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By David F. Smith, F. A. Hartgen

"Incidental to a cooperative investigation with the Carnegie Institute of Technology and the International Combustion Engineering Corporation on the burning characteristics of a powdered coal and the powdered semi-coke therefrom, the U. S. Bureau of :alas has determined the relative temperatures at which rapid self-heating occurs in these two fuels. Determinations were made on various screen sizes of the two fuels. Chemical analyses on different sizes were made in the bureau's Coal Analysis Laboratory, of which H. M. Cooper is in charge. The true densities were determined b the method given in Bureau of Mines Technical Paper 8.4The apparatus used in the determination of the temperatures for rapid self-heating was similar to that used by Wheeler A 10-gram sample of the fuel was placed upon a screen in a glass tube enclosed in a vertical electric furnace. The tube was surrounded with sand. One thermocouple -as imbedded in the sand and another in the fuel. Measurements of the temperatures were obtained at regular intervals with a recording potentiometer, as the furnace temperature was uniformly raised. Dry air was passed down through the fuel samples at a uniform rate of 123 c. c. per minute; the temperature of the air was substantially that of the furnace."

Oct 1, 1929

By G. L. Oldright

This paper is the third1 of a series of five papers that is to appear on smelting in the lead blast furnace. The objects of this investigation are to determine the conditions obtaining within the blast furnace be direct experimentation, and to correlate the behavior of the furnace at various times with the main factors governing the operation of the blast furnace, and metallurgical losses. ACKNOWLEDGEMENTS The writers wish to express their appreciation to the management of the international Smelting Company at Tooele, Utah, for their kind cooperation which made possible the assembling of these data.

Jan 1, 1929

By C. R. Hopkins

"The petroleum refiners of the United States made rapid strides in fuel economy in 1928, when the calculated number of B. t. u. required to refine a barrel of crude petroleum was 637,000 as compared with 698,000 in 1927, a decline of 9 per cent. The major portion of this indicated increase in fuel efficiency was undoubtedly due to the gain in use of the pipe-still and the continuous process of refining as contrasted with the old batch method of distillation.,Almost without exception the new refineries are equipped with one or more pipe-stills, and many of the older plants are changing over to this type of equipment. The refineries of the Appalachian area are among the oldest and most conservative of the country, yet a number of them dismantled their old shell and cheese-box stills and installed pipe-stills in 1928.The more extensive use of the pipe-still was not the only way in which the refiners lowered their fuel requirements in 1928. The use of heat-exchangers, in which the heat from hot vapors to be condensed is used to heat the incoming cold oil, also increased in 1928, and in addition the refiners have kept abreast of the times in saving fuel through better insulation and improved burners.For the year 1928 the refiners burned as fuel the following: 46,400,000 barrels of-fuel oil; 3.362,000 short tons of coal; 114,950,000,000 cubic feet of natural gas; 77,313, 000,000 cubic feet of refinery or still gases; and 470,000 short tons of coke, in addition to a little electricity. This fuel was calculated to have produced a grand total of 582,156 billions of B. t. u., as compared with 578,784 billions B. t. u. in 1927.The total of 46,400,000 barrels of fuel oil burned represents an increase over 1927 of about 5,000,000 barrels, which made it about equal to the 1926 figure. Practically all of the refinery districts used more oil as fuel in 1928. The most important increase - over 2,000,000 barrels - occurred in the East Coast district, where greatly expanded throughput of foreign crude was instrumental in increasing fuel-oil production.The use of coal for fuel at refineries again registered a material decline, the total for 1928 of 3,362,000 short tons being 33 per cent below that of the previous year. The outstanding decrease in the use of coal in 1928 occurred in the East Coast district, where coal was probably replaced by oil. The use of coal for fuel at refineries in the States of Ohio, Pennsylvania, and West Virginia declined materially in 1928; the substitute used in the majority of cases was oil burned in pipe-stills."

Nov 1, 1929

By G. L. Oldright

This paper is the fourth of a series of preliminary papers on smelting in the lead blast furnace.4 The objects of this investigation are to determine the conditions obtaining within the blast furnace by direct experimentation and to correlate these conditions with operating factors, furnace behavior, and metallurgical losses. ACKNOWLEDGMENTS The authors wish to express their appreciation to the management of the International Smelting Co. at Tooele, Utah, for their whole-hearted cooperation in this investigation.

Jan 1, 1929

By G. L. Oldright, John D. Sullivan

"The present article is the second of a series of papers dealing with the dissolution of copper minerals in various reagents. Work done on the problem has been carried out at the Southwest Experiment Station of the United States Bureau of Mines, in cooperation with the Department of Mining and Metallurgy, University of Arizona. The first paper4 dealt with the dissolution of azurite, malachite, chrysocolla, and tenorite. Preceding articles5 have also dealt with other factors involved in the leaching of copper ores.Cuprite (Cu20) is usually considered as a mineral which is not adaptable to sulphuric acid leaching. Hofman,6 in describing leaching by sulphuric acid, states: ""Cuprite is decomposed into CuO and Cu; and ore carrying cuprite has to be oxidized (weathering, roasting) before treatment."" Greenawalt7 says: ""When acted upon by dilute sulphuric acid, it is partly reduced to metallic copper and partly oxidized into copper sulphate. When heated with strong acid it is entirely oxidized to sulphate."" Work to be described in this article was undertaken to ascertain the conditions whereby all the copper in cuprite could be converted into the soluble sulphate."

Dec 1, 1929

By E. J. Schneider

In view of the current interest in the constituents of low-temperature tar, the Synthesis of three known xylenols and their hydroxyacetic acid derivatives has been undertaken by the U. S. Bureau of Mines. One of these xylenols, the 1,3,2 derivative first reported by Steinkopf and Höpner,4 has been described by Brown and Branting.5 The other two derivatives, the 1,3,5 first reported by Schütz6 and the 1,2,3 reported by Steinkopf and Höpner, have now been studied in greater detail. In the present work the synthesis of 1,2,3-xylenol and 1,3,5-xylenol was repeated, with some improvements in the former. The hydroxyacetic acid derivatives were also prepared, and it was found that while the melting point of the 1,2,3 derivative agreed with that of Steinkopf and Höpner. that of the 1,3,5 derivative was found to be 111° instead of 85 to 86° as reported by Schütz, by Steinkopf, and later by Bruckner. The discrepancy between the melting-point figures is doubtless due to differences in the purity of the xylenols used in the synthesis of the acids. Schütz obtained his 1,3,5 acid by recrystallizing an impure sample obtained from a mixture of xylenols. The difficulty of obtaining a pure acid by starting with a mixture is demonstrated by Bruckner, who despite painstaking efforts was unable to obtain the pure 162.5° melting 1,2,4 isomer from a mixture that persistently melted at 138° C. Steinkopf did not repeat Schütz's work but merely used the latter's figures in compiling a table. Bruckner, on the other hand. apparently also made the acid (by an improved method), and it is difficult to explain his checking Schütz's figure, unless it is that he, too used a symmetrical xylenol obtained from a tar and not prepared synthetically, as was the one reported in this paper.

Jan 1, 1929

By Oliver Bowles

"Simple systematic accounting that adequately records all transactions has long been regarded as essential to the welfare of any business enterprise. Some of the defects that detract from the prosperity of the slate industry are attributable to a lack of effectiveness in cost keeping. This condition has prompted the United States Bureau of Mines to make a detailed study of accounting methods for the slate industry, and to present for consideration a system of accounts, which it is believed would enable the industry to attain more economical management and operation if accepted by a fair proportion of its important units.The method of accounting presented herein has been worked out with the assistance of leading slate producers and the recommendation are tentative and are submitted in this form as a means of developing constructive criticism. Believing that cooperative effort in this, as in many other problems, will bring the most enduring benefits to the industry as a whole, the writer urges that the most earnest consideration be given to this vital problem now facing the slate industry.Grateful acknowledgment is made of the helpful assistance rendered by R. E. Eckert of the accounting firm of Eckert, Degan, and Palmer of Easton, Pa., in compiling the charts and the explanatory text. He has brought to this work a wide knowledge of accountancy, supplemented by a background of direct contact with the slate industry, and his presence at the various conferences has been of great advantage in clearing up difficulties. The National Slate Association sponsored the cost study and chiefly through the efforts of President W. H. Smith and Secretary W. S. Hays, has aided greatly in conducting it. Acknowledgment is also made of assistance rendered by William F. Marsh of the United States Bureau of Mines."

Nov 1, 1929

By Oliver Bowles

[Simple systematic accounting that adequately records all transactions has long been regarded as essential to the welfare of any business enterprise. Some of the defects that detract from the prosperity of the slate industry are attributable to a lack of effectiveness in cost keeping. This condition has promoted the United States Bureau of Mines to make a detailed study of accounting methods for the slate industry, and to present for consideration a system of accounts, which it is believe would enable the industry to attain more economical management and operation if accepted by a fair proportion of its important units. The method of accounting presented herein has been worked out with the assistance of leading slate producers and the recommendations are tentative and are submitted in this form as a means of developing constructive criticism. Believing that cooperative effort in this, as in many ether problems will bring the most enduring benefits to the industry as a whole, the writer urges that the cost earnest consideration be given to this vital problem now facing the slate industry.]

Jan 1, 1929

By Wm. W. Odell

In distributing natural and mixed gas, the industry is each year confronted with the problem of manufacturing gas in increasing amounts as the supply of natural gas becomes more nearly exhausted. The manufactured gas is now used in mixtures with the still available natural product, and will subsequently be used straight as a substitute gas. The gases that might be considered, and are producible by tried and developed processes, include water gas, carbureted water gas, and coal gas. Singularly, these gases can be used in this manner in ordinary appliances only when proportional amounts of them in the mixtures do not vary beyond rather definite limits, unless burner adjustments are made. The limits are defined by the specific gravity, content of inerts, and burning properties of the respective gases. Anticipating a future standard for city gas lower than that of natural gas during the period when considerable natural gas is available, there is justification for considering the possibility of re-forming natural gas and making a product that has substantially the same properties as other gases which can readily be generated. This report gives the results obtained during a series of tests made under a cooperative agreement by the U. S. Bureau of Mines with the Ohio Fuel Gas Co., re-forming natural gas at Toledo, Ohio, in full-scale operation in a water-gas generator having a grate area of 25.1 square feet. ACKNOWLEDGMENTS The Ohio Fuel Gas Co. constructed a special water-gas generator for the tests and provided men and the necessary funds for its operation. Appreciation is expressed for the general spirit of helpful cooperation which was evidenced in the activities of all those who took part in the work. Particular acknowledgment is made of the assistance rendered by C. W. Wallace, manager, and by C. F. Cramer, superintendent, and A. Upp, foreman of the plant.

Jan 1, 1929

By N. A. Tolch

[In this partner ?propulsive strength? or "strength" is defined as the relative propulsive effect of an explosive as determined by means of the United States Bureau of Mines ballistic pendulum. The data presented are derived from one particular strength testing device and do not necessarily represent the relative execution value of the different explosives in actual blasting. However, it is believed that the data obtained with the ballistic pendulum fire indicative of the relative propulsive or heaving force and are of value until propulsive strength can be expressed in more fundamental units.]

Jan 1, 1929

By G. S. Rice, H. P. Greenwald, H. C. Howarth

"""Rock-dust barriers""5 as they are termed in this country, are for the purpose of confining a coal-dust mine explosion to the limited area in which it originates. These barriers were first tested in 1910-1911, with favorable results under the conditions of test, at the French official gallery which was then at Lieven, Department of Pas-de-Calais. Shortly afterwards the Bureau of Mines in the course of its investigation of all practical explosion-prevention methods tried barriers in the Experimental Mine near Bruceton, using the primary form of simple fixed cross shelves 20 inches wide extending over the passageway and laden with rock-dust. The Bureau termed them “Taffanel barriers"" in honor of the director of the Lieven testing station. The trials were made in conjunction with tests of explosibility of different coal-dusts.Experience showed that although the principle of barriers had merit when they were used for secondary defence, the primary form was uncertain in effectiveness. This led the senior author to design mechanically discharging barriers to be operated by the compression air waves which precede the flame of an explosion. For the better understanding of the principal involved, it is pointed out that the advance air waves are what make a coal-dust explosion possible by stirring up the coal-dust from the walls and floor of the passageway. If a barrier can throw inert dust into the air to form a cloud as dense or denser than that formed by the coal-dust, it will neutralize the explosiveness of the coal-dust, and the flame of the explosion will be extinguished. When the flame ceases, the pressure dies away in a short distance if the 'area that had been traversed by the explosion is not large."

Jan 1, 1930

By S. P. Kinney

During 1925, at Holt, Ala., the United States Bureau of Mines made a study of the composition of the gases at four elevations in the shaft of a furnace producing foundry iron. A report3 of the work was published in 1927. Some of the results of this investigation are shown in Figure 1. As indicated, the gas at the center of the shaft is low in CO2 content, while the gas in the vicinity of the wall is higher in CO2. The composition of the gases at the top and at the center of the stock column was not far different from the composition of the gas at the top of the bosh. The investigation indicated clearly that lean gas was channeling through the center of the column. More recently the study was enlarged in scope to include investigation of a furnace operating on Lake Superior ores in the Chicago district. A series of planes between the stock line and tuyères was surveyed. Means and apparatus were developed for obtaining, between the inwall and the center of the furnace, the gas composition, gas velocity, and temperature on each plane. A complete report4 of the investigation has recently been published.

Jan 1, 1929

By P. Nicholls

[This paper sets forth the burning characteristics of coke used as a domestic fuel as shown by work of the U. S. Bureau of Mines and others. Coke is a truly smokeless solid fuel and is held in high regard for this quality. Ways are being found for making commercial coke from a wider range of cools than heretofore, and tale use of coke for domestic heating is increasing. ACKNOWLEDGMENTS The experimental work reported in this paper was conducted at the Pittsburgh Experiment Station of the U. S. Bureau of Mines cinder the authority of O. P. Hood, chief mechanical engineer; M. L. Orr, assistant feels engineer, and W. M. Brewer, junior fuels engineer, assisted by Charles Schramm cooperated in making the tests.]

Jan 1, 1929

By G. L. Oldright

[Processes by which silver alone is extracted from ores that also cant contain base metals are usually associated in the mind of the period when mines were changing from the production of noble metals to the production of base metals containing noble metals as a by-product. In this transition period the mixed arcs of the partly oxidized ore zone had to be treated instead of the free-milling ore that had been treated in the past or the deeper-lying sulphide ores that were to be smelted subsequently under improved economic and technical conditions.]

Jan 1, 1929

By F. S. Wartman

Recent changes in metallurgical practice, particularly those in flotation, have altered greatly the functions of the different units of a copper smelter. Gangue minerals are removed from the feed so much more thoroughly that the reverberatory furnace, once virtually a concentrator in which a low-grade ore was concentrated into a rich matte by virtue of the removal of gangue elements as slag, has become very largely a melting furnace in which the rich flotation concentrates are rendered molten so that they may be converted. Moreover, since the proportion of matte to slag in the reverberatory furnace output is greater than it was formerly, the amount of converter slag returned to the reverberatory for cleaning is, in comparison to the amount of slag actually formed in that furnace, also much larger. In some cases, approximately half of the reverberatory dump slag may have originated in the converter. The increase in the proportion of convertor slag to total slag produced has brought about certain consequences not entirely desirable. Converter slags contain a high percentage of iron and therefore are high in specific gravity and are very basic. A considerable guantity of magnetite, both dissolved and suspended as solid crystals, is always a component, The basic nature of the ordinary converter slag and the presence of the suspended magnetite crystals make impossible the reduction of the copper content of the slag below approximately 1 per cent by even the most prelonged settling, and a re-treating process is necessary. At present, general practice in western copper smelters is to return the converter slag molten to the reverberatory furnace. Here dilution by mixing, with slag formed in the reverberatory furnace and reaction with raw sulphides and siliceous materials in the reverberatory feed reduce the magnetite and increase the silicates to the point necessary for a satisfactory dump slag.

Jan 1, 1930

By D. B. Gawthrop, A. Taylor, G. St. J. Ferrott

"This paper presents data obtained as part of an investigation of the explosive properties of ammonium nitrate. During the course of the work: it was found desirable to investigate the sensitizing action of nitrostarch in mixtures of ammonium nitrate containing low percentages of this material. Data were derived as to the sensitivity to decomposition by heat and the completeness of detonation and,of detonation of straight ammonium nitrate, as compared with ammonium nitrate-nitrostrarch mixtures containing 1 to 10 per cent of nitrostarch.The ammonium nitrate was a sample of coated material obtained from the salvage of amatol shells. Its analysis was as follows:"

Feb 1, 1930

By Wm. W. Odell

This report comprises a brief outline of the experimental cracking of natural gas in a water-gas generator at Louisville, Kentucky, and a discussion of the results obtained. The work was done under a cooperative agreement by the U. S. Bureau of Mines with the Louisville Gas & Electric Co. The re-forming or partial cracking of natural gas is not a new process, but one which has been employed in the manufacture of city gas for a number of years. However, the apparatus used heretofore was not a water-gas generator containing a bed of ignited fuel, but instead it was a plurality of connected chambers containing spaced and arranged checker bricks, with means for heating the bricks and for admitting the natural gas. The procedure previously followed was quite different from that used during the tests at Louisville; likewise the results obtained were different. It is not uncommon for companies distributing natural gas to provide gas-generating equipment for producing manufactured gas which is used, mixed with natural gas, during periods of peak demand. Because this equipment is idle much of the time, in some instances being in use only for a few days a year, some of the gas companies have considered using it, during off-peak periods, in the manufacture of some gaseous products and for carbon black which might he produced and marketed with profit. There is one plant of this kind at Louisville. Kentucky. Its maintenance in condition ready to be operated is necessary because of the limited supply of natural gas and because of the variation in demand. The engineers of the Louisville Gas & Electric Co. considered in particular the possibility of cracking natural gas in a water-gas generator by injecting the gas into the incandescent fuel bed, thereby producing a gas comprised largely of hydrogen (H2) and carbon black, an appreciable amount of which is entrained in the gas as it leaves the generator, Because power and gas are available at low prices, Louisville was believed to be a satisfactory location for a plant which could use hydrogen. It was evident that this method of treating natural gas might directly benefit the gas company by: 1. Lowering, the cost of manufactured gas.

Jan 1, 1930

By Martin J. Gavin

During the recent study of lubricating oils carried on in the San Francisco laboratory of the United States Bureau of Mines, it became desirable to distill the oils used in the experimental work at pressures as low as 10 millimeters (mercury column) absolute. In the effort to Overcome difficulties and eliminate sources of error, certain changes were made in the apparatus for vacuum distillation used by the Bureau of Mines for crude petroleum.4 These changes were described in R.I. 2819, issued in July, 1927. Subsequent to the publication of R.I. 2819 several other changes have been made, and the present form of the apparatus for vacuum distillation of lubricating oils is described in this revision of R.I. 2819. These changes were found to give more accurate checks on duplicate distillations. The major part of the credit for the laboratory work which developed the changes in the apparatus and method revised herein is due to Boyd Guthrie, assistant petroleum chemist, and R. V. Higgins, junior chemist, o the San Francisco laboratory, United States Bureau of Mines. DESCRIPTION OF APPARATUS The distilling flask employed is essentially the Hempel flask as used by the United States Bureau of Mines for the analytical distillation of petroleum.5 he complete apparatus is shown in Figure 1. The fractionating column and exposed portion of the flask is wrapped with 4 inch asbestos rope and then surrounded by a cylindrical hood of 1/8 inch pliable asbestos sheet with a narrow air space between the wrapping and the cylindrical hood. This was found necessary to prevent any radiation or convection heat losses from the column, and resulted in obtaining a more even and constant fractionation by eliminating any dephlegmating action caused by temperature changes around the column.

Jan 1, 1930

By R. R. Brandenthaler

The development of the Seminole area into one of the major oil-producing sections of the country has been accompanied by many innovations and departures from former methods of development. On July 1, 1929, two years and nine months from the date of discovery, 20,490 acres were considered proved, and additional acreage is constantly being developed. Because of its peculiar conditions, extent, and rapid rate of development, the Seminole area provided numerous problems, the solution of which necessitated research in connection with practical field operation; as a result, there was a radical departure from methods usually employed in the development of a new field in the Mid-Continent area.

Jan 1, 1930

By H. A. Doerner

"Statistics show3 that in 1927 the United States consumed 60 per cent of the world's production of chromite and produced none. The uses of chromium are rapidly expanding, and a dependable supply is essential to our industries. Since the political and commercial control of our supply of chromite is now in foreign hands it is prudent to determine how this nation can best prepare to supply its need for chromium if the imports were cut off or restricted and whether it is now possible and desirable to stimulate production of chromium from domestic deposits. We have only small amounts of chrome ore of high enough grade to meet present trade requirements. Therefore the Bureau of Mines is making a study of methods for beneficiating our low-grade ores.Chromite (Cr203.Fe0), is the only commercial source of chromium. For refractories, a minimum of 40 per cent Cr203 and a low silica content (5 to 8 per cent) is usually specified. In most instances bricks or lumps having a physical structure that will not crack when heated are required. The only way an inferior ore could be adapted to this use world be to concentrate it and develop a satisfactory binder to make bricks out of the concentrates.For making ferrochrome the requirements are a minimum of 45 per cent Cr203 and an iron content not exceeding one-third of the chromic oxide. On some low-grade ores gravity concentration will give a product meeting these requirements; other ores yield concentrates containing too much iron or other impurities to be saleable."

Jun 1, 1930