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By Antonio Esposito

Saving energy and reducing resource’s consumption by minimizing emissions are today great challenges in the coking industry worldwide. In order to achieve satisfying results, equipment as well as technology should be continuously improved and designed to minimize the energy requirements and to maximize the recovery of materials and energy. The sensible heat in coke pushed out of oven chamber takes up 35 ÷ 40 % of energy consumption of coke oven. Usually the coke thermal energy is lost during traditional coke wet quenching, necessary to reduce the coke temperature for the storage and the following use in steelmaking processes. BPSL CDQ project is a sample how Paul Wurth’s technology allows to reach the energy saving goal and offers an alternative to traditional quenching. With the adoption of Coke Dry Quenching process, a considerable amount of this sensible heat in the coke can be recovered by producing steam; its production depends on various parameters, some of them battery related (Volatile Matters in red hot coke) and others CDQ system related (coke burning losses, superheated steam characteristics (i.e. P,T)), greatly depending also on boiler efficiency (heat exchange efficiency, insulation of the boiler itself, air leakage, etc.). The adoption of CDQ process reduces also the water consumptions in comparison with traditional quenching.

Aug 16, 2017

By F. Navarro, F. Soto, G. Díaz, E. Jélvez, G. Morales, N. Morales

The increasing availability of tools on the web provides a great opportunity for the research community to boost investigation by accessing computational resources from all over the world. For example, data analytics libraries implemented in languages like Python can be accessed through many open and commercial platforms, therefore providing researchers with a common set of tools or shared datasets. Unfortunately, that is not the case with research in resource assessment and mine planning, where the most standardised tools are commercial applications designed to work on the desktop, but there are not many standard platforms for research. As a result, researchers from different groups often need to start from scratch in order to develop their work, and rarely share implementations details. Similarly, apart from a few publicly available examples, there is a lack of common datasets that are validated and can be used to compare results between different approaches. In this paper, we introduce a platform that provides tools for resource assessment and mine planning, which can be accessed remotely utilising Jupyter Notebooks. In its current version, the platform provides (i) definition and implementation of basic structures for managing samples and models (loading, saving, adding or removing columns, etc.), (ii) definition of experimental and modelled variograms for spatial continuity analysis, (iii) definition of standard interpolation methods in resource evaluation (inverse distance and kriging), (iv) definition of standard problems in mine planning (ultimate pit and precedence constrained production scheduling), (v) generation of 2D standard graphs like grade distribution, conditional means, tonnage-grade, and production plans (vi) a set of datasets, which can be used for case studies, and (vii) a set of notebooks with examples and documentation. In this paper, we introduce the platform and show some examples that illustrate some of the possibilities that it has for research and education in the area of resource assessment and mine planning.

Sep 1, 2021

By Y Peng, C Burns, Y Mu, R A. Lauten

In both laboratory flotation experiments and from analysing the composition of the lead concentrate at the Boliden Tara lead-zinc mine in Ireland, it has been found that F-250 may replace cyanide as a pyrite depressant. Replacement or reduction of the cyanide consumption is highly desirable from a safety perspective given the toxicity of cyanide. Scrutiny of results from the plant trial indicate that F-250 is less efficient as a cyanide depressant when the flotation feed contains high levels of pyrite. Statistical analysis of the results does not capture this trend, illustrating a need to collect more data at higher pyrite ore levels. A recent model proposed for biopolymer-induced pyrite depression is reviewed and discussed next to the suggested mechanism for pyrite depression via cyanide. Review of the interactions causing pyrite depression point to different manners in achieving depression. In light of the less efficient F-250 pyrite depression at high pyrite levels, it is speculated if the two depressants may act synergistically at high levels of pyrite in the feed. CITATION:Lauten, R A, Burns, C, Mu, Y and Peng, Y, 2018. Pyrite depression at Boliden Tara using F-250 – a biopolymer, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 385–392 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By V. G. Papangelakis, S. Peters

Pressure oxidation of refractory gold ores can be conducted on ores with high carbonate content using just water or water with alkaline reagents to promote fast kinetics, and suppress the formation of elemental sulphur and CO2. In this work, a fundamental study was conducted to explore the silica-pyrite interaction in the presence of calcium and sodium carbonate. It was found that an alkaline environment increases the pyrite decomposition kinetics on one hand, but on the other dissolves silica, which encapsulates the dissolving pyrite thus hindering ultimately its complete decomposition.

Jan 1, 2011

By W. G. Hubler

History The Aldermac mine is situated on the Nipissing Central railway near the ' centre of the township of Boischatel, Quebec, and is about ten miles west of Noranda. Aldermac Mines, Limited, is a subsidiary company of Towagamac Exploration Company. The property was staked by Messrs. Alderson and MacKay and McMartin, during the winter of 1922-23. During October, 1925, a copper discovery was made by K. W. Fritzsche, who was in charge of exploration work at that time, the first trench on this discovery averaging 8 per cent copper over a width of ten feet. This led to the discovery of another body 200 feet to the north, with an average of 3 per cent copper over fifteen feet in width. A magnetic survey was then carried out which led to the location of the large pyrite ore-bodies which have been developed in the past few years. Development work was carried on to a depth of 1,125 feet, and approximately three million tons of massive pyrite ore was indicated. Extensive metallurgical tests were conducted in the laboratories of the Mines Branch of the Department of Mines at Ottawa to determine the proper metallurgical treatment and the economic possibilities of the ore. Owing to the comparatively low copper content, and the uncertainty of the copper market, it was doubtful if the mine could be profitably operated for the production of copper alone. Messrs. Alderson & MacKay, however, realized the possibility of utilizing the large tonnage of pyrite as a substitute for native sulphur, 'which in past years has been imported into .Canada for the manufacture of acid and sulphate pulp in paper mills. They therefore organized the Sulphite Research Corporation with the object of developing an economical process of utilizing the pyrite.

Jan 1, 1932

By H. Salomon-de-Friedberg

The amount of pyrite in copper concentrates fed to the CESL Process can vary appreciably. The fraction of pyrite that oxidizes influences both capital and operating costs and is therefore an important variable. The present paper explores operating conditions that influence the extent of pyrite oxidation and the probable overall reaction chemistry under CESL conditions.

Jan 1, 2014

By S. K. Kawatra

In most operating coal-cleaning plants, a significant amount of pyrite is recovered in the froth during flotation of high-sulfur coal. Reducing the pyrite recovery first requires that the primary recovery mechanism should be Identified, as different measures are required for reducing entrainment, locked-particle flotation, or true hydrophobic flotation. In this paper, evidence is presented which suggests that hydrophobic flotation is not an important mechanism for recovery of liberated pyrite from freshly-ground coal when the collector is a neutral oil, and that the bulk of the floated pyrite occurs either as a result of simple entrainment or by mechanical locking with floatable coal particles. Column flotation results are also presented which show that significant sulfur reductions can be achieved by reducing levels of entrainment.

Jan 1, 1992

A Discussion at a meeting of the New York Section, Dec. 2, 1914 D. H. BROWNE.-If 35 years ago we had met to discuss the subject that is before us to-night, the criticism that we must all be mad or we would not be here at all would have been perfectly applicable. No group of men would have come together a generation ago to discuss the subject of smelting ores without extraneous fuel, or largely by the oxidation of their own impurities, without incurring the imputation of being crazy. But metallurgy, like all other branches of human industry, progresses by idealism. In every generation there are old men who see visions and young men who dream dreams. Thirty-five years ago John Hollway conceived the idea that in the Rio Tinto ore the sulphur and iron, if properly oxidized, could be made to produce heat enough to carry on the smelting of the ores. He saw the vision. Twenty-five years ago Mr. Austin, of Montana, took out a patent on a furnace in which to carry out Hollway's ideas. He dreamed the dream. Twenty years ago a man working in Montana grasped the possibilities of this idea. To him has been given that inexpressible pleasure which comes from realizing the idea and making the concept concrete. Gentlemen, it gives me great pleasure to introduce to you the man who made the ideal real, Robert Sticht, of Tasmania. ROBERT C. STICHT, Queenstown, Tasmania.-I find it extremely difficult to act up, in the smallest degree, to the enconium passed upon me by Mr. Browne. It is true it has been my good fortune to be able to put some sort of method into the "madness" of 25 years ago; but I am not the originator of the idea, nor the only one who has carried it out. Mr. Browne mentioned the originator, who undoubtedly is Mr. Hollway. He also mentioned Mr. Austin, who gave the first instigation to pyrite smelting as now practiced. As against both of these men I was fortunate enough to be able to command the necessary natural resources to carry out the idea continuously in a practical way, so as to make it permanently possible.

Jan 4, 1915

By DOOLITTLE E. M.

(Canal Zone Meeting, November, 1910.) The following notes are contributed, not with the idea of offering a complete history of the development of this very important process as applied to the Leadville district, but with the hope that the practice, as it was carried out in the Bi-Metallic Smelter, may still be of interest to others. The Bi-Metallic Smelter, at Leadville, Colo., was the first to make a commercial success of the process described in the following pages, which consisted essentially of smelting raw silver- and copper-bearing sulphide ores in blast-furnaces to form a matte, which was generally re-smelted with siliceous ores for a second high-grade matte. Robert Sticht, in his excellent monograph on the subject,1 has outlined briefly the plant belonging to this company. He says, in effect: The Boulder, Mont., enterprise set the example for others with whom the patentee (w. L. Austin) had been negotiating, and the old La Plata lead-smelter at Leadville, Colo., was fashioned into a crude, temporary experimental plant for the Bi-Metallic Company, and the feasibility of the process demonstrated by a trial run. Subsequently, the plant was considerably improved, and, being supplied with very favorable ores, continued to run without interruption from August, 1892, to June, 1893. In September, 1893, smelting was resumed in a completely remodeled establishment, some $200,000 having been expended upon the new work. Thus, aside from the Montana experiments, which, under the direction of W. L. Austin, began as early as- 1885 2 at Toston, and continued with indifferent success for six or seven years, the Bi-Metallic plant at Leadville may be said to have * Formerly Superintendent, Bi-Metallic Smelting Co. + Formerly Chief Assayer and Chemist, Bi-Metallic Smelting Co. 1 Modern Copper Smelting, E. D. Peters, 7th ed., p. 415 (1895). 2 Trans., xvi., p. 259 (1887-88).

Dec 1, 1910

By D. M. Conner

An innovative patented process has been developed to convert high volume wastes--fly ash from coal-fired power plants, municipal solid waste (MSW) ash from incineration, solids from waste water treatment and paper mill sludge into a high value and environmentally benign product in the form of a lightweight aggregate. Lightweight Aggregate is widely used in the building construction industry in the United States, Europe and some Asian countries. This paper will present the development of the process, the process itself and details on the first commercial scale plant. The commercial plant is owned and operated by Wisconsin Electric Power (WEPCO).

Jan 1, 1997

By J. Markussen

The Falconbridge Matte Leach Plant was based on leaching Ni-Cu matte with strong hydrochloric acid in rubber lined equipment. It operated from 1968 to 1983 as a precursor to Nikkelverk's present C12 Leach. The process comprised two S.X. systems. NiC12.4H20 crystallization, crystal drying, NiC12.H20 pyrohydrolysis and HC1 gas recovery. The naphtha fired fluid bed pyrohydrolyzer produced granular NiO, subsequently reduced with H2 to granular nickel for sale. The development and operation of the pyrohydrolyzer are described

Jan 1, 1991

By H. M. Woodrooffe

IT IS WELL KNOWN that chrysotile asbestos from various occurrences exhibits varied physical properties and certain differences in chemical corn position, both of which conditions may have an important bearing on the industrial utilization of the fibre. The usefulness of a harsh fibre in the manufacture of asbestos cement products and of low-iron fibre for certain electrical uses are examples. It is also .possible to obtain a fibre with a texture too harsh and brittle to be of economic value. Much research into the structure of the mineral and to a lesser degree observations relating the water of combination to certain physical properties have ?been reported. This paper is an attempt to show that the pyrolysis of ?chrysotile takes place in three stages and that the conditions of pyrolysis are peculiar to the fibre and may afford some clue to the variations in physical properties of asbestos fibres which affect their utilization.

Jan 1, 1956

By Walter E. Dean

Twenty six samples of carbonaceous gold ores and associated rocks from outcrop and mine localities in northcentral Nevada were analyzed for concentrations of major. minor, and trace elements, total sulfur, and organic carbon. Q-mode factor analysis was used to define six distinctive carbonate, organic, and detrital associations of elements, and to group samples based on these associations. The trace metals that have clearly enriched the organic-carbon-rich samples are V, Zn, Ni, Cu, Cr, and Mo, although few of the samples could be considered "metal-rich" when compared to other organic-carbon-rich black shales. Rock-Eval pyrolysis was used to evaluate thermal maturity and hydrocarbon yield of the samples. Unfortunately, most samples were too thermally altered to be suitable for routine organic geochemical characterization of organic matter. The 813C values of organic carbon in rocks from different deposits have a trimodal distribution, but there is no clear distinction between the three groups of deposits that can be related to age, thermal history, or depositional environment.

Jan 1, 1987

By Atsuhiro Nabei, Ken-ichi Yamaguchi

"Wet chlorination process of de-copperized anode slime is followed by de-chlorination stage in which lead-sulfate and metallic silver form silver residue. The silver residue is subsequently reduced to Ag2Se matte and PbO-SiO2 slag to remove lead to the slag in a short rotary furnace. Although this smelting process is proven well in actual operations, few papers have investigated its metallurgical aspects. This paper will describe the effectiveness of controlling parameters adopted at the Naoshima Smelter & Refinery and discuss the decisive factors influencing silver loss to PbO-SiO2 slag.IntroductionThe precious metals plant at Naoshima smelter & refinery was established in 1989, and has produced electrolytic silver, refined gold and platinum-group metals (PGM) from de-copperized anode slime as by-products of electrolytic copper. The process for gold production has been innovated from conventional smelting process to hydrometallurgical process since 2004 [1], while the process for silver production has still remained the same.The process for silver production at the Naoshima smelter & refinery is illustrated schematically in Figure 1. De-copperized anode slime is, at first, concentrated in the froth flotation process, then leached in the wet-chlorination process, and converted to silver residue in the de-chlorination process. The silver residue, which is a mixture of lead-sulfate and metallic silver, is charged to a short rotary furnace for the oxidation roasting to volatilize selenium dioxide and subsequent reduction smelting. In the smelting stage, silver residue and reverts containing selenium are smelted with flux and carbonaceous materials to form PbO-SiO2 slag and Ag2Se matte. Furthermore, Ag2Se matte is transferred to a rotary cupell and oxidized by air with the addition of sodium carbonate and sodium nitrate to produce silver anodes while removing impurities into litharge. Silver anodes are electrolytically refined by the Moebius process. Electrolytic silver is washed, dried and, finally, cast into 30kg-bars."

Jan 1, 2011

By B. Mishra

The major waste product of the alkaline extraction of alumina from bauxite [Bayer Process] is known as red-mud. Approximately, a ton of red-mud is produced for every two tons of bauxite that is mined. The red-mud produced from Jamaican bauxite is rich in hematite, alumina and titanium oxide. It has been shown that over 90 wt. pct. alumina can be recovered from red-mud by soda-ash sintering and caustic leaching. Hematite can be carbothermically reduced with a degree of metallization of over 94 pct. At this stage, the product could be charged through the tuyeres in an iron blast furnace or smelted to produce pig iron. The mineralogical characteristics of the reduced product are not amenable to magnetic separation for iron recovery. The problems associated with the use of reduced red-mud as an alternative to direct-reduced iron [DRI] has also been discussed. Special attention has been paid to lower the alkali content of the reduced material. If smelted, the concentration of titanium oxide in the slag will be significantly high justifying its recovery by an acid-leach process. This paper describes the successful efforts of iron and alumina recovery.

Jan 1, 2000

By J. J. Moore

Combustion synthesis or self propagating high temperature synthesis (SHS) reaction systems are discussed with respect to thermodynamics and kinetics. In particular, tile effect of the process parameters, ego particle size, AHf, ignition and combustion temperatures on these self sustaining reactions is discussed. Combustion theory is used to investigate the effect of the overall activation energy of the SHS reaction on the combustion front propagation rate and in obtaining a clearer understanding of the transition from stable to unstable propagation. Finally, examples of the application of combustion synthesis to advanced materials processes are made, in particular the synthesis of Ni-Ti -X intermetallic shape memory alloys, TiC-Al2O3 and ZrB2 ?Al2O3 ceramic composite materials.

Jan 1, 1991

By M-A Van Ende, N Kumar, I-H Jung

In order to utilise the powerful thermodynamic databases for process simulations, a concept called Effective Equilibrium Reaction Zone (EERZ) was introduced to couple thermodynamic database calculations and reaction kinetics. Using the EERZ concept, many process simulation models for steelmaking processes have been developed within the FactSage steelmaking consortium. After validation of the simulation results by comparing with plant data, the simulation models have been applied to improve plant operations. Several success stories of the improvement of real steelmaking operations are shared. A new user-friendly FactProSim software developed for building process simulations is introduced.

Aug 21, 2024

By Christoph Pichler

A special desulphurization slag accrues during the processing of iron ore to steel, which is needed to generate high quality steel. Sulphur removing is done by different technologies, but the most common one is the generation of a high sulphur containing slag by sulphur affine elements. Currently, this desulphurization slag is partly recycled, however, huge amounts are still dumped. To utilize this desulphurization slag for future purposes, a recycling process must be established. Therefore, first characterization of this material started some years ago at the Chair of Nonferrous Metallurgy, Montanuniversität Leoben. Subsequent trials in lab scale size were performed, also some investigations for different treatment steps were evaluated, starting with a parameter study in a hot stage microscope at various gas-atmospheres. Finally, the developed recycling process concept was verified in pilot scale trials to confirm the new recycling technology. Due to the successful treatment process, also a patent was applied.

By A. V. Tarasov

The lack of technology for processing of sub-grade ore concentrates and intermediate products for extraction of Zn, Pb, Cu and precious metals at the metallurgical stage was a constraint for an increase in the production of these metals. The technology developed in the Gintsvetmet Institute is based on an improved electrothermal smelting process for treating calcined charge, ensuring thereby a reduction in power requirement and improving the environmental performance of the process. Electric smelting of sub-grade polymetallic concentrates produces lead bullion, to which the bulk of gold and silver reports, as well as well segregated matte and slag concentrating the bulk of zinc. Lead bullion and matte are commercial-grade products; zinc is recovered from high-grade (15% Zn) slag by slag fuming process. Reduced loss of precious metals in slag ensured by the given technology is attributed to the fact that the slag contacts with matte with low contents of gold, silver and lead, rather than with lead bullion. Limited amounts of off-gas typical of electrothermal processes ensure cost-effective operation of dust recovery devices and a reduction in emissions of harmful pollutants into the ambient air.

Jan 1, 2002

By Camille Fleuriault

Continuous development of lead recycling technologies has driven the increasing contribution of secondary lead in battery manufacturing over the years. This review presents and compares the different technologies available for pyrometallurgical processing of secondary lead materials. Smelting is most often achieved in reverberatory, blast, rotary or electric arc furnaces, using single or two stage routes. Thermal re fining is the most common technique used for the production of lead and its alloys. Some improvements in battery breaking technologies and emission control have also specifically contributed to improve the performance of the smelting and refining units. Recycling lead is facing the challenge of increasing production while meeting more and more stringent regulations. This review will also include an analysis of the current secondary lead market as well as an economic outlook for the years to come in regards to rapidly changing environmental standards.

Mar 1, 2018