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By J. A. Lamonica

The Bureau of Mines studied two types of approved coal mine dust personal samplers to determine the effect of decreasing the amplitude of airflow velocity fluctuations on cyclone performance. Results indicate that more dust is collected when pulsation free flow is used. Velocity fluctuations were reduced by means of a pulsation damper; damper efficiency of about 85 percent was needed to reduce the fluctuations to an acceptable level. The data were obtained employing both pulsating and non-pulsating flow. A comparison was made of (1) the masses of respirable coal dust as determined by weighing and of (2) the particle size distributions as determined by an electronic counter. An empirical relationship is given between the ratio of masses collected using pulsating and nonpulsating flow (M') and the ratio of the maximum air velocity to the minimum air velocity (V') as measured in the cyclone entrance channel.

Jan 1, 1972

By H. E. Powell

The smelting of brass and bronze generates a dust composed primarily of zinc oxide, with lesser amounts of other metal oxides, such as copper, lead, and tin. The small quantity of this waste generated by individual smelters and the relatively low unit value of the contained metals, suggests the desirability of reclaiming the metals onsite or at some nearby point. The Bureau of Mines has developed a process that fits these requirements. The technique consists of (1) dissolving zinc and copper from the dust with sulfuric acid, (2) recovery of copper by cementation, (3) recovery of zinc as zinc sulfate crystals, and (4) recovery of lead and tin as a salable residue. Alternatively, zinc may be recovered by electrodeposition. Free acid is recycled and no major pollution problems are generated by the process.

Jan 1, 1972

By P. S. Lewis

Shortage of natural gas is reviving interest in low-Btu fuel gas made by gasifying coal in fixed-bed producers. The Bureau of Mines gasified strongly caking Pittsburgh bed coal over test periods lasting four days in an experimental gas producer located at Morgantown, W. Va, Mechanical stirring throughout the fuel bed was effective for keeping the fuel moving and this stirring made the operation successful; hence, the gas producer was named the stirred-bed producer. Nuclear density gages were applied as control instruments to indicate coal flow and fuel level, and to record the frequency and location of void spaces in the bed, The gas, of nominal 140 to 165 Btu/scf calorific value, could be burned in a boiler for generating steam.

Jan 1, 1972

By James L. Konchesky

Crushed coal, consisting of a wide range of sizes, was effectively blended by recycling it through a bin equipped with a particle distributor. Vertical blending was accomplished by simply recycling the coal; it was not significantly influenced by the horizontal blending that was achieved by the distributor. The method was effective, even though the coal was wet and possessed poor flowing characteristics. Recirculation appears capable of providing uniform blends of solids that can be more efficiently processed. Recirculation also appears useful, preceding packaging operations, to insure for blending of solids into specification products. Continuous measurement of the bulk density of the coal by a gamma ray meter proved to be an effective monitor of vertical blending effectiveness.

Jan 1, 1972

By L. A. Haas

S02 reduction with CO was studied in an integral flow reactor at a nominal flow of 0.5 liter per minute. Reactant gas contained 3 percent SO2, 6 percent CO, and the balance He. SO2 conversion was determined for three different types of catalysts. The first consisted of 16 commercial catalysts used for various chemical syntheses. Only the commercial catalysts which contained transition metals in alumina removed more than 30 percent 80a at temperatures below 510° C. Two other types of catalysts were prepared in the laboratory either by pelletizing equal amounts of powdered alumina and transition metal oxides or by impregnating commercial alumina tablets with transition metal ions. Regardless of preparation techniques, Cr and Fe in alumina were the two best catalysts. The observed results suggest that an intermediate (SCO) is formed by the interaction of surface metal sulfides and carbonyls. Alumina then catalyzes the interaction of SCO with S02 to form the end products (sulfur and carbon dioxide). Over 80 percent S02 was removed at 460° C with 2 grams alumina impregnated with 2.5 percent iron.

Jan 1, 1972

By O. Q. Leone

Composite diaphragms were used in the investigation of electrowinning Ti from TiC14 in a fused LiCl-KCI-TiC'2 electrolyte. Composite diaphragms tested were of two general classes--those consisting of two or more solid materials, and those which contained, in addition, a loose material. An electrowinning cell using a flat diaphragm is described. The maximum current density for these diaphragms was 300 amp per ft2. Lower currents permitted longer operation times. The composite diaphragms gave electrode efficiencies that averaged approximately 60 percent, and the electrowon titanium was of good quality--some Brinell hardnesses were as low as 68.

Jan 1, 1972

By John P. Gooch

The solubility of 1,1,2,2-tetrabromoethane (TBE) in water was determined from 1.0° to 97.0° C. The solubility (S) of TBE in grams of solute per 100 grams water was correlated with [S = 1,920.55 [exp (40292L7 11, T2 10 T 737.577 + 9.923962 ] where T is in degrees Kelvin. A thermodynamic analysis conducted on a system consisting of a TBE phase and a water phase in equilibrium with a vapor phase led to the calculation of the activity coefficient, vapor-liquid equilibrium distribution coefficient, relative volatility, and heat of mixing for saturated solutions of TBE in water. Data required for these calculations were the solubility of TBE in water and the vapor pressures of TBE and water as a function of temperature.

Jan 1, 1972

By T. D. Moore

The use of a partially slotted 6.5-inch-inside-diameter vertical pipe to remove methane from a longwall gob area at a depth of 2,260 feet in the Pocahontas No. 3 coalbed was investigated. The value of gas removed by such a pipe under free-flow conditions was found to equal the cost of the installation in this case. Approximately 25 percent of the available methane passed through the pipe without the use of an exhauster; an additional 10 percent was removed when an exhauster was employed. The diversion of methane through a vertical slotted pipe to the surface permitted the use of increased mining rates and decreased the ventilation air requirements.

Jan 1, 1972

By E. R. Cole

Laboratory heats of an 80 percent copper high-leaded tin-bronze alloy, similar to Brass and Bronze Ingot Institute (BBII) alloy 3A, were made with reduced tin content to determine whether an alloy comparable to BBII alloy 3A could be produced using less tin to aid in conserving this strategic metal. The tin content was lowered from 10 percent to 8 percent and 5 percent (nominal values), respectively, and the reduction in tin was offset by either increasing the lead content or adding zinc. Mechanical properties, machinability, and corrosion characteristics of the resultant alloys were investigated, and the mechanical properties were compared with BBII typical values and American Society for Testing Materials (ASTM) minimums for high-leaded tin-bronze alloy. Results indicate that the tin content of this alloy could be reduced approximately 1 percent (difference between the 8.4 percent actual tin composition obtained and the 9.3 percent BBII minimum) without seriously affecting the desired properties. Results also show the tin content could be reduced without significantly increasing the chances of rejects for mechanical property failures, which might result from normal variations in the casting process.

Jan 1, 1972

By B. J. Scheiner

Extraction of silver from silver mill tailings by an electrolytic oxidation procedure was investigated by the Bureau of Mines. Various parameters affecting silver extraction, such as electrolysis time, particle size, and dissolution of the silver as the tetrachloro or cyanide complex, were studied at 30° C with an electrolyte concentration of 20 weight-percent sodium chloride. Resulting silver extractions ranged from 77 to 90 percent, depending on the tailings being treated. Concomitant extraction of mercury ranged between 90 and 95 percent. Power consumption was 52 to 90 kilowatt-hours per ton for the tailings investigated. Comparative experiments using direct cyanidation resulted in extraction of 46 to 82 percent of the silver and 20 percent of the mercury. Cyanide consumption ranged from 3.3 to 9.4 pounds per ton of tailings, depending on the tailings being treated. Silver and mercury were recovered from leach solutions by precipitation on iron powder, followed by conventional distillation and fire refining steps.

Jan 1, 1972

By H. E. Powell

A solvent extraction procedure was developed on a laboratory scale for recovering trisodium phosphate, zinc, and iron from waste phosphate sludge as separate products. The sludge was dissolved in hydrochloric acid, and iron was extracted as ferric chloride by isopropyl ether. Zinc was extracted by di-2-ethylhexyl phosphoric acid in kerosine. The efficiencies of the one-and two-stage extractions ranged from 98 to nearly 100 percent. Trisodium phosphate was recovered by crystallization from the raffinate. The value of two marketable products is considerably more than than the costs of the major reagent. The process was developed to permit recycling of values in this waste and to consequently reduce stream pollution from this source.

Jan 1, 1972

By D. J. Bauer

A solvent-extraction system employing selective stripping of a pre loaded organic phase was investigated for recovering Sm203 from a light-group rare-earth mixture. The samarium concentrated in the organic phase, and a >99-pct-pure samarium oxide product was obtained at 76-pct recovery in a 20-stage operation using di(2-ethylhexyl) phosphoric acid (EHPA) as the organic phase. The stripping agent was a 1.5-pct hydrochloric acid solution containing 200 g NH4C1/1.

Jan 1, 1972

Synthetic dawsonite [NaAl(OH)2C03] has been prepared with crystallinity similar to that of dawsonite found in oil shale deposits of the Piceance Creek area of Colorado. Optimum experimental conditions were as follows: Na/Al atomic ratio, 43; temperature, 175° to 200° C; pCO2, 15 psig; and reaction time 5 hr. Chemical and spectrographic analysis revealed that the synthetic dawsonite was of high purity and Has essentially stoichwmetric. Similarity of the synthetic to natural dawsonite, demonstrated by X-ray diffraction, infrared spectrophotometry, and electron microscopy, suggests its suitability as a standard.

Jan 1, 1972

By Richard J. Kline

The underground mining industry is presently using the fluid network analyzer and digital computer to analyze ventilation systems. The availability of the digital computer and ventilation programs to mining companies has escalated its use, permitting the design and modification of new or existing mine ventilation systems to be projected completely and thoroughly with consistent precision. Because the analog computer has been analyzing ventilation systems accurately for many years, a comparison of the analog and digital methods was warranted. This report summarizes a detailed comparison for one mine, based on parallel analyses by the two computer systems.

Jan 1, 1972

By R. V. Higgins

A numerical method is presented to calculate the pressure distribution in a petroleum reservoir that has irregular boundaries. The computer program is straightforward and requires minimal data preparation. The method can also be used to determine pressure distribution in many other types of underground reservoirs. In this method, the grid solution of the fluid-flow equations in a reservoir that has regular boundaries (previously published) was expanded to handle irregular boundaries. The computer program locates grid points at the irregular boundaries. The method of mirror images is then used to form a special stencil to determine the pressure at each of these points. Two examples are presented to demonstrate the applicability of the method for virtually any reservoir configuration.

Jan 1, 1972

By K. R. Becker

The addition of a force gage and a reaction detector to the Bureau of Mines drop-weight impact apparatus made it possible to examine the details of the force exerted on the specimen and make estimates of the time to reaction. With the current setup the force was found to be oscillatory and not reproducble. However, single well-defined pressure pulses can be delivered to the explosive sample by modifying the drop-weight tools. With a modified test arrangement, the time to reaction and the peak force and energy at the time of reaction were determined as a function of drop-weight height for several different explosives. All these parameters were found to decrease as the rate of force application was increased. The same parameters were also found to vary with the thickness of the test sample. The implications of these results are discussed in terms of practical drop-weight testing.

Jan 1, 1972

By C. C. Merrill

Columbium, tantalum, titanium, and zirconium are present in solid waste products generated by the chlorination of rutile used for production of titanium tetrachloride (TiC14). The columbium and tantalum were separated from titanium and zirconium by liquid-liquid extraction techniques using a secondary amine. Salts of these elements are in a leach liquor produced by water leaching of mineral waste from the chlorination of rutile. This waste, produced at the rate of approximately 50,000 tons per year, is about 40 wt pct water soluble. Leach liquors, separated by filtration, were further separated into a solid fraction and a liquid fraction by pressure hydrolysis, The solid fraction containing Cb, Ta, Ti, and Zr was dissolved in HC1-HF and used as a feed solution. Columbium and tantalum were removed from the organic extractant with 1 [N] HC1. A miniature 10-stage reactor showed that the columbium and tantalum present in solution could be separated with a continuous flow.

Jan 1, 1972

By A. W. Deurbrouck

The separations achieved by eight conventional cyclone washers have been evaluated to determine their performance when processing intermediate size coal of 28 mesh bottom size. The dense-medium cyclones provided efficient, sharp separations in treating feeds of up to 44 percent of near-gravity material at separating specific gravities ranging from 1.42 to 1,55 (one separation of a secondary feed was made at 1.63). Complete washability analyses are shown by sizes of the composite feed to these cyclones. The magnetite losses per ton of coal processed ranged from 0.6 to 2.0 pounds; however, of the eight plants reporting losses, seven indicated magnetite losses were 1.1 pounds or less per ton of coal processed.

Jan 1, 1972

By C. Melvin Lepper

A solid-state amplifier for the bridge circuit of an atomic-absorption mercury detector is presented and described. Operational advantages over previously used circuitry include improved time and temperature stability, increased measurement accuracy, and simplified setup, calibration, and operation.

Jan 1, 1972

By A. Viksne

A series of tests were conducted by the Bureau of Mines to determine the best means of reducing noise generated by the detonating cord that is utilized for trunklines in quarry blasting. Ten different types of detonating cord were tested and evaluated for their acoustic qualities. The results of the investigation showed that noise levels produced by "low-core-load-per-foot" detonating cord "not covered" were lower than those produced by "high-core-load-per-foot" detonating cord covered with 6 inches of unconsolidated material.

Jan 1, 1972