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By C. Xiao, R. Chi

In recent years, the biosolubilization of rock phosphates by phosphate-solubilizing microorganisms has become a major topic of research studies. However, the microorganisms used in previous studies were mostly single and known species, and studies seldom focused on mixed communities of microorganisms or microbial consortia from natural environments. In this study, a microbial consortium from rhizospheric soil was used to solubilize two different compositions of medium- to low-grade rock phosphates — designated as ore samples 1 and 2 — in a laboratory-scale bioreactor. The microbial consortium showed good growth in the bioreactor, reduced the suspension pH and released soluble phosphates from the ores. Scanning electron microscopy with energy-dispersive X-ray spectroscopy showed the action of the microbial consortium on the ore surface. There was considerable corrosion on the ore surface, and 3.42 and 4.93 percent of the element phosphorus was removed from ore samples 1 and 2, respectively. Microorganisms were sampled from the bioreactor for the analysis of their community structures by Illumina MiSeq high-throughput sequencing. The analysis show that the suspensions added with different ore samples had different microbial diversities and richness. This study provides new insight into the biosolubilization of rock phosphates by a microbial consortium directly taken from rhizospheric soils.

By Gabriela Huamán

La bioosorción es un proceso de formación de metales pesados, basado en la actividad química de una biomasa, cuya tecnología se convierte en una de las más promisorias alternativas para el tratamiento de efluentes que contienen metales pesados en bajas concentraciones. Esta tecnología utiliza diferentes tipos de biomasas como: algas, hongos, levaduras, bacterias, microorganismos y sub-productos agrícolas. En este sentido, el presente texto describe las ventajas de reutilizar dicha biomasa, tales como el bajo costo de operación y la elevada capacidad de remoción de metales pesados, sobre los métodos de remoción convencionales.

Sep 14, 2009

By M. L. Apel

A conceptual approach to the bioremediation of uranium mill tailings (UMT) is presented., This approach focuses on, biosorption to remediate the. effluent solution and bioleaching remediate the. solid fraction. Comparative biosorption studies were performed with synthetic single metal solutions using a commercially available biopolymer. The maximum rate of metal sorption by calcium alginate was found to be 5.43, 6,39, 6.48, and 9.74 mg dm-3 min-1 for U022*, Ba2+, Cd2+ and Zn2+, respectively. Activation energy (AEa) for barium uptake by calcium alginate beads was determined to be 11.5 kJ, indicating a diffusion controlled reaction mechanism. Thermodynamic values (AG+ AH+ and ASt) of the metal-alginate activated complex, as reported in the literature, were found to be in agreement with those calculated from this research. Results show that this biopolymer can be effectively applied in the removal of select metals prevalent in uranium mill tailing effluents and associated waste streams.

Jan 1, 1991

By Yunnen Chen

The test and use of natural materials as biosorbents for the removal of heavy metals from industrial wastewater is under constant development. In the present study, the biosorption capacity of waste microzyme was studied for cadmium The cadmium removal study has been carried out batchwise where the influence of physico-chemical key parameters such as pH value of solution, contacting time and initial cadmium ions concentration have been considered. The influence of metal ion concentration was evaluated and the results were fitted using adsorption isotherm models. The kinetic of cadmium biosorption was also investigated. The maximum percent removal was attained at the pH 7.0 after about 30 min. Waste microzyme was a potential biosorbent for the removal of Cd(II) from the effluent of electroplating industry.

Jan 1, 2009

By R. Marandi

The effective removal of heavy metals from aqueous wastes is among the most important issues for many industrialized countries, How ever biosorption, i.e. the uptake of heavy metals by non- living biomass, has gained increased credibility during recent years. Biosorption of Cr(VI) from aqueous solution, on pretreated and immobilized Aspergillus niger was investigated in a batch and countinuous reactors. A.niger biomass pretreated by boiling in 0.5 N NaOH solution for 15 min, exhibited higher Cr(VI) removal capacity than autoclaved biomass. The optimum adsorption pH value observed for Cr(VI) ions was 2. The Cr(VI)removal rate increased with a decrease in pH. The influence of contact time, pH, Cr(VI) concentration, biomass concentration and temperature on Cr(VI) removal were also evaluated. Biosorption of Cr(VI) on pretreated biomass followed the Freundlich and Langmuir adsorption models.In this study A.niger biomass was immobilized in Na-alginate matrix. The biomass beads packed in a column were able to remove metal ions.In this study we used two different flow rate in a column, 1.5 mL/min and 3 mL/min.The breakthrough data obtained for Cr(VI) was adequately by the Thomas and Yan models and the adsorption capacity of the biomass was found to less than the adsorption capacity obtaind in the batch study. When the beads containing biomass become saturated with metal ions, the adsorbed metals were eluted using 0.5 N NaOH solution. Therefor nearly 90% of Cr(VI) was desorbed by NaOH solution.

Jan 1, 2014

By T. H. Jeffers

The U.S. Bureau of Mines' Salt Lake City Research Center. has developed porous polymeric beads containing immobilized non-living biological materials for extracting metal contaminants? from wastewater&. Immobilized biological materials include peat moss, algae, biological polymers, and other materials that demonstrate high .affinities for heavy metals. The beads, designated as BIO-FIX beads, have distinct advantages over traditional methods of utilizing biological materials in that they have excellent handling characteristics . and can be used in conventional processing equipment or low-maintenance systems.. Toxic metals such as copper, cadmium, zinc, lead, and mercury are several of the many heavy metals effectively removed from mine wastewater& using B'IO"FIX beads. Continuous cyclic testing indicated that the beads continued to produce treated effluents which met National Drinking Water Standards (NDIJS) after 175 loading-elution cycles, Adsorbed metals were removed from the beads using dilute ?mineral .acids. In many cases" the extracted metals were further concentrated to enable processors to reclaim the metals, thus minimizing the generation of a hazardous sludge. Tests indicated that use of the beads in a low-maintenance system was particularly effective for treating remote acid mine drainage waters? and small toxic seeps from hardrock mining districts ..

Jan 1, 1991

By Javier Enrique Basurco Cayllahua

In this work, a gram-positive bacteria was used as biosorbent to elucidate the aluminum load capacity under different conditions related to metallurgical and chemical plants. The sorption data followed the Langmuir, Freundlich, Dubinin-Radushkevich isotherms. In order to determine the best isotherm fit, three error analysis methods were used to assess the data: correlation coefficient (R2), residual root mean square error (RMSE) and Chi-square test. The error analysis established that the Dubinin-Radushkevich model fits better the aluminum biosorption data. The maximum sorption capacity was found to be 41.59 mg.g-1. The maximum removal of aluminum was 95% at pH around 5. The experimental kinetics data was evaluated considering two models (pseudo-second order and pseudo-first order). This study indicated that the R. opacus is an environmental friendly biosorbent.

Jan 1, 2009

By E. Ashirbaeva

"Ores of ferrous metals traditionally make up the bulk of recoverable reserves of solid minerals, and iron ore concentrates - in the processing and consumption. To obtain concentrates, three main methods are used: dry and wet magnetic separation, gravity and flotation. But even their integration into complex developed schemes with finishing operations often do not solve the problem of obtaining high-quality concentrates, which are necessary for powder metallurgy and electric steelmaking. Increasing the iron content in the concentrate by removing harmful impurities is the goal of this work. The possibility of reducing the operations of wet magnetic separation twice and completely eliminating concentrating operations in ball mills from the scheme of operations has been established. Selective leaching agents for each type of iron ores have been created, allowing to obtain concentrates with an iron content of not less than 68-69% and negligible concentrations of harmful impurities. Methodical recommendations for long-term storage of bioreagents in the active state, their immobilization and preparation in industrial conditions at the enterprise Nedropolzovatelja are developed. The proposed biotechnology, which allows to obtain high quality iron and conditional concentrates for harmful impurities, is protected by patents (RU 2537684 ""Method for fine-tuning of high-sulfur magnetite concentrate"" for magnetite ores and Pat. RU 2599068. For the industrial implementation of the new technology, organizational and technological measures have been developed in the system with Road maps for types of ores. The developed technology makes it possible to condition noble metal, tin, tungsten, nickel and other concentrates in harmful impurities such as arsenic, antimony, mercury, sulfur, copper, zinc, iron, phosphorus, manganese, in total 30 components that pass into solution under the influence of bioreagents.INTRODUCTION Consumption of various metals is steadily increasing every year, the volume of mining is constantly increasing. Ores of ferrous metals traditionally make up the bulk of the recoverable reserves of solid minerals. Enrichment technologies for iron-containing ores are reduced to the combination of three main methods: wet and dry magnetic separation, gravity and flotation. But even the use of complex advanced technological schemes often does not lead to the production of high-quality concentrates suitable for metallurgical processing. In this case, either lapping operations or effective technical and technological solutions are used in the main enrichment cycle. Widely used in practice methods for improving the quality of iron ore concentrates include the use of finishing operations (fine screening, reverse cation flotation), staging of concentrates, the use of more sophisticated equipment (separators with running magnetic field, magnetic gravity classifiers, column flotation machines)."

Jan 1, 2018

By Patiño E

Bioleaching is an established technology for the pre-treatment of refractory gold ores and concentrates and the leaching of whole ore copper heaps. In many cases, it offers economic, environmental and technical advantages over pressure oxidation and roasting. However for bioleaching to compete successfully with others pre-treatment processes it needs to be optimized with regard to the parameters that affect the bioleaching reactions and the growth of the microorganism involved. In this sense, this paper focus on the thermodynamic approach applied in bioleaching through of the definition of the growth system and it is thermodynamics analysis, the effect of heat production and energy dissipation on growth and thermodynamic analysis of growth kinetics and the effect of nonstandard conditions.

Sep 12, 2005

By Lee R. Martin, Michael R. Taber

Bird Balls™, the latest development in the ongoing battle at mine sites across North America, help to eliminate accidental avian mortality caused by birds ingesting cyanide leachate. Bird Balls™ are a 4-inch sphere made of high-density polyeth­ ylene (HDPE). They weigh 40 grams and are black in color to provide optimum life in UV intense environments. A floating blanket of bird balls totally excludes birds from a liquid surface. Federal agencies that enforce the Migratory Bird Treaty Act do not specify how to keep migratory birds out of leachate basins. Some state agencies, however, specify that a physical barrier must be in place to exclude migratory birds if cyanide levels are high enough to cause mortality. Industry standards for protecting waterfowl now include Bird Balls™ as well as net­ting, detoxification, and heap leach systems designed in such a manner that no exposed solution ponds or channels exist. Hazing is no longer an option. A bold statement to make? Perhaps, but W. R. Jeffress (1990) covers the subject well when he stated that, "Hazing techniques as a whole have not been effective in excluding waterfowl or other species of wildlife from toxic heap leach solution ponds or tailings impoundments. Research and devel­opment of the new 'Star Wars' hazing techniques, such as laser netting and radar systems, are interesting concepts and will pos­sibly offer an alternative to total physical exclusion or neutral­ization in the future. All of these methods are going to have to be thoroughly tested." For those who may want further docu­mentation, we have included a special reference section cover­ing hazing. R. J. Hallock (1990) stated that, "The Fish and Wildlife Service is particularly interested in migratory birds. In fact, a large portion of our effort, nationwide, is focused on migratory birds. Bird habitats are managed directly through the National Wildlife Refuge System and indirectly through other agency programs. We also have a responsibility to protect birds under the Migratory Bird Treaty Act. Most birds attracted to mine ponds are covered under this Act. The only migratory birds not protected under the Migratory Bird Treaty Act are English Sparrows, Starlings, and Pigeons. Since this is a treaty with five nations, the concept of acceptable losses does not apply. It is not a negotiable situation. There are a few exceptions noted in the Act, including prescribed hunting of selected waterfowl, scien­tific collection, and game bird farming. There is no exception for the loss of migratory birds exposed to solutions of cyanide."

Jan 1, 1996

By Cyril S., Smith

WE cannot but marvel at the fact that fire is necessary for almost every operation. It takes the sands of the earth and melts them-now into glass, now into silver, minium or other lead or some substance useful to the artist or physician. By fire, minerals are disintegrated and copper produced; in fire is iron born and by fire is it subdued; by fire, gold is purified; by fire, stones are burned for the binding together of the walls of houses.... Fire is the immeasurable, uncontrollable element, concerning which it is hard to say whether it consumes more or produces more." Thus wrote Pliny in his "Natural History," that great collection of fact and error which constitutes the principal contemporary description of Roman technology and which until the seventeenth century was the authority most often quoted and requoted by those who wrote on metals, as on many other subjects.

Jan 1, 1940

Jan 1, 1889

Jan 1, 1925

By Frank C. Roberts

Neglecting the hydrogen and hydrocarbons, 1 will assume the following analysis as a fair average composition, by weight, of the waste gases escaping from a coke-burning blast-furnace: CO2............17.25 CO,............25.25 N,.............57.50 100.00 The 25.25 CO requires for combustion 62.6 of air, or 11.398 of oxygen, necessitating the passage of 48.202 nitrogen into the products of combustion. The latter, therefore, have the following composition: CO2,,............ 56.9 N,............105.7 Tile total specific heats of these quantities of the respective gases are 12.31 and 25.79, giving for the combined product, 38.1 approximately. That is, the product of combustion will absorb 38.1

Jan 1, 1889

By James A. Barr

Ferrophosphorus, an alloy of phosphorus and iron or perhaps a physical mixture of definite compounds of iron and phosphorus, has become of increasing importance as the use of the basic open hearth has extended. Commercial ferrophosphorus is a porous, brittle metal of crystalline structure and often with a bluish metallic luster. A typical analysis is as follows: Per Cent. Phosphorus......................................... 18.0 to 22.0 Iron............................................... 80.0 76.0 Oxygen............................................ 0.2 Sulfur............................................. 0.3 Silicon............................................. 0.1 Carbon............................................ 0.1 Manganese......................................... 0.2 This alloy was first made in an electric furnace, as it was thought that the high heat of the electric arc together with the reductive effect of carbon was necessary. About 1898, J. J. Gray, Jr., was producing a high-phosphorus pig iron in his furnace at Rockdale, Tenn., by using high-phosphorus, local iron ores. As these high-phosphorus ores were difficult to obtain, he conceived the idea of increasing the phosphorus content of the pig iron by the addition of phosphate rock to the furnace burden. When the phosphorus content of the pig was kept low and only small amounts of phosphate rock were added to the burden, no particular troubles were encountered, but when he increased the amount of phosphate rock to produce an 18 per cent. alloy, his furnace troubles rapidly multiplied. After many failures and freeze-ups, he was partly successful in making short campaigns on 18 to 20 per cent. "ferro." At first, when the furnace got in bad shape on ferro, he would switch to a regular pig-iron burden until the furnace was brought around sufficiently to start on ferro again. About this time, Mr. Gray applied for and obtained his first patent. As he grew more skilled in the furnace operations, he was enabled to extend the furnace campaigns and produce ferrophosphorus continuously for the life of the furnace lining. These improvements were made the subject of another patent issued in 1916.

Jan 1, 1925

By F. J. Longworth

FoR a number of years an intensive study has been made to improve the blast-furnace practice at Copperhill not only as to cost% but to provide a good grade of gas for the acid plants. This study took us back to the fundamentals of successful pyrite smelting; namely, a blast furnace working on a clean sulfide ore, free from fines, and the use of quartz high in silica as a flux. In 1919, the quality of the flux was improved and its effect on the metallurgy was very marked. To improve the practice further, it was necessary to work out some method of treatment for the sulfide fines and the siliceous and refractory ores, other than in the blast furnace. A series of milling tests indicated that these products could be successfully treated by differential flotation, and in 1922 plans were made and a flotation plant built. It was estimated that the flotation plant would deliver to the smelter 40 to 50 tons of concentrates per day; the problem was what to do with these concentrates. It was out of the question to attempt to smelt them in a blast furnace because of the dust losses and because our practice demands a charge free from fines for satisfactory operation. There is no custom smelter in the vicinity to which concentrates may be sold, pending the time when the tonnage will be sufficient to warrant roasters and a reverbatory furnace. Sintering and nodulizing were investigated but neither method fitted into our scheme of metallurgy. A close study of the converter practice was then made to see if some method could not be evolved to smelt this tonnage of concentrates in a converter without preliminary treatment. At that time, the converter installation consisted of two 12-ft. Great Falls converters, which were handling 12 to 14 per cent. matte. The heat balance of the converters working with 12 to 14 per cent. matte was more than sufficient to smelt the contemplated tonnage of concentrates but the mechanical difficulties of feeding fines into the Great Falls converter made the use of this type of converter impractical. While there was no opportunity to experiment with the Pierce-Smith converter, equipped with a Garr gun, theoretically it seemed practical

Jan 1, 1925

By D. S. Jacobus

The boiler here referred to was of the water-tube type, having 2535 square feet of heating-surface, which the makers held to be capable of generating 325 horse-power of steam; this being understood to mean that 325 times 30 pounds of water would be evap-

Jan 1, 1889

By William H. Wiese

Anecdotal reports of high rates of congenital malformations and spontaneous abortions at the Shiprock Indian Health Service Hospital in San Juan County, New Mexico prompted an interview survey, obtaining data from families of 26 former uranium miners and 30 controls. Results supported the possibility of increased fetal wastage and congenital malformations. However, definitive conclusions were obviated by methodologic limitations in terms of selection of cases and controls and interviewing technique, as well as very low numbers and lack of statistical significance. The Council of Environmental Quality (1980) published a report which singled out San Juan County, nationally, as having an extra-ordinary high rate of congenital anomalies reported from birth certificates in the years 1973-75. San Juan County is in the northwest corner of New Mexico and includes the northeastern edge of the Navajo Indian Reservation. It has been the site of uranium mining and milling and also of coal mining (Clement Associates, 1980). While much attention has been focused on lung cancer and chronic lung disease as health hazards to uranium miners, virtually no attention has been focused upon possible reproductive effects that may result from exposure to radiation. Could these reports indicate such an additional arena of health effect either on miners or on others living in the vicinity of the mines and mills? The biologic and epidemiologic literature does not lend much support for adverse genetic outcome. The UNSCEAR report (UNSCEAR, 1977) summarizes much of the existing data. For example, on the basis of many animal studies and what has been observed in atom bomb survivers in Japan, it has been estimated that mutation rates resulting from low LET radiation to paternal germ cells would be 60 X 10-6 recessive and 20 X 10-6 dominant mutations per gamete per rad. There would be a five-fold increase in the number of recognizable abortions. The doubling dose for genetic disorders in mice is estimated at 100 rads. The assumption has been that low levels of exposure, such as might be received occupationally from uranium mines and mills or environmentally will produce reproductive effects that would defy distinction from background rates. However, the possibility can not be dismissed. In man, spermatogonia are thought to be three-fold more sensitive than in the mouse. Also, the high LET radiation from alpha particles is as much as 20-fold more effective in inducing changes in meiotic and post meiotic stages of cells, compared with low LET radiation. There is some degree of localization of alpha emitters in testicular tissue after inhalation of radon and radon daughters (Blanchard, R.L. and Moore, J.B., 1971; Pohl, E., 1964). The slopes of doseeffect curves are affected by type radiation and rate of administration. Data on such curves are poorly defined and debated as to whether there may be increased or decreased effect per unit dose at low levels of high LET radiation. Increased rates of aberrations of chromosomes in peripheral lymphocytes cultured from uranium miners have been reported (Brandom, W.F., et al., 1978). At cumulative exposures of 100 working level months (WLM) or less, a range of exposure lower than the limit of current occupational standards, the aberrations were increased more than two-fold. Our interest has led us to pursue the question of reproductive effects along three separate paths of inquiry: studies of the secondary sex ratio, cytogenetic study of human sperm, and studies of rates of congenital anomalies. I will present the thrust of our findings, most of which remain preliminary, comment on their interpretation and limitations, and indicate directions needed for future research. The secondary sex ratio is the ratio of males to females at birth. In the U.S., the ratio averages around 1.05. Ratios in blacks are somewhat lower (1.025) than in whites (1.053). For American Indians, the data are less definite. Values from Oklahoma and California are similar to whites (1.05). Southwestern tribes have, as we shall see, varying levels. The theoretical effects on sex ratio resulting from irradiation of the zygote are based on the principles of sex-linked genetics, including differential effects of lethal dominant and recessive mutations on the sex chromosomes, complicated by possible non-disjunctional events. Observations have done little to clarify, confirm or refute the theories. The sex ratio of progeny of survivers of the atomic bomb showed little change (Schull, W.J., Otake, M., and Neel, J.V., 1981). Observations in children of uranium miners having been inconsistent. Most frequently cited is a study of miners in Czechoslovakia (Müller, C., Razicka, L., and Bakstein, J., 1967). Compared with children born to miners prior to the start of mining, the sex ratios of children born after the start of mining were decreased -statistically significant after correcting for birth order. The ratios in first-born children were, before the start of mining, 1.118, and, after the start of mining, .713. In the interview survey at Shiprock, the sex ratio in families of non-miners was 1.03, and in families of miners it was 0.73 (p < .05). Dr. Alan Goodman at the University of New Mexico has studied trends in the sex ratio in the general population in New Mexico and Arizona with particular reference to counties in the Four Corners area and the Navajo Indian Reservation, areas where uranium mining has been active_ His findings (unpublished) are as follows: (1) Beginning in the early 1950&apos;s, there has been a modest, but persistant and statistically significant decline in the secondary sex ratio for the state of New Mexico compared with the U.S., a decline that roughly parallels the emergence of uranium mining in the Grants mineral belt in northwestern New Mexico. (2) Data available for the 11 years since 1969 show that among the five counties with ratios significantly lower than the state

Jan 1, 1981

Since the initial discovery of phosphate rock resources in North West Queensland in 1966, significant changes in ownership and development direction have occurred. Initially development of the resource involved beneficiation to produce a more saleable grade of phosphate rock. However more recently development has focused on the production of a high analysis fertilizer product on the minesite. These changes have been influenced by economics, industry/government cooperation and a changing phosphate industry.

Jan 1, 1998

By J. C. Haptonstall

The Bismark Mine is located in northern Chihuahua, 150 km southwest of Ciudad Juarez. The ore deposit was discovered in 1979, and was placed in production in 1992. The production rate is about 2400 tpd from an ore reserve of 8.5M tonnes. Grades average about 8 % Zn, 0.5 % Pb, 0.2 % Cu and 50 g Ag per tonne. Substantial inflows of water into the under-ground mine complicate the operation. Complex metallurgy poses another challenge for the operators. Bismark was operated through a joint venture, Minera Bismark, S.A. de C.V., with U.S. and Mexican partners, but since early 1993, it is wholly Mexican-owned and operated.

Jan 1, 1994