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By Frederick J. McGarry, Parviz F. Rad

Although tunneling machines have attained very high advance rates in medium-hard rocks, the need for frequent repairs has slowed their use in very hard rocks. Laser- assisted tunneling is expected to improve tunneling machine performance by improving either specific energy or amount and quality of muck. The beneficial effects of lasing are the initiation and growth of microcracks from differential thermal expansion of grains, and overall spalling in the vicinity of the lased area. Using a constant thrust rock cutting device with disk cutters, the effects of cutter geometry, cutter diameter, thrust, and speed variations on specific energy and muck were explored and the improvement in performance of disk cutters caused by lasing was evaluated. It was found that the improvement depends on beam power and density, beam speed, pattern of heating, and cutting pattern and procedure. A focused beam slightly offset from the cutter path gives the most improvement both when cutting on a smooth surface and when cutting in previously cut grooves.

Jan 1, 1971

By Donald P. Tuchman, Robert P. Vinson, Steven J. Page

Researchers at the National Institute for Occupational Safety and Health (NIOSH) have long used stationary tapered element oscillating microbalances (TEOMs®) in laboratory settings. They have served to assess the mass concentration of laboratory-generated particulates in experimental , dust chambers and they provide a reference method for comparison with other particulate- measuring instruments. Current NIOSH research is focused on further adapting TEOM technology as a wearable personal dust monitor (PDM) for coal mining occupations. This investigation's goal is to help identify, quantify, and provide means for resolving certain TEOM- related error. The present research investigated bias caused by thermal effects on filter assemblies. New filters used in the PDM for 8 h tests show an average positive bias of 25.5 pg, while similar tests of equivalent filters used in two 1400A model TEOMs show an average positive bias of 34.3 µg. The derived bias values allow correction of previously collected biased data. Also, pre- heating the filters for 24 h at 46° C shows significant bias reduction, with PDM pre-heated filters subsequently averaging -3.3 µg and 1400A TEOM filters averaging 5.9 µg. On a single-point comparison to gravimetric sampling, a 25.5 µg bias is only significant at low mass loadings. At 2.5 mg, this bias represents a negligible 1 % of the mass measurement. If ordinary linear regression is used, the bias is still insignificant. However, if the more valid weighted linear regression is used, it gives more weight to the smaller dependent variable values, which are more impacted by the bias. Consequently, what is 1% bias on a single high-mass value can translate into a larger bias percentage at high-mass values when performing a weighted regression on data that include a large number of low-mass values.

By Imre Gombköto, Barnabás Csoke

"Raw material management means not only mining and processing of primary raw materials like ores, but means also collecting and processing secondary sources of raw materials. Recycling is one of the most developing field of raw material management in Europe, and its solutions are derived from mineral processing roots and principals. Complexity and challenges of the field of recycling results innovative solutions of material processing- Since European Union identified 20 raw materials as critical (CRM) due to lack of primary sources within the border of the EU, recycling become more recognised as source of different raw materials. WEEE is the waste streams contains many of the critical elements and along them at least 15 different species of plastics of which recycling is delayed by a lack of effective separation technique. Most paper deals with separation methods based on different specific gravity, triboelectric charge or surface properties of plastic species. Plastics however have differences of thermal properties and thermoplastics, duroplasts and elastomers can be recognised. The experiments described in the paper aimed to determine thermo adhesive behaviour of plastic species often identified in WEEE streams for separation purposes. According to the results, some plastic types as PS, PP. PC or PVC and PET pairs are possible to easily separate from each other, however different additives are changing thermo adhesive properties of most of the plastics that makes industrial process difficult to develop. Along thermo adhesive behaviour, combination of physical interaction can be used to enhance separation selectivity.INTRODUCTIONPlastics has a relatively long term of history as a light, multi-functional material in construction, packaging, automotive industry and electric and electronic products. There are a numerous types of plastic species can be used for various applications therefore they amount are growing from year to year. This quantity however become part of the waste stream and while metal recycling has been done for decades due to its economic value - cheap plastic parts are less desirable as secondary products. In 2013 an annual 5% of plastic production growth has been estimated with a base data of 265 million tonnes at 2010 (Guiqing & Zhenming, 2013). Since landfill requirements are increasing while—especially in Europe where actual regulations are trying to deflect waste from landfills - landfill capacities are decreasing, costs are become more and more expensive, Applications like energy production based on plastics as a fuel or recycling are some of the options can be applied. Direct incineration of plastics are applied at many plants - in most cases where waste consist of dangerous substances are incinerated because plastics high calorific value helps correct average mixture composition enable operators reaching high enough temperature for combined power and heat generation while most of substances—like PAH, PCB or dioxins—are destroyed. Another path is using low temperature reductive cracking due to pyrolysis process, however the chance having higher concentrate of carcinogen substances in the products are higher since it applies around 400°C during the process."

Jan 1, 2016

By I. D. Ustinov, V. A. Arsentyev, A. O. Mezenin, A. M. Gerasimov

"The solid mineral raw materials of the sediment deposits containing the argillaceous variations such as the coal and the potash ores are the most multi-tonnage solid minerals mined and processed in the territory of the Russian Federation. Both types of the deposits have relatively simple geology aspects with large and medium-sized solids and as a rule, the most often, with the regular bedding which are characterized by the fitchery thickness and the internal structure. Such deposits are very difficult for mining and processing. The thermal modification of this of ores allows changing the physico-chemical properties of its components in such a way that their further processing - grinding, separation, transportation and storage can be carried out without the use of process water or significantly reduces its consumption. The purpose of the present study is to increase the efficiency of the mineral processing containing the layered aluminum silicate by reducing their negative impact on the basic dressing processes, the separation of suspended matters and the storage of waste. INTRODUCTION Many deposits of minerals are associated with the presence of layered silicates such as the argil, mudstones, argillaceous slate - highly hydrophilic mineral varieties which have the ability to swell in the water. This ability to self-disperse creates the great difficulties both for the extraction and the processing of such ores. Since the dressing of most minerals is associated with the use of wet processes, where in contact with water the swelling layered silicates are dispersed to a particle size of less than 50 µm, but due to their high hydrophylic property they form bonds that promote the formation of so-called structured suspensions having increased viscosity. In this case the structured suspensions make it difficult to perform the separation operations as the classification, the gravity and magnetic separation, the flotation and thickening and filtration operations."

Jan 1, 2018

By D. P. Patil, B. K. Parekh

Water is the mainstay for beneficiation of fine size coal and minerals; however, it is also the least desirable constituent in the final product. The basic concept of the novel process described in this paper is based on the differential surface heat absorption capacity of individual particles, which differs for different species of mineral. When a mixture of fine material is exposed to a radiant energy source, the various solids components present in the mixture will absorb heat energy depending on their composition and there will be difference in the surface temperature of the particles. When this differentially heated solid mixture is placed on a moving belt, which is coated with low temperature melting resin, the hotter component of the mixture will stick to the belt and relatively cooler will stay free on the belt and fall off at the end of the belt run. Experiments were conducted with pyrite, coal and quartz of 6 x18 mesh particle size. The goal of the test program was to find the optimum conditions at which there exists a required temperature difference between minerals and coal particles by controlling the operating and system variables. Preliminary tests results showed that there is a potential for separating mineral matter from coal using the thermo-adhesive separation technique.

Mar 2, 2022

By D. PATIL, B. K. Parekh

Water is the mainstay for the beneficiation of fine-size coal and minerals, but it is also the least desirable constituent of the final product. The basic concept of the novel process described in this paper is based on the differential surface heat absorption capacity of the individual particles. When a differentially heated solid mixture is placed on a moving belt that has been coated with low-temperature melting resin, the hotter component of the mixture will stick to the belt while the relatively cooler component will stay free on the belt and fall off at the end of the belt run. Experiments were conducted with pyrite, coal and quartz particles of 6 × 18 mesh size. The goal of the test program was to find the optimum conditions at which there exists a required temperature difference between minerals and coal particles by controlling the operating and system variables. Preliminary test results show that there is a potential for separating mineral matter from coal using the thermo-adhesive separation technique.

By M. Fafard, M. Dupuis, P. Goulet, J. Bédard

Start-up of a Hall-Heroult cell is a delicate task that can affect pot performance and pot life. Modem practices for high amperage cells involve preheating the lining before the molten electrolyte is poured in. Different preheating methods and heat-up schedules are used throughout the industry, and the optimum between a short start-up and damage minimization to the cell is elusive. Direct electrical coke-bed preheating is one of the most common techniques. This practice typically results in a non-uniform surface temperature distribution and can generate detrimental thermal gradients in the cathode blocks. Numerical modeling is an invaluable tool to study this complex problem and can help improve the preheating procedures. The modeling of the mechanical response of the lining is critical to detect risks of cathode block cracking or the development of gaps where liquids could leak into. Taking into account the baking of ramming paste, the quasi-brittle nature of carbon and the contact interfaces between different materials are examples of key elements to consider. A finite element slice model of a cell was built and simulations of different electrical preheating scenarios were performed using the inhouse code FESh++ to demonstrate what can be learned through thermo-chemomechanical modeling. The potential industrial application of the model is discussed.

Jan 1, 2006

By Tracy Brettmann, Melis Sutman, C. Guney Olgen

"The use of energy piles for geothermal heat exchange has been steadily increasing during the last decade, yet there are still pending questions on their behavior during temperature changes. This paper focuses on the thermo-mechanical response of three full-scale energy piles installed in Richmond, TX. The behavior of test piles subjected to thermo-mechanical loadings was studied in situ with the aim of quantifying the thermal influence on the performance and capacity of energy piles. An extensive field test program, including conventional pile loading tests and application of heating-cooling cycles was conducted on the test piles during a period of six weeks. For thermal load applications, the heat exchanger fluid with maximum temperature of 113°F (45°C) and minimum of 47°F (8°C) was circulated in the geothermal loops placed at the center of the test piles. Optical fiber sensors, vibrating wire strain gages, thermistors and thermal integrity profile wires were installed to monitor the strain and temperature variations along the energy piles throughout the field tests. The strain and temperature profiles during heating-cooling cycles on the test piles under static loads and without a maintained load were monitored to investigate the effect of thermo-mechanical and pure thermal loads on the energy piles, respectively. Conventional pile load tests were applied before and after the application of thermal cycles. The results of the pile load tests are compared to evaluate the effect of temperature cycles on pile capacity.IntroductionEnergy piles are deep foundation elements designed to access and exploit the relatively constant temperature of the ground and its heat storage capacity for efficient heating and cooling of buildings. The deep foundation elements that are already in place for structural support are integrated with adsorber pipes to perform as heat exchangers connected to ground source heat pump (GSHP) systems. With the use of energy piles, the heat energy is fed into and withdrawn from the ground for cooling in the summer and heating in the winter, respectively.Energy piles present an innovative way to harvest near-surface geothermal energy and to provide lower carbon emissions, however, there are still pending question on their performance. During heating-cooling cycles, energy piles experience temperature changes, which result in expansion or contraction of the piles."

Jan 1, 2017

By C. Y. Tang, Z. H. Chen, T. C. Lee

"In sheet metal forming process, the forming limit and strain distribution are governed by plastic instability and fracture following strain localization. It has been proved that the temperature gradient caused by plastic deformation as well as friction is one of the crucial factors to induce the strain localization in high-speed metal forming processes. In this paper, a numerical simulation of the sheet metal extrusion process has been conducted by using thermal-mechanical coupling finite element method. An improved mixed finite element method has been used to solve the large deformation elasto-plastic problem. In thermal phase, the transient heat transfer finite element method together with the Crank-Nicholson algorithm has been employed to determine the temperature field. Both the numerical results and the experimental observations reveal that the temperature gradient plays an important role in inducing the strain localization, which eventually leads to fracture failure in the sheet metal extrusion process.IntroductionSheet metal extrusion is such a process where the extrusion punch penetrates into one surface of the sheet metal material to let it extrude and flow towards the outlet of the die. This process can be used to produce protruding parts on a strip material. In engineering applications, the quality of the product is affected by many factors such as stress state, loading speed, material properties and lubrication condition. The research on failure mechanisms and improvement of formability in sheet metal forming processes by exploitation of differential thermal conditions has been of great interest recently [1-3]. It has been proved that the temperature gradient caused by plastic deformation, heat transfer, and friction between sheet and tools is one of crucial factors to affect 'the formability in high speed sheet metal forming processes [4]. In our previous study of sheet metal extrusion, it has been observed that plastic deformation is highly localized and some specimens are subjected to fracture failure in the form of crack propagation [5]. To understand this failure phenomenon, the effects of temperature gradients must not be ignored."

Jan 1, 2001

By Avijit Moitra

The behavior of the solidifying shell in the early stages of solidification has an important influence on the final quality of continuously-cast steel slabs. In order to understand the thermal and mechanical behavior of the shell, a two-dimensional transient piecewise-coupled finite-element model has been developed. The model simulates a transverse section of the slab as it moves down through the mold and incorporates the effects of heat conduction, solidification, shrinkage, turbulent fluid flow, thermal distortion of the mold and the visco-plastic behavior of the steel. Coupling between the thermal and the mechanical model is based on the mutual dependence of heat transfer across the interface between the shell and the mold and the size of the gap. The effects of mold distortion and taper on the gap size are also included. The effect of fluid flow has been incorporated via a heat flux imposed at the solid-liquid interface, which is obtained from a separate fluid flow model. The high temperature creep and plasticity of the steel is incorporated through a unified constitutive law defining the inelastic strain rates as a function of temperature, time and stress state. The model can be applied to various problems in continuous casting, such as the formation of surface defects and the design of mold taper.

Jan 1, 1992

By Thierno FALL

This paper describes the study of the work-roll during the hot rolling process thanks to a 3D model built with the Finite Element Method (FEM). In terms of computational cost, that method needs high resources compared to 1D model which are mostly used. However, the 3D model is built to have a better understanding of the work-roll thermal and mechanical behavior during the hot rolling process. The thermal model shows that the highest temperature reached during rolling are within the range of 500°C and 600°C. The thermal field input used to simulate the mechanical behavior of the work-roll shows a biaxial thermal stress state, in the circumferential and axial planes. However, a peak of radial stress is observed in the backup zone. It did not generate plastic strain but could influence the fatigue behavior of the work-roll.

Oct 1, 2019

By Dengfu Chen, Yi Yang, Chunmei Chen, Mujun Long, Shikai Gong, Junhao Sheng, Tao Liu

The relationship between thermo-physical properties of petroleum coke and temperature is of importance for determining of the operating parameters during the calcining graphitization process. In this paper, the variations of thermo-physical properties of petroleum coke versus temperature were investigated, such as the DSC-Tg curve, the specific heat capacity, the thermal diffusion coefficient, the thermal conductivity, and so on. The thermal analysis curve of petroleum coke showed synchronous thermal hysteresis at higher heating rates, indicating that a larger heating rate will cause delay of thermal effects. The thermal diffusivity of petroleum coke decreased during the calcining process. With increasing temperature, coefficient of heat conductivity and specific volume heat of the petroleum coke increased with a decreasing variation rate. The research provides a database for the calcining graphitization process of petroleum coke.

Jan 1, 2015

By V. V. Getman, V. A. Chanturiya, T. N. Matveeva

Most of the Au and PGM ores in Russia are characterised by a thin mineral impregnation of noble metals in sulfide minerals, and a large variety of mineral forms that lead to high loss of precious metals with fine fractions during flotation. In modern flotation technology, the rational choice of reagents is one of the main trends for selective separation of minerals and effective metals recovery. New data on the selectivity of the thermo-sensitive polymer with specific functional groups (TMPPh) as a flocculant and collector of Au and Pt fine fractions are available. The selective modified collector (DEDTCm) for the recovery of Au and Pt from complex ores is discussed in this paper. Scanning electronic microscopy (SEAM), laser SIM and AFM microscopy, UV and IR spectroscopy were applied to study the adsorbed layer of new reagents on the mineral surface. Flotation tests of TMPPh on the gold-bearing ore of the Olimpiada deposit showed an increase in Au extraction and Au content in the concentrate of the rougher flotation. Using a combination of reagents TMPPh and ButX, the quality of the Au and Pt concentrates increased in 1.7 time with an increase in recovery up to 15 % compared with the traditional reagent mode. Testing of TMPPh polymers in flotation of Pt-Cu-Ni ore at Norilsk Nickel has shown the ability to obtain a concentrate with a higher Pt content. Recovery of platinum is 17% higher than recovery in an experiment without polymer. Application of DEDTCm helped to achieve higher technological parameters in flotation of lowgrade Rt-Cu-Ni ore. Compared to the basic mode Pt recovery was plus 13%, Pd recovery was plus 9% and the content of precious metals in the rougher flotation concentrate increased in 2,5 - 4 times. The studies have been supported by Grants of the President of RF “Scientific School of Academician V.A. Chanturiya” NSh-220.2012.5, NSh-748.2014.5. Keywords: Au and Pt complex ores, flotation, flocculation, thermo-sensitive polymer TMPPh, modified collector

Jan 1, 2020

By S. E. Pérez-Fontes

An experimental study on the oxidation of chalcopyrite (CuFeS2), pyrite (FeS2), covellite (CuS) and chalcocite (Cu2S) particles was conducted by means of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) techniques. The oxygen concentration in the process gas was set to 40% and 70% (by volume) and a heating rate of 40°C/min was used. Response variables included the temperature of incipient reaction, the total exothermic heat of reaction, particle mass, morphology and mineralogy of the reacted particles. Based on the experimental data and phase stability calculations, reaction mechanisms were proposed to represent the behavior of the particles during oxidation. The reaction mechanisms were verified by X-ray diffraction (XRD) analyses of the oxidized particles and by thermochemical and mass balance calculations to reproduce the DSC and TGA data. Overall kinetic models were developed to represent the evolution of the exothermic heat of reaction as a function of time.

Jan 1, 2007

By Manuel Pérez-Tello

An experimental study on the oxidation of chalcopyrite (CuFeS2), pyrite (FeS2), covellite (CuS) and chalcocite (Cu2S) particles was conducted by means of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) techniques. Oxygen concentration in the process gas was set to 40 and 70% by vol. and a heating rate of 40 °C/min was used. Response variables included: the temperature of incipient reaction, the total exothermic heat of reaction, particle mass, morphology, and mineralogy of the reacted particles. Based on the experimental data and phase stability calculations, reaction mechanisms were proposed to represent the behavior of the particles during oxidation. The reaction mechanisms were verified by X-ray diffraction (XRD) analyses of the oxidized particles, and by thermochemical and mass balance calculations to reproduce the DSC and TGA thermograms. Overall kinetic models were developed to represent the evolution of the exothermic heat of reaction for each mineral as a function of time. Experiments conducted with copper concentrate particles containing the minerals studied suggest that the reaction mechanisms for the individual minerals can be used to represent the oxidation behavior of the copper concentrate particles.

Jan 1, 2006

By A. Kotze, D. Messina, E. Nagels, Y. Cryns, S. Arnout

The FlashPhos process aims to recover white phosphorus (P4) from sewage sludge by drying, flash combustion/gasification, and carbothermic refining steps. This study evaluates the material behaviour of sewage sludge ash melting and reduction in a refining furnace for the novel FlashPhos process. Thermodynamic modelling in FactSage 8.2 is combined with experiments from a tube furnace to determine the possible phosphorus recovery and minor element behaviour. For the two studied sludges, a yield of 40% and 75% white phosphorus is achieved after 1 hour at 1600°C, corresponding with a 60% and 25% loss to the metal phase. This is slightly above the calculated equilibrium yield of 28%–73%, which depends mainly on the Fe/P ratio of the sludge. Temperature is found to have a significant influence on the final phosphorus yield when leading to incomplete melting of the ash. A clean slag is produced in the process free of heavy metals making it suitable to be used as a cement-like binder material. The main heavy metals that co-evaporate with the phosphorus are Zn, Pb, As, Sb, and Sn. Additional processing steps will be required to remove these to produce a pure P4 product. The metal alloy consists of mostly Fe and P with smaller amounts of other components such as Mo, Cr, Cu, Mn, Sn, Sb, and V. The final slag consists of CaO, SiO2, MgO, and Al2O3 with virtually complete removal of P and heavy metals.

Oct 2, 2025

By E. V. Leont'eva, V. R. Vafin, A. G. Kladova, N. L. Medyanik, A. P. Ponomarev

"The thermochemical technology for recovery gold, silver from mature flotation tailings of pyrite ores by two-stage sintering with chlorine-ammonium reagents and leaching of bakes with water is developed. The economic effect of the technology implementation is calculated. KEYWORDS Gold and silver recovery, mature flotation tailings, pyrite ores, chlorine-ammonium reagents, leaching INTRODUCTION The relevance of processing the technogenic reserves of ore mining and concentration wastes accumulated over the long operation periods of mineral deposits is beyond doubt. Hundreds of tons of precious and non-ferrous metals that were not recovered during the primary processing are concentrated in the accumulated wastes. For example, tailing storage facilities (TSF) at the mineral processing plants in the Southern Urals region of Russia hold more than one hundred tons of gold and thousands of tons of silver in the mature flotation tailings (MFT) of copper pyrite ores. Secondary processing of technogenic materials is facilitated by the fact that they are preprocessed — ground and compactly deposited on the surface, but complicated by the low (compared to ores) grade, uneven distribution of the valuable minerals, altered and unstable material composition of the mineral feed. This leads to low recovery rates of valuable metals by conventional physicochemical processing methods. It is necessary to develop innovative methods of deep integrated processing of industrial wastes, based on the study of the material composition of specific technogenic mineral resources and based on ensuring the environmental safety of the resulting secondary waste. MATERIALS AND METHODS The object of this study are the MFT of Uchaly Concentrator in the Republic of Bashkortostan, Russia, which processes copper pyrite and copper-zinc ores. According to the data of particle size, chemical, X-ray phase, and optical microscopic analyzes, samples of the MFT are characterized by considerable particle fineness (the fraction of the size class -41 µm is 89-90%), low grade of gold (1.7-2.0 g/t) and silver (18.0-19.5 g/t), comparable grades of iron (23.0-26.8%) and sulfur (28.1-28.7), but different grades of copper (0.12 - 0.73%) and zinc (0.34-1.26%). The most common mineral in the samples is pyrite (50 - 56%), found in intergrowth with grains of other sulfides (0.1-4%) - sphalerite, tennantite, chalcopyrite, covellite. Quartz and aluminosilicates are the dominant rock minerals (21-36%). Based on the results of the phase analysis, it was established that approximately 70% of the gold in the samples is found in a form that is resistant to cyanidation — it is locked in sulfides (52-56%) and quartz and coated by films. Along with sulfides and rock minerals, common gold and silver minerals (chalcogenides, intermetallides, native gold) in the form of submicro- and nano-sized precipitates are also associated with intergrowth of a complex structure. These features of the material composition allow classifying the MFT of the pyrite ores as a mature feed material and emphasize the need for chemical non-cyanide methods to recover gold and silver from the mature minerals and associations they are found in."

Jan 1, 2018

By S. R. Rao

Interaction of potassium amyl xanthate with pyrrhotite has been studied thermochemically. Heats of adsorption of xanthate on unactivated mineral and the mineral activated with cupric ions have been compared with heats of reactions between potassium amyl xanthate and ferrous and cupric salts. It is shown that xanthate is consumed by stoichiometric exchange with anions present at the mineral surface. The floatability of the unactivated mineral is poor since xanthate is precipitated in bulk without creating a hydrophobic surface on the mineral. At the activated mineral surface, xanthate is adsorbed in certain isolated patches (active spots) and thereby creates a hydrophobic surface. The hydrophobicity of the mineral is greatly improved by lowering the pH to 4.5.

Jan 1, 1972

By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) am-mines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Jan 1, 2011

By E. Asselin

Passivation of Fe-Ni-Co alloys during the Caron leach process is thought to result in low cobalt recoveries in ammoniacal ammonium carbonate solutions. A brief review of the available thermochemical data for the (Fe, Ni, Co)-NH3-H2O systems has been undertaken. The stability of the Co(II) and Co(III), Ni(II) and Fe(II) ammines was examined through the use of speciation and Pourbaix diagrams at 298 and 333 K and at 6 M total ammonia. Increasing the temperature reduces the stability fields of the ammines and generally constrains the thermodynamic window for the leach. The Fe(II) ammines are only thermodynamically stable under reducing conditions. Polarization experiments show that these ammines are unlikely to form if oxygen is present. Fe-Ni-Co alloy passivation may be alleviated by careful management of potential.

Nov 1, 2011