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By D. A. Norrgran

The recent development of rare earth permanent magnets has revolutionized the field of magnetic separation. The advent of rare earth permanent magnets in the 1980's provided a magnetic energy product an order of magnitude greater than that of conventional ferrite magnets. This has allowed the design of high-intensity magnetic circuits operating energy free and surpassing the strength and effectiveness of electromagnets. New applications and design concepts focused on the mineral and metal processing industries have evolved. This technology also led to the development of various magnetic separators specifically designed for mineral processing applications. Applications which were not previously considered are now being applied to primary mineral upgrading and recycling and secondary recovery.

Jan 1, 1993

By I. Filippova, L. Filippov

"The by-product potential of light rare-earth elements (LREE, La, Ce, Nd) and rare-metals (W, Nb, Sn) within the St Austell kaolin deposits (UK) is related to the kaolinisation process, which liberates the accessory heavy minerals of the host granite in the clay matrix and allows their separation in the waste streams. As a consequence these minerals are pre-concentrated in the micaceous residue which displays relatively high LREE content (around 170 ppm) hosted by monazite which is mainly distributed (up to 95%) in the -100 µm fraction. A combined gravity/flotation concentration flowsheet, starting with classification of the residue into 3 size fractions (+150 µm, 150-53 µm and -53µm) was developed. This study presents the results of the clay-rich -53 µm size fraction beneficiation by flotation using sodium oleate and hydroxamate as collectors.The effect of dispersant addition during de-sliming operations on flotation efficiency was also investigated. The LREE grade in the floated product obtained with sodium oleate increased from 3370 ppm to 5350 ppm and recovery from 30% to 80% with dispersant which is attributed to clay coating. Comparison of flotation performance and Falcon Ultra-Fine (UF) concentration of monazite to previous results obtained with Falcon Semi-Batch (SB) gravity concentrator on the unscreened raw residue clearly shows that flotation of the fine residue is more efficient than Falcon UF and Falcon SB. Indeed Falcon UF produced high recoveries (87-95%) but with almost no enrichment (1.3-1.4 ratios) whereas Falcon SB concentration of unscreened residue produced higher grades (up to 0.6 % LREE) but with low recoveries (17-22 %). These preliminary results show that LREE can be pre-concentrated suggesting that the micaceous residue stream (and the associated tailings dams) could be considered as a potential resource for these metals."

Jan 1, 2016

By S. B. Castor

Although production generally satisfies demand for rare earths, new markets may make undeveloped resources, particularly those rich in yttrium, more interesting. A Precambrian carbonalite orebody at Mountain Pass, California, has been the world's largest rare earth producer. Minor rare earth production comes from titanium placer mining in Florida and uranium mining in Canada. Prior to operations at Mountain Pass, North American production was mostly from placer deposits that constitute large, low-grade rare earth resources. Newly discovered North American rare metal resources in peralkaline igneous rocks are potential yttrium producers. Most of these resources are in a continent-wide belt of anorogenic magmatic rocks approximately coeval with mineralization at Mountain Pass. Other untapped rare each resources in North America are generally light rare earth-dominated and small or of low grade.

Jan 1, 1991

By Tetsuya Uda

Our recent achievements of rare earth separation technique[1,2] and new process idea for rare earth magnet recycling[3] are reviewed, (1) Binary chloride mixtures of rare earths were separated by a new selective reduction-vacuum distillation process. According to our experimental results, apparent separation factors were 8.1 for the Pr-Nd chloride mixture and 570 for the Nd-Sm chloride mixture. These values are much higher than conventional solvent extraction methods. (2) A study of recycling process of magnet sludge was carried out. The rare earths in the neodymium magnet sludge were extracted by chlorination with FeCI2, An activated carbon was used as a de-oxidation reagent Metallic iron in the sludge was not chlorinated because the iron monochloride is not stable, The extracted rare earth chlorides were easily separated from Fe-alloy and the excess of FeCh by vacuum distillation, 96 % of neodymium and 94 % of dysprosium in the sludge were extraeted into chloride phase, By the vacuum distillation, a mixture of neodymium and dysprosium trichlorides of 99.2 % purity was recovered, On the other hand, the rare earth chlorides can be converted to the corresponding oxides by a pyrohydrolysis reaction accompanied by a formation of HCl gas, The HCI gas can chlorinate metallic iron to FeCh, Therefore, a new recycling process for rare earth magnet waste can be realized as a chlorine circulation type process. During the process, only carbon and water are consumed and there are no toxic pollutants, Moreover, the obtained rare earth oxide can be directly used as raw material in the conventional oxide electrolysis process,

Jan 1, 2003

By A. Quilodran, B. Jakovljevic, T. McCallum, P. Wong

"Rare earth separation by solvent extraction (SX) requires multiple separation plants each consisting of many extract, scrub, and strip stages to separate the individual metals. SX modeling advances have brought benefits to circuit design and process optimization by quickly narrowing test conditions without the need for exhaustive laboratory studies. Modeling can be used to optimize circuit configuration, O/A ratios, and acidities, which allows for CAPEX and OPEX savings. A comparison between pilot plant data and the results expected from modeling is presented for rare earth separations with CYANEX® 572.INTRODUCTIONRare earth separations can be difficult due to limited separation between the elements (Xie, Zhang, Dreisinger, & Doyle, 2014). This requires relatively complex solvent extraction circuits utilizing multiple extract, scrub, and strip stages as well as multiple SX configurations to achieve the desired metal purities. Designing rare earth circuits can be complex, and significant time and testing may be necessary to determine the required staging and optimal conditions.Circuit modeling for rare earth separations has been introduced to the industry using CYANEX® 572 extractant (Soderstrom, McCallum, Jakovljevic, & Quilodran, 2014). CYANEX® 572 is an acidic organophosphorus extractant formulation which has a weaker ligand-metal complex strength than that of the traditionally used phosphonic acid extractants. This allows efficient extraction while requiring a significantly lower acid concentration for stripping (Wang, Li, Zhao, Dong, & Sun, 2015). The reduced acid requirement in strip is expected to provide OPEX savings.The modeling can be utilized to quickly determine the required acidity and organic/aqueous (O/A) ratio for a given separation. It is also expected to reduce CAPEX requirements as optimal staging can be determined, and implemented.CYANEX® 572, combined with modeling, was utilized to produce a purified dysprosium (Dy) stream. To achieve this separation, multiple SX circuits were designed and operational conditions specified to separate Dy from the mixed rare earth chloride feed."

Jan 1, 2016

By AIME AIME

TWO papers, "Calcium, Strontium, and Barium Metals," by Charles Hardy and Paul M. Tyler, and "The Mining of Gems and Ornamental Stones by American Indians," by Sydney H. Ball, were presented before the Rare Minerals and Metals group at its session Tuesday afternoon in the Auditorium. Donald M. Liddell, chairman, presided. Mr. Tyler summarized the first paper, outlining the uses, history, occurrence, manufacture, production and trade, markets and prices of the three metals. In discussion, in response to the chairman's query on "what are they doing in Russia with calcium, strontium, and barium," Guy C. Riddell replied that nothing is being done on a production basis. The great rare metals plant in Moscow is active, however, on other elements. "They are making radium chloride, uranium oxide, vanadium, cadmium, tungsten, molybdenum, selenium, antimony compounds; and mercury, nickel and arsenic are under production at interior plants. The rare metals plant is busily conducting research on beryllium, rhenium, lithium, bismuth, strontium and zirconium. These are the main rare metal activities. Much hard-alloy work. for cutting and facing, is under way:

Jan 1, 1933

By R. G. Eggert

"A critical element, as the term has come to be used, provides essential properties to a modern engineered material and is subject to supply risk. The rare-earth elements became perhaps the most prominent of the critical elements in recent years because of their important uses in permanent magnets, advanced lighting, and military materials; the geographic concentration of production in China; and the dramatic run-up in prices in 2010-2011 followed by price collapse between 2011 and 2016. Yet criticality extends beyond the rare earths. What is critical depends on your perspective – who and where you are, and when you ask. This paper reviews the many perspectives on, or faces of, critical elements. It compares and contrasts perspectives of industry (General Electric), national or regional manufacturing sectors (Japan, European Union), emerging energy technologies (as seen by U.S. Department of Energy and, separately, Joint Research Centre of the European Commission) and the world as a whole (as evaluated by academics). This comparison reveals a diversity of not only perspectives but also methodologies and time frames of concern.INTRODUCTIONRare-earth elements appeared prominently in the news in 2010 and 2011 because of the dramatic increase in their prices; their important uses in permanent magnets, advanced lighting, and military materials combined with the geographic concentration of production in China, which reduced export quotas significantly. Rare earths became the most prominent of what have become known as critical elements or materials – that is, those that provide essential properties to modern engineered materials and yet are subject to supply risks.Yet criticality, the state of being both essential and subject to supply risks, extends beyond rare earths. What is critical depends on your perspective. This paper begins by reviewing a little history and presenting a general conceptual framework from which to think about critical materials. It then reviews the many perspectives on, or faces of, critical elements – corporate, national, and global, as well several that focus on emerging energy technologies. The paper concludes with thoughts on what to do to mitigate the potentially negative effects of the supply risks associated with criticality."

Jan 1, 2016

By G. D. Sandrock

The science and technology of roan temperature rechargeable metal hydrides began about 1969 with the discoveries that the intermetallic Compounds LaNi5 and TiFe could be, conveniently hydrided and dehydrided at roan temperature and modest H2 pressures. Subsequently, this lead to the development of a broad family of REE-containing AB5 hydrides and numerous applications that make use of the extraordinary H2-absorption and reaction-heat properties of these materials. Some of the applications include H2 storage, compression and separation, as well as heat pumping, heat to mechanical energy conversion and electric energy storage. This paper briefly reviews the fundamental phenomenology of metal hydrides, the history of the use of REE's in rechargeable metal hydrides, the practical engineering properties of these materials and the applications that have evolved around them. The rechargeable nickel metal hydride battery, a new vial alternative to NiCd cells, stands at the forefront of the applications.

Jan 1, 1992

"How Wall Street Darling Molycorp Undermined the U.S. Economy, Degraded our National Security and Distorted the Global Economic Balance and How These Falsehoods Continue to be Promoted Even Today INTRODUCTION & SUMMARY In 2007 the Molycorp Mountain Pass rare earth mine was resurrected from its desert-grave in California by its then-owner Chevron Mining. Responding to elevated rare earth prices Chevron began processing on-site rare earth concentrates left over from past mining operations that were terminated in 1998i. Chinese demand had sparked what was being described as a commodities super-cycleii. Commodity prices were on the move. Wall Street smelled opportunity. In 2008 Goldman Sachs, Pegasus Partners, Resource Capital Funds, Traxys North America LLC and Carint Group LLC acquired the mining assets from Chevron. In an environment of ever-declining ethical standards and regulatory consequences the private capital group and their investment bankers would bring Molycorp to market. Molycorp, with its high powered investment banking team of Morgan Stanley and J.P. Morganiii, easily dominated the contest. Molycorp promoted itself, largely based on its past operating history and proven reserves, as the best company to challenge China’s monopoly control over the production of rare earths: a group of elements critical to most advanced technologies and U.S. defense systemsiv. Most of Wall Street’s hottest investment sectors were dependent on these materials: alternative energy, green technologies, computing, personal communications, advanced electronics and defense systems. By late 2010 there were dozens of prospective rare earth start-up ‘mining companies’ seeking capital. Eventually the number of prospective rare earth mining companies seeking capital exceeded 400, despite the reality that supply requirements of this market were disproportionally small when compared to other natural resource sectorsv. In the world of finance ‘smart money’ picks the winners. Consequently just twovi projects attracted nearly all of the capital (Molycorp and Lynas). Wall street picked Molycorpvii. This paper will primarily focus on Molycorp. By early 2010 the words “Molycorp” and “Rare Earths” electrified many people in the mining industry, most non-Chinese manufacturing technology companies, U.S. & allied defense contractors, technocrats in the U.S. national security community and eager investors across most of the world’s stock markets. It was the hottest story of the yearviii. The financial, technology and defense press coverage verged on euphoric: heaping fuel on fuel until the highly combustible Molycorp-pyre cast a long shadow over all of its rivalsix. When the IPO match was lit the spectacular flaming pyre sucked all of the oxygen out of the rare earth spacex. Molycorp was ranked the most lucrative IPO of 2010, resulting in record breaking profits to its private investors and massive returns for its early stock holding investors."

Jan 1, 2017

By T. Surkova

For the moment reserves of high-grade ores are practically depleted requiring ever-increased involvement of low assay raw materials, such as black-shale ores, in industrial operations. Black-shale ores are constituted of minerals containing such valuable components as vanadium, uranium, molybdenum, manganese, and rare-earth elements (REE). We studied technogenic solutions of black-shale ores processing, after uranium, molybdenum, and vanadium were recovered. Mentioned solutions contain rare-earth elements in substantial quantities (S REE 70-100 mg/dm3) that is very important factor taking into consideration the world demand ever-increasing last years. Higher concentrations of iron and aluminum inhibiting REE sorption and extraction recovery are found in solutions. We propose a method of hydrolytic deposition to cleaning solutions from impurity elements (Fe, Al). Study of hydrolytic deposition kinetics allowed identifying optimal conditions to run this process. Rare-earth elements may be recovered from purified solutions through sorption process followed by their further deposition from eluates in form of concentrates. Keywords: black-shale ores, rare-earth elements, a method of hydrolytic deposition, impurity elements, sorption

Sep 1, 2012

By T. Mulja, Michel Boily, Anthony E. Williams-Jones, Pierre Pilote

"The Preissac-Lacorne batholith is composed of suites of early metaluminous calc-alkalic gabbroic to granodioritic intrusives, three late peraluminous monzogranite plutons and numerous Li, Be and Ta-bearing granitic pegmatites. The Lacorne pluton is dominated by biotite and biotite + muscovite monzogranites containing abundant Be and Ta-bearing granitic pegmatites (40-80% volume). The pluton is surrounded by swarms of unzoned or poorly zoned spodumene-rich pegmatite dykes. The La Motte pluton is composed of biotite monzogranites, biotite+ muscovite monzogranites and rare muscovite + garnet monzogranites. Li, Be and Ta-bearing pegmatites are less abundant than in the Lacorne pluton and are commonly associated with molybdenite bearing quartz-muscovite-K-feldspar veins. In the Preissac pluton, muscovite + garnet monzogranites and muscovite + biotite + garnet monzogranites are the dominant rock types. The pluton rarely contains granitic pegmatites and these are generally barren. However, numerous molybdenite bearing quartz and quartz-feldspar-muscovite hydrothermal veins are observed.Li, Be andTa-bearing pegmatites display a crude spatial zonation around their parent monzogranites. Spodumene-rich pegmatites are generally unzoned or poorly zoned and are confined to the surrounding metasedimentary or metavolcanic rocks or crop out in the early gabbroic to granodioritic intrusives surrounding the monzogranites. Ta and Be-bearing pegmatites are usually concentrated towards the margins of their parent monzogranites. The highly fractionated nature ofmonzogranites (high Rb/Sr, low K?Rb, Ba?Sr, Zr/Nb ... ), their peraluminous composition (corundum normative and muscovite bearing) and the numerous occurrences of Ta and Be-bearing pegmatite dykes represent important criteria for the exploration of fertile granites."

Jan 1, 1990

By Donald M. Liddell, G. C. RIDDELL

THE cosmic ray continues to engage the attention of the physicists, and according to Millikan and Compton, experiments of the past summer indicate that these rays must come from interstellar space, but not from the stars themselves. According to press reports of the International Congress of Physicists at Rome, the view was given there that these rays have an initiating potential of over 750,000.000 volts. In the field of spectrographic investigation great strides have been made. The U. S. Naval Research Laboratories (R. F. Mehl and G. E. Doan of Lehigh) have just finished a year's work with a "radium torch" or "shadowgraphic apparatus" in the field of the X-ray, that bids fair to displace the latter to a great extent. The torch is more powerful., easier to operate and cheaper. Penetration of 10 in. of steel has been accomplished, which. is much -beyond the- -scope-, of the X-ray..

Jan 1, 1932

By Donald M. Liddell

ALTHOUGH the midday lunches of business associations have been re-echoing the phrases that re- search would lead us out of the depression and that the last place to economize is on research, nevertheless most executives apparently concluded that it was their neighbor who ought not to economize in research, and that in their own plants what had been discovered in 1929-30 was sufficient to lead them out of the wilderness. At any rate, I have discovered much less that seems worth noting, and compared with 1931, the report volume of the committee members is off about 40 per cent, and compared with 1929, about 80 per cent. Evidently there is some hookup with the +tee1 industry as to output, and the Report Reading Committee should investigate this and the relative use of commas and periods.

Jan 1, 1933

By Zay Jeffries

HOSTILITIES in Europe, Asia, and northern Africa were responsible for dislocations in rare-metal supplies during 1940. Although the consumption of some of the rare metals is small the dislocations may be relatively large. In some cases these are advantageous to North America and in others they are disadvantageous. Specific instances will be cited later. Barium T HIN films of barium metal on special steel balls greatly improve the life and reduce the friction of rotating anodes in highly evacuated small X-ray tubes and make possible the operation of these anodes at relatively high temperatures. These remarkable results are described in an article by Atlee, Wilson, and Filmer in the Journal of Applied Physics for September, 1940. Oil could not be used because of the high temperatures on the one hand and its volatility on the other. Fig. 3 shows diagramatically the rotating anode and the method of coating the steel balls with barium. The letters K.I.C. refer to "Kemet Iron Clad." The K.I.C. wire was mounted so that the barium could be evaporated by direct passage of the electric current. At high temperatures the barium dif-

Jan 1, 1941

By B. D. Saklatwalla

FOR the proper understanding of the inclusion of certain elements in this review it seems necessary to state the meaning of "rare metals." Certain elements occur in deposits limited in extent or concentration, so that the extraction of the element in relation to market conditions becomes uneconomical. Others may occur in extensive and rich deposits but the reduction of the metal may be difficult and costly. Both these conditions effect the same result, namely, make the metal rare and costly. As an example of the first kind may be mentioned radium and of the second, calcium.

Jan 1, 1939

By Colin G. ink

OUTSTANDI'NG in progress among the less familiar 'metals during 1936 is the electrolytic production of 99.9 per cent manganese meta1 readily and many quantity. Strictly speaking, manganese should not' be classed as 'a rare metal, since there is 800 times as much manganese in the earth's crust as there is zinc or lead. But manganese' as a metal is rare, just as titanium metal is rare though titanium is five times as abundant in the earth's crust as manganese.

Jan 1, 1937

By Zay Jeffries

A SURVEY of rare metals and minerals for the past year places uranium as one of two partners, the other being the neutron, in what historians will probably say is the greatest discovery in physics at least during the year and probably for a consider- ably longer period. The uranium atom has been made to divide into parts somewhat after the style of reproduction of the amoeba. When an amoeba divides into two parts, however, it produces two amoebae substantially alike and each substantially like the parent: furthermore, there is no considerable change of energy when this happens. When the uranium atom divides it yields other atoms such as barium and krypton with the complete destruction of the original uranium atom but with the liberation of a tremendous amount of energy. This will be discussed more at length later.

Jan 1, 1940

By Frank L. Hess

BERYLLIUM is demanding more of the limelight, and the output of beryllium copper (containing 2% to~ 3 per cent of beryllium) seems to have grown 60 per cent above that of 1936, which was double that of 1935. There is increasing interest in beryllium-aluminum alloys and small quantities are being marketed at $50 per lb. for the contained beryllium. Other alloys also can be produced. Further price decreases for beryllium copper (now $23 per lb. for the contained beryllium) seem , possible and desirable. No difficulty has been experienced in obtaining beryl and a 'reserve stock has been built up. One supplier heretofore found reliable has offered to furnish 200 tons per month. Supplies during 1937 have come from the Black Hills in South Dakota, Colorado. India, and South America

Jan 1, 1938

By Paul M. Tyler, Colin G. Fink

THE field of rare metals is so broad that progress can be reported upon many important fronts. Not satisfied with the 92 elements that Mendeleeff and his followers have accepted as legitimate, scientists are trying now to complicate matters by making new elements. Enrico Fermi announced the fabrication of "Element 93". Uranium, instead of being allowed to disintegrate slowly according to its normal habit, was bombarded with neutrons until some of them seemed to have stuck in the nucleus. To understand just what is alleged to have happened all one has to do is to line up the elements in their usual order of ascending atomic weight and imagine, as physicists do, that each atom is a little solar orbit comprising a central mass or planet about which other masses revolve like satellites. Ordinary hydrogen, being very light, consists of only one positively charged proton center, with only one positively charged electron revolving about it. Other atones are progressively more complicated until we come to uranium, which has a relatively big center and 92 particles revolving around it.

Jan 1, 1935

By B. R. Arvidson

Rare-earth elements have some unique properties that are used in many common applications, such as TV screens and lighters. In the 1970's, rare-earths began to be used in a new generation of magnetic materials that have very unique characteristics. Not only were these stronger in the sense of attraction force between a magnet and mild steel (high induction, B), the coercivity (He) is extremely high. This property makes the magnetization of the magnet body composed of a rare-earth element alloy very stable, i.e., it cannot easily be demagnetized.

Jan 1, 1998