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By E J. Hofmann, J E. Hofmann, A J. Hofmann-Fritz

"With its Head Quarters in Perth, global heavy engineering company Hofmann Engineering is one of the largest family owned engineering companies in Australia. The company has pioneered a number of new manufacturing processes and design improvements for components of large comminution equipment.Some of these innovations are: Innovative design improvements of high pressure grinding roll (HPGR) forged steel tyres. Hofmann Engineering has developed unique patented tungsten carbide stud and edge protection designs which improve wear life and introduce quick and cost effective replacement options to further extend the life of the tyre. Development of forged fabricated mill heads using rolled and welded high tensile steel plate as an alternative to cast conical mill heads. Establishment of Australian capability to manufacture and export up to 42 ft. (12.8 m) diameter SAG mill shells. Techniques for fast track, product improved replacements of cracked or damaged mill gears, including in situ profile & wear measurements of girth gears using portable coordinate measuring machine (CMM) technology, forged rim steel and induction hardening technology. Gear and pinion mechanical drive designs to 24 MW or higher for SAG mills of 38 ft. to 42 ft. (11.6 m - 12.8 m) diameter as reliable alternatives to gearless drives.The paper presents case studies from the Australian heavy manufacturing facilities of Hofmann Engineering on large, high powered equipment for both the domestic and export markets.CITATION:Hofmann, E J, Hofmann, J E and Hofmann-Fritz, A J, 2013. Australian innovations in high pressure grinding rolls and large grinding mill manufacture, in Proceedings MetPlant 2013, pp 141-151 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 15, 2013

This modern plant consists of a battery of 72 Otto Wilputte Compound Under-jet Ovens with extensive plant for the recovery by-products. The ovens produce 9000 tons of furnace coke per week together with some 17,000,000 cub. ft. of coke oven gas, which is used for heating purposes throughout the works and for heating the ovens.Coal is supplied from the, company's colliel'ies and is stored under a Coal Handling Bridge of 264 ft. span and 365 ft. overall, capable of handling 250 tons per hour. The coal storage space of 1600 ft. can. be extended to a maximum of 2800 ft.Preparation of the coal for coking involves fine grinding which is carried out as follows:-Coal is dumped from rail waggons on to a conveyer belt which delivers it to a 12 ft. x 22 ft. Bradford Breaker, with a capacity of 400 tons per hour. The coal, then approximately 4 in. in size, passes, to the mixing bins; and after careful blending is reduced in the,hammer mills to a fineness suitable for the ovens.The fire coal is elevated to the main storage bin over the battery for subsequent charging by electric larry car. The average cokingtime is 15 hrs. 36 mins. At the end of ,this period the doors, are removed and the coke pushed from the oven by a mm. The coke, is, then quenched with fresh, water and sent to the Blast Furnace in 50-ton Copper Waggons.The gas is exhausted from the ovens by Brown Boveri turbine, exhausters of 23,000. cub, ft, per min. capacity. Exhaust steam from these is used for various. purposes in the By-Product plant. After removing the last traces of tar by Electrostatic Precipitators', the gas is bubbled through sulphuric acid, the ammonia forming ammonium sulphate, which is subsequently washed, dried and bagged for sa,le as a fertilizer. The gas then goes to the Benzol Scrubber Towers, where benzol and other derivatives are recovered and later redistilled and purified. The cleaned gas is then piped to the main works for heating purposes, being used with tar to fire the steel furnaces, and also the soaking pits and reheating furnaces.BLAST FURNACES.The company is at present operating two Blast Furnaces of 800, and 1000 tons nominal daily capacity respectively. The latter was...

Jan 1, 1938

By V. J. McSweeney

This paper is directed at interested parties outside the Beach Sand Industry : the scope is quite broad. The geomorphology described is a successful working hypothesis which guided the author during prospecting and pegging campaigns : the author is not an expert in this field. The test data used in the text, for illustrative purposes, is original and may constitute a contribution to the state of the art. The operation- al and design philosophy embodied in the text is personal and describes the author's methods : all practising exponents would differ in some degree amongst themselves on these subjects. In this paper, no criticism of any existing operation or brand of equipment is intended and names are used to maintain a real contact with the subject matter. The author believes that the operational and design techniques evolved in the Beach Sand Industry under continual duress, have a wider application in the mining industry. This glimpse of the Industry is intended to enhance the respect for the present and past members. Space does not permit individual acknowledgements.

Jan 1, 1982

By John V. Beall

As recently as 1964, the situation in the Australian iron ore industry was chiefly one of potential. The only producer was the Broken Hill Pty. (BHP). That company mined about 5 million tpy from deposits in the Middleback Range in South Australia and at Yampi Sound in Western Australia. No ore was exported from Australia. Now, just five years later, and after expenditures amounting to approximately one half billion dollars, BHP and seven new companies exported about 15 million tons (long tons) of iron ore and pellets as well as meeting Australia's own annual requirements of approximately 8.5 million tons of ore. Early this year, the volume of iron ore on order stood at 328 mil- lion tons to be delivered over a period of 15 years, but Cliffs Western negotiations for sale of Robe River iron ore have boosted the volume to the new high of 466 million tons. All of this has meant a great deal to Australia in terms of new income. In fiscal year 1967 (ending June 30, 1967) exports of iron ore amounted to $52 million; in 1968, $128 million and by 1'972 the Bureau of Mineral Resources expects the value of exports from iron ore to reach $242 million. In achieving the position of major- supplier of iron ore to the Japanese steelmakers, it was necessary to build a great many new facilities, mostly in Western Australia. Three railroads, 70 miles long, 182 miles and 265 miles were constructed. A new port was created at Dampier; Port Hedland was deepened and otherwise improved; both of these ports are in Western Australia. In Tasmania, Savage River developers built an offshore shiploading station that has received the recognition of engineers internationally. At least a half dozen new communities have been founded. The narrow gage railroad from Kalgoorlie to Perth and Freemantle was replaced with a standard gage line.

Jan 6, 1969

By Patrick J. Williams, Peter J. Pollard

"Abstract - Enigmatic hydrothermal vein/breccia/replacement Cu-Au deposits with magnetite and/or hematite are well-represented in Australian 1850 Ma to 1500 Ma terrains and associated with different-aged synorogenic intrusions in the Tennant Creek Block (ca. 1850 Ma); the Gawler-Curnamona region (1640 Ma to 1590 Ma); and the Cloncurry district (Mount Isa Eastern Fold Belt, 1540 Ma to 1500 Ma with a possible earlier event at ca. 1600 Ma). No deposits are known to be coeval with various 1780 Ma to 1610 Ma anorogenic intrusions. Deposits are hosted by many different rock-types with varying metamorphic grade including granites and various supracrustal rocks. Depth of mineralization varied from many kilometers in semiductile crust (e.g., Cloncurry deposits) to very shallow (e.g., Olympic Dam). Ore deposition near Cloncurry occurred in brittle-ductile shear zones from geochemically variable and complex, CO2-rich, 300°C to 500°C, high salinity fluids with magmatic stable isotopic signatures. Recently published studies of a giant granitoid-hosted magnetite vein complex at the Lightning Creek prospect (>1000 Mt magnetite) suggest it is a product of internal differentiation and endogenous Fe and Cu-rich hydrous-carbonic fluid phase generation within a quartz monzodiorite-monzogranite intrusion. Coupled with other field relationships, this points to a possible genetic relationship with intermediate (55 to 65 wt% SiO2) members of an alkaline and partly shoshonitic granitoid supersuite which appears to have both mantle and crustal source components from ?Nd evidence. In constrast, main-phase mineralization at Olympic Dam in the Gawler Craton is distinguished by hematite-phyllosilicate alteration and chalcopyrite-bornite-chalcocite zoning, reflecting fluid mixing in a high level (<250°C) system with a probable large component of meteoric water. Early high-temperature parageneses and fluid inclusions imply that the extensive hematitic breccias overprinted an older magnetite system which may have had similarities with those at Lightning Creek and Ernest Henry in the Cloncurry district.Deposits of this family are inherently difficult to find and evaluate as even within a single district, there is no reliable relationship between the location of ore and any specific combination of geophysical characteristics. Diverse alteration assemblages, geochemistry and physical characteristics suggest the deposits reflect the interaction of multi-sourced fluids with different host rocks in a wide range of geological environments. Recent discoveries and research in the Cloncurry district have extended the range of deposit models available and aid the development of a rudimentary classification in which economic and exploration characteristics can be linked to variations in the mechanisms and environments of ore formation."

Jan 1, 2001

By Jaques A. L, Heinrich C. A

Mt Todd lies towards the south end of the Pine Creek Geosyncline, sandwiched between the Cullen Batholith and the Edith Falls Basin, in an area of regionally metamorphosed sandstones, siltstones and shales. The Batman deposit, some 3 km west of Mt Todd is a sheeted quartz vein system hosted within greywackes of the Palaeoproterozoic Burrell Creek Formation (Finniss River Group). The gold-bearing quartz veins, trending 010¦-020¦ and dipping 60¦-70¦E, are commonly 0.5 to 5 cm wide and occur at intervals which are from 10 cm to 1 m apart. Gold tends to be restricted to the quartz veinlets and immediately adjacent country rock. Grade Control utilises two 4 m &apos;collar&apos; samples which are collected from each 8 m production blasthole. The irregular distribution of the quartz veins and erratic gold mineralisation has resulted in a disseminated &apos;salt and pepper&apos; type of gold occurrence, with only a poorly defined footwall. Delineation of ore and waste blocks for mining uses an approach which combines the smoothing effect of kriging with a pragmatic view of the raw data. Large ore blocks with simple geometry help to minimise mining dilution, reduce block variance and give good reconciliations to interpreted ore tonnes and grade. Daily mine face advance is reported against truck counts and provides continual comparison with budgeted production. All data processing uses Gemcom software, together with Lotus spreadsheets.

Jan 1, 1994

By C A Heinrich, Jaques A. L, L A I Wyborn

Most orebodies have cross-sections of less than I km2 and hence do not offer a particularly large target for exploration. Fortunately, although in the geological record ore deposits are small and rare and result from the exceptional coincidence of certain geological processes, these processes are mappable on a much larger, district to regional scale and constitute a mineral system in which the ore deposit is the central feature. A mineral system can therefore be defmed as 'all geological factors that control the generation and preservation of mineral deposits, and stress the processes that are involved in mobilising ore components from a source, transporting and accumulating them in more concentrated form and then preserving them throughout the subsequent geological history'. The mineral system concept emphasises that for many ore deposit types, although economically viable mineralisation may only occur on a scale of say, hundreds of metres, the total system offluid-rock interactions that led to ore formation can extend over a distance of tens to hundreds of kilometres around the deposit. When mapped out, the total mineral system provides a far larger exploration target than the actual ore deposit itself. Important geological factors defining the characteristics of any mineralising system include: I. sources ofthe mineralising fluids and transporting ligands; 2. sources ofthe metals and other ore components; 3. migration pathway; 4. thermal gradient; 5. energy source; 6. a mechanical and structural focusing mechanism at the trap site; 7. chemical and/or physical traps for ore precipitation. Many of these factors individually are common through

Jan 1, 1994

By K Williams, G M. Evans, S M. Iveson, K P. Galvin, C E. Loo

The Australian Research Council (ARC) has recently established an Industrial Transformation Research Hub in the area of iron ore, focused on iron ore characterisation, beneficiation, materials handling and end-use functionality. The research hubs are part of a new initiative aimed at building stronger relationships between industry and universities, while addressing issues of national significance. The ARC Research Hub for Advanced Technologies for Australian Iron Ore will focus its attention on developing innovative approaches for creating enhanced value across the full value chain through the characterisation of different ore types, beneficiation and materials handling and transport. This hub brings together five industrial organisations and a research team formed from well-established research groups based at the Newcastle Institute for Energy and Resources. These groups have a record of working closely with industry to create opportunities. Examples include new beneficiation technologies such as the Reflux Classifier for achieving gravity separation, the expertise of TUNRA Bulk Solids in materials handling and the Iron Making Centre at Newcastle, which is a capability maintained by BHP Billiton following the closure of its Technology Centre in 2009. The purpose of this paper is to provide an outline of the research hub and its objectives, some background on the research groups that now form the hub and an insight into the strategy adopted for developing and implementing new technologies. The paper also describes a range of novel technologies that have the potential to be developed and applied to iron ore beneficiation.CITATION:Galvin, K P, Roberts, A, Loo, C E, Evans, G M, Williams, K and Iveson, S M, 2015. Australian Research Council research hub for advanced technologies for Australian iron ore – an introduction, in Proceedings Iron Ore 2015, pp 7–12 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By R Daiyan, G Burge, M Haider Ali Khan

Australia’s mineral and metal exports have a substantial carbon footprint, twice that of its domestic emissions, mainly due to fossil-fuel-dependent downstream processes like processing into secondary metals and their transport. The country’s vast renewable energy and low-carbon hydrogen potential offer a promising alternative to mitigate this impact. These resources can be leveraged to displace fossil fuel use and become embedded into the metals value chain. Ultimately, it will yield ‘Green Metals’ that can be scaled to reduce the environmental footprint and provide an avenue for Australia’s vast green resources to be embedded (incorporated during production and supply) in green metals that can be exported. One potential green metal is copper, which is in great demand and likely to drive global decarbonisation through renewable electrification due to its role as an energy conductor. Given that Australia is a large producer and exporter of copper, this paper provides a techno-economic model of the copper value and applies it to Queensland (a hub of Australia’s copper production) as a case study. The results show that under incumbent hydrogen (A$8/kg) and renewable energy costs, the cost of green copper would be A$9704/t (~10 per cent higher than current copper costs). Further analysis revealed that the cost of hydrogen is a major cost driver; therefore, if the cost of hydrogen can be reduced to A$2/kg (a 2030 target of the Australian government), the cost of green copper would become competitive. Furthermore, if a carbon pricing regime ($54–79/kgCO2) is introduced, green copper would become competitive at a hydrogen cost of A$3/kg. Altogether, these findings provide insights for a future green copper export opportunity in Australia. Additionally, as the next step, the model can be extended to include other metals and released as an open-source resource for assessing global green metal opportunities.

Sep 1, 2024

By Horst Pöchhacker

The largest structure along the Tauern highway section between Salzburg and Villach is the 6.4-km-long Tauern Tunnel. The major geotechnical problems that came up surprisingly while driving the headings of that tunnel and their successful solution form the content of this article. A detailed discussion is presented of the special construction methods developed by systematic application of the principles of the New Austrian Tunneling Method with which even very heavily squeezing ground with large excavation areas can be mastered reliably and economically.

Jan 1, 1976

By Sara Moshfeghi, Seyyed Majdeddin Mir Mohammad Hosseini, Abolfazl Eslami

"Due to variety of current pile bearing capacity methods based on the cone penetration test (CPT), for optimum design, it is necessary to evaluate the performance of such methods in different geotechnical conditions. Geotechnical databases including piling and in-situ testing records have been recognized as useful tools for analysis, design and economical construction. In order to evaluate pile bearing capacity methods, AUT-CPT&Pile database has been compiled including 450 full scale pile load tests and CPT sounding records. This database consists of different pile types with a relatively wide range of geometries and various soil conditions. Forty three records of piles driven in sand deposits were then employed to evaluate effects of ultimate capacity interpretation criteria from load displacement diagrams. The Davisson offset limit criterion, the Brinch Hansen 80% criterion and the load at the displacement of 10% of the pile diameter were compared to estimated capacities from ten CPT based design methods currently used in practice. The Brinch Hansen 80% criterion and the load at the displacement of 10% of the pile diameter lead to reasonable results, the Brinch Hansen 80% criterion showed less scatter. For evaluating the accuracy and the precision of CPT-based methods, the results were compared to estimated capacities. Results of comparison indicate that the CPT-based methods mainly predict the pile capacity withreasonable accuracy.INTRODUCTIONAmong the different approaches of estimating the pile bearing capacity, in-situ tests, especially, the cone penetration test (CPT) are favored due to the cone similarities with piles in modes of installation as well as fast and continuous profiling. This trend is practically well established where deep foundations are to be constructed in soft to medium subsoil deposits (Eslami and Fellenius, 1997; Mayne and Niazi, 2009).Employing different design methods results in a wide range of values which complicates the selection of an appropriate one to determine the pile bearing capacity. Several studies by Briuad and Tucker (1988), Eslami and Fellenius (1997), Abu Farsakh and Titi (2004), Schneider et al. (2008) and Eslami et al. (2011) confirm disparity of different design methods predictions. Thus, for optimum design, it is necessary to evaluate and compare the performance of current methods.Geotechnical databases are known as helpful tools in research and practical applications for optimizing analysis and design and are mainly used for management and interpretation of data, evaluation of design methods, calibrating LRFD or ASD design factors, etc. Pile lateral and axial load tests are examples of databases in geotechnical engineering. A summary of several CPT and pile load test databases is presented in Table 1."

Jan 1, 2017

By D. G. Krige

D. G. Krige: The stimulating contributions from Messrs Cooke, Curtis, Martus, Johnston, Van Wyk, Van Rensburg and Wroth are appreciated by the author and provide clear evidence of the importance not only of the principle of assistance to gold mines, but also of its scope and form. In general all the arguments, raised by Messrs Cooke, Martus and Johnston in favour of extending the scope of the new assistance scheme can be accepted as sound.

Solvent loading: It is agreed that it is advantageous, as far as reagent cost is concerned, to operate at maximum solvent loading. However, owing to the fact that no reliable automatic solvent flow controller is yet available, control tends to be erratic with the result that there is risk of losing uranium. As can be seen from Mr Tunley&apos;s plot, the graph representing total ammonia cost is fairly flat between loadings of 3.5 and 4.0 gpl, while the graph representing uranium loss in the raffinate is steep. It is, therefore, safer to operate slightly below optimum loading in the absence of absolute control. Should the purity of the final product gain importance, operation at optimum loading or even slightly above, may be advantageous. Solvent losses and clarification of pregnant solution: The cost of replacing solvent, as indicated by Mr Carman, represents a high percentage of the overall Purlex costs. It is, therefore, agreed that, amongst other factors, efficient clarification of the pregnant solution and mixer-settler design have an important bearing on the cost. However, as at Blyvooruitzicht, the Buffelsfontein plant can tolerate a suspended solids content of 50 ppm without serious deterioration in efficiency. An increase in the suspended solids content from 15 to 50 ppm normally accounts for an increase of approximately 1 ppm in amine loss. Clarification of acidic pregnant solutions is much more difficult than that of alkaline solutions. Sand clarifiers are being used at Buffelsfontein with moderate success. Clarified solutions containing less than 20 ppm of solids in suspension can be produced, depending on the quantity and type of flocculant used in the filtration process, the thickness and the grading analysis of the sand beds and the quality of supervision. An on-stream duty of approximately 0.15 gallon per sq ft of surface area is obtained. Hydraulic handling of clarifier sand, while cleaning, may effect the efficiency of a clarifier, as size segregation of sand particles may lead to inefficient "pockets" in a sand bed. Control of the solution level in the sand clarifier also affects the quality of the effluent. Exposure of the sand bed invariably causes a cloudy effluent. Recycling of the final and initial solution discharged before and after skimming the clarifier sand improves the clarification efficiency significantly. Post-precipitation of silica and possibly sulphate salts, after clarification, may give a false impression of inefficient clarification. This phenomenon is more pronounced when treating hot supersaturated solutions. Ageing and cooling of the solution before clarification assist in stabilising the solution and reduce precipitation after clarification. The maintenance cost of sand clarifiers at Buffelsfontein is in the order of 0.35 cent per metric ton of solution treated. A redundant ion-exchange column has been tested successfully, either as a primary or a secondary clarifier, depending on the quality of the filtrate treated. The conventional pebble and sand beds in the column have been retained. Operation was enhanced by the addition of a two-foot deep resin bed as a filtering medium. The suspended solids content was reduced to less than 5 ppm. Mixer-settlers: Mixer-settler design is a controversial subject but, in view of the high costs of solvent compared to relatively low pumping costs, it is believed that mixing and pumping functions should be separated. Separate facilities for pumping and mixing not only give greater operational flexibility but also permit eventual changes in the flow circuit as technology develops. Scrub technique: Unlike the pilot plant, where the crud was carried away in the aqueous phase, crud is carried over with the organic phase in the full-scale plant. This carry-over of crud into the strip bank aggravates crud formation in the first strip stage. This phenomenon may result from a slight difference in settler design and/or a variation in the relative phase depths in the two plants. Bypassing of the scrub aqueous solution from the fourth to the second stage was introduced in order to avoid dilution and partial neutralisation of the acid added to the third stage, as it is known that a low pH value enhances the transfer of iron into the aqueous phase. The low aqueous flowrate in the third scrubbing stage was overcome by introducing an aqueous phase recycle. Gleaning: Mr MacDonald&apos;s contribution on "gleaning" was most informative. This process for recovering solvent from raffinate seems to show at least as much promise as coalescers and other methods employed to date. Similar tests conducted at Buffelsfontein pilot plant gave 60 per cent amine recovery from raffinate containing 10 ppm amine. However, the circuit was not operated at equilibrium and recovery may be expected to drop as the amine concentration of the "Gleaner" circuit increases.

Discussion of the paper of R. J. COLONY, presented at the New York Meeting, February, 1921, and issued With MINING AND METALLURGY No. 169, January, 1921. R. J. COLONY (author&apos;s reply to discussion).-The work of Sosman and Merwin on the system lime-ferric oxide, mentioned by Mr. Rankin, was not overlooked. When studying portland cements and portland-cement clinkers petrographically, however, the lime-iron compound was difficult to correlate with the very definite dicalcium ferrite described by those investigators, which possesses such well-defined optical properties. In portland cements, the calcium ferrite (or ferrate?) is an indefinite, fuzzy, and generally amorphous, or apparently amorphous substance that is distributed interstitially with respect to the other grains, from which it was very difficult to derive any satisfactory results. For this reason, the writer, tentatively, chose to regard it as related to the aluminate, and assigned to it the composition 3CaO.Fe203, which may be incorrect, however, as Mr. Rankin suggests.

Jan 8, 1921

Jan 1, 1947

Jan 1, 1947

By H. Arima, Y. Kudo

In general, the iron content of zinc leach residue produced by sulphuric acid leaching from calcine is disposed as jarosite or goethite into a tailing dam. More recently, these iron residues have been treated pyrometallurgically to avoid waste disposal. The Iijima refinery selected a different zinc leach residue treatment process for iron control when it was established in 1971. The Iijima refinery is the only plant in the world that has processed a zinc leach residue by the combination of SO2 pressure leaching and O2 pressure hematite precipitation. The process enhances zinc recovery and recovers gold, silver, copper, lead and rare metals in saleable by-products. This paper focuses on the two stages of autoclave application in the zinc leach residue treatment process. The detailed flowsheet and recent advancements to improve the quality of by-products are discussed.

Jan 1, 2004

A comprehensive understanding of the effects of autoclave configuration (batch, semi-batch, continuous) on the residence time necessary to achieve a target conversion is a prerequisite for design of commercial scale autoclaves. Particle size distribution, mineral and reagent concentrations, temperature and mixing also influence the conversion. This paper outlines the bases of using test data to predict performance of commercial scale autoclaves. Recommendations for coordinating test program design with selection of scale-up method are provided. Examples are given to illustrate the different levels of engineering effort needed to meet corresponding levels of design optimization and accuracy.

Jan 1, 1998

By I. Farr, M. R. Mock, J. C. Robison

"HPAL and POX autoclave vapor-space gasses are vented through an autoclave PCV (Pressure Control Valve). The downstream steam-born mist of liquid droplets and solid particles travels in excess of 1000 m/s with megawatts of kinetic power at temperatures up to 160 C. The characteristics of downstream states often result in problems with corrosion, erosion, noise and vibration. Comprehension of those and related characteristics aids in improved pressure control, overpressure control and autoclave level control. We introduce compressible multiphase flow concepts and constructs germane to such flow including choked flow, continuous phase change, shock waves and supersonic flow plumes. Flow modeling based on first principles quantitatively predicts such flows providing a tool for component sizing and a method to estimate effects of water injection on flow. Insight deduced from modeling aids in mitigation of afore mentioned problems of which we share some from-site examples.INTRODUCTION First principles related to fluid thermodynamics and compressible flow have been employed akin to their application in the rocket industry. We will present the results of the application of those principles conceptually and authentically without mathematical rigour while using language of the pertinent disciplines. The autoclave (AC) vapor space over the slurry of a POX (Pressure Oxidation) or HPAL (High-Pressure Acid Leach) system (depicted in Figure 1) is vented via a PCV (pressure control valve) followed by certain ducting, and perhaps a nozzle, before exiting at atmospheric (typically) pressure. As indicated by its name the PCV controls the AC pressure as the flow control component of a pressure control loop."

Jan 1, 2017

By Claudio Acuña, Sergio Romo, Gerardo Fuentes

The leaching kinetics of a zinc concentrate in autoclave reactors were studied. A sample of concentrate from Bolivia, with typical mineralogical characteristics of the Andes region, was used. A concentrate containing 49% zinc and 145 ppm of silver from Minera Viacha was characterized chemically and mineralogically (atomic absorption, X-ray diffraction, and SEM microscopy) and tested in bench scale reactors. Two types of autoclave batch reactors were used at 40 bars of oxygen pressure and three levels of temperature (150°C, 200°C and 250°C). The solid to solution leaching ratio was 1:10 (10% sulphuric acid concentration). The effect of the particle size of the concentrate on the leaching kinetics was studied (P80: 145 and 45 µm). Iron from the leaching solution was removed by precipitation by increasing the pH in order to generate a clean solution for zinc electrowinning. The zinc solution was used to evaluate the feasibility of cathode production at the laboratory scale. Zinc extractions with higher liberation (P80 = 45 µm) reached up to 98%. Ground concentrate with finer sizes resulted in agglomeration and the use of dispersing agents did not improve slurry mixing. The leaching solution contained 55 g/L zinc and 7 g/L iron; it was purified by precipitating iron. The precipitation was evaluated using sodium hydroxide and ammonium hydroxide. In the first case, a colloidal suspension of ferric salts was formed while in the second case, different iron compounds were precipitated. The precipitate obtained with ammonium hydroxide had better filtering properties. Electrowinning was carried out using two types of cathodes (stainless steel and aluminium) and solutions purified with ammonium hydroxide. Zinc cathodes formed on stainless steel presented a better physical quality than those formed on aluminium.

Jan 1, 2015