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THE slag performs two useful functions in open-hearth steel- making. First, it is the means of disposal of all the impurities, save carbon, which are removed from the charge materials in refining the steel, so it must be suited to receiving and retaining as much as possible of undesirable elements with minimum loss of iron and useful alloying elements. Second, the slag serves as a buffer between the flame and the bath and transfers oxygen to the metal at a measured pace contrasted with the violent and difficultly controlled oxidation of the bessemer process. At the same time, the slag is a thermal insulator that limits the rate at which heat can be delivered to the metal from the flame, and a heavy slag blanket thereby serves as a brake on production rates. It has been said with justification that the secret of good steel- making is to make a good slag and the steel will take care of itself. In a broad sense, the subject of slag control includes not only the adjustment of the composition of the slag but also of its relative weight in terms of percentage of the metal-bath weight. The slag is made up essentially of: (1) oxides formed by oxidation of silicon, manganese, phosphorus, and iron in the charge, (2) Si02, MnO, MgO, and other oxides charged as such or introduced incidentally with ores or fluxes or by refractory erosion, and (3) lime charged or fed to the heat to neutralize the "acidic" oxides present (Si02 and P205). Obviously, if practically perfect control were possible over the composition of the charge as well as over the oxidation process during the melting period, both slag weight and composition would be very nearly predetermined; and the control problem would be solved. Unfortunately, only a somewhat imperfect control over these factors is possible, so the operator must begin during the lime boil and continue through the refining period to discover and correct departures from the normal pattern of slag development. To do this as the heat progresses, the first helper must be able to make quick estimates of the composition and physical state of develop-

Jan 1, 1964

By C. H. Jr. Herty

ALMOST every metallurgist who has given the Howe Memorial Lecture has had a personal contact with the distinguished gentleman to whose honor this hour is devoted. Unfortunately for me, such personal contacts were not possible. However, in the preparation of a thesis on the open-hearth process, one of my earliest tasks was to make a survey of the literature, and it was from Professor Howe's Metallurgy of Iron and Steel that I drew a number of references to previous work which formed the foundation for my reading. In his volume there is such a complete exposition of the then current thought on the subject of slags and on their role in the elimination of phosphorus from steel that I feel no hesitation in discussing in this Howe Lecture the subject of "Slag Control." In the present era of close specification, the drive for uniformity of product, and the close inspection of the product and of the cost sheet, the utmost efforts must be made to control the steelmaking variables to the best advantage of the steel producer. One of the major variables is the slag in the furnace and its effect upon the composition and quality of the metal. What advantages are to be gained from slag control? In the broad sense the advantages must be tremendous, because the very foundations of good steel melting are based on "shaping up" the slag to a point where, with proper temperature, the heat is ready for the final additions. Every melter works toward these ends through his experience with innumerable heats of steel. The elimination of undesirable constituents such as phosphorus and sulphur is entirely a matter of slag composition and physical nature, a point well known for over half a century. The role played by the slag in assisting in proper heat transfer from roof and flame to the steel has been equally well known. In more recent years there has come the problem of oxygen control in the more accurate gaug-ing of additions for making high-grade rimmed steel for the new strip mills, and in the deoxidizing additions for grain-size control and cleanli-ness of forging steels, both carbon and alloy. In this problem the oxidiz-ing characteristics of the slag are of prime importance.

Jan 1, 1940

By M. Zamalloa

Slag foaming is an important phenomenon in many metallurgical processes. It creates large surface areas for multi-phase reactions to take place. In other applications, it protects electrodes and improves the energy efficiency by reducing radiation from hot surfaces. However, it may also be a source of serious disturbances. To control and optimize the use of slag foams, an extensive knowledge of the factors controlling the foam formation and stability is required. Slag foaming experiments were carried out using synthetic FeO-CaO-Si02 slags at temperatures ranging from 1200 to 1350 "C. A data acquisition system was used to continuously measure the foam height, gas flow rate, bubble frequency and temperature. The experimental results show that the gas injection rate has a strong effect on the behaviour of slag foams. At high flow rates and rapid bubbling, unstable foams with short decay times were created. The addition of P20, favours the foam formation and stability by lowering the surface tension of the slag. The average foam life increases with decreasing basicity (CaO/Si02). It is proposed that this is attributed to the increase of the surface viscosity due to surface adsorption of a thin film of silica, retarding the drainage of the liquid films.

Jan 1, 1992

By Marie-Eve Boucher

The slag in iron ore pellets allows wet sintering during firing and leads to suitable bounding. The process of slag formation differs whether it takes place in the core or in the external zone of a pellet. In the core, hematite can be reduced to secondary hematite, depending on the temperature and on the carbon monoxide/dioxide partial pressure ratio. The reaction rim that appears at the outskirts of a silica particle in contact with the FeO bearing magnetite is considered as the slag precursor in the core of the pellet. By contrast, in the external zone of a pellet, where O2 is available and CO partial pressure is very low, the first step towards slag formation is flux decomposition, mainly dolomite and limestone. The CaO liberated through this reaction will be available to react with hematite by solid diffusion to form calcioferrites, which play an active part in the slag evolution process. These two slag formation paths will be explained.

May 1, 2007

By F. J. Guevara

A two-dimensional mathematical model for fluid flow and heat transfer in a sixin- line electric smelting furnace was developed to study the effects of temperature on slag viscosity in both the liquid and mushy zones. The model focused on the fluid dynamics of the molten slag and the effects on the formation of a slag freeze layer on the hot face of the furnace wall. Previous experimental and mathematical work, carried out under Ra number of 109 and using a fluid with Pr number of 65, showed that it is possible to mathematically describe the freeze layer formation over a vertical wall using a fixed-grid model. The chemical composition of the slag was taken into account through its effect on the viscous activation energy as well the solidus and liquidus temperatures. The results show that the flow pattern is strongly modified in areas of high viscosity, in front of the cooling system and at the slag-matte and slag-calcine interfaces. The results are discussed in terms of heat flux over the refractories and their effects on cooling system design.

Jan 1, 2007

By George A. Yurko

The Cominco smelter, located at Trail, British Columbia, Canada, produces 180 000 metric tons of lead bullion annually in conventional blast furnaces. The resulting slag from these furnaces, 210 000 metric tons annually, containing 18 per cent zinc and 2.5 per cent lead, is treated directly in the slag fuming plant for the recovery of these metals and other valuable metals present in smaller quantities. Slag fuming is carried out on a 55 metric ton batch process in completely water-jacketed furnaces where the slag is blown with a mixture of powdered coal and air. The coal-to-air ratio is con- trolled to maintain strongly reducing conditions, thus, fuming the metals from the slag. The metal vapours are subsequently re-oxidized with air above the bath. The mixture of oxides is carried from the furnace by the gases through waste heat boilers and cooling flues to a baghouse where they are collected. The slag fuming plant, under normal conditions, will treat 700 metric tons of slag daily. The throughput in the plant is dependent on the fuming rate of zinc, which is a function of the composition of the slag, and on the economics, which dictate the extent to which zinc is fumed from the slag. Zinc and lead collected daily as fume average 113 metric tons and 17 metric tons, respectively, corresponding to recoveries of 89 per cent zinc and 98 per cent lead from the slag. The waste heat boilers produce 61 metric tons steam per hour, which is distributed to other processing plants.

Jan 1, 1970

By K. J. Heale, G. G. Richards, D. J. Rioux, R. L. Stephens

Slag fuming has remained a key process for the recovery of Zn, Pb, and minor elements in the integrated flow sheet at Teck Cominco's Trail Operations for more than 75 years. Since the start-up of the KIVCETTM process and the #3 slag fuming furnace in 1997, a range of process intensification projects have been completed to improve metals recoveries and throughput based on improved process control, mechanical modifications, and, most recently, the implementation of oxygen enrichment of the blast air. This latter project, initially named 'nitrogen depletion' and now 'nitrogen oxygen performance enhancement' (NOPE), is the primary focus of this paper. NOPE reduces the amount of heat required to heat the inert nitrogen gas, and therefore more of the energy input can be used for reduction. It also frees up boiler capacity because the inert nitrogen gas does not then have to be cooled down. A dynamic METSIMTM model was developed to determine the opportunities to improve the process capacity and heat balance to both assist with justifying the project and to verify the observed furnace behaviour. Several process safety management issues were also addressed and a few key minor mechanical modifications were made to allow the project to proceed to commercial implementation at 25% blast air oxygen enrichment. Short term plant trials have confirmed the model predictions. The first three months of a long term, continuous trial showed a 6% increase in zinc fuming rate from average furnace performance despite the implementation of a KIVCETTM fluxing change to assist with minor element recovery that was expected to negatively impact the zinc fuming rate by 3 to 5%. This encouraging result is also in line with the model predictions.

Jan 1, 2008

By Arthur W. Cooper

This paper contains a review of the development of blast furnace? slag handling and processing technology in the Ironmaking industry over the past 30 years, with an emphasis on economic and environmental factors. The requirements and practice of air-cooling slag for use as aggregate and of pelletizing and granulating slag for use in cement manufacture are described. The operation of slag pits, slag pots or ladles, the slag pelletizer and early granulation systems are compared with the new continuous .granulation, dewatering and handling systems developed in the past decade.

Jan 1, 1992

The effect of composition on electrical conductivity (resistivity), viscosity and liquidus temperature of the slags encountered in electric smelting of PGM containing suphide concentrates is reviewed, along with the relationsip between slag composition, slag-matte separation and metal losses to slag. Optimization of slag composition at furnace temperature is attempted on the basis of opposite and parabolic trends of the viscosity-conductivity relationships of the slags. The importance of surface tension of slags is emphasized using available and estimated information which are grouped into a useful correlation. These values are coupled with or incorporated into slag viscosity plots to illustrate the correlation between the two factors, which influence slag-matte separation as well as refractory attack. The electrode in the slag-resistance furnace is the central factor in the design and operation of the furnace by its role of conveying the smelting power. The obvious parameters are the size and positioning in the slag bath, which are defined by slag resistively, furnace resistance, cell constant and power input. The flow of heat generated by the electrode current determines the energy distribution and furnace dimensions creating viscosity profiles, which in turn affect flow conditions. Thus the flow of slag and matte are discussed in conjunction with the furnace geometry, stirring action of the electrodes, buoyancy and electromagnetic effects. The action of the electric furnace as a settler is discussed. The rectangular furnace is considered as a channel reactor in this analysis, and the action of the electrodes is described to indicate a balanced settling rate in the area of electrode action. Discussion of the design and production capacity of the electric furnace, with reference too perating current, power input, furnace dimensions and electrode size, are based on considerations derived mainly from slag properties such as its resistively, viscosity and liquidus temperature.

Jan 1, 2004

The effect of composition on electrical conductivity (resistivity), viscosity and liquidus temperature of the slags encountered in electric smelting of PGM-containing suphide concentrates is reviewed along with the relationsip between slag composition, slag-matte separation and metal losses to slag. Optimization of slag composition at furnace temperature is attempted on the basis of opposite and parabolic trends of the viscosity-conductivity relationships of the slags. The importance of surface tension of slags is emphasized using available and estimated information, which are grouped into a useful correlation. These values are coupled with or incorporated into slag viscosity plots to illustrate the correlation between the two factors which influence slag-matte separation as well as refractory attack. The electrode in the slag-resistance furnace is the central factor in the design and operation of the furnace by its role of conveying the smelting power. The obvious parameters are the size and positioning in the slag bath, which are defined by slag resistivity, furnace resistance, cell constant and power input. The flow of heat generated by the electrode current determines the energy distribution and furnace dimensions creating viscosity profiles, which in turn affect flow conditions. Thus the flow of slag and matte isdiscussed in conjunction with the furnace geometry, stirring action of the electrodes, buoyancy and electromagnetic effects. The action of the electric furnace as a settler is discussed. The rectangular furnace is considered as a channel reactor in this analysis and the action of the electrodes is described to indicate a balanced settling rate in the area of electrode action. Discussion of the design and production capacity of the electric furnace with reference to operating current, power input, furnace dimensions and electrode size are based on considerations derived mainly from slag properties such as its resistivity, viscosity and liquidus temperature.

Jan 1, 2004

By A. Warczokand

The cleaning of copper smelting slag requires magnetite and cuprous oxide reduction. The slag reduction with coke, injected coal powder or bunker oil is strongly endothermic and requires heat generation by fuel combustion or the use of electric energy. The reduction of fayalitic slag with calcium carbide is slightly exothermic and the formed calcium silicate modifies the slag. Thus, the additional energy is required only for covering furnace heat losses. Results of crucible scale tests showed the rate of slag reduction approximately five times higher in comparison of the slag reduction with coke under the same conditions. It seems that the effect of exothermic reaction and slag modification with CaO at the reaction interface results in very high rate of slag reduction. Industrial scale tests carried out in the Anglo-American Chagres Smelter demonstrated the possibilities of effective reduction and cleaning of the slags from a flash smelter and Peirce-Smith converters in a Teniente Slag Cleaning Furnace. The slag reduction was carried out without any reductant or stirring gas injection, simply by calcium carbide charging through a furnace mouth, and was very fast.

Jan 1, 2007

By Clebson Joel Mendes de Oliveira

Sulfur control in steel have been challenging process experts since the discovering of it deleterious effect on most of steel product properties. To separate this slag from hot metal is mandatory to complete desulfurization process. The preferred method is to skim hot metal surface physically removing the contaminated slag, attributing to the operator the evaluation of skimming efficiency. Thus, we present a new lower cost system using image processing methods foreseeing a future full automation skimming process.

Aug 16, 2017

By Mieke Campforts

The usefulness of the water-cooled probe technique to experimentally study slag solidification and freeze lining formation in pyrometallurgical reactors is evaluated. With this technique a layer of solidified slag is formed on a water-cooled probe that is submerged into a liquid slag bath. The influence of the submergence time and the heat input is examined. The solidified layers are analyzed with light microscopy, electron microscopy, electron probe micro-analysis and X-ray diffraction. Thermodynamic software is used to interpret the solidification microstructure. The results demonstrate that the technique is useful to understand freeze lining formation.

Jan 1, 2006

By M. Y. Mohassab-Ahmed

In an effort to develop a novel flash ironmaking process, the chemistry of selected slags was investigated. In different ironmaking processes, the molten bath (iron-slag bath) is expected to be in contact with gas atmospheres of H2/H2O, CO/CO2/H2/H2O, and CO/CO2. The latter was investigated to allow comparison with the blast-furnace conditions. The slag composition was selected to resemble that of the blast furnace with CaO/SiO2 in the range 0.8 to 1.4. The temperature range was 1550 to 1650°C. The oxygen partial pressure was maintained in the range 10-10 to10-9 atm. The effect of water vapor on the chemistry of the slag as well as the equilibrium reactions involving the slag has been studied for the first time. H2O dramatically affects the chemistry of the slag and strongly affect the phase equilibria in the slag as well as the equilibrium distribution of elements between slag and molten metal.

Jan 1, 2014

By Geysen. Daneel

Better slag valorization is part of improving the sustainability of steel, stainless steel and non- ferrous metal production processes. Besides, it can improve the sustainability of other products and production processes as well. A sound and well established slag valorization is beneficial for the overall economics, marketing and appreciation of the metallurgical process and its products. On 6-7 April 2009, the First International Slag Valorisation Symposium was held in Leuven, Belgium. This paper gives a brief summary of the symposium, providing an overview of slag valorization opportunities. The authors believe that high temperature process slags can have interesting applications and that within the next 10 to 20 years slags will need such valorization options in order to compete with other materials and get general support for further production. On the other hand, the authors also expect a higher demand for slags for the production of various materials. High temperature processes should anticipate on the growing opportunities for valorization of slags and increase the resilience of their process by better understanding slag processing, slag quality and material requirements. More interdisciplinary research efforts are required to reach this level of knowledge for the different high temperature processes. Such an interdisciplinary research platform was recently established at KULeuven, Belgium, named SMART-PRO2 (Sustainable Materialization of Residues from Thermal Processes into Products).

Jan 1, 2010

By Hubert Bril, Priscilla Pareuil, François Bordas, Emmanuel Joussein, Jean-Claude Bollinger

"According to the legislation, valorization type, origin and characteristics of waste material, various standard procedures are available to evaluate environmental impacts. A Mn-rich slag was sampled from a metallurgical plant. After its characterization (elementary analysis and mineralogy), five standard procedures were carried out (i.e. TCLP, EN 12457-1). Each fixed parameter of the standards was systematically studied in a large range: pH, Liquid/Solid ratio, contact time. For example, EN 12457-1 led to a low ME mobilization, increasing with the L/S ratio, the contact time and an acidic pH. As a conclusion, the representativeness of the considered parameters and their potential variations are predominant to assess of the real environmental impact during slag reuse. Introduction Recent studies have been carried out about environmental impacts of waste containing metallic elements (ME) because of their potential mobility [1-7]. Indeed, slags are either dumped or valorized in various activities such as building materials. In order to assess environmental risk, various standard procedures are used depending on country legislation, origin of waste and valorization way. Results of leaching tests are linked either to special legislation (e.g. Dumping: EC, Council Decision 2003/33/EC, Construction products: EC, Council Directive 89/106/EEC) or to legal levels used in drinking water (Directive 98/83/CE) when leachates could migrate to groundwater. If ME in leachates are lower than drinking water authorized levels, the waste will be considered as non-hazardous. On the contrary, if the leachable amounts exceed them, the question about the risk has to be posed. Beyond the abundance of leaching tests available, variety of operational conditions induced by these regulatory tests does not make the choice easier. According to operational conditions induced, ME release could vary from one test to another one. ME concentrations in leachates depend on pH, Liquid/Solid ratio, contact time and particle size [3]. To highlight the importance of these operational parameters, potential risk for valorization of a manganese-rich slag was assessed by comparing several standard leaching protocols [8-12] with a global study dealing with the influence of operational conditions. For each regulatory protocol, the most influential parameters (L/S ratio, pH, particle size and contact time) have been studied in a large range."

Jan 1, 2008

By Q Zhuo, P C. Pistorius, M N. Al-Harbi

A likely increasingly important pathway for future low-carbon ironmaking and steelmaking is the combination of gas-based direct reduction with electric furnace steelmaking (DRI-EAF route), or with electric smelting (DRI-ESF route). In the DRI-EAF route, the gangue that is present in the iron ore is fluxed and removed as slag in the melting (steelmaking) step. This is in contrast with integrated steelmaking, in which the gangue is removed as part of blast furnace ironmaking. For DRI-EAF steelmaking, the amount and composition of slag depend on the iron ore composition, flux additions and iron yield. Slag volume and composition affect phosphorus removal, foaming behaviour and the process energy requirements. In this work, heat data from a year of DRI-EAF production was analysed to test whether the expected relationship between slag volume and electricity consumption for EAF steelmaking was observed. The data include slag analyses (one sample per shift), and heatlevel information on all inputs, final steel temperature and dissolved oxygen concentration, electricity consumption, tapped steel mass and tap-to-tap time. In analysing the data, the slag volume was estimated from the assayed slag CaO concentration and CaO inputs to the EAF. The expected effect of slag volume on steelmaking energy consumption was calculated with a mass and energy balance, considering the heat of mixing of the slag. The calculated energy requirement of slag formation is in line with previous estimates reported in the literature.

Aug 21, 2024

IN A broad sense, the subject of slag control includes not only the adjustment of the composition of the slag but also of its relative weight in terms of percentage of the metal-bath weight. The slag is made up essentially of (1) oxides formed by oxidation of silicon, manganese, phosphorus, and iron in the charge, (2) SiO2, MnO, and other oxides charged as such, and (3) lime charged or fed to the heat to neutralize the “acidic”: oxides present (Si02 and P2O5). Obviously, if practically perfect control were possible over the composition of the charge as well as over the oxidation process during the melting period, both slag weight and composition would be very nearly predetermined, and the control problem would be solved. Unfortunately, we have only a somewhat. imperfect control over these factors, so that beginning at about the lime-boil period in the heat, and later in the early refining period, it becomes necessary for the first helper, as the heat progresses, to make quick estimates of the composition and physical state of development of the slag (as well as of the amounts of phosphorus, sulphur, and carbon in the metal) from which he can judge how much extra lime, roll scale, fluorspar, and other additions will be needed not only to give the desired final slag composition, but also to hasten the complete fusion or shaping to a desired viscosity in the liquid state. The discussion in this chapter is limited essentially to those more or less practical rapid methods of slag estimation that have been used, or at least tried, for these purposes under actual open-hearth shop conditions. Another aspect of importance here is the extent to which the freedom of choice to the operator is limited by available charge materials, product specifications, and the oxidation and other chemical- reaction effects which inevitably occur under the conditions of this furnace process. For a better understanding of these control limitations and of the chemical and physical background of the subject, the reader is urged to read at least part of the discussion in Chapters XVII and XIX. Charge materials are discussed in Chapter IV, and many of the details of charging, melting, and refining practice closely related to slag control are given in Chapters VI and VII.

Jan 1, 1944

By N. A. Barcza

An investigation was conducted into the reactions between the slag system MnO-CaO-MgO-SiO2(AI2O3) and the alloy system Mn-Fe-Si-(C). Synthetic slags representative of plant melts and a plant alloy were reacted in alumina crucibles at temperatures of 1400°C, 1450°C, 1550°C, and 1600°C. In similar experiments, slags were used that comprised a South African manganese ore with various amounts of lime and several synthetic alloys with various silicon contents and manganese-to-iron ratios. These experiments were conducted in a vertical molybdenum-wound resistance furnace with full temperature control. Slag-to-alloy ratios were also varied during the tests. The rate of reduction of Mn.O3 and the MnO from the slag by the silicon in the alloy was extremely rapid, most of the reaction being completed within five minutes. The strongly exothermic nature of the reaction resulted in considerable generation of heat at the slag-alloy interface, causing convectional stirring of the contents of the crucible and promoting the rate of reaction. Equilibrium was usually attained after fifteen minutes. The major limitation governing the recovery of manganese is the need for the silicon content of the alloy to meet a maximum specification of 2 per cent. Higher concentrations of silicon in the final alloy of between 8 and 12 per cent favour good recoveries of manganese from the slag, but, since such an alloy is not salable, lower recoveries must apparently be tolerated. In alloys of 2 per cent silicon, low activities of the silicon are responsible for poor recoveries of manganese. The activity of MnO in the slag can be increased by moderate additions of CaO and small amounts of MgO, i.e., by an increase in the basicity of the slag.

Jan 1, 1979

By J H. Park, R R. Kim, H S. Park, H J. Kim

This study focuses on the recovery of valuable metals, specifically silver (Ag) and palladium (Pd), from copper-containing sludge (with copper content less than 20 per cent) generated during PCB processing and from spent petrochemical catalysts used in vapour decomposition during oil refining processes. The present results indicate that an increase in the mixing ratio of alumina-based spent catalyst leads to a decrease in the recovery rate of Ag and Pd. The recovery rates for Ag and Pd range from 84 per cent to 96 per cent and 80 per cent to 98 per cent, respectively. This trend is attributed to the increased emulsification of copper droplets containing Ag and Pd in the slag. The emulsification is caused by the decrease in the settling velocity of the copper droplets due to the increased viscosity of the slag as well as by the decrease in the slag-metal interfacial tension due to an increase in sulfur content at higher mixing ratio of spent catalyst.

Jun 19, 2024