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By G. Ferrara

Hydrocyclones and other dynamic separators are normally fed with pulps of water and solid particles. The particles have different sizes, shapes and densities and, except in the special case of mono-characteristic particles, are segregated into size, shape and density. Segregation is magnified by the high values of centrifugal acceleration in the hydrocyclones. This paper develops the theory of the segregation, indicates the major variables involved and reports experimental data of segregation under different operating conditions for mixtures of magnetite and/or ferrosilicon and non-magnetic minerals.

Jan 1, 1995

By G. Van Weert

Separation of minerals by shape has received little attention, since minerals normally do not break into different shapes during crushing and grinding. However, comminution of consumer wastes generates opportunities for novel separations based on particle shape. For instance, ductile plastics are broken into longer curved shapes, whereas brittle plastics yield angular particles. Using spouting beds for particle separation in water requires controlling the spout's instability. The preferred geometry for such redesigned spouting beds is reported. Plastic cylinders, discs and spheres were separated as a function of rising water velocity and amount of particles in the system. By using 5 mm particles, differences in settling behavior could be video recorded.

Jan 1, 1999

By G. Djambazov, V. Bojarevics, K. Pericleous

The AC electromagnetic (EM) field effects are investigated for the possibility to extract particles (impurities, precipitates, oxides, bubbles, etc.) from molten silicon during the directional solidification of silicon ingot. The dynamics of particles are affected by the hydrodynamic drag, buoyancy, turbulent fluctuations and the EM force via the local pressure distribution. The EM force leads to high mixing rates, transitional flow structures and turbulence of the melt, contributing to the particle dispersion, transport and separation to a desired location. Application to silicon kerf loss recycling by melting and solidifying in the presence of AC EM field is presented for a variety of cases using 3D models for general flow structure and axisymmetric models for moving solidification front long time tracking. This paper demonstrates the effects of flow on the time dependent particle ‘swarm’ transport and the eventual modified distribution in the final ingot.

Mar 1, 2017

By Kerri-Ann Hue, Kerry Hasapidis, Ken Babcock, Patrick O'Hagan

"Metallic nanoparticles exhibit properties that are significantly different from individual atoms or bulk materials. Their applications are diverse and have varying uses in areas such as cancer treatment, biochemical sensors, nanoelectronics, and drug delivery. For each application extensive characterization must be performed in order to probe the unique properties of these nanoparticles. In this study, ultra-high resolution mass sensors consisting of MEMs-fabricated, suspended microchannel resonators (SMRs) were used to determine the size and concentration of metallic nanoparticles. With femtogram (10- 15 g) mass resolution, ultra-high resolution mass sensors can weigh individual particles suspended in fluid, and so measure their mass, density, and size. Particle size analysis with these sensors provides excellent accuracy and resolution compared to mature technologies such as light scattering. This technique also provides quantitative information via the ability count particles.IntroductionThe unique electronic, chemical, and optical properties associated with nanoparticles vary with their size, shape, and composition[ 1-4]. These properties are attributed to increased surface area and nanosized mean free path of electrons to the particle surface. Nanoparticle colloidal solutions have been prepared and are commercially available. In recent years, noble metals such as gold, copper, and silver have been extensively researched[5-7]. In order to tailor the optical, electronic, and electrical properties of nanoparticles, size and shape must be controlled. For many applications a monodisperse colloidal solution is ideal. Methods of size characterization include Transmission Electron Microscopy (TEM), Dynamic Light Scattering (DLS), and Electrophoretic Mobility Measurements to name a few[6, 8]. Although TEM can provide shape and size distributions, sample preparation requires that samples be dried on a metal grid and cannot be analyzed in solution. DLS uses curve fitting algorithms that while useful for determining mean particle diameters are not ideal for polydisperse colloidal solutions. New technologies are therefore needed to accurately determine the particle size distributions of metallic nanoparticles."

Jan 1, 2011

By B Stump

Reliable particle size analysis in minerals processing plants is a critical factor to the economic return of a plant. As recovery of valuable minerals is compromised for particles outside the optimal size range, effective and reliable particle size analysis is more crucial than ever, particularly in the current upswing of the global commodities market. Inefficient particle size analysis can lead to excessive over-grinding, thereby significantly increasing energy consumption and reagent costs, whilst negatively affecting process operation, thickening capacity, water recovery and tailings disposal.Australia’s first installation of a particle size analyser in Iron Ore has been monitored with great interest by the industry. Previously, manual size sampling at Rio Tinto’s Paraburdoo fines processing plant involved off-site sample analysis, with a turnaround measured in days. The Outotec PSI® 500 particle size indicator, commissioned in July 2009, takes approximately three minutes per line at site.The paper will include details on the following:• plant description,• sampling design,• PSI® 500 analyser functionality description, and• key learnings from site.

Jul 11, 2011

By A. D. Neuman, C. C. Davis, M. R. Lopez, A. C. Martinez, T. A. Nothwang, S. L. Voit

"One of the thrust areas for the Global Nuclear Energy Partnership (GNEP) program is the development of actinide bearing fuels for transmutation in a fast reactor. Mixed Oxide (MOX) fuel has an extensive fast reactor irradiation history and thus is being considered for use as a baseline composition from which minor actinides (MA) can be incorporated for use as a transmutation fuel. This study involves characterization of precursor powders and pellets to be inserted into the Advanced Test Reactor in Idaho. These pellets will have three compositions: one standard MOX composition, (U80Pu20)O1.98, and two compositions of MA-MOX with oxygen to metal ratios (O/M) of (U75Pu20Am3Np2)O1.98 and (U75Pu20Am3Np2)O1.95. The precursor powders, which consisted of, highly enriched uranium oxide, HEUO2, depleted uranium oxide, DUO2, neptunium oxide, NpO2, americium oxide, AmO2, and plutonium oxide, PuO2, were characterized using a field emission gun scanning electron microscope (FEG-SEM) for particle morphology, size, and size distribution prior to pellet production.IntroductionThe Global Nuclear Energy Partnership (GNEP) was created in order for “fuel-cycle supplier” nations to provide assured supplies of nuclear fuel to “fuel-cycle customer” nations. The customer nations would utilize the fuel for electricity generation and subsequently return it to the supplier nation after it is spent. This spent fuel would then be reprocessed by the supplier nation in order to recycle the actinide constituents, mainly uranium and plutonium, in advanced nuclear power reactors, and thus reducing waste volumes [1, 2]. Nuclear materials would also be strictly controlled through the International Atomic Energy Agency. One of the thrust areas for the GNEP program is the development of these actinide bearing fuels for transmutation in a fast reactor under the U.S. Advanced Fuel Cycle Initiative (AFCI) in order to transmute long-lived transuranic actinide isotopes into shorter-lived fission products [3]."

Jan 1, 2008

By C. T. Yavuz

Higher environmental standards have made the removal of arsenic from water an important problem for environmental engineering. Iron oxide is a particularly interesting sorbent to consider for this application. Its magnetic properties allow relatively routine dispersal and recovery of the adsorbent into and from groundwater or industrial processing facilities; in addition, iron oxide has strong and specific interactions with both As(III) and As(V). Finally, this material can be produced with nanoscale dimensions which enhance both its capacity and removal. The objective of this study was to evaluate the potential arsenic adsorption by nanoscale iron oxides, specifically magnetite (Fe3O4) nanoparticles. We focused on the effect of magnetite particle size on the adsorption and desorption behavior of As(III) and As(V). The results show that the nanoparticle size has a dramatic effect on the adsorption and desorption of arsenic. As particle size is decreased from 300 nm to 12 nm the adsorption capacities for both As(III) and As(V) increase nearly 1000 times. Interestingly, this increase is more than expected from simple considerations of surface area and suggest that nanoscale iron oxide materials sorb arsenic through different means than bulk systems. The desorption process however, exhibits some hysteresis with the effect becoming more pronounced with small nanoparticles. This hysteresis most likely results from a higher arsenic affinity for magnetite nanoparticles. This work suggests that magnetite nanocrystals and magnetic separations offer a promising method for arsenic removal.

Jan 1, 2006

By C. Igathinathane

Coal is the most widely used fossil fuel in the world, providing more than 25% of world?s electrical power. Since, the behavior of coal particles in crushing and grinding circuits, concentration operations, and solid-liquid separations is strongly dependent on size, a reliable and accurate measurement of particle size and particle size distribution (PSD) is a vital aspect in coal cleaning. This paper presents a method for the characterization of ground coal particles using image analysis. We utilized a machine vision (MV) approach that used a document scanner as the imaging device and a user-coded ImageJ plug-in that processed the image and automated the PSD analysis and output results in textual and graphical forms. This approach used a sum of volumes (SVolume) as weighting factor for particle length as the primary dimension of analysis and was successfully applied to ground coal. The plug-in was further improved for computational performance in this study. Mechanical sieving (MS) was also used to compare the MV results. MV results showed that the PSD of ground coal followed a uni-modal normal distribution, and the log-normal plot against particle size exhibited a linear trend for most of the range. MS results, however, had three linear segments, when the width-based sieving results were transformed to lengths by applying the shape factor (width/length), but a definite deviation between the PSD plots was observed. This study demonstrates successful application of the MV SVolume approach for PSD analysis of ground coal, which can be extended to similar particulate minerals and products. Keywords: dimension, fiji, image j, image analysis, coal, particle size, plug-in

Sep 1, 2012

By I. O. Otunniyi

The natural hydrophobic response flotation method for beneficiation of printed circuit board comminution fines (PCB CF) still requires many studies to further basic understanding of the process and the flotation traits that the PCB CF presents. Varying particle size distribution (PSD) and water recovery under the scheme show that higher mass pull, obtained at the finer PSD, gave lower water recovery but higher value loss. The reverse also holds: the least mass pull at the coarsest PSD used, -106 + 75 µm, gave the highest water recovery per unit mass pull with the highest reverse recovery. This is unlike what obtains in primary resources processing, where higher water recovery is often with increased fines entrainment. The reverse recovery loss here is, therefore, more due to entrapment with the heavy mass pull characteristic of the method than to the entrainment of value with water. Other peculiarities of the system observed are discussed, with the goal of improving the performance of the process, and broadening the general knowledge of flotation systems.

By R. Hogg, T. F. Dumm

"Procedures for particle size analysis on respirable dust from coal mines have been evaluated. Using respirable dusts dispersed in a laboratory dust chamber, size distributions measured using cascade impactors have been compared with the results of a variety of laboratory sizing methods performed on samples collected on filters placed side-by-side with the impactors. The laboratory techniques included centrifugal sedimentation, laser diffraction/scattering and automatic particle counting. The general agreement among the various methods was very good, with systematic differences which can be attributed to the different definitions of size used. Simple conversion factors have been obtained which can be used to transform the laboratory data to equivalent aerodynamic sizes.Similar comparisons have been made on samples collected in underground coal mines. Again, the results are in quite good agreement although small discrepancies were observed in· some cases. These have been attributed to some degree of agglomeration in the airborne dust, leading to slightly coarser apparent distributions in the impactor samples INTRODUCTIONA primary goal of mine ventilation is the control of airborne dust, especially in the ""respirable"" size range, typically defined as finer than about 5 to 10 µm. It follows that determination of the amount and characteristics of the respirable dust is an important factor in evaluating the performance of ventilation systems. Particle size information on airborne dust in mines is commonly obtained by in- situ measurements using cascade impactors. However, these tend to be inconvenient for routine data collection and the alternative approach of collecting samples in the mine, on filters for example, and returning them to the laboratory for detailed analysis is very attractive. Questions have often been raised, on the other hand, as to the appropriateness of this approach. How well · do such laboratory methods describe the distribution of aerodynamic diameter of the airborne dust particles in the mine environment? The purpose of the work described in this paper was to evaluate some laboratory sizing methods and to compare the results of such measurements with the size data obtained by the direct, in-situ method."

Jan 1, 1989

By S. Narra

Converting biomass into valuable fuel requires various preprocessing of the raw materials. Biomass densification is one of the conversion processes for its utilization. The aim of densification is to produce biomass pellets, which can withstand regular handling stresses and exhibit high densities with uniform size and shape. Physical properties, such as the particle size distribution after comminution is of highest importance for the binding mechanisms in the pelletisation process. Durability and strength of the pellets play an important role indicating the ability to withstand handling stresses. Particle size distributions of the cereal straws (Rye and Wheat) after specific comminution and liberation processes have been carried out with the help of three different image analysis (Microscope, Camsizer and Fibreshape). The durability of the pellets have been investigated as specified in the standards (ASAE standard S269.4) with a quadratic crate and the strength of the pellets with compression and tension testing machine (Zwick Roell type: ZMART.PRO). The particles size results showed differences in both length and width after different comminution processing. An exact comparison between the particle size analyses with the three different image analyses was not possible. The particle size distribution and the different comminution processes displayed influences on the durability and strength of the produced pellets. The particle size distribution displayed approximately 40 % of fines and 60 % of fibers. The particle size distribution displayed a direct relation to the durability of the pellets. Further durability and strength of the pellets displayed a good correlation.

Sep 1, 2012

By Hillary W. St. Clair

In a previous report 1/the author showed that the essential information from particle size analyses of grinding mill products can be represented by three or four parameters derived from the first four moments of the particle size data. These parameters may be used in gamma or beta distribution functions to estimate the weight fraction in any given size range. Moment analysis was used to study the progressive changes that take place in particle size distribution when a homogeneous isotropic mineral such as quartz is reduced in size by impact crushing. 2/ This report briefly reviews the essential features of moment analysis and describes extension of this method to size reduction by ball mill grinding.

Jan 1, 1972

By R. Xiong, A. K. Fallaw, G. Wang, L. R. Moore, S. Dobson, J. Gu

"INTRODUCTION The Central District of the Florida phosphate industry is located in southwest Polk and southeast Hillsborough Counties, with the Southern Extension lying in western Hardee, eastern Manatee and northwest De Soto Counties. (Lawver, 1983) Figure 1 shows the major phosphate formations in Florida. Almost all Florida phosphate production has been in the Central district with additional production from a mine in the Northern District. The Central District is comprised of the Bone Valley Deposit, a relatively thin layer of high grade ore which has been the main source of phosphate mining for decades, and the Hawthorn formation, a thick but low grade formation which covers most of peninsular Florida. (Lawver, 1983) Florida phosphate producers use the Crago process where calcium phosphate is floated with anionic, fatty acid type collectors followed by cationic reverse flotation of silica with amine type collectors. The phosphate matrix is put through various size separation techniques to obtain a typical -28 Mesh (< 700 µm) particle size for fine flotation and a -16 mesh (< 1190 µm) to +28 mesh (> 700 µm) particle size for coarse flotation. In some cases this coarse fraction can be sent to shipping as an intermediate product. The +16 mesh (>1190 µm) to – ¾“ (19 mm) fraction is sent to shipping as a final product called pebble. Figure 2 demonstrates a simplified diagram of the mining and processing of calcium phosphate (matrix) through a Central Florida mine. Particle size and mineralogy are important considerations in the Crago process for two main reasons, the mass of the particle and the particle surface area. Both of which are dependent on the coordination of the anionic collector to available Ca2+ sites on the minerals’ surface. The increased surface area, and available Ca2+, of the smaller apatite particles will allow for more fatty acid molecules to coordinate than the larger particles, with a lower availability of Ca2+. So, the larger particle would require more collector to be introduced in the system to sufficiently cover the apatite particles to produce a surface sufficiently hydrophobic to attach to air bubbles allowing flotation to occur. (Guan, 2009) The Bone Valley deposit has very favorable flotation characteristics when compared to other mining ores around the world. The matrix of the Bone Valley is relatively high grade, BPL (Bone Phosphate in Lime) values typically range from 6-18%, BPL recoveries, from such a matrix, can often be achieved above 85+% with fatty acid based collectors dosed below 1 #/ton. As mentioned, the sizing is an important step as there is also high grade apatite in the +16 mesh (1mm) that is screened to a final product grade, 60-65% BPL. The lack of quartz in the larger size fraction has allowed the Central District to produce high quality, low cost phosphate product, called pebble, through effective screening with no further beneficiation. (Guan, 2009)"

Jan 1, 2015

By Wenjun Duan, Zongliang Zuo, Qingbo Yu, Qin Qin, Junxiang Liu

Moving bed has been widely used in the field of heat and mass transfer and reaction between solid particles and gas. In order to enhance the heat exchange coefficient, there will be tube banks inserted in the moving bed. In the process of drying ammoniates particles or heat recovery from high-temperature particles with moving bed, the particles flow behavior around the tube banks is significant. In this paper, the particles flow behavior around the tube banks is investigated, and all the results can provide guidance for the design and operation of a moving bed.

Jan 1, 2016

By A. V. Bogdanovich

Until recently, in consideration of fundamentals of gravity concentration theory, all computations have been based on determination of particles? fall velocity in an unrestricted medium (hydraulic size). Meanwhile, gravity separation processes are realized under conditions of particles? restricted fall, when important and sometimes decisive role is played by interacting forces of particles, dependent on their varying size, density and shape, i.e., segregation forces. We have developed devices and methods for measuring segregation velocities of fine particles of various size, density and shape during their loosening in air or aqueous medium. Besides, to exclude influence of medium upward flows, loosening was provided by superposition of vertical harmonic oscillations on measuring cell. It was established, that maximum segregation velocities are observed at certain optimal acceleration values and amplitudes of oscillations; excessive loosening leads to mixing and worsening of segregation. Velocity of some particles segregation through others depends on particles? size, density and shape, as well as nature of medium (air, water). Absolute segregation velocities of particles in air medium may reach 1~2 mm/s, in aqueous medium such velocities are by an order smaller. Analysis of rare-metal sands material gravity concentration results showed, that owing to segregation process during gravity separation, fine-size isometric particles of heavy minerals are recovered into gravity concentrates more actively, than larger ones, but more elongated in shape. It is convenient and simple to estimate mineral grains? shape by extent of their oblongness, described as ratio of particle minimal dimension to maximum. Besides, mineral mixtures gravity separation results are directly related to extent of oblongness of heavy particles, recovered in gravity separation process, and also to root-mean-square coefficient of their shape variation. The performed research showed that particles segregation in gravity concentration process plays not a lesser role, than hydrodynamics parameters, and demands further theoretical inquiry and experimental studies.

Jan 1, 2014

By André Luis de Oliveira

O Alto Forno 3 (AF3) da Companhia Siderúrgica Nacional (CSN) é o equipamento muito importante no processo siderúrgico da Usina Presidente Vargas (UPV), situada em Volta Redonda (RJ), por responder por mais de 70% da produção de gusa da UPV. Na produção de gusa é gerado o Gás de Alto Forno (GAF), subproduto de alta relevância, pois este gás sai do topo do AF3 com grande pressão e cinética, energia essa passível de utilização. Em 2007 a CSN, optou por adquirir um equipamento denominado “Top Pressure Recovery Turbine” (TRT), capaz de aproveitar tal energia para gerar energia elétrica. Em 2013, a equipe de supervisores da KHI – Kawasaki Heavy Industrie, fabricante da turbina, veio para o Brasil para realizar no equipamento os testes a frio e a quente para na seqüência vir a operá-lo. Ocorre que fatores alheios ao objetivo desta apresentação impediram a equipe da KHI de partir o equipamento no tempo previsto, bem como de retornar ao Brasil para dar seqüência nas atividades. Em novembro de 2013 a CSN definiu por partir o equipamento com recursos próprios, sendo este o foco do trabalho. A presente contribuição técnica vem mostrar o trabalho desenvolvido internamente pelo grupo técnico a fim de finalizar o projeto e colocar a Turbina de Topo (TRT) em operação, fato este dado total ênfase pela direção da empresa devido ao cenário nacional de crise energética em que os valores de energia estavam no limite máximo permitido pela legislação e impactando diretamente nos custos da empresa.

Sep 25, 2017

By A. Noble

"In coal and mineral processing, several numeric parameters are used to quantify the separation performance of unit operations. For density-based separations, the partition curve is used as the starting point for many stages of diagnostic analyses. The curve is often quantified by its midpoint slope sharpness, and this single value is subsequently used for technical evaluation, benchmarking, and comparison. While this analytical approach does depict misplacement by relative density class, it inherently prioritizes middling separation and does not consider process economics or the micro-price value of individual classes. An alternative parameter, the organic efficiency, does indirectly consider process economics, but it does not reveal information on the root cause of lost revenue or misplacement. In this paper, a new analytical approach, the partition moment of inertia, is introduced. This parameter reconciles the technical misplacement data derived from the partition curve with the economic data derived from micro-pricing. The result is a new analytical procedure that promises better use of performance data. IntroductionPartition curves are commonly used in the characterization, evaluation and simulation of various physical separators. In mineral processing, partition curve analysis is routinely applied to hydrocyclones, screens, density separators and other beneficiation technologies that are based on intensive physical properties. Graphically, the partition curve depicts the recovery of particles as a function of the physical property on which the separation is based, such as particle density, size or magnetic susceptibility. Given the probabilistic nature of many real separators, the partition curve often exhibits a characteristic S shape (Fig. 1), similar to a cumulative normal distribution. Other geometric features of the curve are also depicted in Fig. 1, including the high and low closeout, or bypass, values; the midpoint slope; and the separation cut point, defined as the property value with 50 percent recovery.Partition curve analysis was originally proposed to evaluate coal washability (Tromp, 1937). Given the limited computational resources at the time, the analytical methods relied heavily on graphical construction and interpretation of the curve. Owing to the simplicity of calculation and interpretation, many of these graphical approaches are still widely used for performance analysis today. The most common calculations are based on the slope of the partition curve at the midpoint. Increased slopes correspond to enhanced separation performance, as a perfect separation exhibits a stepwise transition from 0 to 1 at the desired cut point, that is, an infinitely large slope. One common formulation of this slope, the Ecart Probable, Ep, is derived by evaluating the slope between the 25 and 75 percent recovery points:"

Jan 1, 2016

By M. J. Adam

The Bureau of Mines is investigating the feasibility of partitioning complex sulfide minerals to simpler sulfide phases by sulfidation reactions. Such partitioning can afford opportunity to improve selective extraction of mineral constituents of value. This report describes research involving sulfidation partitioning of byproduct chalcopyrite concentrates from Missouri lead ore processing, and a Utah chalcopyrite concentrate from Cu ore processing. Small chalcopyrite samples were sulfidized with elemental S in glass capsules sealed after evacuating and backfilling with He, by heating for 1 to 24 h at specific temperatures in the range of 250? to 500? C, extending from below to above the boiling point of S (-4450 C).

Jan 1, 1987

By M. J. Adam

As part of its research programs, the Bureau of Mines is investigating the partitioning of complex sulfide minerals to simpler sulfide phases by sulfidation reactions. Partitioning in this manner can afford opportunity to improve selective extraction of mineral constituents of value. This report describes research involving the sulfidation partitioning of the mineral pentlandite, which is an important source of Ni in primary production. For the laboratory studies, the pentlandite was synthesized in nominally equiatomic proportions of Ni and Fe. Elemental Ni, Fe, and S powders were blended, compacted, and sealed under reduced He pressure in vitreous silica tubes. The tubes were heated under controlled conditions at SOD? C for 24 h. The product was verified by X-ray diffraction and chemical analysis to consist essentially of (Ni,Fe)9S8. Small samples of the (Ni,Fe) S were encapsulated with sulfur in silica tubes at reduced He pressures and heated for 1 to 24 h at specific temperatures between 400? and 600? C, both below and above the boiling point of sulfur (_445° Cl. Reaction rate increased with temperature. Within this temperature range, partitioning to individual Ni and Fe disu1fides proceeded to essential completion according to the reaction

Jan 1, 1988

By Walter Luiz Corrêa Junior

O fósforo é um dos elementos mais importantes do processo de produção de aço em convertedores a oxigénio, devido à dificuldade de remoção durante o processo de sopro de oxigénio e depois do vazamento para panela de aço. Este trabalho mostra resultados obtidos através da alteração em variáveis de processo como o consumo de cales, teor de FeO na escória e uso de fluorita, durante o sopro e a avaliação da partição de fósforo com base em modelos de autores como Healy, Turkdogan, Basu e Suito, foi realizada utilizando os dados industriais da aciaria da ArcelorMittal Tubarão, com objetivo de comparar estes dados com as abordagens citadas. Um software termodinâmico foi usada para cálculo das atividades, da fração de líquido e do fósforo em equilíbrio, com a finalidade de auxiliar a identificação das principais diferenças termodinâmicas entre os dados experimentais e correntes. O resultado final mostra que as alterações realizadas no processo foram significativos para melhorar a taxa de partição de fósforo.

Jul 30, 2018