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By Oliver Bowles

Slate possesses many admirable qualities, not only as a roofing material, but for blackboards, electrical switch boards, and for various structural uses such as stair trends, floor tile, baseboards, and sanitary enclosures. The American slate industry was established manor years ago, and has made remarkable progress, particularly during the past five years. One of the chief drawbacks to more rapid expansion is the high percentage of waste which reaches 75 to 94 per cent of gross production. Much of this waste is duo to rock imperfections over which man has no control, but a careful study of tae industry by the Bureau of Mines over a period of years indicates that an undesirably large percentage of the marketable slate is wasted in the processes of quarrying and manufacture. The initial step in quarrying slate is to separate from the solid ledge masses of a size that ray be conveniently removed from the quarry. This first step entails a greater waste of material than any subsequent process, and, therefore, invites the most earnest effort toward waste reduction. Attention has consequently been directed toward possible improvements in methods of making primary cuts in the quarry floor. A study of European practice with the wire saw, together with theoretical consideration of its advantages, convinced the writer that it possessed sufficient merit to justify its use as a primary slate cutter in American quarries. No practical conclusion in this matter could be reached except by experiment. Therefore, the desirability of obtaining equipment and trying it out under actual conditions of operation was urged upon operators. While no doubt the equipment could be readily manufactured in America, it had already been developed to the point of practical use in Europe; therefore the writer urged the desirability of purchasing one completely equipped wire saw in Europe, and determining through tests whether it gave sufficient promise of success to warrant its manufacture in America.

Jan 1, 1927

By H. M. Smith

In studying the chemistry of lubricating-oil fractions from so-called ?paraffin-base? crudes, one of the first requisites is a method for the separation and removal of waxy material. A method utilizing solvents for this purpose is described in this report, together with preliminary experiments with solvents that led to its development. The solvents actually used are secondary butyl alcohol, acetone, and mixtures of these.. Isopropyl alcohol was also studied. Preliminary Experiments In previous work on "intermediate-base" crude oil, following the work of Wyant and Marsh acetone had been used for laboratory separations of oil and wax. Then acetone was tried for the separation of the waxes and oils of "paraffin-base" crude, the volume of acetone required (80 parts to 1 part of oil) was found to be too great for large-scale work. For this reason the effectiveness of other solvents was studied; the separation by acetone, however, was used as a standard.

Jan 1, 1927

By E. C. Lane

The motor gasoline that is bring marketed in the United States this stunner is slightly more volatile than that sold a year ago. During the past eight years the Bureau of Mines has made semi-annual surveys of the gaoline marketed in the United States, the survey just completed being the sixteenth in the series. The cities in which samples have been collected have been chosen as representative of the more important marketing territories as it is obviously impracticable to obtain a sample of every gasoline sold in the entire country.

Jan 1, 1927

By F. W. Lane

Some months ago the Bureau of Mines began research of a fundamental character on sulphur in petroleum. In the course of this work, the usual qualitative test for sulphur in organic compounds1 was applied to certain oils that were believed to contain approximately 0.5 percent sulphur. No sulphur was found, and, as a check on the qualitative test, the oils were subjected to quantitative determination of this element by the oxygen-bomb method.2 The sulphur content of the oils ranged from 0.10 per cent to 0.50 per cent. This experience led to further trial of the qualitative test for organic sulphur, both on the oils mentioned above, and on common sulphur-containing organic substances. No difficulty was experienced in detecting the element in the latter, but with the petroleum oils the test, as usually performed, could not be relied upon to detect less than 0.60 per cent of sulphur consistently. The use of mechanically polished pure sheet copper for the detection of free sulphur, hydrogen sulphide, and perhaps other sulphur compounds has been recommended.3

Jan 1, 1927

By Joseph W. Horne

This report presents the results of an investigation by the U. S. Bureau of Mines in cooperation with the State of Colorado, on the yields and properties of oils produced from oil shale, lignite and subbituminous coal using the standard assay method developed by the Bureau for oil-shale testing,. The purpose of this work, which is part of the general study of oil shales being conducted by the Bureau of Mines and cooperating agencies, was to obtain information on the amount and character of the yield of crude oil or tar from different typical oil shales, the yield of light oil or naptha that might be suitable for use in motor fuels, and other products of shale oil. As the west has large resources both of oil shale and low-grade non-coking coals, it is of interest to know the relative yields of tars, light oils, and combustible gases that can be produced from these coals when retorted under conditions similar to those suited for oil-shale retorting. Source of Samples The coal samples were obtained from deposits on or adjacent to the public lands in the States of the Rocky Mountain region. Many of the mines sampled are operating under Government leases or permits. The number of coal samples secured from the various states are: Colorado, 6; Montana, 9; north Dakota, 6; New Mexico. 1; South Dakota, 1; Wyoming, 9. Of these samples, 14 were lignite coal, 16 subbituminous coal, and a bituminous coal. The standard channel method of the Bureau of Mines was used for sampling. Coal samples received at the Boulder Office weighed about twelve pounds each, and duplicate samples were sent to the Pittsburgh Station for proximate and ultimate analyses. The origin of the samples and description of the deposits are given in Table 1.

Jan 1, 1927

By K. B. Nowels

"INTRODUCTION For the last several years the oil industry has been turning more and more toward conservation arid the study of related production problems. It is generally conceded that ultimate recovery is increased by holding the natural gas in thy sand which is net needed in lifting the oil. The retained gas lowers the viscosity and surface tension of the oil and helps flow the oil from the sand. Lewis states that ""while the operator can not control the original conditions of energy and resistance in the sand, he can partly control the efficiency of expulsion. As it is the energy contained in the compressed and absorbed gas rather than the oil that is exhausted, it is but logical to judge the efficiency of a producing method largely by the relative quantities of gas produced with each barrel of oil. If by a change in method the producer lessons the proportion of gas with each barrel of oil, he should increase the total recovery- of oil correspondingly, even if the rate of production is temporarily reduced somewhat.""The effect of ""pinching in"" or controlling the flow of oil wells in an effort to lessen the proportion of has never been definitely known. The general belief has been that ""pinching"" a flowing well causes the oil and gas volumes to be reduced proportionately, maintaining the same gas-oil ratio as before the reduction in flow was made. Studies of gas-oil ratios in many fields have shown that much gas has been wasted, insofar as its effectiveness in oil production is concerned. Swigart and Bopp carried."

Oct 1, 1927

By Ludwig Schmidt

[The use of vapor-tight tanks has proved so effective in reducing the evaporation losses of petroleum that today practically all operators are using this typo of equipment. It has boon shown, however, that vapor-tight tanks should be supplemented with additional measures which will further reduce evaporation. Probably the most effective use of the supplemental measures are found on the small producing leases where the breathing losses from vapor-tight stock tanks materially affect the volume and gravity of the stored oil. The breathing loss from a vapor-tight stock tank that is filled and emptied daily is a negligible quantity. Also, the filling loss, which on the average varies between 0.1 and 0.2 per cent, usually is not of a sufficient quantity to affect materially the value of the crude. However, the combined breathing and filling losses from a vapor-tight tank requiring several days to fill are of sufficient importance to warrant the use of measures in addition to the vapor-tight tanks. The breathing losses are caused by atmospheric variations. Probably the greatest are the changes in atmospheric temperature which cause changes in temperature of the vapors in the tank. During the day, as the temperature increases, the gasoline-saturated vapors in the tank expand and are forced out into the atmosphere. At night the vapors are cooled and contract, drawing into the tank fresh air, which becomes saturated with gasoline vapor and is forced out of the tank during the following day. In Addition to the maximum and minimums temperature variations there are many smaller variations throughout a twenty-four period caused by showers, clouds, winds, and other atmospheric conditions which likewise cause the tank to breathe. The two mist common measures used by lease operators for reducing breathing losses in vapor-tight tanks are, first, operating; lease tanks under pressure, and second, the use of light colored paints anti tank houses. In this report these two methods are discussed together with their adaptability to lease operation. Results of experimental observations are given which show the reduction of evaporation looses where these supplemental measures have been used.]

Jan 1, 1927

By Wm. W. Adell

"These hydrocarbons belonging to the same chemical series as methane, having the general formula CnH2n have many chemical properties in common with methane and their addition to a lean gas charges the properties and burning characteristics of the gas in the same general direction although to a different extent. The hydrocarbons of this series do not readily enter into chemical reaction with other substances and therefore are incapable of combining with oxygen or polymerizing in the disturbing system and thus cannot cause gum and room troubles commonly met with in the distribution of manufactured gas.As the number of carbon atoms in the molecule increases, i.e. in proceeding from methane throughout the series, the oxygen requirements for the complete combustion of unit volume of the gases also increases; in other words, the calorific values of these hydrocarbons (as gases) increases from methane. Similarly the specific gravity increases from methane in the same order. In Table 1 are shown some of the physical constants and properties of a few of these hydrocarbons which hive bearing on their use for enriching gas."

Nov 1, 1927

By Wm. W. Odell

For a number of years there has been a very appreciable annual,, increase in the production and recovery of natural gas and natural-gas gasoline2 in the United States the latter product being used largely for blending with gasoline from petroleum in the production of motor fuel. On account of the increased amount of oil cracking in the production of gasoline and the accompanying increased percentage of low-boiling constituents in the resulting product, the specifications for the natural gasoline suitable for blending have been altered, that is, the amounts of propane and butane which it can contain have been limited. The result has been that large quantities of the latter materials are wasted because there has been no ready market for thorn in large quantities. Because of this wasteage and because it is probable that large quantities of there and similar materials will be produced in the near future us a result of the more general use of oil cracking processes, a study was made by the Bureau of Mines, under a cooperative agreement with the assistance of the Phillips Petroleum Company, of the suitability of these materials alone or in mixtures for use as gas enricher in the carburetion of water gas for city distribution. This investigation included: (a) A study of the properties of the low boiling members of the paraffin series including pentane with particular reference to their utilization as gases.

Jan 1, 1927

By Thomas Varley

"During the past few years, since flotation has become the paramount treatment method for most all kinds of ores, the Bureau has gathered the data on consumption of reagents used in the flotation treatment. The first report was issued in 1916. A brief review of such reports shows the progress made in the art of flotation, and each year brings forth development of new reagents or combinations of reagents that seem sure to survive, but research and progress spell their defeat, if not by entire elimination, at least subjects them to considerable modification. Fortunately, close cooperation between the Bureau and the operators has been the means of an exchange of ideas in research work, and the development, in plant practice, of such research work on a commercial basis, is one of the outstanding features in milling today.In past years flotation has been referred to generally as ""oil flotation""— today it might be more properly called ""chemical flotatioin"" Minerals can be floated today without oil. Chemicals alone will do the work, showing how little was truly known about the process heretofore. The term ""regents as used herein, includes both chemicals and oils. The total pounds of oils and reagents consumed during the year was greater than shown in the 1925 report. The 1926 total was 201,711,795 pounds as compared with 81,688,967 pounds for 1925. The equivalent in pounds of reagent use& per ton of ore for 1926 was 3.933 as compared with 1.7972 for 1925. This increase is due largely to the amount of lime which is added in the alkaline circuits particularly in the mills treating coppers ores, which accounts for the larger tonnages."

Jan 1, 1928

By E. D. Gardner

"The Bureau of Mines has studied blasting practices in metal mines of the Southwest. The investigation of blasting drift rounds showed among other results, that cut-holes in ground difficult to break could be chambered to advantage under some conditions.In open--cut mines, chambering nearly all holes before blasting is the common practice. Two or more free faces are generally maintained in this type of work, and the amount of explosive necessary to break any bench or bank can usually be estimated from the yardage to be moved. However, in blasting drift or tunnel rounds only one free face is available before the cut-holes are shot, and the quantity of explosive required is generally ascertained best by trial.In addition to being the most difficult to break, the cut-holes are the most important of a drift round. When the cut-holes ""break bottom"" less work is required of the other holes, and a full break of the round is generally obtained. In ground difficult to blast, extra care and expense are justified to insure that the cut-holes ""break bottom.""At many mines the work is so organized that all blasting is done at the end of the shift, and a decided advantage would have to be gained to make chambering of the cut-holes economical. Also, in many mines blasting during the shift would not be practical. One or two holes could probably be drilled during the time necessary to do the chambering. However, under certain special conditions, such as in small operations or those where ""leasers"" or contractors are working, drill holes could be chambered should there be an advantage in doing so. Moreover, in some mines it might be practical to chamber the cut-holes at the lunch hour. In ordinary rounds the cut-holes are generally drilled by noon. It would not be necessary to tear down the drill or remove tools from the face to do this work of chambering."

Feb 1, 1928

By Frank E. Cash

The Bureau of Mines in its safety work has for a number of years advocated and recommended the use of permissible portable electric cap lamps for use in all mines. In the course of time required for the evolution from an unsatisfactory to an efficient and safe light, but encouraging increase in their use has been experienced in Alabama. As early as 1916, small installations of these safer lamps were made or an experimental basis by several operating companies, and the first complete mine installation eras made at the Virginia mine of the Gulf States Steel Co., July 1, 1918. From the experiments in 1316 and the complete equipment of the first mine in 1918 gradual progress has been made until there are now 30 installations with 10 operating companies; as a result 20 mines have been put entirely and 5 partly on, closed lights, and 3 companies equip their engineering departments; two installations of closed lights are maintained by other companies for emergency use. One of the mines partly on the electric cap lamp is an ore mine - the only one in Alabama (and one of the very few in the United States) that uses closed lights. ACKNOWLEDGEMENTS The full cooperation of operating officials, lapmen, and lamp representatives was given in the collection of the data in this report, and is hereby acknowledged.

Jan 1, 1928

By E. C. Lane

The motor gasoline that is being marketed in the United States this winter is in general, more volatile than that sold a year ago. This increase in volatility is shown by a lowering of the distillation temperatures, ranging from 2°F. at the average initial boiling point to 5°F. at the average end point. During the past eight and. one half years the Bureau of Mines has made semi-annual surveys of the gasoline marketed in the United States, the survey Just completed being the seventeenth in the series. The cities in which samples have been collected, have been chosen as representative of the more important marketing territories, as it is obviously impracticable to obtain a sample of every gasoline sold in the entire country. Samples were collected in Boston for the first time since 1919. It was believed advisable to include samples from that district in order to give a better balance to the survey for the country as a whole.

Jan 1, 1928

By E. D. Gardner, Edmund Stein

"IntroductionMassive sulphides occurring in metal mines are inflammable and furnish the fuel for many mine fires. Actual sampling has shown that dangerous amounts of sulphur dioxide and hydrogen sulphide may occur in mine atmospheres after blasting in massive sulphides. Probably some .of the finer sulphide in the material being blasted burns while it is in contact with the flame from the explosion. It’s also possible that oxygen of the explosive enters into the reaction.That sulphide dusts are explosive under some conditions has long been suspected, but the theory has not been generally accepted as having been proved. Evidence now at hand appears to be conclusive that such explosions do occasionally occur in mine workings in massive sulphides. Information from several mines working in heavy sulphides shows that occasionally, sulphur dioxide in larger amounts than could be expected from the blasting alone are occasionally thrown out into the mine atmosphere during blasting. Accidents have occurred and lives have been lost by men being caught in such gases. Also it appears in a few cases that damage done to timber in stopes by concussions has been greater than could 112.ve been expected from the regular blasts. In most of these cases the unusually large amounts of Sulphur dioxide could only be accounted for by an explosion or by an ignition of sulphide dusts. When this occurs it is probable that the settled dust is stirred up by the first shot of a round, then the dust cloud is ignited by this or a succeeding shot.In one instance, the senior author, while wearing breathing apparatus, returned to a station to take a gas sample immediately after a raise round had been blasted, and encountered a heavy white fume or smoke that was corrosive to the skin and which forced a retreat. The sample, which was taken farther back in a greatly diluted atmosphere, showed a high percentage (0.18) of sulphur dioxide. The station and the raise which was just being started were very dry and the walls and floor of the station contained settled sulphide dust which apparently was ignited by the blast."

Mar 1, 1928

By John M. Devine

The oxygen bomb-is used extensively for determining sulphur in petroleum, although it has been suspected that the results obtained with this method are somewhat lower than the true varies. In this paper are compared the results given by the oxygen-bomb and Carius methods, the latter being generally accepted as the standard procedure for the determination of sulphur in organic compounds. The Carius determinations given hero were made in connection with a special study of this method.4 Only petroleum oils of the less-volatile type are covered in the present work. Summary and Conclusions. When used with oils containing 2.3 to 0.15 per cent of sulphur the oxygen-bomb method gives results that are consistenly if slightly lower than those obtained with the Carius method. This variation, for the oils used, amounts to 3.1 per cent (on tae basis of sulphur present) for the sample containing 2.47 per cent of sulphur, and gradually increases (as the percentage of sulphur in the oils decreases) to 7.3 per cent for the oil containing 0.15 per cent of sulphur. With the oils studied the presence of ammonium nitrate in the bomb does not influence the results materially.

Jan 1, 1928

By R. E. Head

[Recent investigations at the Intermountain Experiment Station of the Bureau of Mines at Salt Lake City indicate that metallurgists have given little attention to the occurrence of jarosite minerals in the oxidized ores of lead and silver. These investigations have also emphasized the importance of lowing when these minerals occur in the oxidized ores, especially those containing lead, silver, and gold, as their presence is a material factor in selecting a suitable kind of treatment. Since the question of the occurrence of jarosites in oxidized ores has come to the attention of the Bureau of Mines, investigation has indicated that plumbojarosite and argentojarosite are quite common. These two minerals appear to be widely distributed and probably escaped recognition by persons who had attempted to treat certain oxidized lead ores in which the jarosite minerals represented a material portion of the metal content. Consideration of the physical characteristics of the jarosites also indicates that in many cases failure to treat some of the oxidized lead ores with success has been directly due to the fact that the greater portion of their lead and silver content was present as plumbojarosite and argentojarosite. The data and the description of these minerals given in the body of this paper indicate that attempts to recover lead and silver from ores in which appreciable amounts of too metals occur is plumbojarosite and. argentojarosite would be unsuccessful if confined to gravity methods of concentration. There are undoubtedly considerable tonnage of oxidize lead ores in the various mining regions of this and other countries, and it is quite probable tat in some of these ores the metal content of lead and silver may be largely anglesite (lead sulphate) and cerussite (lead carbonate) but that they will also contain cerargyrite (silver chloride), argentojarosite, and plumbojarosite. The treatment of such ores therefore presents an important problem, since a product is discarded from]

Jan 1, 1928

By William A. Sloan

"In smelting operations, finely divided material called ""flue dust"" is carried by the moving gases from the roasters and furnaces; it is partly settled and recovered in the flue system. The flue dust from copper smelters contains a high percentage of copper, usually some gold and silver, and occasionally other valuable metals. It is too valuable to throw away and in present practice is returned to the smelting furnaces for re-treatment. A part of this material again passes out with the gases and forms a circulating dust load in the system. The dust that passesout of the stacks into the atmosphere is an important source of loss in copper smelting. Loss of values also occurs by dust being blown away while in transit from the flues back to the furnace, and of course the greater the amount of rehandling the greater this loss.Dust carried in the gas currents causes corrosion of the roof arches in reverberatory furnaces. Returning flue dust to the furnace increases the quantity of suspended dust. Corrosion reduces the life of the arches and shortens the length of furnace campaigns; also the corrosion of arches limits the temperature at which a furnace may be operated. Every ton of material that must be re-treated in the furnaces reduces correspondingly the amount of new ore or concentrates that could be smelted.As the present tendency is toward finer grinding in flotation plants smaller particles will need to be treated at the smelters, increasing the difficulty of preventing losses in flue dusts. Many schemes and processes for a more economical method of treating flue dust have been proposed or tried, but in the main none of them has been successful."

May 1, 1928

By George S. Rice, C. W. Owings

"Brattice cloth is an important material in coal-mine ventilation practically all coal mines use some brattice cloth, gassy mines a large amount. It is employed in three ways:Crosscut brattices.Curtains in haulageways.Line brattices in gassy mines.In each case brattice cloth is used to deflect part or all of a split of the mine ventilating current into or toward the face of a working place. As a general rule, its use in a particular location is temporary.A crosscut brattice should be employed only until a permanent stopping has been erected. Such a brattice is subject to little wear when in actual service, the chief damage occurring when it is taken down and put up again.When used for curtains on haulageways or haulage crosscuts to deflect the air current up into rooms or headings, the wear on brattice cloth is considerable, as mine cars, machines, and personnel constantly pass under the curtains which last only a few days or a few weeks in an active part of the mine. For such purposes tightly woven smooth cloth is desirable, so that it will not be easily torn. Curtains should not be used back from the working places, as they sometimes are, to deflect the main. split, as the leakage of air is too great. Doors should be used in such places."

May 1, 1928

By Edmund S. Leaver, Jesse A. Woolf

"The Baboquivari mining district is about 60 miles southwest of Tucson, Ariz., the present railroad shipping point. The values are silver and gold. The silver is largely associated with the black oxides of manganese. The ore is highly oxidized, and careful panning shows only a very small amount of pyrite. Our sample analyzed as follows:A flotation mill has been installed in the district, but it does not concentrate the precious metals satisfactorily. Our best laboratory flotation results were obtained by grinding to pass 65-mesh and floating with Xanthate or standard flotation oils plus sodium sulphide and polysulphide. This sulphidizing method gave a concentration of 32 per cent of the silver and 80 per cent of the gold, which about equals plant practice.We do not know of an instance where the oxidized forms of manganese have been concentrated satisfactorily by flotation.Plain cyanide on the original ore extracts practically all of the gold but only one-third of the silver. A preliminary deoxidizing roast, using producer gas or powdered coal, gives a calcine from which cyanide dissolves about 90 per cent of the gold and 75 per cent of the silver. This method of treatment, known as the Clevenger-Caron process, is described in Bureau of Mines Bulletin 226.Preliminary treatment with sulphur dioxide by burning pyrite or sulphur and passing this gas into the pulp until all of the contained manganese is dissolved or changed in form best prepares the ore for cyanidation. The acid consumption will vary with the percentage of manganese and other soluble constituents. Neither gold or silver is dissolved by this acid treatment. The washed residue gives maximum cyanide dissolution of the gold and silver with minimum loss of cyanide,"

May 1, 1928

By Chase E. Sutton

The porosity of a sand is usually the measure of its capacity for holding fluid, although porosity is sometimes selective; that is, a small percentage of the actual pore space (voids), particularly in fine-grained sandstones, may be isolated by the cementing material which prevents the entrance of fluids under normal conditions. Obviously, however, porosity determinations are essential to an engineering study of underground conditions of an oil field, and a simple and reliable method of obtaining a reasonably accurate figure for average porosity is desirable. This report describes a method suggested by Ruasell,3 which was used by the writer in the preparation of a report on the Texhoma-Gose pool, Archer County, Tex.4 The conditions in this pool were particularly favorable for obtaining an average porosity figure, in that some 30 to 35 core samples of the pay sand were available for analysis.

Jan 1, 1928