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By R. H. Clarke

"INTRODUCTION Characterization of waste rock is frequently an oversight in mine planning which can contribute to significant delay in permitting and ultimately development. Thorough waste rock characterization is now a prerequisite to developing operating and closure plans acceptable to regulators and the public. BACKGROUND A long history of mine development has placed virtually all focus on the economic extraction and beneficiation of ore materials, while waste rock characterization and management received substantially less attention and consideration. Inadequate waste rock characterization has contributed to planning and management practices that are having unintended and unforeseen impacts to surface and groundwater, and in some cases lead to significant long term closure liability. In response, the regulatory community has developed guidelines for performing waste rock characterization during the pre- mine permitting process that in some cases seem onerous (BLM, 2013). Additionally, where a project proponent has not met these guidelines or results have been deemed “inadequate”, the Nevada Division of Environmental Protection and Bureau of Land Management (regulatory agencies) will only issue operating permits with rigid management practices to address the uncertainty, including requirements for lining waste rock facilities. WASTE ROCK CHARACTERIZATION FOR NEVADA PROJECTS Newmont Mining Corporation (Newmont) operations in Nevada approaches waste rock characterization like ore characterization, as it requires a similar investment of time, funding and attention to detail in order to pass public and regulatory scrutiny. Newmont follows a tiered approach to characterization that creates three over-lapping data sets representing an “escalation” in analysis at each tier, an approach that has thus far gained regulatory approval. “Tier 1” waste rock characterization for most Newmont projects begins with exploration drilling which follows internal standards and procedures. 20-foot composite samples are prepared from all drilling and analyzed for multiple trace elements using inductively coupled plasma mass spectrometry (ICP-MS) methods and for acid-base characterization using method ASTM-E1915. If the exploration program is successful and further resource or reserve development is recommended, the Tier 1 data are used to prepare a Waste Rock Characterization Plan (Plan) that will be presented to regulatory agencies as a part of baseline project characterization."

Jan 1, 2015

By Donald V. Fites

The evolution of open-pit mining has been rapid during the last two decades. The development of larger, more productive and efficient equipment has been one of the key factors in this open-pit advancement. Selection of the proper equipment and its correct usage is paramount to successful operation while maximizing return on investment. The quantity of material being moved prior to mining the saleable product is increasing at a significant rate. For example, at a southwestern copper mine more than two hundred million tons of over- burden have been removed prior to exposing an ore which contains less than 1% copper. A recent survey of twenty-three Western Hemisphere copper mines reveals the average strippingratio was 2.2:l with a range of 0.9-8.5:l. In the face of increased mineral demand, the resulting technological developments and rising overburden to ore ratios, many open-pit mines now use totally different concepts for the removal of ore and overburden. An increasing number of these concepts now being installed include wheel tractor scrapers as a major part of the material handling system for unconsolidated overburden removal. To say scrapers move only unconsolidated overburden is incorrect. On the contrary, ripped phosphate rock, copper ore, iron ore, and moderately consolidated overburden are also being moved by scrapers in various areas of the world. As reported in the Minerals Year- book, however, about one-half of the material moved in metal and non-metal mines is never drilled and blasted or broken by other means. We will, therefore, in this paper, concentrate on the role of wheel tractor scrapers in unconsolidated overburden; the area of greatest usage.

Jan 1, 1969

By Dee Bradshaw

"Process mineralogy’ is a form of applied mineralogy which focuses on addressing problems associated with the processing of ores. ‘Mineralogy’ is the scientific study of minerals and ‘mineral processing’ is the production of concentrates from ores. ‘Process mineralogy,’ however can be defined as the practical study of minerals associated with the processing of ores, concentrates and smelter products for the development and optimisation of metallurgical flowsheets, including the waste and environmental management considerations. This hybrid discipline consists of teams that include geologists, mineralogists, samplers, mineral processors and often others, working together. The degree of cross-training, communication and trust dictates the potential capacity of the team and where an appropriate work dynamic is fostered, in which relationships flourish as much as does the ethic of technical excellence, it is possible to develop technical capabilities that surpass those of conventional teams. The world’s demand for metals is ever increasing and ore deposits available for extraction and processing are lower grade and more complex, often containing deleterious elements that require tailored treatment. Generally, in the past, the technical challenges only needed to be overcome and assessed economically to make an ore deposit viable; increasingly and in the future, a more sustainable approach including environmental and societal considerations is needed. Process mineralogical assessment is increasingly providing the critical information that stands between failure or collapse and survival or success of some mining operations. In this paper, selected case studies are used to demonstrate the valuable role of the process mineralogy tools being used to provide the platform for innovative technology development. Their common attributes are discussed and distilled, thus providing some insights and potential guidance for addressing some of the likely future challenges of the mining industry."

Jan 1, 2014

By Nagahiro Saito, Takahiro Ishizaki, Mituhito Hirota, Akio Fuwa

"Owing to their extremely high toxicity in the environment, the dioxins have been attracting social, technical and scientific attention in recent years. The authors theoretically had predicted the thermodynamic properties of all the dioxins via quantum chemistry and statistical thermodynamics and elucidated the generation-decomposition behavior of dioxins in the equilibrium calculation· of C-H-0-Cl system. In actual combustion processes, it is said that metallic compounds have much influences on the dioxins behavior. The aim of this study is to reveal the roles of metallic compounds the generation-decomposition behavior of dioxins is revealed from the viewpoints of quantum chemistry. Especially, the catalytic effect of copper has been investigated for the reaction, 2HCl(g)--H2(g}+Cl2(g) and for the etherification reaction from precursors, which is Phenol(g) here, to dioxins. The catalytic role of Cu is shown to have much influence on the generation -decomposition of dioxins.1. IntroductionIt is well known that dioxins are very harmful not only for our health but also for that of our children and grandchildren because they are very stable substance and their reaction rates of decomposition are considerably low. On the other hands, it is not well know how dioxins are generated and decomposed; the generation-decomposition conditions and paths as well as the catalysts to decompose them'1l. The authors believe that the thermodynamic and kinetic study of dioxins is useful to find a solution to these issuers. The authors have been investigating the following problems to reveal the generation-decomposition behavior of dioxins; (a) the prediction of the thermodynamic parameters of dioxins (2), (3), (b) the generation -decomposition behavior of non-chlorinated dioxins by the thermodynamic equilibrium calculations in C-H-O system(4) and (c) the generation-decomposition behavior of dioxins by the thermodynamic equilibrium calculations in C-H-O-CI system(5). Summaries of these thermodynamic researches are as follows.(I) The thermodynamic parameters for dioxins, which had been unknown and/or inaccurate'6 l, could be predicted and are available within the scientific accuracy."

Jan 1, 2000

By E. A. Martell, K. S. Sweder

INTRODUCTION Lung cancer in uranium miners has been attributed to alpha irradiation of basal cells of the bronchial epithelium by radon daughters, primarily by 7.7 MeV alphas from polonium-214 (Altshuler et al., 1964). It also has been was observed that for a given cumulative radon progeny exposure, uranium miners who smoke cigarettes have an incidence of lung cancer about 10 times higher than nonsmoking miners (Lundin et al., 1969). It has been pointed out that the large excess of lung cancer deaths among smoking uranium miners is a multiplicative effect (Doll, 1971), which suggested possible synergistic interactions between airborne radon progeny and cigarette smoking. Experimental studies of the complex pattern of interactions between radon progeny, cigarette smoke particles, and the cigarette smoking process are in progress in our laboratory. Preliminary results, reported elsewhere (Martell, 1981), implicate alpha radiation from indoor radon progeny in the etiology of lung cancer in all cigarette smokers. Cigarette smoking produces high concentrations of smoke particles of low mobility and respirable size--particles between 0.5 and 4.0 µm in aerodynamic diameter (see below). The attached fraction of indoor radon progeny is highly dependent on the air concentration of small particles from cigarette smoking and from other combustion sources (Martell, 1981). The size distribution and other properties of radon progeny associated with cigarette smoke particles enhances their effectiveness in the induction of bronchial cancer in man. In this paper we discuss the properties of radon progeny associated with cigarette smoke, the fractionation of radon progeny and modification of their aerosol properties in burning cigarettes, the role of 218Po in these processes, the production of insoluble 214Pb and 212 Pb enriched particles in burning cigarettes, and the consequent differences in the patterns of polonium isotope alpha irradiation in the bronchial epithelium of smokers. EXPERIMENTAL PROCEDURES Experimental methods used in these studies involve the use of small experimental chambers of known radon and radon progeny concentrations in combination with aerosol collection and sizing techniques and sensitive radioactivity detection methods. The use of low-level [ß-] counting for radon progeny determination, providing a measure of 214 Pb plus 214Bi activity, makes it possible to carry out chamber experiments with small radon emanation sources and relatively low air concentrations of radon and radon progeny concentrations in the range from 100 to 1,000 pCi per liter. Thus, for example, in a typical experiment we use a 10 nanocurie 226Ra solution standard in a 10 liter chamber, providing an equilibrium concentration of 1,000 pCi of radon per liter. In small sealed chambers, radon progeny plate out rapidly on the chamber walls, with steady-state concentrations of airborne progeny less than 2 percent of equilibrium levels. This is experimentally convenient because, upon introduction of high concentrations of cigarette smoke particles or small particles from other sources, there is a systematic ingrowth of attached radon progeny, providing a tagged aerosol source of known age and radon progeny composition. In some chamber experiments a 226Ra solution standard of small volume, acidified to O.1N HNO3, was used as the radon emanation source. When used with a bubbler the holdup of radon in an 8 ml volume of 226Ra solution standard at 0.1N HN03 was only 2% of the total radon in the chamber at equilibrium. For experiments with 212Pb-tagged aerosols, we used a dry Ba(228Th) stearate emanation source prepared by the method of Hursh and Lovaas (1967). 226Ra and 222Rn determinations were made by radon gas counting. The 222Rn in a sealed air or water sample is transferred, using helium gas as a carrier, successively through a dry ice cooled trap at -80°C to remove water, through ascarite to remove C02, and through a small activated charcoal trap at -80°C to collect the 222Rn. Subsequently, by heating the charcoal to 400°C, the 222Rn is transferred next to an LN2-cooled capillary trap, and finally into an alphascintillation counting cell of the type described by Lucas (1957). As already stated, radon progeny activities were determined by low-level [ß-] counting, which provides a measure of 214Pb plus 214Bi. The radon progeny samples, collected on efficient Delbag polystyrene micro-fiber filters or on impactor foils, are placed in close, sandwich geometry between two thin-walled flow counters inside shielding anticoincidence counters and a 15 cm thickness of steel shielding. This configuration provides nearly 4II geometry and a low background of only 0.25 to 0.30 cpm. Aluminum absorber was added to provide a combined thickness of absorber and counter wall exceeding 7.0 mg/cm2 to eliminate the variable contribution of 7.7 MeV alphas from 214Po. 212 Pb determinations also were carried out by low-level [ß-] counting, in this case using a combined absorber and counter wall thickness of 9.0 mg/cm2 to eliminate contribution of 8.8 MeV alphas of 21 Po. In each experiment the [ß- ]activity data were corrected for decay to an appropriate common reference time for assessment of activity distributions.

Jan 1, 1981

By M. Tangstad

Keywords: Pyrometallurgy, ROMA, Norway, furnace, fines The ROMA project is a competence project on optimizing the usage of raw materials and energy in the ferromanganese, silicon, and aluminium industries. One of the items investigated in this project is the effect of fines on the furnace, and the usage of agglomerates versus lumpy ore. From lab-scale experiments it is shown, that for the charge to agglomerate in the furnace, the charge has to be exposed to a temperature higher than about 1200°C, independent of fines content. The fines less than 1 mm also showed higher agglomeration properties, compared to 2?4 mm, which showed no agglomeration property at all. The properties of agglomerates are very dependent on the pre-treatment of the agglomerate. Sinter and pellets, which have been heated to high temperatures, show a better strength, but also a lower CO reactivity. Sinter also shows a lower melting temperature compared to the ore.

Jan 1, 2011

By V. L. Eardley-Wilmot

Introduction We are all familiar with the bright and attractive colours of the roofs of our suburban houses and country cottages, but few of us fully appreciate the complex and highly technical nature of the business which produces these roofings. Roofing granules consist of small broken particles of certain types of rocks, burned clay products, or slag. They are used either in their natural state or artificially coloured and are affixed onto one surface of asphalt sheeting. Their main functions are to protect the roof against external fire hazard, prolong its life, and enable it to withstand extremes of weather over a period of years without deteriorating. Pleasing designs and colours are added attractions. The reverse, or inner side, of the sheeting is coated with a film of talc or fine mica to prevent it sticking when rolled up for convenience of handling for transport. The finished sheets or strips are cut into a variety of shapes for roofing shingles, or for sidings which resemble rows of bricks separated by mortar. In Canada, the consumption of roofing granules has increased fourfold in the past decade and indications are that the industry will continue to expand. At present, fourteen plants are engaged in manufacturing granule-coated roofings, but, apart from a relatively small output of natural granules by two producers in British Columbia, only one eastern producer makes both natural and coloured granules in Canada, and these only for its own use. The annual consumption is now over 77,000 tons of roofing granules valued at more than $1,600,000, but about 62 per cent of the tonnage is imported. It is thus apparent that the production of Canadian-made granules, both natural and coloured, could be considerably increased. This paper is presented in order to give an outline of the industry and at the same time to point out its difficulties and pitfalls.

Jan 1, 1946

By C S. Szentesy, K Howie

The Rosia Montana gold deposit is located within the æGolden QuadrilateralÆ area in the Apuseni Mountains of Transylvania, Romania. The deposit is situated approximately 85 kilometres north of the regional centre of Deva, within the province of Alba, at elevations of up to 1100 metres above sea level. The Rosia Montana deposit contains a current resource of 344.07 million tonnes at an average grade of 1.3 grams per tonne (g/t) gold (Au) and 6.0 g/t silver (Ag) for a total (measured, indicated and inferred) contained resource of 14.29 million ounces of gold and 67.00 million ounces of silver. The resource was calculated using a 0.6g/t Au cut-off, a 10 x 10 x 10 metre block size and multiple indicator kriging. The low sulfidation style epithermal mineralisation at Rosia Montana is hosted within Tertiary age dacite intrusions and related vent breccias. Mineralisation is generally disseminated and associated with silica, adularia, illite, pyrite and carbonate alteration of host rocks, with minor late carbonate-base metal veins. Precipitation of precious metals is generally considered to have occurred as a result of over-pressurization, boiling and subsequent brecciation. The dacite intrusions are hosted in Cretaceous shallow marine and deltaic shales and slates, which overlie older Paleozoic sedimentary and metamorphic rocks within uplifted sections of oceanic sea floor.

Jan 1, 2002

By M. E. Poad

In 1986, a cooperative effort by the Homestake Mining company, the U.S. Bureau of Mines and the University of Utah was initiated to determine shaft stability while recovering high grade ore in a nearby pillar. Premining finite element simulations indicated the shaft would remain in elastic ground. Six years have elapsed and, despite some initial concern during the first lifts, it appears that the bulk of the original reserve will be safely and profitably recovered. An integrated application of rock mechanics tools from laboratory testing through numerical modelling to mine measurements and observations contributed substantially to the operational success of the project.

Jan 1, 1994

By D. R. Rathburn

Jan 1, 1962

An automatic control system of a longwall roof support is dis-cussed. Hydraulic automatic control systems for longwall roof support have not met all requirements for such systems. Utilization of standard hydraulic elements to form a system that would-comply with all demands leads to a very complicated structure with a large number of hydraulic hoses within and between adjacent supports. So, only simplified systems have been made. This paper describes the multifunctional valve that per-mits realization of any desired logic functions, while maintaining a com-pact form, and analyses its application as a fully hydraulic automatic control system of a roof support.

Jan 1, 1985

By Batric Pesic

Dissolution of gold with elemental bromine was studied by using a rotating disc technique. The main parameters studied were: bromine concentration, stirring speed, pH, and temperature. Additionally, effect of copper, iron, and manganese was also examined. A special attention was paid to elucidate the role of cations, primarily Na+, during gold dissolution. It was found that gold dissolution with bromine was characterized with two pH regions. Below pH=7, gold dissolution was independent of pH, and above this value, gold dissolution decreased with pH increase. Gold dissolution rates were proportional with concentration of bromine. Two regions, diffusional and kinetic, were observed with respect to stirring speed. with respect to the role of Na+, and cations in general, they play absolutely no role during gold dissolution with bromine, unless they are in their lower oxidation state and become oxidized by bromine. In that case they have a negative effect because of bromine consumption.

Jan 1, 1991

By Batric Pesic

Gold dissolution with bromine was studied by using the rotating disc technique. Geobram TM 3400 was used as a source of bromine. The parameters studied were: rotating speed, Geobrom 3400 concentration, pH, temperature, sulfuric and hydrochloric acid concentration, and the concentration of various cations (copper, iron, zinc, aluminum, manganese, potassium and sodium) and anions (chloride, bromide, sulfate, nitrate, and iodide) According to the Levich plot and activation energy, gold dissolution was controlled by a chemical reaction rate. Copper, iron, and manganese in their highest oxidation states, aluminum, zinc, sodium and potassium did not have any effect on gold dissolution rate. The presence of manganous ion dramatically decreased the gold dissolution rate. Kinetic performance of bromine, in the form of Geobram TM 3400, was compared with performance of cyanide and thiourea.

Jan 1, 1990

By Batric Pesic

Dissolution of gold with sodium bromate solutions of various compositions was studied by using a rotating disc technique. The role of bromide ion, acid and externally added bromine was examined. It was found that sodium bromate could not dissolve gold in the absence of either acid or bromide ion, or both. When acid was absent, no bromine necessary for gold dissolution could be produced. When bromide ion was absent, formation of soluble gold bromide species, AuBr,-, was not possible. Bromate concentration had a complex effect, and it was dependant on bromide ion concentration. For fixed initial bromide ion concentration, gold dissolution rate increased with sodium bramate concentration increase until certain level, beyond which further increase of bromate concentration decreased the gold dissolution rate. The negative effect of bromate was explained by the depletion of necessary bromide ion. Sulfuric acid concentration effect was a function of initially present bromine.

Jan 1, 1992

By Richard Frentress, Dave Donelon, Robert Henderson, Mike Warnert

"The Round Mountain gold mine is an open-pit mining operation located 97 kilometres north of Tonopah in Nye County, Nevada. Gold has been produced from the property since 1906.Gold is currently recovered using a combination of four independent processing operations. These include a 10,000 ton per day mill, a 30,000 ton per day, crushed ore heap leach, a 150,000 ton per day, run-of-mine ore heap leach and a small high-grade gravity concentration circuit. In 2002, Round Mountain Gold Corporation produced 755,494 troy ounces of gold at a total direct operating cost of US$2.14 per ton ($193/oz).This paper presents a summary of the Round Mountain operations and discusses some of the processing innovations that have enabled the mine to profitably recover gold from a large low-grade ore body.INTRODUCTIONRound Mountain Gold Corporation is a 50/50 joint venture between Kinross Gold Corporation and Barrick Gold Corporation. Kinross acquired its ownership interest in the Round Mountain mine upon completion of combination with Echo Bay on January 31, 2003. The joint venture partners continue to support an aggressive exploration program in the vicinity of the mine in order to add reserves and extend the mine life.The Round Mountain mine currently operates a conventional open pit that is approximately 8,200 feet long, 4,900 feet wide and 980 feet deep. Mining is conducted on 34-metre benches by electric shovels and front-end loaders paired with 150, 190 and 240-ton haul trucks. Blasthole samples are collected and assayed and provide the control for ore segregation. Based upon these assays, blasted pit rock is determined to be run-of-mine Dedicated Pad ore, crushed Reusable Pad ore, high-grade ore or waste.Gold is recovered using a combination of four independent processing operations. These include run-of-mine ore heap leaching (Dedicated Pad), crushed ore heap leaching (Reusable Pad), milling and the gravity concentration circuit. Non-mineralised rock is delivered directly to the waste dumps. Low-grade ore is trucked directly to the Dedicated Pad and medium-grade ore is crushed and placed on the Reusable Pad. High-grade ore is handled in one of three ways: 1) leached on the Reusable Pad and offloaded to the mill; 2) sent directly to the gravity plant with tails reporting to the mill; or 3) sent directly to the mill or mill stockpile. The gold particle size distribution of highgrade ore determines the processing method."

Jan 1, 2005

By J M. F Clout

The Roy Hill Project is an independent integrated port, rail and mine development in the Pilbara region of Western Australia. The bankable feasibility study for the project was completed in January 2011 by Roy Hill Holdings Pty Ltd, a wholly owned subsidiary of Hancock Prospecting Pty Ltd. The Project will deliver 55 Mt/a of premium quality iron ore to a rapidly growing market with a mine life of over 27 years. This study is based on exploiting a 1.2 Bt bedded resource of microplaty haematite-rich Marra Mamba, from which 562 Mt of reserves has been delineated to date. A further 1.1 Bt resource of detritals and low grade bedded is proposed to be mined once the bedded high grade resource is depleted. Roy Hill lump and fi ne ore products will compete strongly with other Pilbara products. As a low cost producer, Roy Hill is on track to capture four per cent of the global seaborne traded iron ore market. The project decision to proceed is targeted for Q2 2011 to enable first ore on ship by Q2 2014.

Jul 11, 2011

By J. D. Price, W. M. Bertholf

One of the chief difficulties with which the operator of a coal washing plant has been forced to contend is the handling of the very fine coal. First he has the problem of separating the fine coal from washery water. This is usually accomplished by the use of settling cones or Dorr thickeners: in either event the separated fine coal contains a high amount (40 to 80 pct) of water and, somewhat loosely, dependent upon the size of the coal particles present, may be known as sludge or slurry. His second problem is the satisfactory further dewatering of such separated sludge and/or slurry.

Jan 1, 1949

By V. GUDKOV

THE iron-ore deposits of Russia were estimated at 2,200,000,000 by the Russian Geological Survey, in 1910; but this estimate must be considered as being far too low. The estimate for Siberia, which had been explored very little for iron ore, was placed at about 27,000,000 tons. The exploration, in 1912-14, of the three iron deposits-Blagodat, Baakal and Kamensk-raised the estimate of the iron-ore reserves or the Urals from 282,000,000 tons to about 400,000,000 tons. Conservative estimates of the explored deposits made by the writer in 1915, gave the following figures: Southern Russia 900,000,000 tons, Ural Mountains 500,000,000 tons, Central Russia 900,000,- 000 tons, Siberia 100,000,000 tons, Caucasus 20,000,000 tons, or a total of 2,420,000,000 tons of iron ore, or 1,200,000,000 tons of pig iron.

Jan 1, 1921

By C. W. Washburne

Continued discussion of the paper Of ROSWELL H. JOHNSON, presented at the New York meeting, February, 1015, and printed in Bulletin No. 98, February; 1915, pp. 221 to 226. See also Bulletin No. 101, May, 1915, pp. 1157 to 1162, and No. 103, July, 1915, pp. 1449 to 1450. C. W. WASHBURNE, New York, N. Y. (communication to the Secretary*).-Mr. Johnson recognizes that connate waters must be driven, outward toward the earth's surface. He considers the ascent due to the settling and packing of the underlying sediments and to the formation of gas within the rocks, supplemented by abyssal pressures. The origin of the methane in the sedimentary strata probably is not simple. There are three possible modes of origin: (1) as marsh gas formed near the surface and entrapped in the sediments; (2) from abyssal sources; (3) by the decomposition of organic matter buried in the sediments. The abyssal source is generally negligible, and in all cases doubtful. The third origin is the most important in the gas fields. A fourth mode of origin, by the dissociation of liquid hydrocarbons, frequently has been suggested, but it is improbable, because crude oils are exothermic. Therefore they have no tendency, to split or decompose at low temperatures, as do endothermic substances, such as coal, which is geologically by the loss of methane, water, and carbon dioxide. This cannot happen to a hydrocarbon until its temperature of dissociation (" cracking point") is reached, which is over 250'.C. for the most easily cracked hydrocarbons and over 400° C. for others. Engler says that the dissociation of fats and waxes into oils is an endothermic process, thereby unconsciously nullifying his own theory of the dissociation of these substances at low temperatures. However, recently I have found reason to think that heat is liberated by the disruption of the molecules of fats and waxes, as it is in the molecular decomposition of the substances of wood, coal, etc. If this tentative opinion is correct, and Engler wrong, then it seems that the Engler-Höfer hypothesis of the origin of oil becomes not only possible, but even probable.

Jan 9, 1915

By Blake M. Loring

RECENTLY the S-curves for 30 to 40 alloy steels have been published.1,2 These steels show individual characteristics, which make each additional S-curve of great interest. There are important differences in the mechanism of the transformation process, the type of transformation product, and the influence of alloying elements. Steels of the same general alloy composition may possess such variable characteristics with regard to the length of time of isothermal transformation that an S-curve for each heat of steel may be desirable. In the present work the isothermal transformation of a steel having the following composition and grain size was studied: 0.20 percent carbon; 0.21 manganese; 0.026 phosphorus; 0.017 sulphur; 0.056 silicon; 1.45 chromium; 3.25 nickel; austenite grain size, 7. The progress of the isothermal transformation was followed by several different methods, including hardness measurements, dilatometer observations, and examinations of the microstructure. It was not expected that these methods would be in precise agreement.3 Accordingly, the changes in microstructure and hardness were given additional weight in determining the initial stage of transformation and the dilatometer measurements were relied on in estimating the completion of the process. The beginning of transformation was indicated by I per cent of transformation products and the end of transformation by about 99 per cent. The reproducibility of the various methods in the ranges of highest sensitivity was checked by several observations at each time and temperature. The steel used in this investigation was annealed for 24 hr. at 925°C. Macroetching revealed no serious segregation. The specimens for the metallographic and hardness investigations were 1 1/4 by 1/2 by 1/8 in. Wires attached to the samples were used for handling, instead of tongs, to avoid chilling. The specimens were heated at 845°C. for 1/2 hr. and quenched into constant-temperature salt baths held at various temperatures from 205° to 650°C. The time required to transfer the specimens was found to be about x 1 1/2 sec., and nearly 5 sec. more was required for them to come to the temperature of the bath. After various lengths of time in the constant-temperature baths the specimens were quenched in water at 21°C. The specimens were cut in half for the metallographic examination, to provide a surface free from decarburization. To determine the beginning and end of the transformation the percentage of transformation determined metallographically and by hardness was plotted against time. A planimeter was used in the metallographic determination. The hardness and metallographic determinations made at room temperature were confirmed reasonably well by dilatometer measurements taken during the process of transformation at the various temperatures. Two dilatometers were used to

Jan 1, 1941