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By J-P Franzidis, M Esvelt, E V. Manla

The Floatability Characterisation Test Rig (FCTR) is a self-contained, highly instrumented, mobile pilot plant that is able to treat up to 2 tph solids. It consists of a bank of six 130 L WEMCO« SmartCells« and a bank of six 50 L WEMCO« SmartCells«. It was developed as part of the AMIRA P9 Project, primarily to determine ore floatability characteristics and to develop and validate flotation plant modelling, scale-up and simulation methodologies. However, it may also be used to carry out pilot-scale flotation test work. This paper briefly describes the circuit modelling, simulation and scale-up test work performed using the FCTR and the use of the FCTR in pilot-plant test work performed by the metallurgical staff at WMCÆs Kambalda Nickel Operations and Mount Keith Nickel Operation. At both Kambalda and Mount Keith the FCTR was found to be very flexible and straightforward to run, with an easily changeable circuit configuration and stable operation. Testwork was facilitated through having full stream sampling on all streams, and a high degree of instrumentation providing accurate measurement of process variables. The results obtained from the FCTR testwork were highly repeatable. As a consequence of using the FCTR, WMCÆs Kambalda Operation and Mt Keith Operation were able to complete a rigorous programme of pilot plant testwork more quickly than in the past, and with a high degree of confidence in the results.

Jan 1, 2003

By R. R. M. Cousens, W. S. Garrett

Discussion: L. T. Campbell Pitt: When Mr Garrett and I discussed the design and construction of plugs and bulk head doors to resist great water pressures in mines about ten years ago, we visualized an emeregeny when there would be no time for site preparation. We could not however, anticipate a problem of such magnitude and urgency as the one described in the paper under discussion. The paper very clearly describes the flooding and the measures taken to save the mine. The complete flooding would have been a national disaster. The account of the combat between man and water reads like the account of a military operation. It was an endeavour which achieved success because there was a master plan, tenacity and, in fact, heroism. The paper is of necessity a long one. In my contribution I will mention some historical facts and factors that I believe have relevance to the flooding and the saving of the mine. It is of great satisfaction to me to have been one of the two initiators of a new approach to underground plug design and construction. The investigation was taken over by a Chamber of Mines Committee which combined our early work with further research and the resulting data had a significant bearing on the West Drie emergency plug designs. The final plug length was correctly based on the requirements to obviate leakage. A plug to have structural strength only would have been very much shorter but so ineffective as to have become a waste of labour, material, and in consequence, wasted the limited time available to prevent flooding of the whole mine. The figure of 75 lb per sq in. sheer stress provided a very ample margin, in my opinion, but under the very difficult site conditions and the limitations of plug material suitable for the very unusual construction, justified such a figure. There must have been considerable temptation to reduce the safety margin due to the urgency to complete and commission the plugs, but it is much to the credit of the directors of this operation that nothing less than a safe design was permitted. In about 1945 Blyvooruitzicht Gold Mining Company, which was then mining in to the West Driefontein area to assist in early development, decided to protect themselves from a possible inrush of water from the latter mine. A bulk head door was accordingly designed and installed on 2 level between 1945 and 1948 at 4,218 ft below surface. Since West Driefontein paid for it, Gold Fields consulting mechanical engineers collaborated with their colleagues of Rand Mines who completed their design after a few modifications were agreed. This door was never used to prevent an inrush into Blyvooruitzicht but the exercise was very useful to Gold Fields when the high pressure doors initially installed on 10 and 12 levels between Nos. 2 and 3 shafts to enable isolation of one section of the mine from another were designed. At that time the capacity of West Driefontein to cope with an inrush of water was comparatively small because the storage in stoped areas and the installed pump capacity were much less than in later years. These doors together with others of the same design were later moved to the lower levels served by sub vertical shafts. In addition, doors to prevent flood water entering the pump chambers on 18 level were installed at each end of that level, and designed for a head of 360 feet so that water would have to reach 16 level before the pumps were flooded. All these doors were called upon to hold water and it is reported that only a small plug in one of the doors and a 4 in. dia flanged pipe joint failed. The lesson is that in these cases the smallest details warrant as much attention as the major ones. That these were the only equipment failures when so much depended on equipment, is very much to the credit of design engineers, both of the Gold Fields head office and companies who supplied both mechanical and electrical equipment. Until I had read the paper I wondered why the policy of isolation by bulk head doors was not continued as the development moved eastward towards the Bank Compartment and particularly when it pierced the Bank dyke. The reasons have been given in the paper. It was unreasonable to expect provisions to be made to counter the remote contingency that the large installed pumping capacity and mine capacity to store water would be exceeded during a peak inrush. When pumps were being considered for West Driefontein, it was decided that the Gold Fields standard underground main pumps at that time of 1 million gallons per 24 hours would be too small. Three alternatives were considered. 1. Very large units that would require underground sub assembly and dismantling of both pump and motor. 2. The largest pump and motor that could be conveyed as a complete pump or motor from surface to the pump chamber. 3. Pumps of higher speed to reduce dimensions and weight. It was decided to adopt alternate 2 because of avoidance of transporting pumps in parts and assembling underground. Alternative 3 was not favoured because high speeds would have introduced problems of more exact rotor balancing. I believe the decision was correct and in the crisis enabled comparative easy transport of pumps and motors to surface for overhaul and, if required, transfer to other pump stations. The standard pump thus became a 10 stage 1,500 rpm pump with a capacity of approximately 2 million gallons per 24 hours against a static head that varied

Jan 3, 1969

By Rustyn Sherer

Curis, the name of a new Arizona-based mineral development company, is an acronym which stands for ?Cu? (elemental symbol for copper), ?r? (recovery), ?is? (in situ, the Latin for ?in place?). The company was created specifically to advance the development of the Florence Copper Project in Florence, AZ and to pursue other next generation copper development projects in progressive jurisdictions around the world. ?We are extremely excited about this project,? said Curis Resources president and chief executive officer Michael McPhie. ?We?re here to set the standard for Greenfield in situ copper recovery (ISCR) operations in Arizona and around the world. We believe in our people, our technology and our process; and we are passionate about our commitment to environmental stewardship and community development. We?re making a long-term investment in Florence, and in Arizona.?

Jan 1, 2011

By R. J. Smith

Tar sand deposits in Utah represent more than 25 billion barrels of in-place bitumen, 96% of the known U.S. reserves. The technological development of a hot water processing strategy for the Canadian tar sands and the commercial Production of synthetic crude oil from this natural resource suggest that similar success may be possible for the utilization of Utah tar sands to provide our country with a new domestic source of synthetic crude oil. In this regard an active research program to develop a hot water processing strategy for Utah tar sands has been sustained at the University of Utah for the past five years. The hot water process for Utah tar sands differs significantly from that used for Canadian, tar sands due to the inherent differences in the respective bitumen viscosities and the nature of the bitumen-sand association. These differences have led to the identification of certain design criteria necessary to achieve satisfactory phase disengagement during digestion. (8,9) Subsequent flotation of the digested tar sand is a subject of current attention and is considered in this contribution for the Asphalt Ridge tar sand deposit. Although contact angle measurements of pure Asphalt Ridge bitumen indicate moderate hydrophobicity, air bubble attachment to the bitumen concentrate taken from a 37 liter flotation cell is not possible. This surprising result suggests that the flotation separation is dependent on air bubble entrapment rather than on attachment due to surface hydrophobicity. The occlusion of air bubbles in the bitumen is apparent from visual examination of the concentrate, especially at lower temperatures. It seems that a bitumen bubble agglomerate forms in the impeller region of the flotation cell, the effective density of which is such to allow the agglomerate to float to the surface. A factorial design of the major operating variables in the flotation separation indicated that the quality of separation was significantly dependent on the flotation temperature and to a lesser extent on the degree of agitation. For a flotation temperature of 77C recovery of 96.7 percent was realized at a grade of 61.0 percent bitumen. The improved separation at higher flotation temperatures was found to be due to the decrease in bitumen viscosity resulting in more effective rejection of coarse sand from the concentrate.

Jan 1, 1980

By T. V. Lord

Minerals containing uranium have been successfully pre-concentrated by flotation at Queen's University, Kingston. In particular, uraninite, uranothorite, euxenite, and fergusonite, have responded to flotation to yield grades of 0.2 to 6.0 .per cent U .o. with recoveries of 85 to 98 per cent, from heads analysing approximately 0.10 per cent U3Os. Of the ten or so radioactive samples examined to date, two distinct groups were recognizable, firstly, those samples in which uranium was the sole constituent of economic interest, and, secondly, those in which Columbium (with minor amount of tantalum) was present in addition to uranium. For the purpose of this paper, the results of investigation on two samples of each of the above groups have been selected as typical.

Jan 1, 1945

By F. Baczek, S. S. Rocks, D. Chaiko, C. Eyzaguirre, S. Asihene, T. Walters

The majority of efforts to improve primary copper sulfide leaching have focused on solution chemistry, temperature, O2 pressure, ultra-fine grinding, the use of catalysts, etc. Historically, very few studies have focused on the solid/solution interface. A new, patent pending approach to catalyzed, copper sulfide leaching has been discovered by FLSmidth that enables manipulation of the 2-D semi-conductor properties of chalcopyrite surfaces to the benefit of higher electrochemical reactivity. Copper dissolution rates are then further accelerated by incorporating a Stirred Media Reactor (SMRt) into the process. By using minute amounts of Cu2+ to "pre-activate" chalcopyrite, leach times have been reduced from >20 hours with incomplete Cu dissolution to <2 hours with 98+% Cu dissolution at 80°C. The pre-activation process takes only minutes to complete at temperatures of 80°C or less. The total atmospheric leaching process, incorporating the pre-activation and Stirred Media Reactor is compatible with existing SX/EW processes. Results of batch leach testing are presented and possible mechanisms are discussed.

Jan 1, 2015

By J. B. McKay

It is the purpose of this paper to present an initial report on the construction and operation of the Fluo-Solid roaster at the property of Campbell Red Lake Mines, Ltd., Balmertown, Ontario. The roaster prepares for subsequent cyanidation the bulk flotation concentrate obtained from four hundred tons per day of gold ore. The mill flow-sheet &apos;includes jigging and amalgamation; flotation; cyanidation of flotation tailing; and roasting followed by cyanidaition of flotation concentrate plus amalgamation tailing. Overall mill recovery for the year 1950 was 90.2 per cent. Recovery possible by straight cyanidation of this ore would not exceed 80 per cent. The ore contains considerable arsenopyrite and pyrrhotite as well as pyrite, with lesser quantities of nickel, zinc, and copper minerals. The mineralization is for the most part extremely fine. The roaster first went into operation on August 7th, 1949, and at the end of 1950 it had roasted 10,916 tons of concentrate. The average recovery of gold from calcine during that period was 94.86 per cent in the primary stage of calcine cyanidation. The average assay of calcine residue from primary cyanidation for the entire period was 0.37 oz. per ton. Both laboratory tests and plant metallurgical balance calculations indicate a further recovery of approximately 10 per cent of this 0.37 oz. when the calcine residue is again cyanided, in the flotation tailing cyanidation circuit.

Jan 1, 1951

By P. D. S. St. Pierre

IN REGENT YEARS, blast furnace operators have found it necessary to improve their technology in order to handle increasingly low-grade feed and yet satisfy the demands for greater tonnages of metal. Studies have been made covering several aspects of the problem, and in this connection the slags produced in the iron-making process have been critically examined with a view to discovering the slag with the optimum properties for a given operation. A good slag should combine, as far as possible, the properties listed in Table I. Unfortunately, some of these desirable properties are incompatible. For example, the advantage of the small ?bulk of a low-flux slag is offset by its low desulphurization potential and high viscosity. Similarly, a very fluid slag increases refractory wear. It will be seen, then, that a balance must he struck between these conflicting requirements. In the .present paper only the melting relationships of blast furnace slag ?compositions will be considered in detail. In interpreting the data herein presented, the optimum property requirements listed in Table 1 must strictly be borne in mind. It should also be noted that the discussion presented here always relates to calcined fluxes, since this facilitates reference to the final slag composition. Thus, in making calculations pertaining to the ?burdening of the furnace, due allowance should ?be made for the fact that the fluxes are added as carbonates.

Jan 1, 1956

By T. S. Spicer, C. C. Wright, R. G. Bowman

IN recent years considerable publicity has been given to the problem of atmospheric pollution by fuel-burning equipment. Legislation has been stimulated and smoke ordinances have been enacted, the provisions of which show a definite trend toward stricter control of the emissions not only from the stacks of industrial fuel users but also from the chimneys of domestic consumers. As a result of war conditions, some slackening in the enforcement of these ordinances may be noted, but this is only a temporary expediency caused by the changes necessary in the distribution of the nation&apos;s fuel supplies and difficulties in securing the necessary equipment. Previous trends may be expected to continue in the postwar period. Largely because of the consumer demand for automatic heat, but partly because of the legislation against smoke emission, there has been a marked increase in the use of domestic underfeed stokers with the past decade. When correctly adjusted and operated, these units reduce the smoke emission materially, so that even the high-volatile bituminous coals may be burned with little or no emission of objectionable smoke. Unfortunately, however, the use of the domestic underfeed stoker introduces another problem; namely, fly-ash. PRODUCTION OF FLY-ASH The term "fly-ash" is a misnomer, since the fly material is generally a mixture of small carbonaceous particles varying from green coal to coke, and inorganic particles ranging from fluffy ash to small particles of fused clinker. For want of a more comprehensive name, however, the term fly-ash is used throughout this paper to include all the fly material. Even with hand-fired furnaces a certain amount of fly-ash is produced, which necessitates periodic cleaning of the boiler flues or furnace radiator, the smoke pipe, and occasionally the chimney itself. With stoker operations the amount of fly-ash is increased many fold, because of the higher velocity of air travel through the fuel bed. Frequently the amount of this fly-ash attains such proportions as to constitute a definite nuisance to the householder and his neighbors and distracts very materially from the otherwise automatic or semi-automatic performance of the stoker. Virtually all the boilers and hot-air furnaces marketed in the domestic field

Jan 1, 1944

By Anne Kathrine Kalager

"Stretching from Norway’s capital, Oslo, to the city of Ski, a new railway line is under construction with a 20 km long hard rock tunnel. This is a major project with high demands regarding quality, cost and schedule. In addition, restrictions concerning locations close to sensitive urban infrastructure require execution with the highest level of precision and expertise. The new double track railway line forms an important part of the intercity rail development southwards from the capital and includes the longest railway tunnel to date in the Nordic countries. With its novel methods and solutions, this project offers a model for future railway project developments in the region. This paper provides general pertinent details and facts relating to this current railway project and includes a description of the project with information relating to concept and design of the tunnels, geological conditions, particular challenges, selected tunneling techniques and contracting strategies. THE FOLLO LINE PROJECT The Follo Line is a new 22 km long double track railway line under construction between Oslo Central Station and the city of Ski. The project is divided into four subprojects, as shown in figure 1. The main part of the project consists of a 20 km long hard-rock tunnel, which will be the longest railway tunnel in the Nordic countries to date.The Østfold Line is the existing double-track railway line running between Oslo Central Station and Ski serving 12 local stations. The new Follo Line will offer a direct service, without stops, between Oslo Central Station and Ski and reduce the travel time from 22 minutes to 11 minutes. After completion of the Follo Line, these two railway lines will, in combination, more than double the capacity for train transport in the region south-east of Oslo."

Jan 1, 2016

By GEORGE D. RAMSAY

ABOUT three miles west of Fontana San Bernardino County, California, and fifty miles east of Los Angeles, the Kaiser Co., Inc., has built an integrated steel plant. By integrated, I mean that from its wholly owned iron ore and coal supply, the Kaiser Co. is producing in its own mills iron and steel products. Pig iron to meet the West Coast needs has been produced at Fontana since Jan. 1, 1943; steel ingots were first poured there May 14, 1943; and steel plate for ships was first rolled Aug. 15, just sixteen months after ground was broken. Briefly, the plant consists of: (I) Two batteries of by-product coke ovens, totalling ninety ovens, carbonizing about 1740 tons of coal per day at capacity; with by-product facilities for the production of tar, ammonia, and ammonium suIphate, light oil distillates, and tar distillates. (2) One blast furnace producing at

Jan 1, 1944

IT is most remarkable and valuable property of mediurn and high carbon steels that they should be so susceptible to heat treatment, the wide range of variability in tenacity, ductility, etc, due to the normal influence of the carbon in the untreated material being enormously inereased thereby.The physical properties of steel and other metals are much more closely related to their structure than to their ultimate analysis.For instance, we may by chemical analysis determine the carbon content of a steel to be 0.5% ; but this information alone is insufficient to enable us to say what are the physical properties of the metal.Such a steel may possess 11 tensile strength of anything from 35 tons per sq. in., with much ductility, up to 80 tons per sq. in., with practically no ductility, according to its heat treatment. A microscopie examination, on the other hand, would show the structural composition of the steel, from which its physical properties could be approximately deduced. From this it will readily be understood that the microscope has played an important part in the development of modern rnetallurgy, and to-day it is in daily use for the examination of metals and alloys in the laboratories of most works dealing with the rnanufaeture and working of metals.THE IRON-IRON CARBIDE EQUILIBRIUMTo understand fully the mode of occurrcnce of the different constituents of a knowledge of the Iron-Iron Carbide equilibrium diagram (Fig. I) is essential to heat-treat steel successfully and to interpret microstructures correctly such a knowledge isabsolutely indispensable.A portion of the Iron-Iron Carbide Diagram, dealing with steels below 1000 and containing up to 1 carbon is given below.It should be noted that the diagram deals entirely with pure carbon steels, and does not indicate the influence of the usual so-ealled &quot;impurities&quot; present in all commereial carbon steels...

Jan 1, 1926

By X. Grant Chen, A. R. Farkoosh, M. Pekguleryuz

Nano-scale Al-(Fe,Mo)-Si dispersoids form during solution treatment in grain interiors (intradendritic regions) of cast Al7Si0.5Cu0.3Mg alloyed with 0.3Mo (wt.%). Unlike the Q-Al5Cu2Mg8Si6 and ?-Al2Cu age-hardening precipitates which coarsen resulting in loss of strength in Al-Si-Cu-Mg alloys, these Mo-containing dispersoids are thermally stable and retain their strengthening effect at elevated temperatures. Consequently, the age-hardened Al7Si0.5Cu0.3Mg0.3Mo (wt.%) exhibits high strength and creep resistance at 300 °C.

Jan 1, 2014

By Linli Wu

During the measurement of contact angle, a misty band was observed near the substrate. Hsien-Nan Ho and Shinn-Tyan Wu thought this was because the oxygen atoms on the interface migrate to the droplet surface to form an oxide band near the substrate. But from our experiments misty band appeared before the drop reach to the substrate. Theoretically speaking, the oxygen partial was the same everywhere in the vacuum furnace. So there was no condition to provide enough oxygen forming oxide. This appearance would be explained more reasonably with the optics principle. Most reflected light would be absorbed by the substrate and the light cannot reach the observation area, so the misty band formed.

Jan 1, 2006

By William Petruk

The mineralogy of the primary and oxidized ores from the Malanjkhand porphyry copper deposit in India was studied to determine ore characteristics that affect metallurgy, and to assess applicable processes for recovering the copper. Three mineral assemblages were found. One occurs in primary ore, another in moderately oxidized ore, and a thir:d in intensely oxidized ore. Chalcopyrite, the main mineral in the primary ore, is relatively coarse-grained, with grain size increasing as the ore grade increases. High chalcopyrite liberations should be achieved at a relatively coarse grind, and good chalcopyrite recoveries should be obtained. The chalcopyrite, however, tarnishes readily and oXidizes to chalcocite in a relatively short time (several months). The presence of both the tarnished chalcopyrite and chalcocite may affect chalcopyrite flotation and reduce copper recoveries, The moderately oxidized ore occurs in an oxidized cap immediately above the primary ore, and stockpiled primary ore alters quickly to a moderately oxidized ore. Chalcocite is a major copper-bearing mineral in moderately OXidized ore. The concentrator processing this ore should be capable of handling a chalcocite-rich ore. The intensely OXidized ore contains a wide variety of acid-soluble copper-bearing minerals. Leaching may be required to recover the copper from them.

Jan 1, 1987

By Walshe JL, Solomon M

The Emperor vein system lies on the eastern margin of the Tavua volcanic structure. This is of Miocene age and occurs in basalts(the Mba Volcanics) probably underlain at about 2 km by calcite-rich sediments (the Vatukoro Formation). The lodes are generally flatmakes, or steep fault fillings, or complex shatter zones, and consist of quartz and altered wall rock. In areas of open cavities it is possible to establish a paragenesis which involves five quartz stages and two ore mineral stages. The first ore stage contains calaverite, krennerite, sylvanite and native tellurium, the second petzite, hessite and native gold. The quartz stages are thought to have formed slowly (102 years) from boiling solutions of low salinity at temperatures varying with time from about 250¦C to 190¦C. The system was sealed, the temperature gradient near vertical and the mass flux small. The ore mineral stages probably formed relatively rapidly (101years) from boiling solutions at 250¦ to 200¦C when the system was mainly open. Gold deposition was probably largely a result of fall in aH2S due to boiling, the calculated solution concentration falling from a maximum of about 8 ppb at 250¦C to about 8.10-3ppb at 200¦C. Boiling is also probably responsible for an increase in a02 (by loss of H2) and fall in aTe2 (by loss of H2Te). The fluids are thought to have had a large component of meteoric water and to have been heated by plutons in the core of the volcanic structure. Stable isotope data indicate that they derived their carbon from the underlying Vatukoro Formation and their sulphur from sediments. Circulation may have been confined to the outside of the volcanic structure because of the relatively low permeability of the flows, pyroclastics and dykes within it.

Jan 1, 1987

By F. Ajersch, P: Tsantrizos, K: Shanker

"TiN films have been deposited on various substrates by a novel reactive plasma technology. In this process, a nitrogen source (NH3 or N2) and TiCl4 are reacted in the jet of a plasma torch, and are deposited onto a substrate forming TiN films at a high growth rate ( > 2µm/min). It was found that the process parameters strongly affect the microstructure, thickness, density, and growth rate of the TiN films. These parameters include source of nitrogen (NH3 or N2, N/Ti ratio, temperature of substrate, and spray distance. In general, it was found that thick and dense coatings were deposited when the N:Ti ratio was kept low, and the substrate temperature was high. Also, for the series of conditions investigated, NH3 was found to give much better results than N2•. The limitations and advantages of this technique are also discussed in this paper.IntroductionTiN is an extremely hard material and is used in many wear applications, particularly as a protective coating on cutting tools to extend their Iife(1.2). Owing to its excellent chemical stability, TiN is also frequently used as a diffusion barrier in the electronics industry for sub-micron Al/TiN/Si ohmic contact systems (3) or as a coating on high-temperature resistant alloys in gas turbine applications (4), based on its good resistance to oxidation. Other applications include decorative coatings in the jewelry industry, and specialized applications such as solar energy absorbers and transparent heat mirrors(5).TiN films can be deposited/formed using various techniques. The main techniques of deposition are CVD (Chemical Vapour Deposition) and PVD (Physical Vapour Deposition). Each of these techniques can have many variations in equipment characteristics, reactants as well as a range of process parameters (pressure and temperature). In the CVD process, TiN is generally deposited onto a heated substrate where a chemical reaction takes place. The reaction can be one of reduction(6) (e.g.: TiCI4 + 0.5N2 + 2H2 --> TiN + 4HCI), of thermal decomposition(7) (e.g. decomposition of titanium dialkylamide), or of displacement (e.g. TiCI4 + NH3 --> TiN + 3HCI + 0.5CI2)' The displacement and reduction reactions are the most common."

Jan 1, 1994

By R. Bruce Graham

The formation, evolution and classification of peat bogs is discussed. Factors resulting in the internal and external morphological changes in a bog are described. The fibrous, absorptive and sterile properties of peat moss account for its widespread use in horticulture and related fields. These properties also account for its usefulness as a binder in pelletizing, as an insulating material in bat tons and in panel construction. Peat, the humijied product of peat moss is used in market gardening and sod growing. It is utilized in Europe as fuel. It is a source of activated carbon and gas. Potentially peat can be used to produce waxes, resins, tannins, cellulose, hemicellu/ ose, humic acids, lignin and hymatomelanic acid. At present other cheaper sources are available.

Jan 1, 1984

By T. P. Meloy

The packed column flotation cell is an awesome separation device. Virtually unknown and untested, the packed column flotation cell is one of the ten most important developments in mineral processing of the 21st century. Though experimental and industrial data is limited, it is clear that the packed column flotation cell is two to three orders of magnitude better than the conventional flotation cell and one to one and a half orders of magnitude better than the open column flotation cell. With the modern packing taking up less than one percent of the packed column, column blocking does not occur. For a packed column operating 24 hours a day, 365 days a year, the estimated mean time between failures (MTBF) is one hundred thousand hours or roughly twelve years. With no moving parts, lower maintenance costs, lower power consumption and inherent operating stability, the packed column is a powerful separating machine. Because there is little meaningful data for comparing the packed column to the conventional flotation cell and the open column flotation cell, much of the material presented in this paper are guesstimates. They are disinterested guesstimate made by the authors after extensive theoretical work and reviewing the known facts. In the authors&apos; opinion, no available data contradicts the guesstimate. The authors expect that there may be errors as large as three hundred percent. Even three hundred percent errors will not change the conclusions of this paper. The packed column flotation cell is a formidable separating device. To understand the problems of comparing the three types of flotation cells, consider the fact that the three cells may have different modes of separation. One of the authors, Meloy, believes that in the conventional cell, the primary particle separation takes place in the liquor with secondary separation taking place in the froth, while for open column flotation, all the separation takes place in the froth. However, he believes that in the packed column a large part of the separation may take place on the walls of the packing. If this is true, not only is the method of modeling each type of cell different, but the method of particle selection in the cell is different. This means that one type of cell may be better at differentiating between two different types of particles. There is a growing body of literature on open and packed column flotation. Suggested reading: (Clarke et al; Hucko et al; Li; Smith & Warren; and Yang).

Jan 1, 1994

By O. Norman Lotter

The formulation and use of mixed collector suites in sulphide flotation can be traced back as far as 1957 with the work of Glembottskii and his co-workers in Moscow. The subject was reviewed by Lotter and Bradshaw in 2010, and proposed a synergy between ideally-selected different reagent types to deliver improved performance, in particular the in situ catalysis of a xanthate to dixanthogen by a dithiocarbamate. Correctly formulated for a particular application, an optimally arranged mixed collector suite delivers the following improvements to the flotation process: • An increase in the flotation kinetics • Improvement in coarse, or middling, particle recovery • Reduction in total dosage requirement • Best results are found from testing the ratios of the collectors. This is of critical importance. In all an optimally formulated mixed collector system usually delivers an increase in paymetals recovery of 1–4% absolute, with a gain in concentrate grade in the range 10–20% relative. In recent years, the addition of semi-conductor theory and associated electrochemistry has contributed significantly to this toolbox by way of identifying optimum domains of Eh and pH for the flotation of individual minerals. In the case of mixtures of minerals, this is where the mixed collector system delivers significant value by way of presenting a mixed set of collector radicals and dimers in a common Eh and pH domain for overall performance. This calls on a fundamental understanding of organic chemistry, mineralogy, semiconductor theory, and electrochemistry. Whereas the selection of grinding media type effectively influences the Eh, the pH can be easily controlled by pH modifiers. The theory of this system, and some industrial case studies, are discussed.