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By Zhucheng Huang, Zhikai Liang, Ronghai ZHONG, Lingyun Yi

In this work, research of reduction process was studied by means of rotary kiln (u1.5 m /C215 m) process anatomy in order to provide fine guidance to large-scale operation. It was shown that the average reduction degree of 89.96% and metallization ratio of 85.15% were obtained at the highest temperature of 977°C and total residence time of 90 min. The generation amount of metallic iron in section of temperature higher than 900°C and lower than 900°C was 34.15 and 56.38%, respectively. The section of lower temperature of 830–900 °C played an important role in formation of metallic iron, making it possible for mini-pellet to reduce quickly at lower temperature. Two main tasks were completed for mini-pellets in rotary kiln: the reduction of iron oxides in the range of 15.0–4.5 m as well as migration and bene ficiation of metallic iron, facilitating the subsequent separation of iron and gangue minerals.

Mar 1, 2018

By Xi-Shan Li, Qian Li, Yong-bin Yang, Li-na Cui, Tao Jiang, Jie Ge

"With regard to control environment pollution in the roasting pretreatment of sulfur & arsenic-bearing gold concentrate, roasting of double-layered pellet was proposed. In the paper, the characteristics of double-layered pellet roasting were studied. Removal and solidification rates of sulfur and arsenic were investigated as primary factors. The result indicated that the removal and solidification rates of arsenic reached up to 95.91 % and 98.95% while the sulfur was 97.19% and 97.90% respectively on the premise of adopting slaked lime as solidified agent at temperature of 6000, the package proportion of 2.14 and roasting time of 3h. However, pyrite and arsenopyrite were transformed to hematite and magnetite and product of solidification mainly consisted of calcium sulfate, calcium arsenate and calcium sulfite within optimum roasting parameters.IntroductionUtilization of refractory gold resources has been gradually concentrated on with the depletion of the gold resources which are easy to deal with in the world [1]. Sulfur and arsenic-bearing gold ore is a typical refractory gold one, in which ultrafme gold is encapsulated in the structure of metal sulfide minerals [2,3], so it gives poor recovery through direct cyanide leaching. These refractory ores need pretreatment before the process of cyanide leaching to undermine lattice structure of pyrite and arsenopyrite containing gold [4] so that the gold could touch with cyanide solution [5]. Among various methods of pretreatment, conventional roasting method is most effective, but this process generates gases such as S02 and As203 harmful to environment. Therefore solidification roasting was proposed to solve this problem occurring in the conventional roasting at the end of last century."

Jan 1, 2013

By Zhiqiang Han, Anil K. Sachdev, Baicheng Liu, Guomin Han, Alan A. Luo

The growth of precipitate phase ,B-Mg11Al12 in Mg-Al alloy is closely related to interface anisotropy and elastic interaction. The aim of this work is to investigate the effects of the interface anisotropy and elastic interaction on the morphology evolution and growth kinetics of the precipitate. In the work, the precipitation of ,B was studied using phase field modeling. In the model, the chemical free energy of the precipitate and the matrix were obtained via thermodynamic calculation. It is demonstrated that the interface anisotropy results in lath-shaped precipitate and the elastic interaction affects the shape of the end of the precipitate. The interface anisotropy causes uneven growth in different directions and the elastic interaction influences its preferential growth orientation. By combining the interface anisotropy and elastic interaction in the phase field modeling, the results showed that the precipitate phase has a lath-shape with lozenge ends, which is in agreement with experimental observations.

Jan 1, 2013

By T. X. Hu

Pyrite ore is one of the main raw materials in the production of sulfuric acid. For a long time, the raw material containing the pyrite, which is used to produce sulfuric acid, generally contains S only 32%~45%. A plenty of residue from the sulfuric acid production contains 40%~50% Fe and 1%~2% S. Some of the residue also contains Cu, Pb, Zn and other harmful elements like As, thus it pollutes environment seriously and is solid waste. The research on comprehensive utilization of the residue has been made by many scholars. Through the study, the residue can only be used to pro-duce iron concentrate and the iron oxide red pigment. But because of the complex techniques, the low recovery, the low grade of iron concentrate , high sulfur in iron concentrate, causing second waste residue and the environmental pollution, the residue is mainly used as an accessory material in the production of cement, and is of a low value. Therefore, the iron resource in pyrite has not been used efficiently until now. In the paper, the flotation condition test, the flotation open circuit test and the flotation closed circuit test to produce high-purity pyrite concentrate with the low-grade pyrite ore in oceanic ore deposit have been carried on. Flotation reagent scheme of sulfuric acid used as activator and butyl xanthate as collector is determined. After four times depth cleaning, high-purity pyrite concentrate containing 52.82% S, 44.29% Fe, and only 2.89% impurities has been obtained. The S recovery is 99.13%, and the Fe recovery is 96.00% in the high-purity pyrite concentrate. The oxidizing roasting depth desulfurization experiment of the high-purity pyrite concentrate has been conducted. The results show that the Fe grade in the residue obtained is 68.58%, the content of S is 0.25%, the content of P is 0.0084%, the content of As is 0.0065%. The residue is a kind of high-quality iron-smelting raw material. Based on the above experiments, the industrial experiments on producing high-purity pyrite concentrate with the low-grade pyrite ore, and producing sulfuric acid and iron concentrate with high-purity pyrite concentrate have been done. The results indicate that the high-purity pyrite concentrate with the S grade of 51.24%, the Fe grade of 44.15% has been obtained. The iron concentrate obtained with 65.73% Fe and 0.23% S is a sort of high-quality iron-smelting raw material applied to the production of steel and iron smelting. Through the experimental study, the sulfur and iron resources in the pyrite ore have been recovered and utilized efficiently.

Jan 1, 2014

By Jong Hyeon Lee, Go-Gi Lee, Chang-Kyu Lee, Hong Youl Ryu, Sung-Koo Jo

This study deals with research on the reduction process of neodymium oxide by molten salt electrowinning. Neodymium fluoride and lithium fluoride electrolyte were used for feed stock of electrolyte and neodymium oxide was added as precursor. Cell current was confirmed that cell potential was applied as constant potential of 4.5V. Argon gas injection into the electrolyte was carried out to confirm convection effect on current efficiency. Applied current was gradually decreased without argon flow, but applied current was kept within a certain range with argon flow in electrolyte.

Jan 1, 2015

By Jing Zhan, Tian-zu Yang, Wei-feng Li, Li-Hua Jiang, Shi-yan Xu, Jian-yang Huang, Chuan-fu Zhang, Yan-qing Fan

The amount and activity of coal, reduction temperature and other parameters of the process of bottom-blown reduction of liquid high lead slag were investigated in laboratory. Methods to strengthen the bottom-blown reduction process were studied by industrial production. The results were in the follows: the reduction temperature was 1150℃; reduction time was 1.5h; the reductant was anthracite; lead content in slag was controlled to 2%; the rate of coal was 7% and gasification loss of coal in high temperature was severe; liquid lead slag reduction rate was faster with coal; prolonging the reaction size had little effect on reducing lead in slag; the size of the reactor can be further reduced.

Jan 1, 2015

By Han Xing, Cui Jianzhong, Qin Ke, Shao Bo, Zhang Haitao

In this paper, a new approach that uses hot-top DC casting process to producing multi-alloy ingots is present. The different type and size of composite and coated ingots (4045/3004/4045 three-layer composite ingots with section 630mm by 1500mm and 4045/3003 coasted ingot with F140mm/F110mm in diameter) are cast by this approach. The macro-morphologies and microstructures of the composite ingots, the temperature distribution and the element distribution in the interface zone were investigated, also and the interface bonding strength was measured. Results show that the solid supporting layer formed on the cooling plates plays a key role in the casting process of composite ingots. The solid supporting layer can prevent the blending of two melts by resisting the impact of alloy melt, which ensures the stable casting process and casting high quality composite ingots, because the contact height is increased using hot-top DC casting. In addition, fabrication and properties of 4045/3004/4045 three-layer composite ingots with section 630mm by 1500mm are reported in detail.

Jan 1, 2015

By C. L. Peng, F. F. Min, S. X. Song

"Using a parameter representing the degree of hydration of particles in a liquid called hydration index I, which we derived based on Einstein’s viscosity equation, we evaluated the degree of hydration of fine montmorillonite particles in different aqueous solutions by measuring the viscosities of the montmorillonite dispersions and plotting relative viscosity against volume fraction of dry montmorillonite particles in the dispersions. We investigated the effects on the hydration of montmorillonite in aqueous solutions of (1) the type and (2) the concentration of electrolytes in the solutions and (3) pH. For the same concentration of electrolytes, the hydration index I of montmorillonite was found to increase in the order of Na+ > K+ for monovalent cations and Mg2+ > Ca2+ for divalent cations, and to decrease with increasing valence of cations in the order of Na+ > Ca2+ > Al3+. For both Na+ and Ca2+, the hydration index I first increased with increasing concentration of electrolytes and then decreased after a certain concentration. The hydration index I increased with increasing pH. IntroductionClay minerals have the distinctive ability to adsorb water molecules and hydrated cations in aqueous solutions, resulting in hydration on their outer surfaces and in their interlayer spaces. Many investigators (Jurinak, 1963; Anderson and Tice, 1971; Costanzo et al., 1982; Israelachvili, 1992) had found evidence of ice-like structures of water on clay minerals.This phenomenon of hydration plays an important role in the dispersion and sedimentation of clay minerals in aqueous solutions. To understand clay hydration, numerous experimental and simulation studies have been carried out since 1933, including the recent ones of Hawkins and Egelstaff (1980), Skipper et al. (1995), Karaborni et al. (1996), Salles et al. (2013) and Morrow et al. (2013). Among the factors that can influence a clay mineral’s hydration characteristics are chemical composition, type and degree of isomorphous replacement in its structure, and number and nature of associated exchangeable cations."

Jan 1, 2015

A new short combined flow sheet including high intensity magnetic separation and flotation for a rare earth ore in Maoniuping deposit, China has been investigated. Massive conclusive results demonstrate, that it is critical to separate the ore by high intensity magnetic separation prior to flotation for tons of slimes and nonmagnetic gangue existing. The vital technological parameters affecting flotation have been studied in detail. Modified hydroxamic acid is an efficient collector for bastnasite flotation because of its high selectivity. Flotation results also indicate high temperature that play an unfavourable role on the recovery as well as the grade of bastnasite concentrate, when the rare earth ore is floated with modified hydroxamic acid and sodium silicate depressant. Bastnasite concentrates, averaging over 65 percent REO at an overall recovery of 82-84% is achieved by the new beneficiation technology. Keywords: bastnasite, REO, magnetic separation, flotation, chelating collector, desliming

Sep 1, 2012

By Tiejun Chun, Marcus Emrich, Jian Pan, Deqing Zhu, Vinicius Mendes

"Joint projects of studies of hematite acid pellet have been implemented to develop technological solutions for using Vale hematite pellet feed in Chinese palletizing plant. Beneficial improvements on the pellets quality were achieved by adjusting the blends composition and using new technology of pre-treating the blended pellet feed with HPGR (High Pressure Grinding Roller) on rotary kiln pellet technology. The drop strength of green balls increased from 3.4 to 6.0 times from 0.5m height, at the same time, the bentonite dosage decreased from 1.5wt% to 0.7wt%. The compressive strength of roasted pellets reaches 2500 N/pellet. The reduction swelling index of roasted pellets is below 15%.IntroductionWith the fast development of steel industry in China, the production of pellets has been further expanded. Pellets are used as a high quality charge for blast furnace and the annual output is around 80Mt pellets [1]. According to the developmental trend, sinter will be replaced by pellets due to the larger environmental impact of sintering plants when compared to pelletizing plants. For example, the specific CO2 emission in sintering process is around 2.5 times higher than in pelletizing process. However, the steel industry of China has been confronted with a serious shortage of domestic pellet feed due to the low iron grade of Run-of-Mine ore despite of huge reserves of iron ores [2]. Therefore, more pellet feed, mainly hematite, has been imported to make pellets."

Jan 1, 2011

By Guohua Bai, Lin Zhang, Shan He, Xuling Chen, Min Gan, Xiaohui Fan, Yanbin Tang

"For reducing the dust content in flue gas during copper smelting in the Ausmelt, technologies and mechanism of strengthening the pelletizing of copper concentrate were studied. The results show that adding bentonite, organic binder or composite binder can effectively enhance the strength of green pellet and reduce the rate of shedding powder in drying process, and composite binder works best. When adding 1 % of composite binder, the drop strength of green pellet increased from 1.9 times/P to 4.5 times/P, the rate of damage dropping from 2 m reduced from 50.12% to 13.08% and the rate of shedding powder reduced from 60.28% to 25.13% at drying temperature of 400111. In addition, the mechanism of binder absorbed in the surface of mineral was investigated by infrared spectroscopy. The results showed that composite binder absorbed in the surface of copper concentrate was in the form of chemisorptions, which made hydrophilic enhanced, while bentonite absorbed in the surface of copper concentrate was physisorption.IntroductionWith the technologies of copper smelting developing, the equipment of copper smelting steps into a large-scale and efficient level in recent years. As Ausmelt smelting is characterized by being efficient, environmentally-friendly and energy-saving, it is generally recognized by the enterprises of copper smelting [l]. The process of Ausmelt smelting starts with materials mixing, and then pelletizing. From this point onwards, pelletized balls are charged to the top of the furnace, undergoing drying and smelting reaction[2]. Since copper concentrate is fine-grained, directly adding into smelting furnace can make it blown out of the furnace together with the airflow upwards, rendering flue gas high in flue dust, which can cause the loss of concentrate greatly, and make smelting environment poor as well. The concentrate transported into the furnace and smelted after disc balling is conducive to improve the capacity of melting furnace during copper concentrate smelting, reduce the powder shedding rate and improve enterprise benefits."

Jan 1, 2013

By Guanyong Shi, Zhihe Dou, Cong Wang, Ting'an Zhang, Hongyan Zhang

We prepared the CuCr alloy by thermit reduction-electromagnetic casting. But there are the defects such as stomata and oxide inclusions in CuCr alloy. In this paper, the existing state and distribution of inclusions and stomata in CuCr alloy are systematically analyzed. The alloy was characterized via SEM, EDS and metallographic microscope, in which the existing state and micro-structural defects of inclusions are analyzed. The results show that: there are three distinct areas: copper-rich areas, chromium-rich areas and the inclusion areas. Inclusions are mainly in the form of stomata and Al2O3 phase, mainly locating in the copper-rich phase and the interface area of chromium-rich phase and the copper-rich phase. Then, the composition of phases of the smelting slags and alloy were characterized via XRD. The results show that: the slag consists of Al2O3 and a little of Cr, the alloy consists of Cr, Cu and a little of Al2O3.

Jan 1, 2015

By Ming Li, Li Ma, Yunqing Tian, Haoyu Cai, Luyao Zhao, Wenwang Liu, Wenbin Huang, Gele Qing, Yan Zhang

In this paper, study on the in fluences of different Ti-bearing materials on MgO-bearing pellets metallurgical properties was carried out. The results show that, pellets compression strength will decrease while using ilmenite. However, TiO2 reagents help to improve pellets compression strength. The reduction swelling decreases while using TiO2 reagents, but different ilmenites have diverse impacts on the reduction swelling. Pellets compression strength will decrease and reduction swelling will be improved while adding magnesium additives. In order to produce qualified Magnesium-Titanium bearing pellets, the firing temperature should be no less than 1270 °C.

Mar 1, 2018

By L. Yuan, J. H. Rowland, R. A. Thomas, D. Bahrami, G. P. Cole

"The past several decades have seen a steady increase in the use of atmospheric monitoring systems (AMS) in underground mines as sensor technology has advanced and costs for this technology have decreased. The AMS is a reliable tool for early mine fire warning by detecting gaseous products of combustion in underground mines. During a mine fire emergency, mine decision makers rely heavily on the prompt and accurate knowledge of the ventilation and fire situation in the mine, such as fire location, fire size, and the spread of smoke to make effective and efficient decisions on firefighting strategies and miner evacuation. Meanwhile, a prediction of the potential for fire development at a later time, such as whether the currently designated mine escapeways will be contaminated by smoke and toxic gases with the progress of the fire, is critical for effective decision-making to save lives that are in danger. The AMS monitoring data, including carbon monoxide (CO) concentration, airflow rate, smoke, etc., can provide information as to whether the smoke has reached the locations where AMS sensors are installed and if a mine-wide smoke spread has occurred. The National Institute for Occupational Safety and Health (NIOSH) has undertaken a task to integrate real-time AMS monitoring data with the mine fire simulation program, MFIRE, to simulate and predict the spread of smoke and toxic gas in a ventilation network based on the real-time AMS data. This paper reports the developed real-time method for characterizing the size and location of an underground mine fire and for predicting the spread of contaminants throughout the mine ventilation network using sensor data from the AMS.INTRODUCTIONNIOSH conducts research to develop workplace solutions to improve detection of and reduce the risk of hazardous conditions in underground mines. The advancement of senor technology and the increasing demand for real-time mine parameters monitoring have led to extended applications of atmospheric monitoring systems (AMS) in underground mines worldwide. In the United States, AMS is primarily used for early mine fire warning by detecting carbon monoxide (CO) in fire hazard areas, such as belt entries. Mine fires can grow rapidly, and time is the critical element. Prompt detection, timely and accurate warnings to those miners potentially affected, and a proficient response by underground miners can have a tremendous impact on the social and economic consequence of a small underground mine fire (Conti et al., 2005). The early detection of a mine fire could gain time for the first responders to put out the fire before it develops into a disaster. An AMS system with CO sensors has especially played an important role in the early detection of mine fires. The continuous monitoring of an underground mine atmosphere with an AMS could generate a large amount of data in a mine fire event. However, the current application of AMS is mainly limited to sending out an alarm when monitored CO concentration exceeds a certain level. An opportunity arises as to whether these data can be further used in fire emergency response. In order to make effective decisions on firefighting strategies, mine workers’ seeking refuges, evacuation and escape, and the timing on when to send rescuers, decision makers need accurate and timely knowledge of the ventilation and fire situation in the mine. Information about the fire intensity, where in the mine the smoke and toxic gases have spread, and whether designated mine escapeways have been compromised by smoke and toxic gases from the fire would greatly increase the effectiveness of these decisions. However, the monitored AMS data only provides atmospheric conditions in the vicinity of sensor locations. What is concluded from the monitored AMS data highly depends on the decision makers’ capability and experience. Predictive insight into fire growth and smoke transport would greatly help decision makers during a fire emergency."

Jan 1, 2019

By Z. D. Tan

The continuous digestion technological conditions of phosphate tailings with high magnesium content in sulfuric and phosphoric mixed acid is studied in this paper. The influences of excess coefficient of sulfuric acid, weight liquid to solid, reaction temperature and time on conversion of P2O5 and MgO are discussed. The influence of infiltration capacity of phosphogypsum by the concentration of liquid-phase SO3 is discussed too. Under the optimal technological conditions, the conversion of P2O5 is 95.56% and MgO 98.63%, the filtration rate of phosphogypsum increases with the increasing of liquid-phase concentration of SO3, the optimal apparent concentration of SO3 is 0.135~0.14g? mL-1 in liquid-phase. The filtration rate of phosphogypsum is 1473kg? m-2? h-1. N-P-Mg compound fertilizer was produced by adding magnesia powder and inflating ammonia in filtering medium.

Jan 1, 2014

By Neng-Wen Yu, Miao Wang, Ji-He Wei

The mass transfer characteristic between powder particles and liquid steel in the RH-PTB (Powder Top Blowing) refining has been investigated in a water model of 1/5 scale for a 90t RH degasser. The sodium chloride powder with analytical purity has been used as the flux for blowing. The mass transfer coefficient of the liquid side has been determined under the conditions of RH-PTB process. The influences of the main technological and structural parameters on the mass transfer rate have been examined. The results indicated that under the conditions of the present work, the mass transfer coefficient on the liquid side increases with raising the lifting gas blowing rate, inner diameter of the up-snorkel, circulation rate of the liquid and particle size of powder flux. And it decreases with an increase in the inner diameter of the down-snorkel. It is in the range of (l.36-7.30) x 10·4 mis, the appropriate dimensionless relationships have been obtained as follows:

Jan 1, 2000

By Xinming Chen, Huazhe Jiao, Qi Zhang, Yunfei Wang, Liuhua Yang

The effect of initial damage generated by weakly cemented interlayer surfaces on the physico-mechanical properties of layered cemented tailings backfill (LCTB) is considered for the interlayer inclination structure generated by multiple layered backfills in large-scale mining voids. Utilizing the theory of damage mechanics, the damage evolution and constitutive model of LCTB with interlayer inclination is constructed by considering the coupling of interlayer inclination effect and loading. Based on Mitchell’s mechanical model, we analyze the damage mechanism of the inclined cementation surface of LCTB, and derive the expression for the strength of LCTB considering interlayer inclination. The mechanical properties test of LCTB with different inclinations was carried out, and the results showed that the damage model of LCTB established was highly consistent with the experimental curves, which verified the correctness of the model. The initial inclination damage leads to the decrease of adhesive cohesion of cemented surface, and with the increase of inclination, the separation of layered surface, aggravation of misalignment, layered cemented surface is more prone to shear damage, and the mechanical properties of cemented tailings backfill in the lower part of layered surface are not effectively played, which reduces the overall performance of the material.

Nov 23, 2023

By Liu Jie

Refractory iron ore deposits in China have various genesis and complicated types, the nature of which is poor, fine-disseminated and complex. Therefore, refractory iron ore could scarcely be separated and utilized by traditional mineral processing technology at present. It is necessary to explore deep reduction technology to change the characteristics of refractory iron ore and to use effectively the iron resource. And deep reduction technology is that on the condition of higher reduction temperature than that of magnetic roasting and stronger reducing atmosphere, the iron oxides from iron ore was reduced to metallic iron particle that is easy to dissociate. And then production from deep reduction is easily separated by magnetic separation and iron powder production was obtained finally. Deep reduction technology for Lingyang iron ore from Jilin, China, as the refractory iron ore, was studied in this paper. The influences of such main factors as reduction temperature, time and coal content were investigated. The results showed that the Metallization rate of reduction product was up to more than 90% under optimum conditions, and then higher iron grade and recovery of reduction iron powder were obtained from subsequent magnetic separation. Furthermore, the deep reduction mechanism in the system was studied by the means of XRD and SEM analysis for reduction production and Physical Chemistry of Metallurgy. Analytical results indicated that during deep reduction, the size of iron particle from deep reduction materials was increasing as reduction temperature rising and reduction time extending. The growth of metallic iron particle from deep reduction production was divided into such three stages as reduction nucleation, deep reduction and growth of metallic iron particle.

Sep 1, 2012

By Qingchun Yu, Baoqiang Xu, Yongnian Dai, Bin Yang, Fulong Zhu

"In this paper, the mechanism of the carbothermic reduction-chlorination process to extract aluminum from alumina in vacuum was investigated. The carbon monoxide (CO) content of the gas, phases of the reduction slag, surface morphology of the reduction slag and the product aluminum were measured by means of gas chromatography (GC), XRD, and SEM. The experimental results indicated that the content of CO in the gas decreased, but Al4C3 increased with time at 1773K during the carbothermic reduction process of alumina. AlCl(g) and graphite (C) were produced by the reaction between Al4C3 and AlCh(g) at 1773K, and then aluminum beads generated after the decomposition of AlCl(g). It implied the mechanism of alumina carbothermic reduction-chlorination process in vacuum involves three steps as follows: the carbothermic reduction of A}z03 to produce Al4C3, the chlorination of Al4C3 by AlCh(g) to produce AlCl(g), and the decomposition of AlCl(g) to produce Al(l).IntroductionAluminum is the basic raw material for many industries [1], and it is used extensively because of various excellent properties such as light weight, good malleability, high strength, excellent thermal conduction, high corrosion resistance and so on [2]. Industrial production of aluminum currently includes refining alumina and electrolytic aluminum processes. However, its development has been effected by some factors such as high energy consumption and heavy environmental burdens [3]. In the past several decades, there had been numerous attempts to produce aluminum by new methods. Extracting aluminum from alumina or bauxite directly by carbothermic reduction-chlorination process had been studied [ 4-6]. Although the alumina carbothermic reduction process [7~9] had been studied, the mechanism of the carbothermic reduction-chlorination process had not been systematically elucidated.In order to investigate the mechanism of the carbothermic reduction-chlorination process in vacuum, GC, XRD and SEM techniques will be used to determine the CO content and to characterize the surface morphology and composition of the slags at various temperatures."

Jan 1, 2011

By J. Stawovy, A. Fourie, J. D. Quaranta

Coal refuse impoundments are disposal facilities specifically designed for the coal mining industry. Re-purposing refuse impoundments for co-disposal with natural gas flowback water and waste rock overburden has been investigated. The aims of this study were to investigate properties of coal refuse classification under the influence of co-disposed wastes as geochemical material exposure pathways from hydraulically exposed sodium and calcium ( Na+, Ca2+) cation loading from disposal of flowback water produced during the development of horizontal drilled natural shale gas frack wells, and waste rock having limestone characteristics. The geotechnical index classification of saturated cohesionless refuse is required to evaluate the liquefaction potential for strain or strength loss contributing to ground movements. This study is relevant to identifying changes in the coal refuse geotechnical index classification as sand-like, clay-like, or a borderline transitional material from the effects of ion and waste exposure in the impoundment’s reservoir porewater. Laboratory geotechnical tests were performed on fine coal refuse blended with different cations to classify the altered plastic behavior and index classification. Following determination of the index classification, the specimen’s stress–strain responses were investigated through isotropically consolidated undrained (ICU) triaxial compression tests. This experimental study culminated with two salient findings: the first is that introduction of ions alone into the refuse tailings or impoundment porewater resulted in significant material changes in property index classification, and the second finding was that the difference in refuse index classification did not correlate into noticeable effects of the monotonic undrained triaxial strength parameters.

Jul 5, 2022