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By Filiz Sahin

This paper presents a synthesis of TiB2 via carbothermal reduction method using a mixture of TiO2, B4C and C prepared in molar ratio of 2:1:3. Reduction experiments were carried out in a high temperature graphite furnace in a graphite crucible under argon atmosphere at different time (0, 15, 30 and 60 min.) and temperatures (1400, 1500 and 1600 °C). The products obtained were investigated using XRD technique.

Jan 1, 2008

By Sedef Pinar Basag, Onuralp Yucel, Ahmet Turan

Niederschlag process is commonly used to produce metallic antimony. The process is a metallothermic process which is conducted in one step for metallic antimony production. Using this method Sb2S3 is mixed with coal and metallic iron and subjected to reduction. During heating, antimony sulfide is decomposed and sulphur combines with iron to form the matte phase. Metallic antimony is collected at the bottom of the crucible. In this study, evaluation of Sb2S3 concentrate, extracted and obtained from West Anatolian Region of Turkey was investigated by using Niederschlag process. The reductant stoichiometry, reduction temperature and duration were carried out in the experiments. Chemical analysis methods by using atomic absorption spectrometry (AAS) and X-ray diffraction spectrometry (XRD) techniques were used for the characterization of the concentrate, metallic nuggets and matte phases.

Jan 1, 2016

By V. Sheikhzadeh, M. Saghaeian, R. Hejazi, A. Abazarpoor

The research aimed to compare the chemical analysis (K, Na, Cl) of Iranian concentrate plants, which are the main source of materials corrosion in the pelletizing plants. Cl alongside alkaline elements (especially K) may cause corrosion and plug in the grate plates and other involved equipment. Therefore, it is tried in the processing plants to remove impurities from the concentrate to prevent potential problems in pelletizing and iron/steel making processes. Part of these impurities are existed in the nature of ores and others are sourced in the processing water. Various samples from the largest Iranian concentrate plants including Chadormalu, Gol-e-Gohar, Jalal-Abad and Sechahun were prepared to investigate the possibility of alkaline problems for each samples. The amount of Cl, K and Na of Chadormalu sample was obviously low and therefore no alkaline problem is expected. The Cl content of Gol-e-Gohar sample was high (980 ppm) while amount of K was less (0.008 Wt. %). Due to low content of K, most of Cl will release as Cl2 or HCl and so problems caused by KCl plugging would not be a problem. The amount of Cl in Sechahun case was nearly same as Jalal-Abad (400-600 ppm), higher than Chadormalu and less than Gol-e-Gohar samples. However, the K content was higher than all samples (0.04 Wt. %). Therefore, the amount of evaporated K would be 2-4 times more than other samples. Since the amount of Cl and K is simultaneously higher than usual iron ores, therefore alkaline problems may be a serious prevention factor for the continuous operation of this plant. In order to solve this problem some counter-measures is suggested and discussed including cleaning system, partial dust enriched with KCl removal and variation in the materials type of involved equipment.

Jan 1, 2018

By B. T. Lu, J. L. Luo, J. F. Lu

The present paper investigates the chemo-mechanical effect in slurry-erosion corrosion process of carbon steel to understand the synergistic mechanism due to interaction of chemical and mechanical factors. The erosion-corrosion tests were conducted with A1045 steel in slurries comprising tap water and silica sand. Various heat treatments were adopted to achieve different hardness in the test material. The chemo-mechanical effect is evaluated in line with the correlation between the degradation of hardness in the surface layer and anodic current density. During the erosion-corrosion tests, various anodic currents were applied to find the relation between the anodic dissolution rate and erosion rate. The experimental results indicate that the hardness decreased with increasing anodic dissolution. Based on the fact that pure mechanical erosion rate increased with decreasing hardness, this result suggests that the corrosion-induced degradation of mechanical property is a mechanism of corrosion-enhanced erosion. This theoretical prediction is verified by erosion-corrosion experimental results.

Jan 1, 2004

By F. Y. Kang

There are rich resources of natural graphite in China. It would be a good opportunity to upgrade national graphite industry if natural graphite with modification is used in lithium ion battery. Micro-crystalline graphite in high purity was coated with a carbon film on the surface. The initial cycle efficiency was improved to be 89.9% and cycle stability was remarkably improved. The experiments proved that microcrystalline graphite with carbon coating have excellent electrochemical performances at low cost as anode materials for lithium-ion battery. In addition, H2SO4-GIC technique was used to prepare the natural flake graphite powders with mild-exfoliation. Sub-micro and nano pores were found in the graphite samples. In correspondence the reversible capacity, rate capacity and cycle life were improved, which would meet the demand of high-power lithium-ion battery. Natural graphite is the most promising anode material for large-scale lithium-ion batteries. The demand of modified graphite grows up greatly in the market. Microcrystalline graphite with surface coating and flake graphite with mild-exfoliation are the promising commercial anode materials for the industry of lithium ion battery.

Jan 1, 2014

A. O. GATES, Salt Lake City, Utah (communication to the Secretary*).-The writer is delighted by the results shown in Mr. Bell's paper, which prove in an experimental way different from that followed by the writer' that "the work clone in crushing is proportional to the surface exposed by the operation," per Rittinger's Law. Mr. Bell's work was all clone in commercial types of crushing machines, while my work was clone in a testing machine; his work represents fully one hundred times the expenditure and time that my work represented; a great number of tests were made by his organization to determine single points, while I was obliged to depend on the general trend of a curve for results; we agree absolutely that "Kick's law," for which Mr. Stadler was sponsor, does not apply to rock crushing. While my work indicated the reliability of Rittinger's theory, Mr. Bell's work clearly establishes the reliability and makes it Rittinger's law.

Jan 5, 1917

By M. L. Cunha

The lack of control of As and Sb compounds from copper smelters and converters has rendered some chalcopyrite containing arsenopyrite, stibnite and tetrahedrite minerals unusable for metal extraction. In the present investigation, we have studied the carbothennic reduction of Portuguese chalcopyrite mineral concentrate in the presence of lime/CaS04 and CaS04/Si02. Thermodynamic equilibrium calculations were performed to study the distribution of As and Sb between metal and the CaO-Si02-FeO slag phase. The phase equilibrium calculations also show the effect of oxygen partial pressure on the increase in the volume of the slag phase, which helps in lowering the copper metal formation temperature and facilitates a better separation between metal, matte and slag. The reduction reaction kinetics was studied between 850°C and 1100 °C, and the phases formed were identified by X-ray powder diffraction and scanning electron microscopy techniques. The importance of this research for using recycled matte, lean and rich minerals with As and Sb is also explained.

Jan 1, 2001

By Wang Zhi

High-Mg-content concentrates are usually treated in Jinchuan flash smelting Furnace. Because the viscosities of high-Mg-content slag is very high, the operation of flash smelting becomes very difficult. To solve this problem, the viscosities of the semi-synthesized FeO-MgO-Si02 slag of different compositions were measured. The results showed that when in the slag the weight percentage of MgO [m(Mgo)] is 6-10%, the ratio of the weight percentage of iron to that of Si02, m(Fe)/m(SiO2) is 1.1-1.4 and the temperatures are within 1473?1773K, the slag viscosities increased with the increase of m(Mgo) and m(Fe)/m(sio,). When m(Mgo)<6%, the smelting temperature should be controlled at I 300°C in order to to keep the smooth operation. When m(Mgo» 10%, the temperature should be kept above 1633K. When the content of MgO is higher, a lower viscosity slag ean be produced by decreasing the ratio of m(Fe)/m(sio,). The appropriate ratio of m(Fe)/m(sio,) for Jinchuan flash smelting furnace is about 1.2.

Jan 1, 2003

By Wang Zhi

High-Mg-content concentrates are usually treated in Jinchuan flash smelting Furnace. Because the viscosities of high-Mg-content slag is very high, the operation of flash smelting becomes very difficult. To solve this problem, the viscosities of the semi-synthesized FeO-MgO-SiO2 slag of different compositions were measured. The results showed that when in the slag the weight percentage of MgO [w(MgO)] is 6-10%, the ratio of the weight percentage of iron to that of Si02, w(Fe)/w(Si02) is 1.1-1.4 and the temperatures are within 1473-1773K, the slag viscosities increased with the increase of W(MgO) and w(Fe)/w(SiO,). When w(Mgo)<6%, the smelting temperature should be controlled at I 300°C in order to to keep the smooth operation. When w(MgO)>10%, the temperature should be kept above I 633K. When the content of MgO is higher, a lower viscosity slag can be produced by decreasing the ratio of w(Fe)/w(SiO,). The appropriate ratio of w(Fe)/w(SiO,) for Jinchuan flash smelting furnace is about 1.2.

Jan 1, 2003

By L. Lehasa

The purpose of the project was to investigate the challenges faced by Khutala Colliery pertaining to underground road construction and maintenance. Furthermore the influence of these challenges on productivity and safety requirements were taken into consideration. The operating standards required for the construction and maintenance of the 2 seam road transport infrastructure was investigated, together with reasons why the standards of operating procedure are not met. The Code of Practice put in place by Khutala Colliery was used to view the standard operating procedures. Leading practices on underground road construction were researched. The project aims to discover the gaps that Khutala Colliery must bridge to implement enhanced practices with regards to underground road construction. During the period of study, observations were carried out to determine whether the road construction standards of operating procedure were being adhered to at all times for both road construction and road maintenance. Khutala Colliery has put in place a traffic management plan, which includes safety practices and work policies that must be adhered to while travelling on underground transport roads.

Jan 1, 2012

By Xiao-hui Fan, Li-shun Yuan, Xu-ling Chen, Wei Lv, Min Gan, Yi Wang

"As the amount of ferrous scrap increases every year, it becomes more and more urgent to deal with this iron-bearing resource properly. This paper puts forward a method on resource-oriented utilization of ferrous scrap (cold-bonded pelletizing), and these cold-bonded pellets can be used as coolant in a converter. The influence on the pellets qualities by using different kinds of chloride as rust agents is studied, and results show that the strength of cold-bonded pellets increases significantly by using a combination of the three kinds of chloride -NaCl,MgClz,FeCh, their best dosages are 1.2%, 0.2%, 0.1% respectively. Other iron-bearing materials also have an effect upon the pellets strength, by adding 5% iron powder and maintaining for 48h, the compressive strength of the clumps surpass 2500N/A, dropping strength surpass 4 times/ A, and 10% iron slag or 20% steel slag can replace 5% iron powder while obtaining the comparative quality. The influence of different ratios of three ferrous scrap (converter mud, iron scale and dust) is further studied, and results show that when the ratio is 30% : 30% : 40%, the pellet strength reaches the maximum. After maintaining for 24~48h, the clumps can meet the mechanical as well as the physical-chemical requirements as BOF steelmaking refrigerant.IntroductionGreat amounts of converter mud, dust and iron scale are produced in steel production process. These materials are of great values, and their accumulation not only leads to environmental pollution, but also wastes the precious resources, which restricts the sustainable development of the steel industry [1,2] The main approach at present to dealing with the ferrous scrap is to add them into sintering. But in this way, the utilization factor of sintering and the quality of sinter decline while the energy consumption increases [3].Therefore, more advanced and efficient technology is needed to make the best of these iron resources. Cold consolidation of ferrous scrap is a simple process that has many advantages such as less investment, quicker effect, lower energy and lower cost [4-5] But the conventional maintaining period is too long, usually up to four-six weeks, and the pellet strength is low. Therefore, the key points of the cold-bonded pelletizing are to develop a new adhesive [4,5] to shorten the natural maintenance cycle and to improve the strength of the pellets. A method on resource-oriented utilization of ferrous scrap (cold-bonded pelletizing) is brought forward, and these cold-bonded pellets can be used as coolant in converter. After maintaining for 48h, these cold-bonded pellets can satisfy the mechanical requirements to replace the converter coolant [6]."

Jan 1, 2013

By S Udayakumar, S Biswal, N Sarmadi, V Sahajwalla, F Pahlevani

Recent times have witnessed a notable momentum in the interest surrounding technology dedicated to harnessing waste as valuable resources, prompted by the mounting challenges posed by waste accumulation and the swift depletion of natural resources. The carbon dissolution process within a molten iron bath stands as a pivotal reaction within the metal processing sector. The current study explores the utilisation of waste graphite electrodes (WGE) (obtained after being utilised in an electric arc furnace) as a secondary resource of carbon for dissolution into liquid iron. Experimental investigations were carried out at 1550°C using the sessile drop approach. High purity iron powder was used and the carbonaceous substrates were prepared from the ground WGE. The carbon pickup was determined using a suitable carbon analyser. Furthermore, an examination of the interfacial area between the molten iron and the WGE substrate was conducted beneath the metallic droplet, which effectively represents the iron/carbon interface. This interfacial analysis was carried out on two different samples obtained after a varying period of heat treatments at 1550°C. The interface layer was investigated using scanning electron microscopy (SEM) in conjunction with energy-dispersive X-ray spectroscopy (EDS).

Jun 19, 2024

By P. Hadzeriga

Ion exchange techniques have been growing fast and spectacularly in all phases of Science for the last two decades, but still its acceptance as a unit operation in Metallurgy is resisted. Mainly this is because ion exchange procedures are thought of as glamorous techniques by which only relatively expensive metals are to be recovered. Perhaps this concept comes from the early and basic marriage of uranium and other high price metals and ion exchange procedures. The general trend is that ion exchange technique requires equipment and materials which are too expensive to economically perform a chemical step whenever "cheap" commodities are produced. However, we are here presenting a means of utilization of waste hydrochloric acid by an ion exchange technique. We have studied this from the engineering and economic standpoint in a number of variations of the main procedure discussed here and we-conclude that under proper economic circumstances, the cost of the ion exchange material as well as the equipment and labor involved in the ion exchange section, is by no means unreasonable.

Jan 1, 1964

By E R. Ramanaidou

Two unknown iron ore samples were found by a geologist from Ok Tedi Mining Limited copper, gold and silver mine at an old wharf site dedicated to a 1970s drilling program in Lake Murray in Papua New Guinea (PNG). These iron ore samples could not come from a PNG mine and it was decided that a study should be undertaken to understand their origin. Lake Murray is the largest lake in PNG with a total surface area of 647 km2. It has a high-water 2038 km long convoluted shoreline with seasonal water level changes (Osborne, Kyle and Abramski, 1987) and it is located around 200 km south of the Ok Tedi mine (5°13’25”S, 141°09’37”E). The petrology, mineralogy and chemistry of two Fe samples (Ok Tedi 1 and Ok Tedi 2) included optical microscopy, X-ray fluorescence (XRF) analysis and a comparison with worldwide iron ore deposits. The two rock samples were cut to produce two subsamples: (1) a polished thin section; and (2) a pulp that was used for XRF analysis including major, minor and trace elements. Ok Tedi 1 and Ok Tedi 2 were petrologically and chemically compared to a range of known iron ore samples from Australia, Brazil and South Africa. The petrological study of Ok Tedi 1 indicates that it is composed of granoblastic recrystallised hematite and the overall texture is uniform without any obvious original ‘sedimentary’ texture. Ok Tedi 2 is a ‘specular’ or platy hematite with recrystallised and fused grains. Using both petrological and chemical clues, the two Ok Tedi samples likely originated from the Iron Quadrangle in Brazil.

Sep 18, 2023

By L Cain, C Every, S Mirlatifi, J Ashley

This paper presents a geographic information system (GIS) based method for the prediction of ground movement and the associated impact on existing buildings and structures due to tunnelling in the North West Rail Link (NWRL) project. The NWRL is a priority rail infrastructure project for the New South Wales (NSW) Government and includes 15 km of twin tunnels between Bella Vista and Epping, which will be Australia’s longest rail tunnels. The NWRL tunnels will be constructed in an urban environment where the prediction of ground movements induced by tunnelling and the associated impacts to existing structures must be assessed in the early design stages of the project. An assessment process was developed using GIS able to respond to design changes.An iterative GIS analysis methodology was developed to generate ground settlement contours and identify impacted buildings and structures in response to multiple changes in tunnel alignment during design development stages. The GIS analysis undertook to rapidly provide detailed and accurate parameter information including tunnel depth from surface, tunnel separation, diameter and sample point proximity to the tunnel and assess ground movement contours along the project alignment. Determination of the ground surface settlements were based on empirical methods proposed by Peck (1969) and Mair (1993). The control parameters and the relationship between damage categories and risk classifications for impact assessment were based on Burland, Broms and de Mello (1977), Rankin (1988) and Boscardin and Cording (1989) methods.The GIS-based ground movement impact assessment approach adopted for the NWRL project demonstrates an efficient, iterative and robust approach and could provide an initial framework for other similar tunnelling projects where rapid design changes and early understanding of tunnelling impacts are required to bring greatest benefit to all stakeholders.CITATION:Mirlatifi, S, Cain, L, Ashley, J and Every, C, 2014. An iterative geographic information system based approach for the assessment of tunnelling impact to existing buildings and structures, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 647–652 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By Vladislav Kecojevic

Both Canada and the United States are endowed with significant reserves of mineral resources. Mining industries in these two countries have a strong safety and health culture; skilled, dedicated and well-paid workforce; applications of state-of-the art technologies and high productivity, strict environmental requirements and social responsibility. Both countries are global leaders in safe, economic, productive, environmentally responsible and sustainable mining practices. Mining schools/ departments in Canada and the United States provide a strong and comprehensive education and training, hands-on learning experience, with support for internships and co-op opportunities to prepare graduates for careers not only nationally but also in the global mining industry. While there are many similarities in their industries and mining schools, there are also some differences. This article examines the contribution of mining to the economy, the political climate, the regulatory framework, the investment climate, environmental regulations, the language, the perception of mining, news and press coverage, and the academic landscape in both countries. Opinions, observations and perspectives shared in this article are of the author, and do not necessarily reflect the views, policies or positions of any organization, employer or affiliated group.

Nov 1, 2025

By J Field

Many aspects of water use in mining are driven by the technical requirements for water. There has been little consideration given to both the safety and the health requirements. Workers in the mining industry are exposed to water from a range of treated and untreated sources. The intended use of this water dictates the required quality of the water, sometimes with limited consideration for contact with miners. Particularly for underground workers, there is exposure while working in and walking through groundwater possibly contaminated by hazardous substances. Where controls are inadequate the outcomes of this exposure can result in disease, illness and injury û the costs of which can be significant. The situation could also arise where, due to the lack of human exposure, the controls are unwarranted and the financial cost unjustified from a health perspective but warranted from an equipment management standpoint. In addition to the health aspects, water can impact on a range of safety issues resulting from high pressure usage, dust suppression, fire fighting and other processes. The protocols and procedures in place need to consider the safety issues in addition to managing water usage. The current state of water management in mines from an occupational health and safety perspective has been ascertained from a survey targeting underground and surface coal and metalliferous mines. This survey considered the health and safety issues associated with water use, the types of surveillance, control protocols and the strategies that the mines have in place to manage the health and safety risks associated with water systems. The results assisted in the identification of potential occupational health and safety risks associated with water systems and the management processes that may be appropriate from a risk management perspective. Health and safety issues are often neglected but remain critical issues affecting the value of water to the mining industry.

Jan 1, 2006

By Henry T. Miller

INTRODUCTION The basic purpose of this paper is to suggest procedures and practices to insure that no employee working in a uranium milling operation receives exposure to radioactive, toxic, or other materials or agents that might produce a permanent, deleterious effect upon his physical health and well-being. This program is also designed to insure that each employee can carry out his assigned duties without risk to his health or to that of his fellow workers. The assumptions underlying this program are by necessity, conservative, with emphasis being placed upon prevention rather than correction or reaction to an undesirable situation. The limits specified-either as Threshold Limit Values (TLVs), Maximum Permissible Concentrations (MPCs), or Radiation Protection Guides (RPGs)--represent both standards of best practice and those of law and regulation. The total program is envisioned as a balanced combination of occupational hygiene and radiation monitoring. This includes surveying, air sampling, personnel dosimetry, bioassay, medical surveillance, epidemiology, and training--all backed by a thoroughly tested and evaluated set of emergency procedures. The program, as presented, is keyed to the results of monitoring, surveying, air sampling, medical surveillance, and epidemiology--it being obvious that no problem can result when no hazard can be identified. The lack of an identified hazard, however, does not negate the need for such a program and prudence suggests the need for routine surveillance programs in the best-designed facility. [The Model Mill] The model mill used in this paper is that presented by the U. S. Environmental Protection Agency in its study of the uranium fuel cycle1. The model mill processes 600,000 metric tons of ore per year into 1,140 metric tons of U308 as yellowcake per year using an acid leach process. Other characteristics of the mill such as location, tailings dam design, number of light water reactors supported, and geographical location are not pertinent to this paper. The usual remote western location of these facilities produce some difficulties in delivering the required occupational medical services and is not within the scope of this paper. The operating lifetime of most mills is commonly estimated as from 12 to 15 years in actual practice; however, the U. S. Environmental Protection Agency estimated a 20-year lifetime for its model. The principal steps in the acid leach process include :2 (a) Ore is blended and crushed to pass through a 2.5 cm (one inch) screen. The crushed ore is then wet ground in a rod or ball mill and is transferred as a slurry to leaching tanks. (b) The ore is contacted with sulfuric acid solution and an oxidizing reagent to leach uranium from the ore. The product liquor is pumped to the solvent-extraction circuit while the washed residues (tailings) are sent to the tailings pond or pile. (c) Solvent extraction is used to purify and concentrate the uranium. (d) The uranium is precipitated with ammonia and transferred as a slurry. (e) Thickening and centrifuging are used to separate the uranium concentrate from residual liquids. (f) The concentrate is calcined and pulverized. (g) The concentrate or yellowcake is packaged in 208 liter drums for shipment. This process is illustrated in Figure 1.3

Jan 1, 1981

By Russell L. Wood

The title of this session seems to have been picked especially for this paper. It is 1984, it is the morning after, and there is one monumental hangover among many if not most of the oil companies that have invested in mining in the past decade or so. How an oil company looks at mining depends on what time period you are talking about. A few years back around the time of investment this is what they were probably looking at: 1. A balance sheet of their own that was beginning to go wild, with many of their commodity prices having already seen increases of two, three, or four fold, and with no end in sight. 2. A need to invest their earnings someplace fast before the stockholders or the government got too interested. And that someplace should be in an industry where their own management skills could be applied. (Only a true cynic would suggest that this is a form of job security) 3. In mining there was an industry amazingly similiar to their own, one working with non-renewable natural resources, dealing with the same types of government agencies, and having the same type of critics and pressures from the general population. 4. An industry that was somewhat backward as compared with their own, and one where a generous ration of the capital and management skills so handsomely bestowed upon the oil industry could be used to great advantage.

Jan 1, 1984

Population growth, social inequality, pollution, global warming, poverty, overexploitation of natural resources and biodiversity loss, are a few examples of the many challenges facing the world today. Sustainable development is about meeting these challenges and improving the standard of living for the benefit of the maximum number of people. These issues concern governments, communities, environmental and social action groups and individuals all over the world. Business too, has a fundamental role to play in delivering sustainable development. In particular, sustainable development is becoming increasingly recognised as a critical issue for the oil and gas industry to address and act upon. BP is committed to positively respond to the challenges posed by the objective of sustainable development.

Jan 1, 2002