a fluidized bed is created in the flotation cell. The flow conditions are very gentle, and the high solids concentration leads to rapid rates of capture of the particles. Experimental results are presented. It is apparent that the maximum floatable size for coal and minerals can be increased by a factor often over the limits found in current practice. Advances

Jan 1, 2009

By Jorge Rubio, Gabriel Berkowitz, Fabiano Capponim, Carlos Perez Guerrero, Elves Matiolo, Denise G. Nunes

This paper describes some advances in flotation research in fines (“F” 38 to 13 µm) and ultrafines (“UF” < 13 µm) mineral recovery by two different techniques, at laboratory scale. Extender flotation and flotation with .multi-bubbles. (bubbles with a wide size distribution) of copper sulphide fines (ore feed of about 1 % Cu) were compared with a .standardised. mill laboratory procedure. Comparative evaluation was made through concentrate grade and recovery (size by size results included), .true. (bubbles-particles attachment only) flotation recoveries and process kinetics. Both techniques yielded higher metallurgical efficiencies than the mill standard but better results were obtained with the extender flotation, with emulsified diesel oil (90 gt-1). Concentrate recoveries were of the order of 85-90 % (84 % in standard conditions), 14-17 % Cu grade (15 % Cu in the standard) and 3.5-4.5 min-1 for the Klimpel rate constant (3 min-1 in the standard). Size by size and true flotation results proved that metallurgical and kinetic gains, obtained with the two techniques, might be attributed to fines and ultrafines enhancement. Data obtained are discussed in terms of physical and physico-chemical parameters related to aggregation and capture (of particles by bubbles) phenomena and the practical potential of these techniques are envisaged.

Jan 1, 2003

By lves Matiolo, Jorge Rubio, Carlos Perez Guerrero, Denise G. Nunes, Fabiano Capponi

The problem (very old) of processing by flotation, the fine (“F”, 38-13 µm) and ultrafines (“UF”, < 13 µm) mineral particles continues to be a major technical challenge in the area of mineral processing. Many different processes have been proposed over the last three decades but, unfortunately, most of them have not found practical applications yet. This paper describes some advances in flotation research in fines (“F”, 38-13 µm) and ultrafines (“UF”, < 13 µm) mineral recovery by two different techniques. Extender flotation (EF) and flotation with bubbles with a wide size distribution-SB of copper sulphide ore fines (1 % Cu) were compared with a “standardised” (STD) mill laboratory procedure. Comparative evaluation was made through concentrate grade and recovery (size by size results included), “true” flotation recoveries and process kinetics. Copper porphyry samples, containing about 1/3 of the mass and about 37 % of the total copper content in the fines and ultrafines fractions were used. In the EF tests diesel-in-water emulsions were used as an extra reagent, added after the collector and frother addition. In SB tests, drawing air through an aspiration nozzle, directly in the pulp, generated bubbles sized about 50-200 µm. Both techniques yielded higher metallurgical efficiencies than the mill standard but better results were obtained with the extender flotation, with emulsified diesel oil (90 gt-1). Concentrate recoveries were of the order of 85-90 % (84 % in standard conditions), 14-17 % Cu grade (15 % Cu in the standard) and 3.5-4.5 min-1 for the Klimpel rate constant (3 min-1 in the standard). Size by size and true flotation results proved that metallurgical and kinetic gains, obtained with the two techniques, might be attributed to fines and ultrafines enhancement. Data obtained are discussed in terms of physical and physicochemical parameters related to aggregation and capture (of particles by bubbles) phenomena and the practical potential of these techniques are envisaged. The following figure shows size-by-size copper recoveries results, after classification of produced concentrates and tailings using micro-sieves. Results clearly show that flotation of the F and UF fractions is highly improved with injection of small bubbles (SB) and with the addition of an extender collector. It is believed that the techniques presented here will establish shortly a new basis for the flotation enhancement of the F and UF, aimed at solving a very old problem. This work is being continued, now at pilot plant scale, and results will be published en the near future.

Jan 1, 2003

By S. Frisch

Selenium (Se) in effluent waters has become a significant challenge for a number of industries. Toxicity studies and new reports of occurrence have certainly caused increased scrutiny and actions in the mining industry today (Sandy, DiSante, 2010). While initial activity in addressing selenium-laden waters were conducted in the coal mining industry, today a much broader range of mine types are beginning to search for solutions to selenium treatment of their mining waters, including both hard rock mining operations (gold, nickel, zinc, etc.) and soft rock mining (phosphate, uranium, etc.) Throughout North America, new regulations covering selenium discharge are either in place or being developed. While a number of physical/chemical approaches show promise in selenium treatment, when considering optimal cost and treatment efficacy issues, biological treatment ? particularly fixed-film biological treatment - is reported to be one of the most promising approaches to managing selenium-containing waters. Among biological treatment options, the fluidized bed reactor (FBR) has undergone extensive pilot testing for Se treatment in the last three years, including eight pilot programs, and the first FBR system is now operating at a coal mining site. In all tests, the FBR has been shown to be a highly cost-effective approach to selenium treatment based on its physical and performance characteristics. This is consistent with its history for reaching low levels of treatment in similar service for other oxyanions including perchlorate, nitrate and various metals. With the results from the most recent testing, the technology has been shown to be adaptable to an ever-broadening range of influent water conditions and flow rates, in varying terrains and weather conditions. Selenium occurs in various valence states from -2 to +6 (Sobolewski, 2005). The speciation of selenium plays a critical role in understanding the effectiveness of any approach for removal, especially to low levels. Elemental selenium is insoluble and has little effect on living organisms. Colloidal fractions are known to occur. In aqueous environments such as coal mining runoff, selenium is most often found as the oxygenated anions of selenite (SeO32-, Se4+) and selenate, (SeO42-, Se6+). Selenium is commonly found in mining waters in concentrations ranging from 3 to >12,000 µg/L. The U.S. National Primary Drinking Water Standard MCL is 50 µg/L for selenium (EU 10 µg/L; WHO 40 µg/L). The National Fresh Water Quality Standard is 5 µg/L for selenium. The U.S. Fish and Wildlife Service has recommended that the National Fresh Water Quality Standard be lowered to 2 µg/L to protect fish, waterfowl, and endangered aquatic species. Several states have followed with enforcement actions at these same low levels. In Canada, permits may require stakeholders to monitor levels in water or biota, or to comply with guidelines, at either the National or Provincial levels, which can be as low as 1 or 2 µg/L in surface waters. Treatment of selenium in all mining waters presents a series of challenges. It can be present in relatively dilute concentrations and in streams with variable and often high flow rates. It can be present in many soluble and particulate forms, which may affect process design and treatability. The conditions of influent selenium-containing waters can vary, with issues such as temperature, pH, total dissolved solids and other contaminants affecting the ability to remove selenium selectively and economically. Treatment of selenium often results in the generation of a concentrated by-product requiring disposal, and re-release from residuals can occur. Beyond these issues, the physical environment of a mining operation can offer challenges such as remoteness and harsh and/or cold weather. Currently available selenium treatment technology (Table 1) includes biological treatment and a number of physical-chemical processes ? such as ion exchange, membrane filtration and adsorption ? that vary widely in efficiency and cost. Most treatment options remain either too costly and/or unproven for selenium-containing streams for reasons that include poor removal efficiency, variability in volume and composition of influents, system sizing and logistics considerations, as well as operating requirements.

Feb 23, 2014

By R. MacRosty

The demand to increase production levels in smelting furnaces has driven the increase in the power levels. Consequently, greater cooling capacity of the furnace shell has been necessary, resulting in the widespread use of water-cooled elements to protect the refractory linings. Since water ingress into the furnace is an explosion hazard, monitoring and maintenance of the water-cooled elements is of key importance. Some of Hatch&apos;s recent research and development efforts have been focused on methods to provide an increased level of monitoring of water-cooled furnace elements; this paper focuses on two technologies developed for this purpose. The first involves the installation of a fibre optic temperature sensor in a water-cooled tapblock. The sensor is capable of providing high accuracy temperature measurements with a fine spatial resolution throughout the tapblock. Hatch has already developed a diagnostic system that uses multivariate statistical analysis to interpret the large quantities of data generated by the sensor. A second technology under development is concerned with enhancing the operating integrity and safety through detection of leaks in the water circuits. A successful leak detection strategy requires minimal maintenance and the ability to detect minute leaks. An instrument that meets these criteria has been investigated and is currently under development. This paper focuses on the technology and results from the test work that has been completed to date.

Jan 1, 2007

By P. D. Nolan

Smelters operating under pollution control orders have become increasingly dependent upon the reliable operation of sulphuric acid plants and no factor affects the long term reliability of those plants more than efficient gas cleaning. The sources and characteristics of contaminants in smelter of fgases and the conventional approaches to removing these contaminants to accepted levels are discussed. New technology is described which offers advantages of lower capital cost, lower operating cost and reduced space requirements over the conventional approaches. This new technology has been developed by LAB s.a. and is licensed for metallurgical gas applications by Chemetics International Company.

Jan 1, 1983

By M Salu, G J. Kay

"As underground mines increasingly face the challenge of maximising production without losingfocus on safety excellence, the ability to predict the eff ectiveness of mine seals and stoppings andthe identifi cation of defects plays an increasingly important role in mine ventilation management.While technologies for sample testing installed seals provides signifi cant assurance, the difficulty of conducting tests in operational environments, combined with the production impact of destructive testing procedures, has led to the development of a new method for non-destructively testing ventilation control devices (VCDs). This paper addresses the challenges of in situ testing and reviews the approaches previously employed to verify the quality of VCD installations. It then describes a new testing methodology jointly developed by Whitfield Minerals PTY Ltd and Parsons Brinckerhoff (PB) and the range of tests that have been carried out in the laboratory, above ground, at trial underground sites and in active coal mine operations. Although this is a new approach to testing underground VCDs, the method employs recognised testing equipment in a new application. The aim of the new non-destructive technology is to not only verify the thicknessand therefore overpressure rating compliance, of new VCDs, but to allow mine operations t oidentify and locate defects in installed VCDs without causing damage to the material structure.Currently it is difficult, time-consuming and costly to carry out physical sampling and testing ofevery VCD. Therefore, a reliable and accurate means of non-destructively testing concrete andplaster seals in situ will provide substantial operational and safety benefi ts to the underground coal mining industry."

Jun 1, 2012

By T. P. Weldum, W. Conger

"These studies address the relationship between mill media sizing and its grinding efficiency. Starting with the results from a review of the literature, the issues of initial media sizing for a new ball milling circuit, and then optimal media sizing for an existing milling operation, were studied. The Functional Performance parameters “Mill Grinding Efficiency” and cumulative “Mill Grinding Rates” from both plant and test-scale equipment were used, and provide valuable new insight into this topic. A plant media sizing diagnostic tool is presented, as are newly developed testing equipment and evaluation methods, and recent case studies. REVIEW OF MEDIA SIZING LITERATURE For a plant metallurgist to answer the question “How can I maximize plant profit by manipulating this grinding circuit variable?” she must know what effect the variable has on grinding circuit efficiency. Despite the significant cost of grinding media and its potential effect on production capacity, the ‘best’ media sizing remains ill-defined for any given ball mill circuit in the industry today. The underlying reasons for this will be discussed. But the importance of this issue drove Metcom and its industrial partners to take on the challenge of how to engineer the ball charge for an existing grinding circuit. In the absence of any proven method, the first step was a review of the literature. Sponsored by Cleveland-Cliffs, Inc., a broad review of the literature was undertaken, producing “The Effect of Media Sizing on Ball Milling Efficiency” (McIvor, 1997). Among hundreds of publications that were reviewed that discuss the topics of media sizing or wear, forty-five were studied in detail. These were grouped into: plant experiences; laboratory and pilot plant investigations; media wear studies; population balance modeling studies; and general papers on ball milling which included the topic of media sizing. The reader is encouraged to refer to that review. The findings remain unchanged, although some relevant papers have been written since (e.g. Staples et al, 1997; Banasi et al, 1999; Orford et al, 2006; LaMarsh, 2015). The main findings of the review were as follows."

Jan 1, 2018

Infrared spectroscopic data collected using HyloggerTM technology is being used to assess the mineral composition of Archean iron ore bedrock and Cenozoic detrital units in Western Australia’s Pilbara region. Analysis of infrared spectra enables quantification of: (1) composite iron mineralogy, (2) composite clay mineralogy, (3) hydrous silicates and (4) carbonate mineral abundances. Stratigraphic and rock mass unit logging of core has identified several detrital and bedrock units recognisable across the Pilbara. However, due to alteration related to mineralisation, weathering and later stage precipitate overprinting, it can often be difficult to assess the detrital-bedrock boundary and the occurrences of specific geotechnical units in the detritals and bedrock, particularly when using non-core drilling techniques and traditional geochemical assays. Infrared spectroscopic data collected concurrently on core from several sites has shown distinct correlation against existing unit subdivisions and associated geochemical parameters. Where infrared spectroscopic data have also been collected on rock chips recovered from reverse circulation infill drilling, these correlations allow robust geological and geotechnical models to be developed based on the typical mineralogical-geochemical signatures. The geotechnical sub-units identified in core can be readily distinguished using the various iron and clay minerals captured by the HyloggerTM technology as opposed to total iron, potassium, and alumina captured by geochemical assays. Further, some of the minerals targeted by infrared spectroscopic analysis (eg gibbsite, white mica, vitreous goethite) and their ubiquitous presence as the products of weathering, assist in recognition of various ancient weathering surfaces and help to define the origin of the material, whether bedrock or detrital. Overall, HyLogging of core and chips allows important mineralogy focussed data to be captured at minimal additional financial outlay. Correlations against geochemical unit identifiers are robust both within deposits and between deposits. Significant improvements in the confidence of geological and geotechnical models are attained.

Jan 1, 2015

By F. J. McMulkin

This paper, the 1965 Airey Memorial Lecture, reviews the world-wide technical advances in iron and steelmaking, and offers an appraisal of the new techniques which will be applied in the future. After a review of blast furnace operations, the continuous steelmaking process is described, and the resulting techniques of degassing and continuous casting are discussed at length. Pressure pouring, hot rolling, cold rolling and coating practices are also outlined, and considerable space is devoted to the direct reduction process. Finally, the application of the computer to steelmaking operations is discussed in some detail.

Jan 1, 1966

By W. A. Crosby

The ability of open pit mines to steepen overall final wall angles allows significant cost reductions as a result of reduced waste movement requirements. Final wall angles are principally controlled by three factors: geological conditions; hydrological conditions; and wall control blasting practices. The first of these factors is not controllable by the mine operator, the second can be influenced to some degree, but the last one certainly can be controlled, hence the current interest in final wall blasting practice at many mining companies. This paper discusses common blasting techniques employed to steepen final pit walls and outlines the attractiveness of moving from small hole high cost systems to the use of full size production drills as a means of reducing wall control blast costs. Attempts to make this change have been limited at many mines by the physical size of the drills and their inability to reverse drill. In the past, pres pi it, pre-shear or trim holes have had to be drilled vertically, at considerable distance from the upper bench toe, with the result that inter-berm face stability is reduced and final wall angles have to be made somewhat more shallow than desirable. The paper concludes with a description of how these problems can be overcome by utilizing the new Bucyrus 39R which has the capability of drilling at a ?15 degree angle underneath the machine. It is concluded that the resulting wall control blast designs will offer large mines improved final wall angles with resulting significant overall cost reductions.

Jan 1, 1998

By D. Farnell

Large semi-autogenous (SAG) or autogenous grinding mills have become the work-horse of the modern high volume concentrator. They typify the economy of scale - fewer, larger machines doing more work, more economically. With fewer machines, equipment reliability becomes of paramount importance. Realizing this, companies installing new or modernizing existing facilities have placed extraordinary emphasis on purchasing a reliable mill. This, in turn, has had a significant impact on mill design. Kennecott And Codelco - Two Different Approaches Last year, two of the world&apos;s largest copper producers, Codelco and Kennecott, undertook the modernization of their main grinding facilities at Chuquicamata and the Utah Copper Division (UCD) respectively. Both selected semi-autogenous milling and both, recognized the importance of the reliability of the primary mills. Each, however, decided on a different approach to optimizing reliability. Codelco placed the emphasis on technical innovation in design and opted for a gearless driven mill. Kennecott chose the more conservative approach of active participation and exceptional quality assurance in mill design and manufacture.

Jan 1, 1987

By J. Iannicelli

Spray drying is the principal drying method used in the production of over six million tons annually of beneficiated kaolin in Georgia. Thirty-three dryers in the Georgia Kaolin belt comprise the highest concentration of large tonnage spray dryers in the world. The steady growth of spray drying in the U.S. kaolin industry is paced by advances in design and development of large spray dryers which have led to large scale new applications in mining and related industries.

Jan 1, 1982

By R. M. Reynolds

Engitec Impianti, S?.p.A. of Milan, Italy has successfully designed, constructed and has in operation state-of-the-art battery breaker systems at two European locations. A third facility i:s partially completed in Toronto, Ontario, Canada. The CX system crushes whole batteries, separates the various components and desulfurizes the battery paste. The system also produces sodium sulfate from the sulfuric acid and lead sulfate contained in the batteries. Actual plant operating data indicates that the desulfurized paste contains less than 0. 6 percent sulfur and less than 0. 5 percent antimony. The CX system utilizes mechanical screening and an up-flow hydrodynamic separator to accomplish the component separation. Sodiwn hydroxide or sodium carbonate is used for desulfurization. The sodium sulfate brine is evaporated and crystallized to produce clean anhydrous sodium sulfate suitable for use by detergent or glass manufacturers. Plant data also indicates that an increase in furnace productivity of about 25 to 30 percent is achieved using feed from the CX system. The desulfurized paste is very suitable for electrolytic processing as an alternative to pyrometallurqical processing.

Jan 1, 1990