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By T C. Westerfield, G, M J. Mankosa

An innovative separator known as the HydroFloat cell has been developed specifically for the upgrading of coarse particles that are difficult to recover using conventional flotation cells. The novel characteristic of this separator is the formation of a hindered teeter-bed of fluidised solids into which small air bubbles are injected. The air bubbles selectively attach to hydrophobic particles and form particle/bubble agglomerates that segregate atop the teeter-bed due to their lower apparent specific gravity. The low-density agglomerates are eventually carried into the product overflow launder by the rising current of teeter water. Hydrophilic particles remain in the teeter-bed and are discharged to underflow as a high solids content tailing. Benefits of this hybrid flotation-density separator include enhanced bubble-particle contacting, increased particle residence time, and very low air demand. Test data indicate that significant improvements in the recovery of coarse particles can be achieved using this innovative technology. This article describes the theoretical basis for the development of the HydroFloat cell and provides an overview of recent pilot-scale tests conducted for the phosphate industry.

Jan 1, 2005

By Marc C. Bétournay

Replacing diesel power in underground metal mining vehicles with available clean energy (e.g. hydrogen, lithium-ion batteries) is now a priority due to worker health issues, the increasing price of diesel, ventilation costs and air quality. Hydrogen fuel cells are a known and broadly applied power technology. They have been the focus of a dedicated research program to carry our proof of concept projects as well as regulatory developments for mining application. However, hydrogen remains a demanding energy vector to use in confined, underground applications. Standardization and safety considerations are being addressed in the industrial consortium Hydrogen Mine Introduction Initiative (HMII). Research projects are being carried out to resolve the gaps for regulated use. This article focuses on HMII objectives and Project results. The first has reviewed the relevant codes and standards and mine regulations, indicating that hydrogen and fuel cells could be allowed underground and that current codes, especially the Canadian Hydrogen Installation Code would be sufficient for hydrogen use. The second project established the standard hydrogen storage and distribution architecture along with related risks and safety requirements for its use in the third project, using an underground test chamber to delineate the behaviour of hydrogen leaks in confined conditions with various ventilation regimes and ignition studies. This project will end in 2013. It will be followed by the last project, which will establish best practices in support of regulations development, and develop the ISO standard for mine hydrogen infrastructure and underground application.

Aug 1, 2013

IN the ordinary course of treatment of pyritic ores or concentrates, whether for the recovery of copper, tin, gold, or any other contents, the removal of some or all of the sulphur contents is almost invariably the first step. The practice is to roast the ore in a current of air so that the sulphur is oxidized to sulphur dioxide and the metal constituents are changed from sulphides to oxides. If it is feasible to produce sulphuric acid in conjunction with the treatment process, the sulphur can be usefully employed; but if this is not possible, then the sulphur contents not only become a dead loss, but tend to be a nuisance as well in the surrounding neighbourhood.The problem of avoiding this disadvantage and making economic use of the sulphur has had attention from the early days of scientific metallurgy, and in the past few years very special efforts have been made both to drive part of the sulphur as such from pyrites and recover it, and to replace the sulphur in the S02 by carbon, with the production of carbon dioxide and precipitation of the sulphur. So far economic success does not appear to have crowned these efforts. In the case of pyrites, of the two atoms of sulphur which go to make the FeS2, the first is very lightly held. Dissociation is effected by heat alone at a temperature which is given by Peters as 5160 C.Now, sulphur and hydrogen will unite or burn together, with the production of sulphuretted hydrogen. It occurred to the writer that, if hydrogen was passed over pyrites heated to the above temperature, this first atom would be snatched away by the hydrogen, and could possibly be economically recovered.The first step consisted of some simple laboratory experiments. From these it was found that this first atom was readily removed, and that the extraction was practically complete. Further, the reaction took place at a low temperature, a dull red heat being sufficient.

Jan 1, 1923

By L Smith, R Beckie

Controls on environmental loading from acid rock drainage (ARD) are not well understood in waste rock material. In particular, relationships between subsurface flow and the timing, duration, and intensity of leaching of metals and acidity from waste rock dumps remain ill defined. This study investigates field-scale relationships between subsurface flow processes and geochemical processes in unsaturated waste rock. A 12-metre tall, unsaturated waste rock pile, constructed in 1994, was deconstructed and sampled at Key Lake, Saskatchewan, Canada, during the summer of 2000. A detailed sampling methodology was developed to characterise physical and chemical properties of waste rock material within the waste rock pile. Physical properties were characterised by measuring soil-water suction, volumetric water content, and grain-size distribution at 60 random locations within the pile and grain-size distribution at 20 grid locations within the pile. Attempts to develop a field-based soil water characteristic curve from physical field-data failed due to spatial variability and hysteresis of waste rock properties. As a result, grain-size distribution was used as a relative measure of subsurface flow. Paste pH, pore-water geochemistry, mineralogy, and water-soluble extraction results were used to characterise geochemical processes and sulfide oxidation at each of the 20 grid locations. Geochemical characterisation results demonstrated the preferential weathering of marcasite relative to pyrite and chalcopyrite. Dolomite was the main buffering carbonate mineral. Gyspum, jarosite and iron oxyhydroxides were the main secondary minerals. Pore-waters contained up to 800, 11.7, and 6 mMolar (78 000, 690, 1400 mg/L, respectively) of sulfate, nickel, and uranium, respectively, suggesting significant weathering has occurred. Measures of weathering indicators show no discernable correlation with grain-size distribution nor do they show any spatial relationship within the sampled grid. Reasons for this may include limited duration of waste rock exposure to weathering and development of fluid flow-paths, and limitations of characterisation methods used. Indeed, six years may not be long enough for weathering patterns to develop due to fluid flow-paths in this unsaturated waste rock pile.

Jan 1, 2003

The investigations of the Leningrad ruining lilstitute on this problem are carrying out in the following main directions: 1) The analysis and study of contaminants migration at particular sites of mining development; 2) The working out of theoretical and me- thodical basic principles of aquifers migration tests; 3) The work- ing out of methods of the forcasting of groundwater pollution pro- cesses; 4) The theoretical and uethodical substantiation of hydro- geological observations of groundwater pollution processes; 5) The wort ing out of the measures at the groundwater control and their rational use at the particular sites of mining development. The research that have been carried out by the present moment have covered the wide range of wining and geological conditions -- as from the point of view of specific genetic types of water-be- aring rocks (porous, fissured and fissured-porous), as well as from the point of view of pollution sources (surface waste water basins and underground basins of non-standard water) and the cha- racter of the latter's migration (tracers, physically neutral ef- fluents, heavy or light ones). The combination of specialized mi- gration tests and observations carryed out at uoayi, sites, as well as the following ar~,alysis o:i the data of field study allowed to get useful theoretical, methodical and practical results on the all directions above mentioned, ns the summing up of these results the author proposed the concept of controlled ground :ester polluti on. This conception is based on three whales" - groundwater self- purification, engineering prevention measures and ground-water monitoring correlated with each other by succes i.vely refined (ac- cording to the observation data) hydrogeologicZl forecasts.

Jan 1, 1988

By V. A. Mironenko

The combined study of ground water regime and rock deformations has resulted in the theoretical substantiation of the common principles for analysis of the hydrodynamic and geomechanical processes Within the scope of unique scientific direction -hydrogeomechanics (Mironenko and Shestakov, 1974). The hydrogeomechanical models are widely used now for the analysis and forecasting the extremely important processes connected with the safe and efficient mining operations, as well as with the protection of geological medium. Among these processes are: -deformations of the open-pit slopes and spoil dumps; -consolidation of rocks due to the ground-water pressure drop; -water-end-rock material inrush into mine workings caused by deformations of the undermined rock mass; -geodynamical processes due to the changes in ground water regime; -artificial hydrofracturing in rocks; -transformations of clay linings under the tailing ponds and other technical water basins.

Jan 1, 1990

By Fiona M. Doyle Garner

Hydrolytic stripping is the process whereby metal ions in a loaded solvent extractant are hydrolyzed by water, typically at 130°-200°C. Equilibrium hydrolytic stripping tests were done on Versatic 10 solutions of various metals, singly and in mixtures. Single solutions of Fe, Xi, Cu, Mg, and tin precipitated aFe2O3, Ni(OH)2, Cu2O, Mg(OH) 2 and ?Mn203 respectively during hydrolytic stripping. Several mixtures containing iron precipitated magnetic spinel ferrites, MFe20k. No other combinations formed mixed oxides. It is proposed that the mechanisms for hydrolysis and precipitation of iron in loaded Versa- tic solutions are similar to those for iron hydrolysis in aqueous solutions. Infrared spec- troscopy and thin-layer chromatography of mixed iron-nickel Versatic solutions indicated that mixed Fe-Ni carboxylate complexes are present. Magnetic interactions between mixed complexes are thought to be responsible for the homogeneous nucleation of magnetic mixed oxides in preference to single oxides.

Jan 1, 1984

By T. Sterry Hunt

WET processes for the extraction of copper from its ores have of late attracted much attention, especially in Europe, where the use of oupriferous iron-pyrites as a' source of sulphur prevails. These processes present an additional interest, when, as is often the case, the copper-ore's to be treated contain one or both of the precious metals, since the complete separation of these from copper, either in the dry or the moist way, is, as is well known, one of the difficult problems of metallurgy. The principal wet processes hitherto in use for the extraction of copper from its ores, may be included under three classes : I. Those in which the copper in snlphuretted ores is rendered soluble in water by calcining them, after a preliminary roasting which removes the greater part of their sulphur, with a portion of common salt, by which the copper is converted into a chloride (Long-maid and Henderson), or with sulphate of soda, by which sulphate of copper is formed (Monnier). Allied to these is the method by which a portion of the copper is got as soluble sulphate by roasting without addition, a process which is sometimes modified and rendered more complete by re-roasting the lixiviated residues with the addition of a portion of raw sulphuretted ore (Bankart). II. Those methods in which free chlorhydric or sulphuric acid is used to dissolve the copper- from oxidized or roasted ores. These, while simple and efficient, are too costly, except in certain localities where chlorhydric acid is a waste product. Related to them is the plan which consists in exposing the oxidized and moistened ores to the slow action of sulphurous acid mixed with air, by which a soluble sulphate of copper is formed. It has been proposed to decompose the solutions of sulphate or chloride of copper by sulphuretted hydrogen, thus separating the copper as sulphide, and using the liberated acid to dissolve fresh portions of oxidized copper. It is, however, the almost universal practice to throw down the copper from its solutions, however obtained, in the metallic state by the use of iron, either scrap-iron or iron-sponge; although in some instances

Jan 1, 1882

By A. D. Pittuck

Refractory minerals .containing uranium and columbium have been successfully treated at Queen's University, Kingston, to produce high-grade concentrates. Recoveries of over 90 per cent of the uranium and columbium have been obtained when treating concentrates containing euxenite, fergusonite, betafite, and pyrochlore. The processes ?consisted -of leaching the columbium with hydrofluoric acid, and the uranium with nitric acid, sulphuric acid, or sodium carbonate solutions. The leach liquors were extracted with organic solvents from which the values were stripped and precipitated, producing final products assaying 45 to 55 per cent Ob2O5 and 60 to 70 per cent U3Os.

Jan 1, 1958

By Richard W. Herzer

Introduction Thermal methods have been predominant in the metallurgy of the base-metals ever since the foundation of the industry thousands of years ago. Development in hydrometallurgy has been confined largely to the past six or seven decades. It was at first necessarily slow, then for a number of years rapid progress was made. At present, the uncertain state of the metal industry has curtailed research on the subject; however, in the next few years one may assuredly look forward to an ever increasing use of wet processes. Leaching methods have attained the dominant position in the case of certain metals, notably zinc. For others, they have made no headway at all. Copper presents a situation all its own. Due to the varied nature of its ores and to the large number of localities in which it is mined, a great number of processes have been developed, each suitable in its own particular field. In the case of this metal, therefore, it is more difficult to arrive at definite conclusions. It is the purpose of this paper, first, to review the outstanding developments of base-metal hydrometallurgy, and, secondly, to consider possible Canadian applications of some of the processes in use. The discussion will be confined to the three metals, zinc, lead, and copper, with particular reference to the last mentioned. Zinc General Note At present, zinc is produced by two principal processes, the older retort process and the electrolytic process. The latter is a development of the last twenty years and, judging by its present progress, bids fair eventually to supplant older methods in a large proportion of cases. It is certain, at least, that in the erection of a new plant, a hydrometallurgical process would be given the most serious consideration

Jan 1, 1934

By B. J. Arnold, F. F. Aplan

"The captive bubble and sessile drop contact angle techniques have been used to evaluate the hydrophobicity of petrographically identified coal macerals. The magnitude of the contact angle on vitrinite is shown to be a function of coal rank ( %C, %0 and % vitrinite reflectance), increasing with increasing rank to a maximum for low volatile bituminous rank coals then decreasing for anthracite. The least data scatter is found when vitrinite reflectance is used as a rank parameter. Contact angles measured or estimated for other discrete macerals, indicate a variation in hydrophobicity based on coal type. These data correlate well with known flotation results. Coal is a heterogeneous mixture of plant remains and associated minerals that have undergone chemical and physical changes by biological and geological processes. These plant remains form coal macerals, discrete organic entities in the coal which have characteristic chemical and physical properties. As the differing chemical nature of each maceral will affect its behaviour in processes such as carbonization the separation of macerals during coal preparation may provide an important asset in coal utilization.Separation of some of the macerals based on specific gravity has been achieved in the laboratory, and by Sun and Cohen , in a study of two Pennsylvania bituminous coal preparation plants. It was indicated that the lighter exinites report almost exclusively to the clean coal while the denser inertinites are concentrated in the higher gravity fractions. The Longwy-Burstlein process6 took advantage of the difference in hardness or friability of the macerals by using impact breakage followed by screening to remove the more friable vitrain,clarain and fusain. The remaining durain, often high in spore content, was then recrushed. The re-mixed fractions produced the optimum size for obtaining the best coke strength for a particular coal.Separation or concentration of rnacerals by froth flotation largely depends on differences in the hydrophobicity of the macerals. Sun and Cohen 5 . indicated an order of decreasing floatability as exinite, vitrinite and inertinite, while a Russian study (as cited by Brown 7 ) showed that vitrains floated more readily than the duller types. More recently, Hirt and Aplan8 showed that 'pseudovitrinite' floats somewhat faster than does vitrinite while fusinite floats very slowly. Olson and A plan found that vitrinite floated easily while substantial quantities of the non-floated coal contained fusinitic material. Burdon noted that vitrinite is more floatable than semifusinite, and Sarker et a/. 11 have shown that vitrinite is selectively concentrated by froth flotation and oil agglomeration. Sun indicated that flotation, based on his calculated floatability index, should decrease in the order clarain, vitrain, fusain and durain; while Horsley and Smith 13 indicated the decrease to be: vitrain, clarain, durain and fusain. These differences can be attributed to the specific coals used in each study and to the individual macerals composing each coal type within a given coal."

Jan 1, 1989

By Gerardo Fuentes

The stoichiometry and kinetics of the hydrothermal reaction of enargite in copper sulphate solutions was investigated in the range 140–300 °C, and particle size under 15 and 50 μm. The stoichiometric experiment was performed at 300 °C, using one gram of sample (96% enargite, 4% tennantite) and 100 mL of copper sulphate solution (10 gpl) at 1.2 pH. Enargite reacted completely after 80 min. A solid product was obtained and characterized by XRD. The main product was chalcocite (M) and some traces of djurleite and chalcocite (Q). Tennantite did not react under these conditions. The kinetic experiments were conducted at 140 °C, 190 °C, 250 °C and 300 °C. From fitted data and Arrhenius equation the calculated activation energy (Ea) was 51 kJ/mol. According to the hydrothermal transformations studied, the reactivity of different phases found in the copper concentrates was bornite > chalcopyrite > covellite > sphalerite > pyrite > enargite > tennantite.

By John E. Appleby

Grupo Acera, HYLSA originated in 1942 when Hojalata y Lamina began operations to supply steel strip for the Cuauhtémoc Brewery, the parent company. Production began in April, 1943 with growth accelerated because of World War II. By 1948 the company was producing its own steel from electric furnaces charged with scrap iron. Further expansion was hampered by the fluctuations in availability, price and quality of scrap iron. As a result, a search was made for a suitable process to enable HYLSA to satisfy its need for a reliable source of feed for its steel-making facilities. Their relatively low iron requirements at the time did not justify the very high capital investments required using the conventional blast furnace method. Processes which by-passed the blast furnaces were very much in their infancy and were not commercially tested. HYLSA then undertook an investigation of the direct reduction processes, knowing full well that much larger companies in other countries had investigated several processes but their work had not established a trend toward direct reduction or any particular process. However, after much effort and persistence HYLSA arrived at a process which suited their conditions. By using Mexican iron ore and natural gas they developed the now well-known H. y L. Process to produce sponge iron. Concurrent with the start of investigations which led to the H. y L. Process, HYLSA began an exploration program for a suitable source of iron ore. Thus in 1951, Cia. Minera Las Encinas, S.A. was formed, culminating in the development of the ore bodies near Pihuamo in the State of Jalisco. Mining commenced and ore was

Jan 1, 1971

By M Fuchs

Roadheaders were introduced to mining and tunnelling in the early-1960s. Since this period their main field of application has been for roadway drivages in coal mines and for mineral production, for instance in coal, rocksalt, potash and gypsum mines. Their main field of application in tunnelling is in softer and partly friable rock formations, a suitable area for non-blasting excavation. However, in longer tunnel sections excavators with high ripping forces have replaced roadheaders in many situations. The main arguments against roadheaders have been and still are:a sharp increase in excavation cost with increasing rock strength and increasing abrasivity; and greater risks in conditions which have not been, or could not be, investigated to a sufficient extent. These arguments have, to a great extent, restricted practical roadheader application in production mining and in a lot of æstandardÆ tunnel projects. To address these limitations, factors which could make roadheaders attractive for such conditions and could overcome existing technological difficulties have been investigated. Extension of the economic field of application in hard rock was found to be the most important and the most effective step forward.

Jan 1, 2002

By Frederick Laist

IT IS obviously impossible to design a copper smelting plant which could be considered, ideal under all conditions. For example, a plant properly designed to smelt the concentrates resulting from the treatment of porphyry ores by flotation would not be the kind of plant that one would design for the treatment of a coarse pyritous copper ore. The smelting of flotation or other fine concentrates is generally accomplished in a reverberatory plant, although occasionally the concentrates are sintered and then smelted in blast furnaces. On the other hand, coarse self-fluxing ores, whether pyritic or semi-pyritic, are generally smelted in a blast-furnace plant. Even this statement is only- approximately true, since the choice will be influenced by many factors; for example, the kind of fuel available (coal, oil or coke), the value of power (electric or steam), the uses to which waste steam may be put (heating, drying, etc.), the cost of refractories (silica and fire brick), the permanence and continuity of the ore supply and the relative first costs of the two types of plant (the reverberatory plant is generally more expensive to construct and to shut down), the contour of the site on which the plant is to be built (rugged, rolling or flat), the intelligence and character of the labor avail-able, and many other factors. From these remarks, it is evident that no copper smelter can be ideal for all conditions of ore and locality, and inasmuch as most of the copper now being pro-duced comes from fine or flotation concentrates and these are generally smelted in reverberatory furnaces, I shall confine my remarks to this type of smelt-ing plant.

Jan 5, 1923

By Mine F. J, Woods P. H

Waste waters from mine sites may be screened for all constituents of significance as a first step in establishing water quality criteria for protection of aquatic ecosystems. Inductively-coupled plasma mass spectrometry (ICP-MS) offers the capability to screen water samples and digest solutions for virtually all elements in the periodic table. This technique is therefore able to identify elements whose concentrations are elevated in waste waters and may be rarely present in background surface or ground waters. Such elements may be present in waters at only a few ¦g/L. ICP-MS has sufficient sensitivity to detect sub-¦g/L or even ng/L levels of many elements. Waste waters from most mining activities in the Northern Territory have been examined by ICP-MS. The concentration data provide the basis of a contaminant data base. The data can show specific tracers in the ore or mineral itself, subsequently found in waste water. An example is the presence of rhenium in uranium ore. Such trace elements may be present in soluble or insoluble chemical forms and are more useful as indicators when soluble and exemplifying conservative chemical behaviour. The approach described, based on ICP-MS screening of mine site waste waters, together with general physico-chemical variables, provides the most comprehensive means yet available of selecting variables for monitoring programs and ensures that key elements and/or their chemical species are not excluded from monitoring programs.

Jan 1, 1994

By H. Y. Sohn

The ignition and combustion of chalcopyrite particles under suspension-smelting conditions, in which the particle-particle interaction is neglected, has been analyzed by considering the intrinsic kinetics of oxidation and heat and mass transfer between the particle and its surroundings. Reasonable agreement has been obtained between the calculated results and experimental results from a laminar-flow furnace reported in the literature. This computation- al procedure has further been applied to flash-smelting conditions. Under suspension-smelting conditions (Sh = Nu = 2), chalcopyrite particles ignite at around 960 K. The effects of various parameters, such as oxygen concentration, particle size, and gas temperature, have also been evaluated. Comparison between calculated results in this work and experimental observations indicates that SO is the important gaseous product that forms at the surface of the particle.

Jan 1, 1993

By W. M. Weigel

WHILE electric lamps both of the cap and hand type are being introduced into many mines requiring the use of safety lamps, the oil-burning safety lamp is still used in the great majority of cases, and even where the former are used the latter must continue to be employed when testing for gas. It is not the intention to discuss here the relative merits of the two types, but simply to give a comparison of the illuminating effect or candlepower of several kinds of ordinary safety lamps used for general work and for testing. Few data have been published in recent years on this subject and because of this it is hoped that the following information may be of some interest and value. The lamps tested were in all cases. of standard size and in good condition, all practically new, and were selected from a collection of about 100 with a view to obtaining results on as many different common types as possible. With the exception of the gasoline-burning lamps, five different oils were used in each lamp to determine whether -particular oils were suited to particular lamps and whether there was any great difference in the illuminating power of the different oils, or whether some oils would maintain their illuminating power better than others throughout a working period of 8 hr. No attempt was made to determine the amount or cost of oil burned by each lamp, but the condition of the lamp, wick, glass, and gauzes was noted after each test.

Jan 8, 1916

By E. R. Vance, D. R. M. Brew

"Historically, Ordinary Portland cement has been the preferred medium to immobilise arsenic. However, arsenic in cement gives rise to calcium-arsenic phases and their known decomposition to calcium carbonate and arsenic trioxide via atmospheric carbonation raises serious questions about the long-term suitability of cement for arsenic immobilisation. Alternative matrices such as low-temperature ceramics (LTCs) potentially offer superior resistance towards carbonation owing to the absence of calcium. Consequently, the potential for arsenic immobilisation using LTCs has been investigated. Both AsIII and AsV have been incorporated and samples assessed according to a standard leaching protocol. AsIII persists in the porewater of alkali-bonded LTCs as sodium arsenite rendering them unsuitable for immobilisation. Thermal treatment of these LTCs to consolidate the microstructure and reduce open porosity resulted in sodium-rich cryptocrystalline matrices that leached arsenic and sodium readily. The omission of sodium in acid-bonded LTC formulations resulted in leach data that were close to the target value of 5 µg/ml in Toxicity Characterisation Leaching Protocol tests.IntroductionArsenic is a carcinogenic substance and its adverse effects of on humans, flora and fauna have been well documented [1-5]. As a consequence, many papers have been written on the prospective handling of arsenic-bearing waste. These can largely be divided into: (a) cleanup of arsenic-contaminated water using bacteria, precipitation, and/or UV irradiation to generate arsenic-rich sludges for subsequent immobilisation; (b) cleanup of arsenic-contaminated soil via chemical extraction for immobilisation of the As concentrate; and (c) immobilisation of industrial waste contaminated with As."

Jan 1, 2008

By G. Southam

Bacterial populations play an active role in mineral weathering in subsurface and near-surface environments e.g., supergene enrichment of Cu at Morenci, AZ. An in vitro bacterial biofilm model was used to examine the interaction between Sporosarcina ureae and ionic gold (which is toxic) or amino acid-gold complexes in gold mobility. The immobilization of ionic gold was between 80-90% for 1 week but as the available, cellular reactive sites became saturated immobilization decreased to 14% within 2 weeks. In the asparagine-gold system, gold immobilization occurred at a high rate (80-90%) throughout the experiment with limited toxicity towards Sporosarcina ureae.

Jan 1, 1999