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By Zhou Wenbin

In this paper the mechanical properties of high carbon equivalent cast iron for automobile brake discs were analyzed through thermal analysis curves. Experiment results show that the mechanical properties have a strong correlation with thermal analysis curves and an effective way to predict the mechanical properties of high carbon equivalent cast iron was proposed based on the features of thermal analysis curves.

Jan 1, 2010

By G-L. Wu, S-W. Wu

"The hot deformation behaviour of Nb-Ti microalloyed high-strength steel was investigated. Hot compression tests were conducted in the temperature range 900 to 1100°C under strain rates of 0.1, 1, and 5 s-1. Dynamic recrystallization (DRX) occurs as the main flow softening mechanism at high temperature and low strain rate. The hot deformation activation energy was calculated to be about 404 699 J/mol. The constitutive equation was developed to describe the relationship between peak stress, strain rate, and deformation temperature. The characteristics of DRX at different deformation conditions were extracted from the stressstrain curves using the work hardening parameter. The Cingara-McQueen equation was developed to predict the flow curves up to the peak strain. The processing maps were obtained on the basis of a dynamic materials model. The results predict an instability region in the temperature range 1010 to 1100°C when the strain rate exceeds 0.78 s-1. IntroductionThe 700 MPa grade HSLA steel is widely used in engineering machinery, automotive beams, carriages, and axle tubes, etc. (Pan et al., 2017 ). Generally, such grades contain a moderately high amount of Mn (approx. 1.4% and above), and microalloying elements like Nb, Ti, V, and Mo to impart the desired strength and toughness through solid-solution strengthening, precipitation hardening, and grain refinement dislocation strengthening (Chen and Yu, 2012; Opiela, 2014). However, the production costs can be greatly reduced by replacing part of the Nb, V, or Mo with inexpensive Ti and adopting the compact strip production CSP process (Opiela, 2014; Chen et al., 2015). Furthermore, the microalloying technology coupled with new-generation thermomechanical control processing (NG-TMCP) has proved efficient for achieving the proper balance between strength, toughness, ductility, and formability by means of a suitable combination of chemical composition and thermomechanical treatment parameters (Shukla et al., 2012; Wu, Zhou, and Liu, 2017).In hot forming processes, the complex microstructural evolutions are often induced by multiplicative hot deformation mechanisms, such as work hardening (WH), dynamic recovery (DRV), and dynamic recrystallization (DRX) (Zhang et al., 2014; Liang et al., 2015). Dynamic softening behaviour during hot processing has generated considerable interest because component properties are influenced significantly by its corresponding microstructural evolution (Wu et al., 2010). During deformation in the DRX process, deformed grains are replaced with substructures and newly formed fine and uniformly distributed grains. This occurs only when a critical strain for the onset of DRX is reached, and at the same time, the minimum rate of energy dissipating is reached (Ferdowsi et al., 2014). DRV occurs at a high strain rate and low temperature, reducing the stored energy greatly and making DRX difficult (Liang et al., 2015). The microstructural changes during DRX are sensitive to the processing parameters, such as strain rate, deformation temperature, and strain (Zhang et al., 2014; Ferdowsi et al., 2014). Therefore, in order to optimize the hot processing parameters, it is important to understand the behaviour of hot deformation visà- vis control of microstructural evolution."

May 1, 2019

By Sumantra Mandal

The hot deformed microstructure of the 15Cr-15Ni-2.2Mo-Ti modified austenitic stainless steel (commonly known as alloy D9) was investigated employing electron backscatter diffraction (EBSD). Hot compression tests were conducted in a Gleeble thermo-mechanical simulator at temperatures of 1173K-1373K (in steps of 100K) with a strain rate of 10 and 100 s-1 to different strains. Various kinds of deformation patterns were observed inside the deformed grains. These were inferred as the development of geometrically necessary boundaries or formation of parallel set of micro-bands. Recrystallized grains were partitioned from the deformed grains employing grain orientation spread approach. Extent of dynamic recrystallization (DRX) was found to be minimal at 1173K. DRX was predominantly found to happen at and above 1273K which increases with increase in strain. DRX nucleation and development mechanisms were discussed with respect to bulging of the parent grains and sub-grain rotation. Special emphasize is given on the role of annealing twins on DRX nucleation and subsequent expansion.

Jan 1, 2009

By D. E. Walsh

Over a period of seven years (1989-1996) the Mineral Industry Research Laboratory (MIRL) University of Alaska Fairbanks, has investigated the effects of temperature, residence time, and particle size on the degree of low-rank coal (LRC) upgrading for a non-evaporative, hydrothermal drying process, also known as hot water drying (HWD). Three Alaskan LRCs were used in this study: Usibelli coal (Seam No.4) from the Nenana Coal Field, Little Tonzona coal from near McGrath, and Beluga coal from the Beluga-Yentna field on the west side of Cook Inlet. Replicated, factorial tests were conducted. Experimental results indicate that most of the low-rank coal upgrading via HWD occurs rapidly within the first 10-20 minutes of residence time. Thereafter, the upgrading process slows down and over 100 minutes of additional residence time are required to produce similar percentage increases in coal properties to those achieved in the first 10-20 minutes. The properties of the hot water dried products were very sensitive to process temperature. Calorific value, carbon and oxygen contents, equilibrium moisture levels and Hardgrove grindabilities all appear to change linearly with temperature within the 275" C to 325" C range.

Jan 1, 1997

By S. Yannacopoulos, L. Bichler, P. Wanjara, J. Gholipour

Characterization of a virgin and in-service Inconel 718 alloy was undertaken to study the changes caused by the service conditions on the grain size, ?? phase, MN-type nitrides and MC-type carbides. The size, distribution and volume fraction of these phases and grain size were studied using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and electron backscattered diffraction (EBSD) analyses. A considerable difference in the grain size, as well as distribution and volume fraction of the precipitates was observed in the in-service material as compared to the virgin Inconel 718. As a result of these microstructural changes, a notable dissimilarity in hardness between the materials investigated was observed. The results presented in this study are important for proper development of repair parameters and heat treatment of in-service Inconel 718 material.

Jan 1, 2014

By C. Blais, G. L’Espérance

Characterization of second phase particles is important with regard to their influence on mechanical properties of materials. Analytical electron microscopy offers the possibility to achieve complete characterization of inclusions. Complete characterization of inclusions means quantitative evaluation of their chemistry and the stereological parameters. A characterization technique based on integrated microscopy and involving scanning electron microscopy, image analysis and energy dispersive X-ray spectrometry is presented. A discussion of the use of transmission electron microscopy and electron energy loss spectroscopy is also presented for the characterization of very small particles and compounds (>100 nm).

Jan 1, 1998

By Mohan Ram

Structural impurities in the crystal lattice of rock phosphate of Indian origin is a great challenge for beneficiation and practically possesses remote scope of upgradation to the desired level for industrial utilization. There is a wide occurrence of rock phosphate in different parts of India with different characteristics viz. siliceous, carbonaceous and ferruginous. The structural cationic replacement in the composition of apatite is due to the exchangeable cations present in the external impurities associated with the rock phosphate ore. The Indian rock phosphate ore from Purulia district, West Bengal is characterized as unusual structural composition due to the exchangeable cation in its composition. The elemental distribution of ore exhibits the disproportionate ratio of P2O5 and CaO which is 5.88: 3.31 in reference to the theoretical composition of P2O5: CaO in apatite which is 4.23: 5.55. The substitution by trivalent Al+++ cations within the structure of apatite in place of divalent Ca++ is found upto 18% and substitution of exchangeable cation in place of PO4 and F ion by CO3/SO4 is found upto 0.1% and OH ions upto 0.2% respectively in a lattice of apatite thereby diluting the grade of rock phosphate and restricting its industrial use even after beneficiation. This paper reveals the unusual compositional features of rock phosphate under study and is a guideline to the mineral industries using such rock phosphate. Keywords: external impurities, exchangeable cation substitution, structural compositional features, electron probe micro analyzer

Sep 1, 2012

By N. Krishna

The utilization of Electrochemical Impedance Spectroscopy (EIS) in conjunction with Atomic Force Microscopy (AFM) is a powerful surface characterization technique to study the role of sulfur formation during acidic oxidation of chalcopyrite. It has been established that the chalcopyrite dissolution kinetics is controlled by the formation of passive sulfur layer during leaching. The objective of the study was to characterize the intermediate sulfur layer formation at different oxidation conditions in acidic solution. The chalcopyrite samples were subjected to anodic oxidation and the oxidation process was analyzed using impedance spectroscopy. The sulfur growth on the chalcopyrite surface during oxidation was further analyzed using Atomic Force Microscope for sulfur roughness and grain size, peak height and sulfur growth.

Jan 1, 1999

By M. Misra, J. Nanor

The precipitation and removal of arsenic from process waters can be accomplished with addition of lanthanum chloride alone or in conjunction with ferric sulfate. The long term stability of these corresponding precipitated compounds is critical from the disposal stand-point. In this paper the characterization of ferric, lanthanum and lanthanum-ferric arsenate compounds formed at room temperature in acidic and alkaline pH is presented. The characterization techniques used included zeta potential, XRD and SEM. Zeta potential measurements of ferric and lanthanum hydroxides in the presence of arsenate indicate that oxyanions of arsenate are chemically adsorbed onto the positively charged surfaces of these hydroxides. In alkaline pH there is desorption of arsenate species from the ferric hydroxide surface, hence the product is thought to be unstable. On the contrary, lanthanum arsenate is stable in alkaline pH. XRD patterns show that the ferric arsenate formed in acidic and alkaline pH is amorphous, whereas lanthanum arsenate and lanthanum-ferric arsenate formed in acidic and alkaline pH are crystalline.

Jan 1, 1999

By Yuanbo Zhang, Bingbing Liu, Zhuyin Chen, Xiao Kang, Chen Liu

Composite agglomeration process (CAP) is an effective method to utilize the iron-bearing dusts generated in the ironmaking plants, by which the dust percentage in the sinter feed can be increased up to 20 wt %. In the current study, a comparison on behavior of iron-bearing dust in the conventional sintering process (CSP) and CAP was characterized. The results showed, in the CSP products, the scattered iron-bearing dust in the mixture was disadvantageous for the sintering indexes and consolidation of the finished sinters. In the CAP products, the main phase in the iron-bearing dust pellets was well-crystallized Fe2O3 grain particles. In the matrix parts, there were more Fe3O4 particles generated, which caused to high RDI+3.15 and low RI of the finished products. The pellets and the matrix parts were bonded by iron oxides and acicular calcium ferrite.

Jan 1, 2016

By Engin Burak Anil

Objective, accurate, and fast assessment of damage to buildings after an earthquake is crucial for timely remediation of material losses and safety of occupants of buildings. Laser scanners are promising sensors for collecting geometrical data regarding the damaged states of buildings, as they are able to provide high coverage and accuracy at long ranges. Yet, we have limited knowledge on the performance of laser scanners for detecting earthquake damage, and requirements of such data collection. This paper focuses on characterizing the performance of laser scanners for detecting thin cracks for damage assessment of reinforced concrete frames. We identified a series of crack parameters based on the state-of-the-art damage assessment codes and standards. Similarly, we identified parameters, which affect the performance of laser scanners for detecting cracks, based on prior research in this area. We studied the width, depth, and orientation of cracks; sampling interval of the scanner, and the range of the laser beam from the surface. Effects of these parameters on the detection of the minimum crack size were determined in an experimental setting. An automated algorithm was used to analyze the data. The results show that it is possible to detect as small as ~1mm cracks.

Aug 1, 2013

Three high-grade limestone ores (CaO content over than 53 %) with different geological origin have been characterized for the synthesis of aragonite precipitated calcium carbonate. Limestone ores examined in this study showed different crystal particle size that cause difference in disintegration degree and surface area of the synthesized slaked limes. The limestone ore with smaller crystal particle size showed higher disintegration degree and also yielded slaked lime with smaller surface area, which is good for the synthesis of aragonite precipitated calcium carbonate. The synthesis of aragonite PCC using the limestone with a small crystal particle size was yielded needle-shaped aragonite with the aspect ratio of about 14. Keywords: limestone, lime, slaked lime, precipitated calcium carbonate, aragonite, accelerated carbonation

Sep 1, 2012

By A. D. Neuman, C. C. Davis, M. R. Lopez, A. C. Martinez, T. A. Nothwang, F. G. Hampel, S. L. Voit

"One of the thrust areas for the Global Nuclear Energy Partnership (GNEP) program is the development of actinide bearing fuels for transmutation in a fast reactor. Mixed Oxide (MOX) fuel has an extensive fast reactor irradiation history and thus is being considered for use as a baseline composition from which minor actinides can be incorporated for use as a transmutation fuel. The current study involves characterization of precursor powders and pellets destined for the Advanced Test Reactor in Idaho. These pellets will have three compositions: one standard MOX composition, (U0.80Pu0.20)O1.98, and two compositions of minor actinide mixed oxide (MAMOX) with oxygen to metal ratios (O/M) of (U0.75Pu0.20Am0.03Np0.02)O1.98 and (U0.75Pu0.20Am0.03Np0.02)O1.95. The precursor powders were characterized using a field emission gun scanning electron microscope (FEG-SEM) to determine particle morphology, size, and size distribution. An electron probe microanalyzer (EPMA) was used to characterize element distributions in the pellets.IntroductionThe fundamental purpose of GNEP is to enable a fuel recycling partnership between member nations. The customer nations utilize the fuel for electricity generation provided by and subsequently recycled by the supplier nation. The supplier nation recycles the actinide constituents, mainly uranium and plutonium, in advanced nuclear power reactors, and thus reducing waste volumes [1, 2]. Nuclear materials are strictly controlled through the International Atomic Energy Agency. One of the thrust areas supported by the GNEP program is the development of actinide bearing fuels for transmutation in a fast reactor under the U.S. Advanced Fuel Cycle Initiative (AFCI) in order to transmute long-lived transuranic actinide isotopes into shorter-lived fission products [3].MOX fuel has an extensive fast reactor irradiation history and thus is being considered for use as a baseline composition into which minor actinides can be incorporated for use as a transmutation fuel [4]. Irradiation performance data on oxide fuels with high concentrations of minor actinides is limited, which has prompted this study. This paper discusses the characterization results of precursor powders and pellets prepared for the Advanced Test Reactor in Idaho to determine the effects of including minor actinides in the fuel, and addresses two fuel test matrices proposed by Hilton et al. [3]. The pellets will have three compositions: one standard MOX composition, (U0.80Pu0.20)O1.98, and two compositions of MA-MOX with O/M of (U0.75Pu0.20Am0.03Np0.02)O1.98 and (U0.75Pu0.20Am0.03Np0.02)O1.95. The precursor powders, uranium oxide (depleted, DUO2 and highly enriched, HEUO2), neptunium oxide, NpO2, americium oxide, AmO2, and plutonium oxide, PuO2, were characterized using a FEG-SEM for particle morphology, size, and size distribution. The morphology of the actinide powders was studied in the areas of flowability and porosity in order to predict manufacturability. The MOX pellets were characterized using an EPMA in order to determine impurity levels and locations."

Jan 1, 2008

By Dongok Kim

Regardless of the advantages of the Friction Stir Process (FSP), for age-hardened aluminum alloys, the mechanical properties such as hardness in the stir zone decreased after FSP due to the growth or dissolution of strengthening precipitates. Here, as a new technique, FSP was introduced to alloy copper nanopowders in Al7075 T651. Mechanical properties of copper nanopowder- alloyed Al7075 T651 together with micro and nanostructures were compared with those of as-FSPed Al7075 T651 using SEM, TEM, and Vickers hardness testing to understand structure-property relationships. It was observed that Vickers hardness of the stir zone in copper nanopowder alloyed Al7075 T651 increased by 20% compared to that of the heat affected zone, while the as-FSPed samples did not show a noticeable increase in hardness in the same zone. Xray mapping showed traces of copper nanopowder after the process. TEM is being used to verify if there was CuAl2 formed in the copper alloyed sample.

Jan 1, 2006

By E. C. L. Cardoso

Hydrocarbon polymers, as PP, made from cheap petrochemical feedstock are important in many branches of industry. However, they have an undesirable influence on the environment and cause problems due to waste deposition and utilization. Polymeric materials composites account for an estimated from 20 to 30% of total volume of solid waste disposed. Thus, there is a tendency to substitute such polymers by those ones that undergo biodegradable processes. Polypropylene (PP) is a commodity, with high melting point, high chemical resistance, low density, with a balance between physical and mechanical properties and easy processing at low cost. Nevertheless, PP shows limitations for some special applications in automotive industry and civil construction. In order to minimize this deficiency, related to rheological behavior of polymer melt, especially referring to viscosity in processing temperature, a 50% mixture with HMSPP (High melt Strength Polypropylene) was used. PP/HMSPP was blended with 10, 15, 30 and 50% of natural (sugarcane bagasse) and synthetic polymers (PHB and PLA) aiming to partially biodegradable materials. The admixtures were subjected to gamma-irradiation at 50, 100, 150 and 200 kGy and then further assessed by mechanical tests in order to evaluate their degradability.

Jan 1, 2015

By Susanne Pignolet-Brandom

Fourteen samples of crushed Duluth Complex rock were characterized by the QEM?SEM automated scanning electron microscope image analysis system to evaluate the application of the system to mining waste rock characterization. The system can reliably distinguish the iron sulfides, the copper-iron sulfides and the nickel-iron sulfides. Calcite was distinguished from all other minerals except fluorite. The volumetric abundances were verified by comparing elemental abundances calculated using the QEM"SEM volumetric percentages and appropriate mineral compositions with elemental abundances determined by standard laboratory procedure. The pH and sulfate concentrations of rinse water from laboratory leach experiments correlated well with the mineralogical data.

Jan 1, 1989

By M. V. Chari

A prime objective of physical coal cleaning is the separation of raw coal into a clean coal product with the required low ash and pyritic sulfur content and a high ash refuse. The refuse should also contain a minimum amount of combustible matter. In order to be effective, cleaning processes require that the mineral matter in the feed, including pyrite, be largely discrete and free particles, liberated so that the particles are not attached or embedded in coal. Liberation of mineral matter from coal, particularly pyrite, was investigated by Bechtel as part of two fine coal cleaning research programs sponsored by the Department Of Energy (DOE), Pittsburgh Energy Technology Center (PETC). Two proof-of-concept (POC) plants, each with a capacity of 900 kg per hour, were installed and tested to evaluate production of ultra-clean coal using microbubble flotation and spherical agglomeration technologies. The plants were designed to produce clean coal with 2 percent ash and pyrite content lower than that achievable by conventional methods. Also, the quality targets were to be attained at energy recoveries above 80 percent. Bench-scale flotation and agglomeration tests indicated that it would be practical to grind the 6 mm top size feed coal to a mean particle size (050) of 10 micrometers in the POC test plant. In this part of the paper, the steps taken in the grinding circuit to maximize liberation of mineral matter are described.

Jan 1, 1991

By C. W. Whitten

Solis from an abandoned Pb battery processing facility were characterized prior to the selection of the extraction technique. Reflected light microscopy and electron beam methods were used to locate Pb-bearing phases and to quantify the compositions of the phases. It was found that the soils are composed primarily of quartz and feldspars with minor amounts of iron and titanium oxides. Lead is primarily present as an oxide or sulfate that is associated with the silicate minerals. Specific phases identified were PbO; Pb02; cerrusite, PbCO3; angleslte, PbSO4; galena, PbS; and magnetoplumbite, 2PbO3Fe2O3; or plumboferrite PbO2Fe2O3?

Jan 1, 1989

By O. P. Sinha, Biswajit Mishra, A. K. Mandal, Raj Kumar Dishwar, G. S. Mahobia, Ram ji Omar

Most of the mineral deposits found in North-East India remain unexploited due to inadequate knowledge on their status, economic viability, and requisite mining technologies. The aimof this study is to characterize the multimetallic magnetite mineral deposit from the Nagaland area in India. The quality of iron ore was evaluated to establish its suitability as a raw material for iron production. Detailed studies were conducted to establish the composition and properties of the samples. X-ray diffraction (XRD), X-ray fluorescence (XRF), electron probe micro-analyzer (EPMA), and petrographic microscopy techniques were employed in the investigation. Shatter and tumbler test was performed for analyzing the mechanical properties of the ore. XRD studies indicated that magnetite is the major mineral with low amounts of martite, maghemite, and quartz. XRF/EPMA results indicated that magnetite contains 35–65 wt.% of iron and 1–5 wt.% of chromium. It also confirms the presence of Ni and Al up to 1 wt.% and Si up to 6 wt.%. Chromite-rich ore contains up to 30 wt.% Cr and 15–20 wt.% of Fe.

May 10, 2021

By Shadia J. Ikhmayies

Nanocrystalline CdS:In thin films with particle size in the range (3-36 nm) were produced by the spray pyrolysis technique on glass substrates. The films were characterized by investigating their X-ray diffractograms (XRD), scanning electron microscope images (SEM), transmittance curves and photoluminescence (PL) spectra. The size of the nanocrystallites was estimated from XRD difractograms and then from the hyperbolic band model and the bandgap energies of the nano- particles, which were calculated from the positions of the minima in the first derivative curve of the absorbance. Fine-structured PL spectra confirmed the nanocrystalline nature of the films.

Jan 1, 2010