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By G. Anger, J. Enser, H. Antrekowitsch, S. Koch

Homogeneous chemical composition and microstructure are always necessary, but not always attained in practice. As-cast aluminium alloys tend to have a segregation microstructure. Features of the cast structure, which affect subsequent processing or properties, can be altered by the homogenization. The main task of the Department of Nonferrous Metallurgy was to investigate the effect of homogenization treatment on precipitation hardening of aluminium alloys 6061 and 6082. The effect of the solution heat treatment (SHT) temperature on the mechanical properties was also analyzed. The homogenized and non-homogenized rolling slabs were produced according to the usual conditions and methods. The metallographic investigations were carried out on the as-cast samples, after homogenization, after the hot and the cold rolling mill, and after natural and artificial ageing. Then, Brinell hardness measurements and tensile tests were conducted on both alloys in order to examine the influence of the homogenization.

Jan 1, 2006

By C. Aldı, O. Yaral

For the more economical excavation of tunnels in underground mining activities, the selection of mechanised excavation machines (such as roadheaders, electro-hydraulic drills, etc.) and the analysis of performance prediction that can be used in estimating machine energy consumption have been subjects of research from past to present. One of the parameters to be considered in studies examining these methods, is the grinding process. The success of increasing efficiency in grinding is expressed by a reduction in energy consumption. The goal of a grinding process is to maximise the grinding amount at the appropriate grinding size while minimising the energy consumption per tonne of the fragmented material. Today, the depletion of high-grade ore deposits has largely directed the mining industry towards low-grade but large reserve ore deposits. This shift has particularly increased the importance of the grinding process, as it is dependent on particle liberation. Grinding is a critical step in reducing the mineral to the appropriate size, and energy consumption poses a significant challenge in this process. As a result, researchers have conducted various studies focusing on energy efficiency and cost optimisation in this field. In this study, the grindability of 7 different coal environment rocks (sandstone, siltstone) from the Zonguldak Basin, Uzulmez Region was investigated. For this, Hardgrove Grindability Index and Bond Work Index tests were conducted. While determining the relationships between grindability and other parameters, the results obtained from the Hardgrove Grindability Index (HGI) test were used. The energy values found in the Bond Work Index (BWI) test were used to evaluate the excavatability of the rocks. Additionally, tests for strength, hardness, drillability, and abrasiveness were conducted to observe the impact of other parameters on grindability. Considering the results obtained from the experiments, significant relationships were found between the grindability of the rocks and other parameters.

Mar 30, 2026

By P. N. Anyalebechi

Keywords: Aluminum alloy 3004, Solidification rate, Homogenization, Second phase particles The effects of the fineness of as-solidified cast microstructure and temperature on the response of aluminum alloy 3004 to homogenization heat treatment (a.k.a. preheat) have been investigated. The study was conducted at 538oC and 595oC on directionally solidified laboratory-size ingots with a range of solidification rate of 0.10oC/s to 29.4oC/s. Optical and electron microscopy, quantitative image analysis, electrical conductivity, and electron probe microanalysis were used to quantify the effects of the homogenization heat treatment on the microstructure of aluminum alloy 3004. In general, increase in fineness of as-cast microstructure and homogenization temperature enhances the a-transformation reaction, dissolution of Mg2Si, elimination of dendritic microsegregation, and dispersoid formation. The homogenization heat treatment reduces the average size of second phase particles in castings solidified at <1oC/s. However, in castings solidified at above 1oC /s, homogenization causes the coarsening of the second phase particles. Mn in solid solution is independent of homogenization heat treatment temperature.

Jan 1, 2005

By P. N. Anyalebechi

"The effects of solidification rate, initial melt hydrogen concentration, and grain refining on porosity formation in aluminum alloy 2024 have been investigated with unidirectionally cooled laboratory-size ingots. The ingots were prepared from melts containing hydrogen concentration of 0.059-0.27 cm3/100 g and solidified at 0.2-37 °C/s. As expected, the amount of porosity, average pore size, and pore number density increased with increase in melt hydrogen concentration and decrease in solidification rate. However, the effect of solidification rate was greater at the very low melt hydrogen concentration (0.059 cm3/100 g). These results are consistent with reported effects of solidification rate and melt hydrogen content on porosity formation in other aluminum alloys. Interestingly, addition of grain refiner slightly increased the amount of porosity and the average pore size, especially at solidification rates above 1°C/s. IntroductionIn shaped castings and wrought products fabricated from ingots, billets, bars, or slabs of aluminum and its alloys porosity formation is a problem. This is because it compromises their tensile strength, fracture toughness, and fatigue properties [ 1-18]. The pores are usually the crack initiation and propagation sites [6,8,9] and the largest pores tend to dictate the fatigue life of the aluminum products [9,10,14]. Porous regions within an aluminum product probably yield first due to the reduced tensile load bearing capacity, causing the concentration of the strain near the voids which subsequently results in premature fracture. In aluminum alloy ingots, billets, bars and slabs porosity formation is particularly problematic because of its persistence through fabrication and potential for reappearance or exacerbation during subsequent thermal treatment processes before and/or after fabrication [19]. In fact, persistence of microporosity is a serious problem in large thick plates of wrought aluminum alloy products that must be rolled from correspondingly large direct-chill or electromagnetic cast ingots. Some of these thick plate products are machined into large aircraft components that are required in service to withstand multi-directional stresses and to possess high fatigue strength, fracture toughness, resistance to stress corrosion cracking, and strength in the short-transverse direction [1,20]."

Jan 1, 2011

By G. L. Mowrey

One critical element of the U.S. Bureau of Mines (Bureau) autonomous mining research program is the development of a reliable coal interface detection (CID) system. Several candidate CID concepts currently being investigated by the Bureau include vibration, passive infrared, radar, and natural gamma radiation (NGR). To establish which CID sensor technologies need to be developed for a given seam, coal and adjacent rock samples (i.e., immediate roof and floor) are being collected from selected major coal seams in the U.S. and are being analyzed in terms of NGR and other geophysical measurements. Results of the NGR measurements indicate that, in general, all shale and shale-like materials (e.g., drawslate, slate, and fireclay) have higher NGR readings than the coal seam. Consequently the NGR method appears to be a potentially useful CID tool, provided that the immediate roof and floor are both composed of a high percentage of shale-type material.

Jan 1, 1990

By G. Gauvin

Life span of aluminum smelting electrolysis cells can reach up to 3000 days. During this period, cathode blocks go under various physical and chemical changes that could result in an increase of electrical resistivity. The increase may be due to carbon migration from the cast iron to the steel bars, gap evolution between the cathode block and the cast iron, cathode cracking, etc. This paper focuses however only on the collector steel bar electrical resistivity evolution. To reveal the main phenomena responsible for the electrical resistivity increase, chemical analysis, metallographic and electrical resistivity tests were conducted on two steels bars picked from two Hall-Héroult cells after autopsies. Cathode voltage drop and temperature were measured using electrically insulated internal probes and thermocouples on 16 samples from each steel bar. Electrical resistivity can reach up to 1.21µO-m for a steel bar aged 2505 days compare to 0.142µO-m for steel AISI 1008 at room temperature.

Jan 1, 2011

By J. DuCarme, A. Smith, M. Reyes

"A magnetic proximity detection system is mounted on a mobile mining machine to prevent underground workers from being pinned or struck by machine motion. The system generates magnetic fields around the machine to determine safe working distances. The minerworn component measures the magnetic field in order to approximate location. Large masses of steel, such as those from mining equipment, can alter the magnetic field distribution. This affects the locational accuracy of the system, thus adversely impacting worker safety. To examine this problem, U.S. National Institute for Occupational Safety and Health researchers developed a method and test system to study the influence of a steel mass on the magnetic field distribution. The results show that a steel plate can strengthen the magnetic field perpendicular to the generator by up to 40 percent. Furthermore, they show that the degree of the influence on the field distribution is a function of distance. The results from this study can be used to further develop and improve the performance and reliability of electromagnetic proximity detection systems used in underground mining applications.IntroductionOn average, 250 miners are injured every year, and 43 miners were reported to be killed by striking or pinning accidents involving continuous mining machines in the United States between 1984 and 2015, according to the U.S. Mine Safety and Health Administration (MSHA, 2015). Continuous mining machines are large mobile machines used to mechanically cut coal in underground mines. These machines weigh approximately 60 t (132,000 lb) each. Although modern continuous mining machines can be remotely controlled, operators still need to be close to the machine primarily because of the low visibility and wide blind spots of the underground working environment.The MSHA promulgated a final regulation in 2015 that requires the use of proximity detection systems on all continuous mining machines except fullface machines. MSHA has approved five such systems to be intrinsically safe for use in underground coal mines: (1) Strata Worldwide’s HazardAvert System, (2) Frederick Mining’s Model 200 HazardAvert Detection System, (3) Nautilus International’s Coal-Buddy System, (4) Matrix Design Group’s M3- 1000/Joy Global SmartZone Gen 1 and (5) Matrix Design Group’s IntelliZone/ Joy Global SmartZone Gen 2."

Jan 6, 2018

By Th. Hassel

The application of magnesium as an absorbable biomaterial demanded the consideration of the alloy composition, the mechanical properties and the corrosion a special adapted material development in terms of the human biological system. Magnesium for technical applications mostly comprised alloying elements up to 10 wt%. Thereby often metals (e.g. rare earth and aluminum) with high toxic potentials are used to optimize the mechanical properties. To minimize toxic reactions during the degradation of a absorbable magnesium alloy, the Mg-Ca system is being selected and investigated because both elements belong to the mineral nutrients. Rods and small tubes are produced by extrusion of gravity die casting billets (Ca-content 0.4 to 4.0wt%). The positive grain fining influence of calcium and its improvement of the corrosion behavior are additional advantages. The microstructure, the mechanical properties and the corrosion attitude are investigated. The results show that an optimal composition of micro alloyed Mg-Ca and ideally processing parameters lead to 16% strain and a tensile strength up to 185MPa. Electrochemical investigations and measurements of the hydrogen production demonstrate the influence of the Ca-content to the corrosion behavior of the investigated alloys.

Jan 1, 2006

By J. W. van der Merwe, K. G. Moloko

Furnace wall tubes from 600 MW subcritical boilers at three coal-fired power stations were sampled and the fireside deposits examined to determine the mechanism of fireside corrosion. This involved an indepth investigation into the morphology and composition of the fireside deposits and the conditions of the furnace that enable this type of attack. SEM-EDS analysis revealed high concentrations of oxygen, iron, and sulphur, QEMSCAN and XRD analyses identified the presence of Fe3O4, Fe2O3, FeS, and FeS2. Differential thermal analysis showed thermal activities at temperatures of 500–600°C, 900–1100°C, and 1100–1250°C, which are associated, respectively, with FeS2 oxidation to FeS and Fe2O3, at 475–525°C, formation of aluminosilicates at 925–1100°C, and melting of FeS around 1190°C. The absence of sodium and potassium eliminates the contribution of molten alkali sulphates to the corrosion. The consistent coexistence of iron sulphide and iron oxide is indicative of the substoichiometric conditions in the furnace, while the detection of pyrite suggests that the coal is not completely combusted, which points to a poor combustion process. These observations were affirmed by gas analysis at one of the stations, where very high levels of carbon monoxide were measured at the furnace wall (≥ 14 000 ppm) and furnace exit (≥ 3500 ppm). The high CO concentrations are indicative of limited combustion caused by limited O2. These reducing conditions promote the formation of FeS-rich deposit, which is the corrosive species responsible for degradation.

Jun 1, 2021

By S. Middlemiss

The Indentation Fracture technique is being developed as a tool for use in comminution and mineral liberation analysis. Fracture toughness measurements for a number of mineralogical materials were made and comparisons were drawn between these and properties measured with the Ultrafast Load Cell drop weight apparatus. The technique has also been used as a probe to quantify differences in fracture properties at different areas in the microstructure of a material. In both a Utah limestone and a South African quartzite, material near a grain boundary fractures very differently to that in the bulk. Ongoing work is ultimately aimed at producing a comprehensive fracture model for a multi-mineral system based on its micro-fracture characteristics.

Jan 1, 1994

By G. Akdogan, I. Mwandawande, S. M. Bradshaw, M. Karimi

The mixing characteristics of industrial flotation columns were investigated using computational fluid dynamics (CFD). Particular emphasis was placed on the clarification of the relationship between the liquid and solids mixing parameters such as the mean residence time and axial dispersion coefficients. The effects of particle size and bubble size on liquid dispersion in the column were also studied. An Eulerian-Eulerian method was applied to simulate the multiphase flow, while additional scalar transport equations were introduced to predict the liquid residence time distribution (RTD) and particle age distribution inside the column. The results obtained show that particle residence time decreases with increasing particle size. The residence time of the coarser particles (112.5 μm) was found to be at least 60% of the liquid residence time, while the finer particles (19 μm) had a residence time similar to the liquid. The results also show that an increase in the particle size of the solids results in a decrease in the liquid vessel dispersion number, while a decrease in the bubble size increases liquid axial mixing. Finally, the simulated axial velocity profiles confirm the similarity between the liquid and solids axial dispersion coefficients in column flotation.

May 2, 2022

By Qinmeng Wang

The oxygen bottom blown copper smelting process is a new technology which has been widely applied to the copper production in China. In this work, a computational thermodynamics model for this technology has been established, based on smelting mechanism and theory of Gibbs free energy minimization. The calculated results from the model agree well with the actual industrial data, indicating that the model can be used for the predictions under different operating conditions. The tendencies of the key parameters (such as Cu losses and Fe3O4 content in slag) and the distribution ratios of the minor elements (such as Pb, Zn, As, Sb and Bi) can be predicted by adjusting the oxygen/ore ratio charged into the bottom blown copper smelting furnace. The model can be used to monitor and optimize the industrial operations of the oxygen bottom blown copper smelting process.

By Z. L. Xue, J. L. Li, X. Y. Wang

"In low-carbon energy-efficient basic oxygen furnace (BOF) steelmaking processes, limestone partly or completely replaces the active lime. The effects of limestone calcination temperature (1200–1500°C) and time (5–15 minutes) on lime reactivity and CaO grain size were investigated. The reactivity was evaluated by titration with hydrochloric acid, and the CaO grain size was analysed using scanning electron microscopy. The results revealed that for calcination temperatures higher than 1300°C, the reactivity reached a maximum and then decreased . The higher the temperature, the earlier the peak of reactivity appears. The CaO grains grow with increasing temperature and time, which leads to the decrease of reactivity. Notably, the effects of temperature on CaO grain size and reactivity are more marked than that of time. To obtain active lime calcined at ultra-high temperature by flash heating, the calcination conditions should be 1300–1400°C for 10–15 minutes, or 1400–1500°C for 8–10 minutes. IntroductionLime is one of the most important slag-making materials for dephosphorization and desulphurization in the basic oxygen furnace (BOF) steelmaking process. The reactivity of lime is a measure of its capability to take part in slag-making. Lime having a reactivity of more than 300.0 mL (4 N HCl), determined by hydrochloric acid titration is generally referred to as active lime (Rusjan et al., 2007; Zeman, 2008). At present, the active lime used for BOF processes comes primarily from a kiln or shaft kiln, where limestone is preheated at 700– 900°C, and then calcined at 1050–1200°C (Drenhaus et al., 2010; Oates, 2007)."

Jan 1, 2016

By Jin Yu, Fang-Qiu Zu, Yun Xi, Li-Na Mao

"According to the behaviors of resistivity-temperature of Cu-Sb70 melt, which suggests a partly reversible temperature-induced liquid structure transitions (LST) could occur in this alloy, in this paper, we investigated the dependence of solidification on the liquid state. Both resistivity and temperature were measured to track solidification process. The results show that the nucleating undercooling of the melt which experienced the LST increased and the solidified time decreased. Meanwhile, the solidified microstructures refined evidently, with the microscopic pattern of primary phase changes from disordered pillarlike dendrites into homotaxic ones. Moreover, it is verified that the microstructures would be different if the reversible part of the LST was restrained. The new phenomena and results reflected in this paper suggest that grasping the rules of melt structure change with temperature before material processing will give help for controlling the solidification more effectively and finally resulting in more ideal microstructures.IntroductionThe structure and quality of liquid alloys have a direct and important influence on the structure, performance and quality of the solidified ones. In recent years with in-depth study of liquid structure, researchers have found that some liquid structure transitions (LST) could occur on dependence of the temperature or pressure [1-5]. And the article [6] reported that a pressure-induced reversible LST was found in liquid triphenyl phosphite, which further confirmed the authenticity of the existence of the LST. Furthermore, in our earlier studies of Sn-based melts using resistivity method, some abnormal structure changes induced by temperature have been found at hundreds of degrees above liqiudus, and these LSTs are partly reversible[7]. This phenomenon has been discussed and it is suggested that the reversible LST in Sn-based melts are related to the short-range ordering (SRO) structures of Sn, which are tetrahedron structure with covalent bonding. However, does this reversible LST exist in other melts too?"

Jan 1, 2012

By Stanisław Prusek, CHONG WEI, Huawei Xu, Jun Wang, Andrzej Walentek, Artur Dyczko, Derek B. Apel

The excavation-induced stresses transferred from the panels or pillars in upper coal seams play a key role in the occurrence of rockbursts in driving roadways during close-distance coal seam mining, which has become a common problem and threat to many underground mines. The authors established a 3D finite-difference numerical model via FLAC3D software using the closedistance coal seam mining conditions in the Zofiówka Mine as a case example to reveal the rockburst mechanism in such conditions. The excavation-induced vertical stresses are analyzed, which provides a basis to build a conceptual model to explain the possible source mechanism of the rockburst under such conditions. Nine typical rockburst indicators considering different contributing factors are then selected as the evaluation criteria to assess rockburst potential in the study site. The results suggest that the superposition of multiple excavation-induced stresses of the main drift and tailgate provides an environment for stress concentration and energy accumulation. The side abutment stress induced by mining in the upper coal seam has a “strengthening” effect to the rockburst occurrence. The great deviatoric stress induced by complex excavating situations is another important exterior cause. A strict calibration procedure should be implemented before using indicators to predict rockburst potential. A methodology was proposed to estimate the location and magnitude of rockbursts combined with numerical modeling, laboratory tests, and feedbacks from the field. The study could provide some references and guidelines for preventing and mitigating rockbursts in underground mines under similar engineering conditions.

Aug 26, 2021

By T. Loos

The Norddeutsche Affinerie operates an Outokumpu-Flash-Furnace as a smelting unit. The pyrometallurgical slag cleaning process is based on the slag reduction and settling in the electric furnace. Since 1972 when the slag cleaning furnace was built the throughput could be increased fourfold. However, an extensive optimisation effort is required in order to keep the copper loss low. A parameter study with a neuronal network model based on real process data was conducted to identify parameters impacting on the copper loss in the slag. It could be demonstrated that the main parameters responsible for copper loss in the final slag are fixed parameters of the flash furnace. For a better understanding of the copper loss in the electric furnace microscopic analyses of the slag structure and viscosity measurements were performed. Based on these results the reduction and settling of the copper containing droplets could be increased in both pilot plant studies and industrial scale. 4

Jan 1, 2007

By B. Burke

Magnesium and its alloys are attractive materials for use in automotive and aerospace applications because of the low density and good mechanical properties. However, difficulty in forming magnesium and the limited number of available commercial alloys limit their use. The present paper reviews the efforts to improve the attractiveness of magnesium through non-traditional processing, and presents preliminary results of current work on producing magnesium alloys via powder metallurgy P/M. P/M can be used to alleviate the formability problem through near-net-shape processing, and also allows unique chemical compositions that can lead to new alloys with novel properties. The feasibility of producing magnesium powder metallurgy products utilizing the industrially dominant process of mixed powder blending, uniaxial die compaction and controlled atmosphere sintering was investigated. An alloy composition based on the commercial Mg alloy AZ31 (3% Al, 1% Zn) was used to facilitate comparison to similar wrought products. The optimal processing conditions (compaction pressure, sintering time and temperature, and quenching temperature) were found to maximize sintered density and mechanical properties.

Jan 1, 2007

By Mingmei Zhu, Xin Qiu, Xiaofei Dou, Yu Wang, Tiancheng Lin, Bing Xie

In this study, the slag forming route of the single-slag steel melting when smelting medium phosphorus hot metal was investigated. The CaO-SiO2-FeO-MgO-MnO-P2O5 as hexahydric slag system was adopted in the converter. The effect of slag composition on liquidus was calculated by FactSage, the isogram of phosphorus distribution ratio was calculated by using the regular ion solution model, combining these two tasks, the theoretical slag forming route was obtained. Through experiments, the actual melting point ofthe corresponding components on theoretical slag forming route was obtained, in this way, the theoretical slag forming route was confirmed. Then, the theoretical slag forming route was applied to industrial test in a 210t BOF. After using the new slag formating route, the dephosphorization ratio was increased 3.6% while the auxiliary materials consumption was reduced, and the cost of steelmaking was reduced.

Jan 1, 2015

By Jim Hall, Denis Rickman, Jon Windham, John Ehrgott, Stephen Akers, Byron Armstrong

With the growing concerns about terrorism world-wide, numerous agencies conduct experiments to investigate the effects of terrorist vehicle bombs. In many cases, the vehicle bomb of interest utilizes some form of ammonium nitrate/fuel oil (ANFO) as the explosive source. Due to the high cost of fullscale testing, it is advantageous to conduct at least some vehicle bomb experiments at reduced scale. Extensive testing has shown that ANFO is a non-ideal explosive, and its explosive output does not scale reliably at explosive masses below approximately 400 lb (182 kg). Most scale-model testing requires explosive masses 1 to 5 orders of magnitude smaller. Thus, scale-model testing is typically conducted with “ideal” explosives, such as composition C-4, which perform in a scalable manner at virtually any charge mass. The utilization of an ideal explosive to model ANFO requires the existence of an accurate means of equating the performance of the two explosives. The airblast equivalence of C-4 and ANFO has been well established. However, the cratering equivalence of these explosives is not thoroughly quantified. This is especially true for the case of an above-ground detonation, which is precisely the scenario of interest in vehicle bomb studies. A study has been conducted to better define the cratering equivalence of C-4 and ANFO for above-ground detonations. This paper presents a discussion of results from this research.

Jan 1, 2008

By Musa D. Manzi, Raymond J. Durrheim, Richard T. Masethe

An investigation into the source mechanism of mining-induced seismic activity plays a vital role in understanding the various modes of failure observed in the underground deep-level South African mining environment. The seismic events data for this study was captured by the mine-wide seismic system operating at Kloof Gold Mine. This system comprises 40 4.5 Hz tri-axial geophones sampling at 6 kHz installed at locations that surround the stopes mining the Ventersdorp Contact Reef (VCR), Main Reef (MR) and Kloof Reef (KR). A set of 103,753 mining-related seismic events (-3.0≤ ML ≤2.7) that occurred during 2017 and 2018 was selected for this study. The mining depth of these seismic events ranges from 1600 – 4200 m; most located close to stopes mining the VCR ore body. The main criteria used to select a subset of events for detailed analysis were the number of stations that recorded the seismic event and the azimuthal distribution of the sensors.

Apr 26, 2022