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By Renate Wellen, Olgun Guven, Mariane Y. T. Oide, Julyana Satana, Francisco Valenzuela-Díaz, Esperidiana Moura

Poly[(ethylene)-co-(vinylacetate)] (EVA) is a thermoplastic copolymer composed of randomly distributed polyethylene and polyvinyl acetate sequences within the molecular chain. EVA combines toughness with excellent flexibility, impact and puncture resistance. Because of these properties, this material is largely used for foam production as padding in equipment for various sports and as a shock absorber in sport’s shoes. This work aims to study the influence of clay reinforcement on the performance of recycled polymer foams. The blend containing recycled HDPE (high density polyethylene) and recycled EVA (70/30 wt%, respectively) reinforced with 2 wt%of clays were prepared by melt extrusion, using a twin-screw extruder to obtain the composites. The composites and foaming agent were fed into a special single screw extruder for foaming. The samples of HDPE/ EVA/Clay foams were characterized by tensile test, Field Emission Scanning Electron Microscopy (FE-SEM), Thermogravimetric Analysis (TG), Differential Scanning Calorimetry (DSC), X-ray Diffraction (XRD), density measurement and the correlation between the results was evaluated.

Mar 1, 2018

By P. R. La Pointe, H. C. Ganow

The production of both over- and undersized coal fragments is a constant problem to open pit operators in the Powder River Basin. Operators strive to achieve production blasts that economically minimize the weight percentage of over- and undersize coal. However, natural fractures influence blast fragmentation, and can impose limits on the final fragment size distribution. ARCO&apos;s Anaconda Minerals Company studied the limits placed by natural fracturing as part of a wider geotechnical study of the Wyodak Coal in the eastern Powder River Basin, Campbell County, Wyoming. Measurements of fracture orientation, size and spacing were made at ARCO&apos;s Black Thunder Mine. These data were used to form statistical distributions for natural fracture size, spacing and orientation. An algorithm was created to select fracture properties at random from these distributions and to form hypothetical blocks. The blocks were then numerically "sieved" to derive pos- sible particle size distribution curves. These curves are compared to fragmentation results from samples taken from three test blasts. All test blasts yield very similar lognormal fragment size distributions. The median particle size varies from 1.25 to 2.0 in.(3.2 to 5.1 cm), the mean from 4.0 to 8.5 in. (10.2 to 21.6 cm). The standard deviation was about 1.6 in. (4.2 cm). Coal fines (fragments < 0.25 in. or 0.64 cm) are about 15%. Calculated fragment distributions for the natural fractures predict the median size well but underestimate the variance. Algorithm modifications to account for processes known to occur in the comminution zone near the blast hole significantly improve the match in the fine coal size range. The match suggests that spacing of fractures, rather than fracture length, controls the formation of fine- and medium-sized fragments. On the other hand, the oversize coal is controlled by the fracture lengths, rather than the spacing. Data from subsequent test blasts support this idea. By increasing delay times from 8 msec to 17 msec, engineers were able to reduce fines to 7% - 10% but could achieve no further improvement, despite changes in shot pattern geometry, decking and hole size. The hypothetical fragment distributions show that, even without blast enhancement, about 5% of the natural coal blocks are fine-sized.

Jan 1, 1986

By K. W. Morris

Of the fossil fuels used for power generation coal is by far the most variable and complex in its properties. A thorough review of the characteristics of the coal to be fired is essential before boiler design can begin. Major parameters such as heating value, moisture content and ash properties will determine not only the boiler size and configuration, but also the performance of the unit with respect to the thermal efficiency, particulate and gaseous emissions, and unit availability and reliability. An example of a review completed on a large low-rank coal deposit for a power plant will be described.

Jan 1, 1983

Jigging is a process of particle stratification in which the particle rearrangement results from an alternate expansion and compaction of a bed of particles by a pulsating fluid flow. The rearrangement results in layers of particles that are arranged by increasing density from top to bottom of the bed. The particles, in addition to the vertically expanded and compacted bed motion, move continuously, horizontally across the supporting screen and helped and influenced by the feed material that is introduced at one end. Following the particle stratification, the particle bed is physically ?cut? at a desired horizontal particle density plane to separate the desired product from the less dense gangue material. The issue of correct pulse characteristics (shape, amplitude and frequency) for the optimal metallurgical stratification of air pulsating jigs has been the subject of much discussion over the years. The accuracy of the dissymmetric stratification depends on the control parameters and the mechanical condition of specific equipment used. This paper will touch on some of the control and mechanical parameters affecting the separation efficiency.

Jan 1, 2010

By B. A. Wills

Much research effort has been spent in attempting to reduce the high energy costs in grinding, but relatively little in developing methods to enhance the liberation of the minerals from each other. This paper presents some ideas on the nature and role of grain boundaries in mineral assemblies, and their influence on the propagation of cracks through the rock. It is argued that if the mechanisms of fracture are more clearly understood, crack propagation may be controlled in such a way that intergranular fracture dominates breakage, producing less fines and a higher degree of liberation.

Jan 1, 1995

By A. R. Kiani-Rashid

Controlled graphitization has become known as a practical method for improvement of wear resistance and machining properties in steels. In this paper, the effect of heat treatment on microstructure of CK45 steel has been investigated. Austenitising was carried out at 920°C for 5 hours. Besides, isothermal transformation was conducted at 750°C in the time range of 1-20 hours. The microstructure of the steel considerably changes by this heat treatment process which exhibits the effects of temperature, appropriate austenitising duration and isothermal transformation. Conducted experiments show a suitable distribution of semi-spherical graphite particles especially on the surface of the steel. Also, analyses demonstrate that the amount of formed graphite in the austenitising temperature 920°C is more than graphite in single heat treatment temperature of 750°C.

Jan 1, 2010

By Francis C. Furman

Microscopic evidence indicates that the high sinterability of certain commercial dolomites is tied to specific dolomite textural characteristics. This study encompasses detailed characterization of the unprocessed dolomite and sintering doloma results. The chemical and mineralogical compositions, insoluble residue, chemistry homogeneity, crystal size, primary carbonate texture, secondary dolomite texture, deformation structure, porosity type, porosity, and density of the raw dolomite were observed. These characteristics are compared with sintering trials of <74um powder-compacts samples in which holding times were varied. The evolution of the dolomite characteristics are reviewed and related to the final sintered doloma characteristics. The critical characteristics of a single-stage sintering brick dolomite are the following: 1) primary oolitic texture, 2) dolomite purity, 3) dolomite stoichiometry 4) minimal impurities, less than 1 weight {%} Fe2O3 Al2O3 and SiO2, 5) chemical homogeneity, 6) high density, 7) very low porosity, S) very coarse homogeneous crystallinity, 9) nonplanar dolomite texture, 10) abundant strain related slip microdeformation structures, 11) minimal subsequent alteration. Even with grinding to <74um the nonplanar dolomite texture and slip deformation still have a major effect on doloma sintered density. The three newly identified characteristics of single-stage sintered refractory brick dolomite are their primary oolitic texture, secondary nonplanar texture and abundance of stress related microdeformation structures. The primary oolitic texture reflects a homogeneous pure carbonate with respect to chemistry and crystal size secondary nonplanar texture produces crystals with large surface area to volume ratio. Stress related slip deformation moves CO, groups in to the same site of another CO, group but different orientation which is very unstable. All of these characteristics may facilitate the formation of higher density dolorna sinters.

Jan 1, 1995

By Dion Weatherley, Raúl Castro, Pablo Cid, René Gómez

In underground mining, hang-ups due to coarse fragmentation are frequently observed in drawpoints, drawbells, and ore passes during ore draw. Hang-ups can often require operational interference and hang-up removal activities. Drawpoint and drawbell design has been shown in some studies to influence hang-ups; however, the full extent of this influence remains open to question. In this study, the discrete element method was used to analyze the effect of hang-ups on three distinct drawbell geometries: the Drawer type, Circular type, and El Teniente type. The drawer type was used as the base case given that data was available from a physical model in which hang-ups were studied. The drawer type base case data was then used to calibrate our numerical model. Results show that the El Teniente drawbell geometry sustained 13% more hang-up events as compared with the base case, while the circular drawbell geometry had 16% fewer hang-up events than the base case. From this study, it can be concluded that fewer hang-up events will occur with a rounded drawbell geometry.

Apr 11, 2023

By AJ Rorke

Blasting trials using Daveytronic Electronic Delay Detonator systems (EDD’s) were conducted at the Alpha Ferro Quany (Pretoria) and the Eikeboom Colliery near Witbank in November 1999. The objectives of the trials were to determine the influence of accurate hole firing on rock fragmentation, blast-induced vibration and blast throw. This paper provides an outline of the trials and an analysis of the results. The results were compared with a normal shock tube initiation system. Fragmentation was measured using video-imaging techniques at the hard rock Ferro Quarry for one conventional shock tube blast and two EDD blasts. No significant difference was measured in the fragmentation between the shock tube blast and the two electronic detonator blasts. Joint planes mostly defme the fragments at Ferro Quarry. The fragment sizing was therefore controlled mainly by the rock structure and the blast timing appeared to have no influence. Vibration measurements made at Ferro Quarry indicate that electronic detonators have a marked effect on vibration frequencies compared to shock tube systems. The more accurate detonators resulted in a narrower f+equency band at lower amplitude with similar timing. By modifying the blast timing, the dominant frequencies were changed. The electronic detonators had a significant positive influence, therefore on blast vibration and its control. The timing scatter measured from the shock tube blast was considerable, with measured inhole detonator scatter at 48 ms over a sample of 19 units. Surface delay periods less than 42 ms would therefore not be able to provide effective sequential firing. The scatter of the Daveytronic units was below the 2 ms resolution of the high-speed camera used to film the blasts. Reliable sequential firing, even at very short delay intervals was considered the main reason for notable improved throw in an overburden blast at Eikeboom Colliery. Blast throw was improved by 25% for the test blast.

Jan 1, 2000

By Barry J. Welch

The production of primary aluminium can potentially lead to metal that, with minimum treatment, meets a high purity standard. Smelters that can achieve a significant proportion of their production in this manner have a competitive edge which is of growing importance as the use grows for such items as compact discs and the like. Superimposed on the desire to produce high quality metal are stringent environmental requirements that the industry must adhere to. The environmental &apos;legislation focuses on fluoride emissions and the approach adopted is towards a zero waste management philosophy. The fluoride recycling process does, however, result in volatile impurities being captured and recycled to the cell. Aluminium has an extremely high reduction potential and this results in a significant proportion of the recycled impurities being reduced at the electrolyte metal interface and thus contaminating the metal. This paper reviews sources of impurities and the impact of the operating procedures adopted on metal treatment.

Jan 1, 1996

By John J. J. Chen, Barry J. Welch

"The production of primary aluminium can potentially lead to metal that, with minimum treatment, meets a high purity standard. Smelters that can achieve a significant proportion of their production in this manner have a competitive edge which is of growing importance as the use grows for such items as compact discs and the like. Superimposed on the desire to produce high quality metal are stringent environmental requirements that the industry must adhere to. The environmental legislation focuses on fluoride emissions and the approach adopted is towards a zero waste management philosophy. The fluoride recycling process does, however, result in volatile impurities being captured and recycled to the cell. Aluminium has an extremely high reduction potential and this results in a significant proportion of the recycled impurities being reduced at the electrolyte metal interface and thus contaminating the metal. This paper reviews sources of impurities and the impact of the operating procedures adopted on metal treatment.IntroductionSeveral factors have contributed to the immense growth in the aluminium smelting industry. Initially the ready availability of hydro electricity provided a primary reduction energy source for the production of the light-weight metal. Because of its unique properties and innovation in the industry there has been a continued exploitation of its unique properties, especially at the high purity end of the metal. The industry has shown considerably versatility and innovation in adapting to the ever increasing demands of quality and purity. It is however a competitive industry and the ability to produce high purity grade metal (>99.9% pure) gives a competitive edge. Emerging markets such as for CD ROM disc production etc, will keep the quality demand stringent.While the industry has met the continuing demands for metal quality, it has also had to respond to stringent environmental requirements for emissions from the production plant. Like all extractive metallurgical processes carbon dioxide is an inevitable reaction byproduct. However, the volatilization and hydrolysis of the solvent electrolyte leads to fluoride emissions that are potentially harmful. Accordingly, the industry has adopted essentially a zero non-process waste management approach. All cell emissions, including reducible impurities, are recycled back to the cell. This has had a significant influence on the metal treatment processes."

Jan 1, 1996

By Dermot M. Ross-Brown

The more important factors controlling the design of pit slopes are related to the local geology over which the designer has little or no control. Nevertheless, there are some factors over which the designer does exert some control and these concern the say in which the rock is excavated and supported. They include blasting, face cleaning, water control, and the use of rock improvement techniques. The paper discusses these factors and relates the extra costs incurred to the steeper slope angles that can usually be obtained. It is demonstrated that even a modest increase in bench angle of 5° through improved excavation techniques can pay off in a single push-back.

Jan 1, 1975

By Lex L. Udy

External detonation generated plasmas, highly ionized zones of reacting material ejected from the surface of detonating ex-plosive charges, are shown to be the cause of channel desensitization, i.e., the self-quenching of a detonating explosive column loaded in a borehole with an air annulus between the explosive and the borehole wall. The effects of this phenomenon on several explosive compositions and types are demonstrated and discussed. Explosives tested include aluminum sensitized and explosive sensitized slurries, ANFO, liquid explosives and dynamites. Various techniques are described that can be used to reduce or eliminate the plasma effect.

Jan 1, 1978

By M. Rudolph, A. D. Renno, H. Wu

In this study, synthetic pure cassiterite and cassiterite doped with Fe were successfully produced by sintering. Their crystal structure and chemical compositions are characterised by optical microscopy, X-ray powder diffraction (XRD) as well as scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) based chemical composition analysis. The electrostatic behaviour of synthetic and natural cassiterite was studied by electrophoretic measurements. Their floatability was studied by microflotation with two types of anionic collectors. Results show that the cassiterite floatability with these collectors behaves differently and lead to two opposite results: Natural cassiterite (enriched with Fe) > undoped pure SnO2 by using sulfosuccinamate (Aerosol® 22) Undoped pure SnO2 > Fe3+ doped > natural cassiterite (enriched with Fe) by using styrene phosphonic acid (SPA). Keywords: Synthetic cassiterite, lattice impurities, flotation, zeta potential, Aerosol® 22, styrene phosphonic acid

Jan 1, 2020

The introduction and subsequent ascendancy of autogenous and semi-autogenous milling for comminution circuits has undoubtedly lead to many economic advantages. From a process viewpoint, however, at least one downside has been the sensitivity of these machines to process input variations. Foremost among these is ore competence, though feed size comes a close second. This sensitivity is due to the reliance of ag/sag mills on the feed ore for their grinding media competence and size. Autogenous (ag) mills are the most sensitive in this respect with semi-autogenous (sag) mills being increasingly less so as the ball charge is increased. Increasingly designers and operators are recognising the importance of feed size and the benefits of manipulating it to improve performance. This has been achieved by installing additional crushing/screening capacity ahead of the ag/sag, better operation of the primary crusher, better control of segregation cased by stockpiles and bins and by changing blast design/practices to modify the ROM size distribution. This paper describes the influence of feed size distribution on ag/sag mill performance with reference to a range of plant data. It particularly concentrates on how changing blasting practice to modify ag/sag feed size can have a considerable overall benefit.

Jan 1, 2003

By H. J. Schulze

From a colloidal science point of view (Schulze 1984, Nguyen & Schulze, 2004) five micro-processes are responsible for successful particle-bubble formation: the approaching of the particle to the liquid-air interface, the thinning and rupture of the intervening liquid film, the expansion of the three phase contact perimeter, the generation of sufficient large capillary force to stabilise the aggregates and the transport process of particles into and within the froth layer. Flotation reagents influence mainly the thinning and rupture of the intervening liquid film between particles and air bubbles, the expansion of the three phase contact after the rupture of the liquid film and the stability of the aggregates against external destruction forces in the flow field. But it exist also a non-negligible influence on the approaching of particles to the bubble surface during the encounter process and on their passing over into the froth layer and the froth stability.

Jan 1, 2003

By S. P. Singh

"The geological features of a rock mass have a direct influence on its blasting characteristics. It has been observed that perimeter control techniques provide excellent results in massive crystalline formations but may give poor results in weak and or highly jointed formations.A field study was conducted with the objective of understanding the role played by the geological features of a rock mass in producing and controlling blast damage. The field work involved the assessment of blast damage at several operating mines and the blasting of drift rounds in a geologically dominant rock mass.The effect of rock strength, rock quality designation (RQD), joint parameters and hydrogeological conditions on blast damage is described below. The influence of number and thickness of weak layers on blast damage is also discussed below on the basis of quantitative data. In addition, critical particle velocity ranges for damage to different rock types have also been outlined in this paper."

Jan 1, 2001

By T N. Little

The aim of any rock breaking activity is to achieve success by developing designs that are blasting objective-specific and geology-specific, and then implementing such designs. This paper targets mining geologists with the aim of extending their knowledge of the rock fragmentation processes and providing insights to the significant relationships between geology and blasting. There are two main relationships, and if mining geologists appreciate both these relationships, then they can play a key role in optimising production. The business risk continuum is introduced to support this understanding. The first relationship is between geology and potential blasting hazards, and the operational complexity required to manage those risks. The risks associated with eight different ground types are discussed in terms of ground conditions, hazards and controls. These types are: reactive ground, hot ground, geothermal ground, fibrous ground, cavernous ground, combustible ground, pyritic ground and conductive ground.The second relationship is between the bench geology and blasting results. The blasting results discussed include: muckpile characteristics, remaining rock faces and blasting emissions. In this regard, some detailed insights and graphical examples are given for the influence of geology on blasting emissions, in particular, vibration, airblast and flyrock.A detailed description of the geological materials themselves can convey much useful information for blasting operators provided they are able to utilise this knowledge. Geologists are ideally suited to provide this description more effectively if they are familiar with the blasting process and the rock mass properties that influence blasting hazards and blasting results. It is also important to have clear statements of blasting objectives and associated operational targets, and this will maximise the likelihood of achieving the desired outcomes. The main aim of the paper is to highlight that geology is currently not fully utilised in the blasting process. In this regard, geologists are often not entirely aware of the blasting process and how they can contribute. The two significant relationships discussed above are integral parts of this process, and thus they are discussed as separate issues in the main body of this investigation.

Aug 22, 2011

By F. E. Pawlek

Copper concentrates can be comminuted in an attritor within a very short time to a particle size of 1 - 0.1 um. Addition of sodium hydroxide enhances commninution. The concentrates, suspended only in water, can be completely dissolved under oxygen over pressure and temperatures ranging from 120 - 180°C (248 - 356°F), because the surface area of the concentrate has been significantly increased by the ultra fine grinding. Addi¬tion of a small amount of silver ions to leach liquor containing sulfuric acid acted as a catalyst for the dissolution of chalcopyrite, because of the formation of local elements on the surface. The addition of C1- ions was also catalytically very effective. With this method it is possible to completely dissolve the copper contained in chalcopyrite concentrates after ultra fine grinding within 30 min at 110°C (230°F) under an oxygen partial pressure of 1 atm (14 psig). Several flowsheets demonstrate the industrial feasibility.

Jan 1, 1976

By J. M. Cases

Diffuse - reflectance Fourier - transform infrared spectroscopy, Hallimond tube flotation and microelectrophoresis have been utilized to investigate the reactions involved in the adsorption-abstraction of K-amylxanthate on finely ground galena and pyrite. In order to work under well-controlled conditions both minerals were wet ground in a specially built laboratory stainless steel or iron mill. Four surface products were found to be formed on galena: monocoordinate lead xanthate, non-stoichiometric lead xanthate, dixanthogen, and amyl carbonate disulphide. Only dixanthogen was observed on pyrite after using stainless steel rods, while ferric iron xanthate was found when iron rods were utilized.

Jan 1, 1989