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By Emily Sarver, Cigdem Keles, Jonathan Gonzalez

The study re-examines respirable coal mine dust samples using scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). It finds that SEM tends to overpredict the abundance of dust from rock strata and underpredict coal content, possibly due to coal-mineral microagglomerates (MAGs). The findings suggest that MAGs could be valuable in improving dust controls in mines.

Feb 10, 2022

By S. Afrouz, C. Keles, E. Sarver, A. Greth

While respirable dust monitoring has long been done on the basis of mass concentration, it is increasingly recognized that specific dust characteristics may play an important role in health outcomes. Scanning electron microscopy with energydispersive X-ray (SEM-EDX) can be used for detailed particle analysis, but the quality of results can be dependent on the sample substrate; ideally, particles should be deposited on a smooth, uniform substrate like polycarbonate (PC). While direct air sampling onto PC filters is possible, this is not the standard approach in many situations. For example, in coal mines, polyvinyl chloride (PVC) filters are often used. They enable conventional mass-based analysis — of the total respirable dust, and the content of crystalline silica in this fraction — but are fibrous and thus not ideal for SEM-EDX or other microscopy. To address this issue, the current work tested a simple method to recover respirable dust particles from PVC filters and redeposit them to PC. Results generally indicated that recovered particles are representative of the original dust sample in terms of mineralogy distributions. Where this was not the case, the issue appeared to be with high particle loading density during SEM-EDX work rather than related to the recovery/redeposition method itself. This bodes well for applications where a single PVC filter sample could be used for nondestructive analysis to determine respirable dust mass and/or respirable silica mass, followed by preparation for SEM-EDX analysis to evaluate particle characteristics. The recovery and redeposition method might also be adapted for other applications, such as to enable the analysis of respirable dust samples collected by the continuous personal dust monitor (CPDM).

Oct 1, 2024

By J. Rostami, J. Brune, S. Slouka

Respirable dust poses long-term health issues to personnel working in mining and civil projects where mechanized mining and tunneling machines are used for hard rock excavation. Machines, such as longwall shearers, roadheaders, or continuous miners, use consumable picks to cut rock. However, rock dust is generated in the work environment each time the pick tip contacts the rock surface. Additionally, the generated dust can be reintroduced into the air further down in production, such as at transfer points. The purpose of this study is to characterize respirable dust particles generated at the pick tip at two stages of pick wear: new and moderately worn. Understanding dust characteristics in terms of concentration, size distribution, and particle shape throughout the life-cycle of the pick will provide a basis to mine and tunnel operators for changing out picks to mitigate dust generation at the source. This paper discusses the dust characteristics generated from preliminary full-scale cutting tests in a laboratory of an igneous rock block cut with conical picks at new and moderately worn levels of wear. The moderately worn pick generated a size distribution that favored smaller particle sizes compared to the new pick. The moderately worn pick also generated more overall dust, as the concentration level in mg/m3 was over double the amount of the new pick. Lastly, both picks generated particles that had similar aspect ratios and roundness measures.

May 18, 2022

By R. Sellaro, E. Sarver

It has long been understood that extended occupational exposures to respirable mine dusts can lead to chronic lung disease. In underground coal mines, coal workers pneumoconiosis (CWP) and silicosis are major concerns. While many efforts have been made with the aim of understanding the mass-based concentrations and silica contents of respirable dusts under a variety of mining conditions, little research has been completed in characterizing dust at the individual particle level (by composition, size and shape). This study employed scanning electron microscopy with energy dispersive x-ray (SEM-EDX) to analyze dust samples collected from an underground coal mine in Central Appalachia. The results indicated that particle characteristics can vary widely between locations, though many trends might be explained based on knowledge of mining conditions. A continuous personal dust monitor (CPDM) was also used during the collection of some samples to determine respirable dust concentrations, which were compared against estimated concentrations based on the particle-level analysis.

Jan 1, 2014

By R. L. Grayson, S. S. Peng

"Abstract. Sampling of respirable dust and analyses of samples have been partially completed for a longwall panel. Physical and compositional properties which have been characterized include:l. Respirable mass concentration, 2. Mineral composition,3. Particle size distribution by mineral,4. Particle shape distribution by mineral,5. Particle angularity distribution by mineral, and6. Respirable size distribution.Analytical techniques used in the characterization of samples are described, and results are reported with emphasis placed on relationships between the various characteristics and worker locations. Details of existing mining conditions, equipment arrangements, dust control methods and operating system parameters are presented.INTRODUCTIONThrough the work of many researchers worldwide, the health of coal miners in modern societies is now protected from dangerous exposure to respirable coal mine dust. A vast amount of research culminated in the exposure-response model of Jacobsen, et al. (1971) whi3h has been used to establish the 2mg/m exposure limit in the United States. According to the model, exposure to respirable dust for 35 years at this level or less would prevent the occurrence of a clinically significant case of coal workers' pneumoconiosis (CWP). The exposure limit, of course, must be adjusted whenever greater than five percent free silica exists in the respirable dust.The Jacobsen model was built around a mass concentration exposure, which showed the highest correlation with incidence and progression of CWP. As Morgan; et al. (1973) noted, howev.er, the quantity of respirable dust inhaled is not the only significant factor. It is noted that although mass of respirable dust correlates highest with the incidence of CWP, it is not a causal factor. Indeed, the insidious processes causing the disease occur on the cell-particle scale, requiring microscopic investigation."

Mar 1, 1989

By Priscilla P. Nelson, Francis L. C. Fong

Introduction Fracture mechanics is the study of the behavior of cracks and their modes of propagation. During cracking, energy is consumed in creating new surface area. The more energy a material absorbs, the higher is its fracture resistance. This fracture energy is provided either by work done externally, by the release of elastic strain energy within the cracked body, or by a combination of these two effects. Fracture resistance is measured in terms of either the stress intensity factor, K, or the energy release rate (also referred to as crack driving force), G. For linearly elastic materials, these two quantities are related by the following equation: [ ] where [u] is Poisson's ratio and E is the modulus of elasticity. Both K and G are direct functions of the applied force and the crack length. The process of rock cutting with full-face tunnel boring machines (TBMs) involves the indentation of a rock surface by rolling disc tools. Excavation occurs as fractures, extending from the locus of chip indentation, propagate between concentric disc grooves and liberate rock chips from the intact rock face. Since disc cutting is achieved by a fracture process, it is logical to anticipate that differences in cuttability of a variety of rocks should be related to the variation of fracture material properties among the rocks. Such a relation has been demonstrated between the performance of full-face TBMs and the critical crack driving force for excavation in relatively high strength, brittle, low porosity, isotropic rock (Nelson et al., 1985). The objective of this paper is to report on the results of a continued investigation of the relationship between fracture material properties and the effectiveness of disc cutting. Additional reliable data on full-face TBM performance is difficult to obtain, so that the results of disc linear cutter tests performed by the Transport and Road Research Laboratory (TRRL) (U.K.) are utilized in this study. Fracture Material Property Evaluation If a crack tip is subjected to a perfectly plain strain condition, many materials will behave in a brittle manner, and the material resistance to fracture is constant during crack growth. This resistance is referred to as the plain strain fracture toughness, believed to be a material property. The standard testing procedure for this parameter is given in the American Society for Testing and Materials (ASTM) test designation E399. To ensure plain strain conditions, acceptable specimen geometries are specified. Unless these geometric specifications are adhered to, the measured fracture resistance is regarded as the apparent fracture toughness, and a subscript Q is used, as [ ]. The methodology adopted by ASTM E399 is within the framework of Linear Elastic Fracture Mechanics (LEFM). This approach assumes that material resistance against cracking is developed instantaneously, without initial stable or subcritical crack extension. Prior to crack advancement in rock, however, much of the crack driving energy is absorbed in a localized volume in front of the crack tip, referred to as the plasticity or microcracking zone. This capability for energy absorption substantially increases material resistance, and a crack may be arrested unless an increased crack driving force is applied. The LEFM or plain strain assumptions would underestimate the actual fracture resistance of such a material. Such a conservative approximation may be desirable in the design of structures against fatigue or brittle failure. In mining or tunneling, however, an underestimation of crack resistance can lead to the selection of underrated excavation equipment and a decrease in production efficiency. The development of fracture resistance in rock is best described by the material resistance curve, or R-curve, which is a plot of fracture resistance as a function of crack extension. Typically, peak resistance is only reached after a finite amount of subcritical crack growth. The

Jan 1, 1986

By Rodrigo Sanchotene Silva

Currently the industries of paint have directed their efforts on cleaner production of products that provide effective performance in corrosion protection of metallic materials. This work search introduce a new alternative of organic coating, without the presence of hazardous metals and replace equipments commercials used method of anodic protection for protection of oxidized metals. From this it, was produced Smart Paint (SP), consisting of Paint Acrylic Commercial (PAC) mixed the 1 % of binder, compound by the conducting polymer, Polyaniline Emeraldine Base (PAni EB) and plasticizer 4-chloro-3-methylphenol. The SP and PAC were applied to plates of carbon steel AISI 1010, with the aid of dip coat technique and then were subjected to drying for 48 h. The SP was characterized by thermals and physicochemical analyzes in order to verify possible changes in chemical properties of the ink produced, beyond perform electrochemical tests of Open Circuit Potential and Electrochemical Impedance Spectroscopy, employing equipment Potentiostat/Galvanostat Autolab PGSTAT302 Ecochemie, and aqueous 2 mol.L-1 of H2SO4. The results obtained allow us to state that the plasticizer does not alter the electrochemical properties of PAni and application of binder PAni EB to PAC does not alter the physicochemical properties of commercial coating. The binder PAni EB adds to PAC the capacity to induce the formation or maintenance of protective oxides in oxidizable metals submitted to harsh environments, method known as anodic corrosion protection.

Aug 8, 2018

By Jilai Xue

Experiments with various industrial cathodes ranging from 35 wt.% to 100 wt.% graphitic and fully graphitized carbons were carried out in a laboratory aluminum electrolysis cell. Sodium and cryolite bath penetration into the cathode samples was measured by XRD and SEM-EDS analysis. For a higher cryolite ratio in the bath, the cathodes with lower graphitic carbons exhibited more sodium penetration than the fully graphitized. The increased graphitization in the cathode materials can reduce Na, NaF and Na3AlF6 penetration. SEM-EDS inspection reveals that the sodium and fluorides penetration within the cathode samples has different patterns for varying graphitization of the carbon materials. XRD quantitative analysis indicates that there is a large percentage of Na3AlF6 in the penetrated bath. The results can provide useful information for quality evaluation of the industrial cathode products.

Jan 1, 2010

By A. M. Ramalho

In the synthesis and sintering processes to obtain superhard materials, such as diamond and cubic boron nitride, deformable ceramic capsule is used as gasket to transmit and support the required high pressures and high temperatures, HPHT. The ceramics materials for these capsules should have special physics and chemical characteristics such as refractoriness, shear strength and compressibility. In this work, Bridgman?s anvil made of hard metal or speed steel was used to characterize some ceramics materials in terms of their maximum compressible thickness. Tests were also performed with different resin polymers used as binding mixture with ceramics powder. Chemical analyses and investigations through scanning electronic microscopic (SEM), X-ray and real tests for the synthesis of diamond were also performed. The results showed that local Brazilian calcite can be successfully used in the manufacture of HPHT gaskets.

Jan 1, 2006

By Sergio Neves Monteiro

This work had as its objective the characterization of a waste material, steel slag, generated from an integrated steel plant, with a view to its recycling and incorporation into red ceramics fabrication. The characterization was performed in terms of chemical composition by X-ray fluorescence (XRF), particles size distribution, X-ray diffraction (XRD), thermal analysis (DTA/TG) and scanning electron microscopy (SEM). The results indicate that the steel slag presents high amount of Ca, Fe, Mg and Si. The weight loss of the steel slag at temperatures above 800oC is associated with calcium carbonate decomposition. The coarse particle size of the steel slag is inadequate for its direct recycling into red ceramic fabrication. It is necessary to screen or to grind the waste. As a possible solution, it is suggested that screening or grinding the steel slag to a convenient particle size distribution would allow its successful industrial incorporation into red ceramics products.

Jan 1, 2006

By Mingming Zhang, Mallikharjuna R. Bogala, Ramana G. Reddy

Steelmaking desulfurization slag samples were characterized using chemical, X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) methods. The objective of this work is to investigate the occurrence of sulfur and phosphorus components in the slag samples and to identify their origin and associations with the iron phases. Thermodynamic calculations results confirm the presence of phosphorus and sulfur components in the slag sample at high temperatures (1400 to 1800oC). The main constituents of slag include Ca3SiO5 (28.1%), MgO (9.31%), Ca3(PO4)2 (9.18%), CaS (8.39%) and CaO (5.68%). The major phosphorus and sulfur components of the slag are Ca3PO4 (99.2%) and CaS (79.3%) respectively. Characterization studies indicate the presence of microparticles of different sizes and shapes in the slag sample. Elemental analysis of these particles confirm the presence of major elements (O, Mg, Al, Si, S, Ca and Fe) in the slag sample.

Jan 1, 2015

By R. D. Dukimo, M. V. Sevian

The nature of fracture and factors that control the extent of fracture in the tumble-drum and drop-tower tests have been identified. The product-size distribution, on which the standard strength indices for these tests are based, and the breakage rate constants depend on a number of factors other than the strength of the lumps. The standard indices and rate constants are meaningful only in a comparative context and for events whose loading mechanism is similar. The results of experiments on three Australian ores, from Yandi, Koolan and Mount Whaleback, are used in combination with fracture mechanics theory to explain why different tumble-drum standards have been found to be fully consistent. A more meaningful measure of strength could be the parameters of the Weibull function, scatter and average strength

Jun 19, 1905

By Yuanbo Zhang, Zhixiong You, Li Qin, Guanghui Li, Tao Jiang

Low-grade manganese oxide ore is generally characterized by high iron content. In this work, sulfidation roasting of an iron-rich manganese oxide ore with elemental sulfur was characterized. The experimental results indicated that manganese dioxide can be selectively reduced over iron oxide by using elemental sulfur. The manganese phases in roasted product included low-valence manganese oxide, manganese sulfide and manganese sulfate, while those of iron mainly depended on the sulfur addition. Iron oxide would only be reduced or sulfidized at larger sulfur additions. The effect of roasting temperature and S/Mn mole ratio on the phase transformations was also investigated; extractions of Mn/Fe by sulfuric acid were evaluated. An extraction of Mn greater than 95% was obtained while that of Fe was controlled less than 10% under the optimal conditions.

Jan 1, 2016

By Steven Derycke, Stephen C. Tadolini, Anand Bhagwat

"The tensile and shear strength of intrinsic bolting support systems has always been a major concern of designers. A comprehensive laboratory testing program was designed to evaluate the tensile and shear strength of individual wires and completely wound PC-strand cables. PC-strand cables with smooth wires and the recent anchorage enhancement innovation of indentation were evaluated and compared. The testing protocol detailed in ISO Standard 15630 utilizes a mandrel system that was investigated at 3 different diameters which alters the wire to mandrel ratio from 2:1 to 9:1. The results demonstrate that the difference between smooth and indented wires is statistically insignificant when larger diameter mandrels are used, and that indentation does not adversely affect strand properties and performance. Insight into the shearing mechanism and evaluation techniques are discussed with the introduction of triaxial loading to describe the PC-strand tensile and shearing mechanisms. Another important result indicates that the shear strength of PCstrand cable bolting systems has a greater shear strength value than traditional steel bar bolting systems.INTRODUCTIONPC-strand cable bolts have proven to be a global cost effective ground control solution in metal/non-metal and coal mines. The inherent strength to weight ratio of cable supports, combined with flexibility has been used in underground entries that range from 20 to less than 1.2 m in height (65 to 4 ft). In coal mining, the systems are used as primary and secondary support installed both passively or actively with installation tensions that range from 38 to over 178 kN (8,500 to 40,000 lbs) . While cable can be specified in several diameters, the most predominant sizes in the US remain 15.2mm (0.6 in) and 18mm (0.7 in). The capacity of the systems defined in the ASTM 432-13 is 90% of the minimum strand strengths of 260 kN (58,600 lbs) and 320 kN (72,000 lbs), respectively.Cables are not only suitable to support vertical loads, but are also often used to effectively support fractured and jointed materials and can be exposed to shear forces across the wound PC-strand structure. In fact, Goris et al. reported that cable bolts placed across jointed surfaces could more than double the shear resistance. These results were duplicated for both smooth and rough jointed surfaces (Goris et al., 1996). An example of tensioned cable bolts used to support a fractured and sliding roof in a longwall tailgate entry is shown in Figure 1."

Jan 1, 2015

By L. B. Kilius

The composite cathode system based on Ce0.9Gdo.1O2_,5 electrolyte with a painted cathode was used for an intermediate temperature (500-700°C) solid oxide fuel cell. This cathode system was chosen due to its excellent thermal expansion match to the electrolyte, its relatively high conductivity (115 S cm-1 at 700°C), and its low activation energy for oxygen reduction (99 kJ/mol). It was found that the decrease of sintering temperature of the composite cathode system produces a significant decrease in charge transfer resistances to a level of 0.25 SI cm2. The conductivity measurements of porous samples produced values between 40 and 88 S/cm for porosities of 30-40%.

Jan 1, 2005

By T. Inoue, K. Okaya

"Movement of mill charge in the centrifugal mill is essentially different from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. As proved e.g. in [11], this results in substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Back in 1983, Bradley et al. presented a model of the centrifugal mill based on the kinetics of the mill charge by regarding it as a lumped mass. On the other hand, numerical modeling by ‘discrete element method (DEM)’ enabled us to observe the movement of each ball in the centrifugal mill with an extremely minute time intervals (Inoue et al., XX IMPC in 1997). The former approach rendered simple, even though approximate, expression of the mill behavior, while the latter method was advantageous in describing the behavior of the mill in terms of individual events taking place in the mill body, even though the result did not reduce to a simple expression. The characteristics of the centrifugal mill described by both these approaches proved to be in a degree of agreement. Thus, the kinetic approach was capable of presenting the overall view of the mill, while the DEM model was informative of the details that could not be depicted well enough by the simple math expressions."

Jan 1, 2003

By S. Y. Tan

As continual complementary metal?oxide?semiconductor (CMOS) scaling requirements, metal gate/high-k dielectric/Si gate stacks are expected to replace poly-Si/SiO2/Si gate stacks in the future CMOS sub-45 nm technology node. Hafnium based oxide is a promising candidate to replace SiO2 as a gate dielectric, due to its much higher dielectric constant (high-k) and stability. The key challenges of successfully adopting the high-k dielectric/Si gate stack into advanced CMOS technology mostly come from the interfacial properties. The origins of the electrical and physical characteristics of the dielectric oxide/bulk interface were studied in detail. The leakage current density-voltage (J-V) and capacitance-voltage (C-V) measurement techniques were employed to study the dielectric oxide/Si interface. The effects of the post-deposition annealing (PDA) treatment on the interface charges of dielectric oxides were studied. We found that the PDA can effectively reduce the trapping density and leakage current, and eliminate hysteresis in the C?V curves. Besides, the changes in chemical bonding features at HfO2/Si, HfSiO/Si and HfSiON/Si interfaces due to PDA treatment were evaluated by XPS measurements. The XPS analysis provides a better interpretation of the electrical outcomes. As a result, both HfSiO and HfSiON films have exhibited superior performance in terms of thermal stability and electrical characteristics.

Jan 1, 2010

By Sergio N. Monteiro

Jute fiber reinforced polymer composites are among the most investigated and applied natural composites. In this past decade the mechanical properties of these composites has been assessed for various types of test conditions. However, the reported results correspond mainly to short-cut jute fiber composites, which do not present the highest mechanical strength as compared to continuous fibers of the same kind. In order to complement these results, the present work evaluated the mechanical behavior, by means of flexural tests, of polyester matrix composites reinforced with continuous jute fibers. Bend tests were conducted in standard specimens with up to 40% of jute. Fracture analysis by SEM displayed the rupture mechanisms. The results showed an improvement in some flexural properties with incorporation of jute fiber. However, a low fiber/matrix interfacial stress was responsible for limitation in the values attained by some properties.

Jan 1, 2010

By C. L. Schneider

The problem of predicting the liberation spectra produced by a closed continuous grinding circuit is of fundamental importance for the design, optimization and control of most operations in an ore dressing plant. The only known approach through which such a calculation can be performed is the population balance model equation. The latest and certainly most significant progress made in this area is the solution proposed by King (1990), which requires one textural parameter that can be measured directly from the ore being studied. The main advantage of King's solution is that it does not require the estimation of hundreds of arbitrary parameters that cannot be independently measured, as required by the existing conventional solutions. However, King's solution relies heavily on a knowledge of the detailed internal structure of the Andrews-Milm diagram (Andrews and Mika, 1975). This has never been measured for any ore. The characterization of the internal structure of the Andrews-Mika diagram requires the measurement of the liberation spectra at several progeny sizes produced by the breakage of monosize, monograde particles at several different grades. In this paper, a procedure based on magnetic fluid fractionation for generating seven narrow-size, narrow-grade samples is presented. Each of these samples was then broken into six progeny size classes in an ultrasonic mill. The one-dimensional liberation spectra of each of the 42 progeny and seven parent particle samples were then measured by image analysis. The measured linear-grade distributions are presented in this paper. The calculation of the correspondent volumetric-grade distributions is discussed.

Jan 1, 1994

By P. N. Anyalebechi

"The as-cast microstructure of two commercial-size ingots of aluminum alloy 3004 produced by the electromagnetic casting process was quantitatively characterized. This involved the quantitative determination of through-thickness and across-width variations in dendrite cell size, grain size, macrosegregation of alloying elements, interparticle spacing, and the types, volume fractions, and sizes of the constituent or second phase particles. More than ninety-five percent of the constituent phases in the ingots consisted of the A16(Mn,Fe) phase; the desirable a-Al 12(Fe,Mn)3Si phase was not detected in any of the ingots by Guinier X-ray diffraction analyses or electron probe X-ray microanalyses. A significant microstructural heterogeneity through the thickness and across the width of both ingots was observed. For example, macrosegregation, and the sizes of the constituent phase particles, dendrite cells, and grains increased concomitantly from edge to mid-width and from surface to center of the ingots. There was a -20% depletion (negative macrosegregation) of Mg and a +54-87% enrichment (positive macrosegregation) of Ti in the center of the ingots. With the exception of grain size, there was no significant microstructural difference between the two ingots examined. The causes and practical implications of the observed microstructural heterogeneity in the ingots are discussed.IntroductionThe first step in the fabrication of majority of wrought products of aluminum and its alloys is the casting of large ingots or billets of simple shapes (round or rectangular). The sizes of the ingots vary from 10 mm to 450 mm diameter or 25 mm to 780 mm thick. The quality of the finished products is established at the ingot casting stage. This is because the microstructural characteristics, such as secondary dendrite cell size or arm spacing, amount of alloying elements retained in solid solution, macrosegregation, and the characteristics of second phases, produced during casting cannot be reversed by subsequent processing. Up until twenty-five years ago, the effect of as-cast microstructure of large ingots on the structure and behavior of thin sheets (0.34 mm thick) during drawing and ironing processes was incorrectly assumed to be minimal or nonexistent. This was based on the erroneous notion that the thermal treatments and large reduction (>99.94%) and strain that the ingot undergoes during production of the sheets completely destroys the original ingot structure and its inherent heterogeneity. However, the effects of ingot structure can, a priori, be deduced from the observed effects of constituent phase particle size, type and volume fraction on recrystallization, development of texture during annealing and deformation, and earing. In fact, careful examination of the behavior of products produced from different size ingots or castings have shown that the original microstructure of the ingot has a direct impact on the properties and performance of the end products."

Jan 1, 2011