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By Robert Linton

SPECIFICATIONS for clays serving raw materials in the ceramic industry usually contain the following items: (1) Chemical analysis, sometimes with mineralogical structure determined by microscopic investigation. (2) Maturing temperature and firing range, usually expressed in terms of pyrometric cone equivalent. (3) Shrinkage (drying and firing shrinkage separately). (4) Degree of plasticity. (5) Color after firing. Clays may be classified, according to the purpose of the classification, in several different ways, based on (1) Geological occurrence-transported, altered An place, indurated (shales). (2) Physical properties-plastic (bonding clays, ball clays) and nonplastic (flint clays, kaolins or china clays, bone clays). (3) Color. (4) Use. A common classification of clays for commercial designation, and one fol-

Jan 1, 1936

By S. J. Page, W. E. Wallace, P. Bolsaitis, D. Eppelsheimer, M. J. Keane, J. Poston, J. Harrison

"Respirable-sized dust particles from a clay mine and mill were examined for aluminium and silicon content by scanning electron microscopy-energy dispersive X-ray analysis at incident electron energies of 5--20 keV. Most of the high silica content particles, those which had a silicon to silicon plus aluminium signal fraction, measured at 20 ke V, of0.9 or greater, showed a decrease in the silicon fraction of signal with decreasing incident electron energy, down to values of between 0.6 and 0,8 at 5 keV: this decrease was a function of particle size and composition. Simple models for silicon fractiol) of signal vs incident electron voltage suggest this behavour is due to a heterogeneous particle structure in which an aluminosilicate coating occludes the surface of a silica particle core. The coating survives incubation in a major component of pulmonary surfactant.INTRODUCTIONMINING and some other dusty workplace atmospheres are monitored for respirable dust and quartz dust for purposes of occupational health protection, respirable quartz dust being a known cause of pulmonary disease. Respirable quartz exposure data are acquired also for epidemiological research on the correlation of pulmonary disease prevalence with respirable dust composition and concentration. For these purposes quartz content often is measured on collected dust samples by X-ray diffraction or in spectroscopy. Scanning electron microscopy-energy dispersive X-ray analysis spectrometry (SEM-EDX) is also used. The first two methods measure the bulk composition of a multi-particle dust sample; SEM-EDX measures the elemental composition of single ·particles. These methods as typically applied, including SEM-EDX with a 20-30 kilo-electron volt (keV) electron beam accelerating potential, do not distinguish homogeneous distribution of impurities in a particle from possible heterogeneous surface distribution. These measurements of quartz content are not always accurate predictors of the prevalence of dust-induced disease (ROBOCK and BAUER, 1990), which implies that the biologically available quartz surface may not be equivalent to conventionally measured quartz content of respirable dust in some exposure settings. Using a minor modification of conventional scanning electron microscopy-energy dispersive X-ray analysis (SEM-EDX) protocols on samples of settled and airborne dust from a clay mine and mill we have detected heterogeneity with depth for aluminium impurity in high silica content particles, indicating that some of the quartz or 'free silica' respirable particles of the dust are aluminosilicate occluded. Coatings were not removed by incubation of the dust in a surrogate pulmonary hypophase surfactant fluid."

Jan 1, 1990

By Haydn H. Murray

The area from Ohio on the east, Tennessee on the south, and Minnesota on the west: contains some very unique and useful clay deposits. Included are fireclays and plastic clays in Ohio, Kentucky, Indiana, Illinois, and Missouri; flint clays in Kentucky and Missouri; ball clays in Kentuckv and Tennessee; adsorbent clays (fuller's earth) in Missouri, southern Illinois, and Tennessee; and alluvial clays and shales for structural clay products from every state. Unique kaolin clays are known in Minnesota, Missouri, and southern Illinois and halloy-site localities are known in southern Indiana. The geology, physical properties, and uses or potential uses of these midwestern clays are described.

Jan 1, 1980

By D. Steele, B. Ndlovu

"Adequate characterisation of clays is becoming increasingly important as operating mines move into areas of more complex ores. The processing therefore needs better mineralogical characterisation to identify problematic ores for better planning before issues arise. While a number of instrumental mineral characterisation methods are available, X-ray Diffraction (XRD) is widely recognised as perhaps the best technique for the identification and quantification of minerals, particularly clays. When an appropriate sequential and systematic sample preparation and treatment protocol is employed with instrumental XRD analysis individual clays can be uniquely identified, and the proportions of interstratified clays can also be quantified. The effect of sample preparation on the XRD analysis and identification of clays was investigated in this study. The results showed that sample preparation protocol is indeed critical to accurately analysis and characterisation of clays. For example, both dry grinding and micronizing affected the degree of crystallinity of kaolinite leading to the formation of reactive surfaces or changes in the physicochemical behavior. It was also found that the apparent degree of preferred orientation in platy minerals correlates directly with the amount of force/pressure applied during the preparation of backfilled powder samples. This work showed that manual preparation can produce highly variable peak intensities especially with minerals that show any preferred orientation. KEYWORDS Clay; XRD; kaolinite INTRODUCTION Clays are important in our life and they have numerous applications in modern world from cosmetics to environmental remediation. Therefore, clays have been extensively investigated for many years. Adequate characterisation of clays is becoming increasingly important as the mineral processing industry faces more complex mineralogy with the need for better mineralogical characterisation to identify problematic ores and plan accordingly. In most studies, X-ray diffraction (XRD) method has shown the unique capability to characterise mineralogy, especially for the fine grained size materials. The XRD technique is particularly diagnostic for clays. It is known that under ideal conditions, the peak intensities of an XRD diffractogram are proportional to the concentrations of individual minerals present in the sample. Hence, the qualitative mineralogical data obtained from XRD can be quantified, using either the internal or external standard methods. However, it is also known that clays are particularly sensitive to the influences of sample preparation method due to their physical characteristics (e.g. fine grain size, morphology, relative physical softness, crystallinity, thermal sensitivity) that could be destroyed by inappropriate preparation prior to the analysis. Thermal and mechanical treatment and grinding of clays can change their crystalline structure, and consequently, their characterisation results by XRD analysis. The behaviour of clays in grinding has been widely studied, especially for kaolinite (Miller and Oulton, 1970, Milocevic et al., 1992, Tomasevic-Canovic et al., 1992). With prolonged grinding time, the crystallinity of the clays can decrease (Filipovic-Petrovic et al., 2002). It has been shown that grinding may gradually cause the loss of hydroxyl ions of kaolinite (Gonzalez Garcia et al., 1991)."

Jan 1, 2018

By T. McCallum, C. Cooper, B. Hutzler

"In copper solvent extraction, managing the quality of the organic phase is a key parameter to ensure optimal physical and metallurgical performance in the plant. Increased throughput as a result of declining ore grades coupled with advances in plant design and practice, resulting in reduced organic losses, has pushed the limits of the status quo with respect to organic quality. Clay treatment of plant and recovered organic at the optimal dosage is critical in maintaining quality, however, achieving the optimal dosage through existing filtration capacity and practice can be difficult. Cytec has developed a process aid that increases efficiency of existing filtration equipment that has been successfully implemented at two commercial SX operations. ACORGA® CB1000 enables higher dosages of clay while allowing for more efficient use of existing filtration capacity. This study analyzes results from commercial trials and demonstrates that improved organic quality and clarity is achievable through optimization of current treatment practices. INTRODUCTION Decreasing ore grades have prompted copper solvent extraction operations to raise PLS flow rates, increasing plant throughput to maintain production1. The ability to process higher flow rates through existing mixer-settlers historically came at the expense of increased entrainments2. However, advances in mixer-settler design, practices and improvements in organic recovery processes have enabled operations to maintain, and in some cases reduce organic losses while achieving higher flow rates through existing equipment. Based on the increased demand on the SX equipment and reduced losses (or more efficient recovery) maintenance of the circuit organic quality through efficient clay treatment is now more important than ever. This paper discusses common industry practices and related issues in organic clay treatment, and presents benefits achieved in commercial operations through the use of ACORGA® CB1000 Clay Binder. IMPROVEMENTS IN DESIGN AND PLANT PRACTICE Mixer-settler design has improved since the first commercial copper SX operation in the late 1960s. Advanced designs in mixer, settler, and settler internals have contributed to reductions in entrainments. For example, improved impeller designs have been reported to decrease organic in aqueous entrainment from the ‘old designs’ of 50-200 ppm3 to as low as 4 – 10 ppm confirmed via diluent and reagent consumptions . Similarly, operations are reporting a 20-50% decrease in reagent consumption when compared to the original design criteria3. Operations have optimized settler internals to increase coalescence and have improved settler operating practices which have been shown to reduce entrainments7. Comparison of the SX world operating data from 1999 and 2007 shows reductions in organic entrainment losses with increases in flow rates."

Jan 1, 2015

By R. H. Beaton

"About 1905, a plant was constructed at C1ayburn, in the Lower Fraser valley, 4'5 miles east of Vancouver, to process shales from Sumas mountain into heavy clay products. In time, mining operations were found to be more favourable on the opposite side of the mountain, and by 1913 a plant, which soon became the centre of activities, was completed at Kilgard. Destroyed by fire in 1949, the plant was rebuilt on modern lines, and a second plant was established at Abbotsford, six miles to the west. The Company, from its beginning, has grown with development of the Province. In recent years, operations have kept abreast of latest developments, particularly in materials handling. Latest innovation has been the complete conversion of fuel from Bunker C oil to natural gas. In 1957 the Company became associated with Harbison Walker Refractories, Limited, a leader in its field in the United States, and its title was changed from Clayburn Company, Limited, to Clayburn-Harbison, Limited. Currently, the Kilgard plant produces sewer pipe, agricultural tile, and flue liner; the Abbotsford plant, refractories and facebrick. Improvement of products and development of new ones are tasks of a recently-completed testing and research laboratory.Almost all ware produced is marketed in Western Canada or Washing-ton State. The Vancouver area absorbs the bulk of structural clay products."

Jan 1, 1959

By S. N. Monteiro, C. M. F. Vieira, M. M. Ribeiro

"This work has as its objective to evaluate the effect of incorporation of the powder waste retained in the eletrostatic precipitator of the sintering stage from an integrated steel making plant on the physical and mechanical properties of a red ceramic. Formulations were prepared with incorporation of the waste in amounts up to 20 wt.% into a kaolinitic clay. Rectangular specimens were prepared by uniaxial mold-press at 20 MPa and then fired at 750, 900 and 1050°C. The evaluated physical and mechanical properties were: linear shrinkage, water absorption and flexural rupture strength. The results showed that the waste has a potential to be used into red ceramics. The incorporation of the waste enhanced the properties of the ceramic, decreasing the water absorption and increasing the mechanical strength at all investigated temperatures.IntroductionThe sintering stage of an integrated steel-making plant is dedicated to the agglomeration of a mixture of iron ore, coke or coal, fluxes and water [1]. It is a common practice in this stage to use of solid wastes with great amounts of iron in the form of sludge and powder. One of the atmospheric pollutants generated during the sintering process is the particulate material, which is normally retained in an equipment denote as electrostatic precipitator. This equipment retains very small particulates, present in the gaseous emissions by application of an electrical potential difference in between the plates that the fluid is forced to go through. [2]."

Jan 1, 2011

By Haydn H. Murray, Sam H. Patterson

The term "clay" is somewhat ambiguous un¬less specifically defined, because it is used in three ways: (1) as a diverse group of fine-¬grained minerals, (2) as a rock term, and (3) as a particle-size term. Actually, most persons using the term "clay" realize that it has several meanings, and in most instances they define it. As a rock term, clay is difficult to define be¬cause of the wide variety of materials that com¬pose it; therefore, the definition must be gen¬eral. Clay is a natural earthy, fine-grained ma¬terial composed largely of a group of crystalline minerals known as the clay minerals. These minerals are hydrous silicates composed mainly of silica, alumina, and water. Several of these minerals also contain appreciable quantities of iron, alkalies, and alkaline earths. Many defini¬tions state that a clay is plastic when wet. Most clay materials do have this property, but some clays are not plastic; for example, halloysite and flint clay. As a particle-size term, clay is used for the category that includes the smallest particles. The maximum-size particles in the clay-size grade are defined differently on various grade scales, Soil investigators and mineralogists gen¬erally use 2 micrometers as the maximum size, whereas the widely used scale by Wentworth (1922) defines clay as material finer than ap¬proximately 4 micrometers. Some authorities find it convenient to use the term "clay" for any fine-grained, natural, earthy, argillaceous material (Grim, 1968). When used this way, the term includes clay, shale, or ar¬gillite, and some argillaceous soils. Even though no standard definition of the term clay is accepted by geologists, agronomists, engineers, and others, the term is generally un¬derstood by those who use it. Clay is an abun¬dant natural raw material, and it has an amaz¬ing variety of uses and properties which will be discussed in this chapter. Clays rank among the leading industrial min¬erals in both tonnages produced and total value. Their importance is indicated in Table 1, which lists the 1970, 1971, and 1972 production and values according to the U.S. Bureau of Mines (Ampian, 1972). Adequate reliable statistical data on which to summarize world production of clay are un¬available; this paragraph outlines the world re¬quirements for clay only in a very general way. According to one estimate, the world bentonite production in 1972 was 3.5 million tons (Anon., 1973a), but in the authors' opinion it was prob¬ably at least 5 million tons. The total fuller's earth produced was at least 1.5 million tons and may have been as much as 2 million tons. The total world kaolin production in 1972 was more than 10 million tons. Approximately 7 million tons of this total was produced in only two regions-the Georgia-South Carolina kaolin belt in the United States and the Cornwall re¬gion, United Kingdom. The world's 1972 out¬put of ball clay, which is also produced pri¬marily in the United States and the United Kingdom, was approximately 1.5 million tons or perhaps a little more. The total world fire clay production in 1972 was probably about one and one-half to two times and the miscellaneous clay production three times the United States production. As industrial minerals, clays are a complex group that consists of several mineral commodi¬ties, each having somewhat different mineral¬ogy, geologic occurrence, technology, and uses. In this chapter these commodities are organized

Jan 1, 1975

By Haydn H. Murray, Sam H. Patterson

The term clay is somewhat ambiguous unless specifically defined, because it is used in three ways: (1) as a diverse group of fine-grained minerals, (2) as a rock term, and (3) as a particle-size term. Actually, most persons using the term clay realize that it has several meanings, and in most instances they define it. As a rock term, clay is difficult to define because of the wide variety of materials that compose it; therefore, the definition must be general. Clay is a natural earthy, fine-grained material composed largely of a group of crystalline minerals known as the clay minerals. These minerals are hydrous silicates composed mainly of silica, alumina, and water. Several of these minerals also contain appreciable quantities of iron, alkalies, and alkaline earths. Many definitions state that a clay is plastic when wet. Most clay materials do have this property, but some clays are not plastic; for example, halloysite and flint clay. As a particle-size term, clay is used for the category that includes the smallest particles. The maximum-size particles in the clay-size grade are defined differently on various grade scales. Soil investigators and mineralogists generally use 2 micrometers as the maximum size, whereas the widely used scale by Wentworth (1922) defines clay as material finer than approximately 4 micrometers. Some authorities find it convenient to use the term clay for any fine-grained, natural, earthy, argillaceous material (Grim, 1968). When used this way, the term includes clay, shale, or argillite, and some argillaceous soils. Even though no standard definition of the term clay is accepted by geologists, agronomists, engineers, and others, the term is generally understood by those who use it. Clay is an abundant natural raw material, and it has an amazing variety of uses and properties which will be discussed in this chapter. Clays rank among the leading industrial minerals in both tonnages produced and total value. Their importance is indicated in Table 1, which lists the 1978, 1979, and 1980 production and values according to the US Bureau of Mines (Ampian, 1980). Statistical data summarizing world production of kaolin, bentonite, and fuller's earth are compiled by the US Bureau of Mines (Ampian and Polk, 1981). The total world bentonite production in 1980 was 6,625,204 st of which the United States produced 4,184,619 st. The total fuller's earth produced in the world in 1980 was 1,952,600 st of which 1,534,000 st was produced in the United States. The total world kaolin production in 1980 was estimated at 22,971,000 st. Approximately 13 million tons of this total was produced in two countries, the United States and the United Kingdom. World production data on ball clay, fire clay, and miscellaneous clays are not available. As industrial minerals, clays are a complex group that consists of several mineral commodities, each having somewhat different mineralogy, geologic occurrence, technology, and uses. In this chapter these commodities are organized as follows: (1) bentonite and fuller's earth; (2) kaolin, ball clay, halloysite, and refractory clays; and (3) miscellaneous clay and shale. Bentonite and fuller's earth are grouped together because they are closely interrelated. Though bentonite is a term based on mineral composition and fuller's earth is a term based on use, the two are virtually inseparable, because much, but by no means all, clay sold as

Jan 1, 1983

By Haydn H. Murray

The term clay is somewhat ambiguous unless specifically defined, because it is used in three ways: 1) as a diverse group of fine-grained minerals, 2) as a rock term, and 3) as a particle size term. As a rock term, clay is difficult to define because of the wide variety of materials that comprise it; therefore, the definition must be general. Clay is a natural, earthy, fine grained material comprised largely of a group of crystalline minerals known as the clay minerals. These minerals are hydrous silicates comprised mainly of silica, alumina, and water. Several of these minerals also contain appreciable quantities of iron, alkalies, and alkaline earths. Many definitions state that a clay is plastic when wet. Most clay materials do have this property, but some clays are not plastic, e.g., halloysite and flint clay. As a particle size term, clay is used for the category that includes the smallest particles. The maximum size particles in the clay size grade are defined differently on various grade scales. Soil investigators and mineralogists generally use 2 pm. as the maximum size, whereas the widely used scale by Wentworth (1922) defines clay as material finer than approximately 4 pm. Some authorities find it convenient to use the term clay for any fine-grained, natural, earthy, argillaceous material (Grim, 1968). When used this way, the term includes clay, shale, or argillite, and some argillaceous soils. Even though no standard definition of the term clay is accepted by geologists, agronomists, engineers, and others, the term is generally understood by those who use it. Clay is an abundant natural raw material, and it has an amazing variety of uses and properties which will be discussed in this chapter. Clays rank among the leading industrial minerals in both tonnages produced and total value. Their importance is indicated in Table 1, which lists the 1988, 1989, and 1990 productions according to the US Bureau of Mines (Ampian, 1992). As industrial minerals, clays are a complex group that consists of several mineral commodities, each having somewhat different mineralogy, geologic occurrence, technology, and uses. In this section these commodities are organized as follows: 1) bentonite, 2) common clay, 3) hormites, and 4) kaolin. Fuller's earth is discussed in both the bentonite and hormite chapters. Fuller's earth is a term based on use, and both bentonites and hormites are sold as fuller's earth. The overlapping is particularly evident where both bentonite and non-bentonite fuller's earth are used for the same purposes or products, such as in drilling mud, bleaching or clarifying fats and oils, and carriers for insecticides and fertilizers. Kaolin, ball clay, halloysite, and refractory clays are grouped together because they consist mainly of minerals of the kaolin group. Common clay is a grouping of several fine-grained materials, including shale, sometimes referred to as miscellaneous clay. The scientific and technological publications pertaining to clays

Jan 1, 1994

By G. Armand, G. Arnold, A. Giraud, C. Auvray

The knowledge and understanding of the mechanical behavior of claystone is of critical importance in the aim of nuclear wastes storage. In this study, specimens of Callovo-Oxfordian claystone (COx) have been obtained from the ANDRA underground research laboratory in Meuse/Haute-Marne (France). This claystone is composed of carbonate inclusions (10-50µm) embedded in an argillaceous matrix (representing expanding clay minerals, such as smectites). The matrix itself is also multiphase and composed of clay aggregates of 1µm-size carbonate and quartz inclusions. This multiphase microstructure leads to a high heterogeneity witch was analysed through nanoindentation test grids. Moreover, the mechanical behavior of the claystone matrix is highly sensitive to humidity and temperature. The nanoindentation tests were performed in a climatic (i.e. temperature and humidity controlled) chamber at relative humidity levels from 50% to 98% and at two temperatures: 20°C and 60°C. In a first step, the curves of indentation were analysed using the commonly used Oliver and Pharr’s approach. Other wellknown parameters as the creep factor were also extracted. In a second step, Fisher-Cripps model (Fischer- Cripps, 2004) and Vandamme and Ulm model (Vandamme & Ulm, 2006) were used to identify viscoelastic properties. A statistical analysis is used in order to extract mechanical characteristics of the different phases. Hardness and elastic modulus decrease drastically with saturation (above 80% humidity) and to a lesser extend with temperature.

Jan 1, 2015

It is a very great pleasure indeed to participate in this interesting and important seminar. My two visits to Australia in the past have been extremely pleasant and this one is equally so. My task is to tell you what has been happening in the United States, in these past few years especially, in regard to the management of our air resources and to present in some detail the difficulties we in the copper, lead and zinc smelting industries have been experiencing. The sudden upsurge in interest in air pollution in the United States is a strange phenomenon indeed - strange because we've had air pollution a long time, just as long as there have been large cities using fossil fuels for heating purposes. And the problem has been studied for quite a long time. As early as 1919 studies by the U. S. Bureau of Mines were done in Salt Lake City, where I .live. In the winter of that year extensive measurements were made of airborne particles - dust and smoke. The average concentration of particles found was 870 micrograms per cubic meter of air. A very large number compared to levels we find today. A microgram of course is a very small unit, one twenty-eight millionth of an ounce. A fine human hair two inches long weighs about 100 Micrograms.

Jan 1, 1971

By K. Hasselwander, K. Knabel

"A significant area of Outotec’s business involves fluidized bed roasting. With several decades of experience, more than 300 reference plants and strong R&D capabilities, the company provides several industries with optimum processing solutions. Applications include oxidation and sulfation of sulfides found in copper, pyrite and zinc concentrates. Gold production and de-arsenifying roasting are also within this scope. This paper describes the latest furnace developments and includes novel trends. Moreover, hot and wet gas cleaning systems are examined focusing on unit operations related to the removal of components such as dust, SO2 for sulfuric acid production, fumes, halides, Hg, hydrocarbons, nitrous oxides and metals.INTRODUCTIONGenerally, when defining roasting processes, it can be stated that the respective primary pyrometallurgical reaction is exothermic, of gas-solid nature and relates to a value solid product. These processes are a key focus within Outotec’s scope and include: (i) dead roasting (ii) sulfating roasting (iii) partial de-arsenifying roasting and (iv) two-stage, de-arsenifying roasting.Dead roasting involves the oxidation of a given sulfide, thus allowing for a subsequent leaching process, and has been applied to producing ZnO. Dead roasting of pyrite has also been extensively utilized with a primary goal of producing sulfuric acid. In contrast, sulfating roasting involves converting a sulfide to its sulfate, enabling a selective sulfation of components, such as Cu or Co, and their separation from ferrous components during leaching (produced sulfates are soluble). Partial roasting involves partially oxidating the metal sulfide to its oxide with the simultaneous production of gaseous As4O6, which is handled during gas cleaning. The solid product, containing hardly any As, is rich in S and can be fed to a respective smelter (e.g. in the case of Cu). Alternatively, if the production of oxide is required, a dead roasting step is added after the partial roasting step, with the overall process considered as two-stage roasting."

Jan 1, 2012

By D. B. Eccleston

Natural gas and mixtures of natural gas and hydrogen were used as fuels in a laboratory engine to determine the relationship of emissions to air-fuel ratio and to establish practical lean limits for air-fuel ratio. Synthetic gas manufactured from coal (Synthane) and natural gas were used as fuels in a vehicle to obtain comparative data on emissions and performance. Results showed that lean limits for air-fuel ratio when using hydrogen-enriched natural gas were extended significantly beyond Chat of natural gas. Synthane pro¬duced exhaust that was significantly less reactive than exhaust from natural gas. With lean air-fuel ratios, the acceleration performance of a vehicle fueled with Synthane was improved over its performance when fueled with natural gas.

Jan 1, 1972

By A. J. Forney

A high-Btu gas was made at the Bruceton, Pa., laboratories of the Bureau of Mines to demonstrate the feasibility of using the gas as a nonpolluting fuel for automobiles. The pilot plants at Bruceton were revised to combine the processes of coal gasification, gas purification, and catalytic methanation in one overall system. Tests in the Bureau's test automobiles at Bartlesville, Okla., showed the Synthane gas was less polluting than natural gas.

Jan 1, 1972

By R Memary

The environmental and economic impacts of a significant dependence on fossil fuels are affecting the future of sectors such as of mining. These impacts are prompting the Australian Government to seek solutions for reducing its dependence on fossil fuels more generally, such developing clean energy and improving energy efficiency. However, limited research has been undertaken to assess the potential synergies between clean energy and mining in an uncertain global future. This paper analyses current energy use by mining in Australia and reviews the drivers and opportunities for energy efficiency and cleaner energy technologies to be coupled to mining under three future scenarios. Linkages between mining and clean energy are investigated for three global scenarios for mining and metals to 2030, developed by the World Economic Forum (WEF), namely Green Trade Alliance, Rebased Globalism and Resource Security. These scenarios are applied to assess how they could change the barriers, opportunities and trade-offs required for the development of a more sustainable energy sources by the minerals industry in Australia.

Nov 22, 2011

By L. L. Anderson

Western bituminous coal can be processed to low sulfur liquid fuels by fast reactions. A process (LEFCO) under development at the University of Utah uses coal and catalyst under hydrogen pressure to convert 60 to 70 percent of the coal matter to fuel liquids and gases. Coals have been processed in small diameter (less than 1/2 inch) tubes and at reaction residence times of less than 10 seconds. Effects of process variables on the yield and quality of products have been studied. General features of the process and the properties and characteristics of the products produced are presented. Special features of the process that distinguish it from other liquefaction processes under development are also discussed.

Jan 1, 1975

By Jean P. Murray

The extractive metallurgical industry is a major consumer of high-temperature process heat. It is, consequently, a major contributor of C02 emissions and other greenhouse gases derived from the combustion of fossil fuels for heat and electricity generation, or from the process itself. These emissions can be substantially reduced by replacing fossil fuels with solar energy as the source of process heat. Concentrated solar radiation can supply a large amount of thermal energy to endothermic reactions at temperatures exceeding 2000 K. Another potential for C02 emission reduction exists as well. Thermodynamically, the total amount of energy required for metal production at any given temperature is the enthalpy change of the reaction, AH. Of this total, an amount equal to the Gibbs free energy AG must be supplied as high quality energy in the form of electrical work or by using a reducing agent. Many conventional metallurgical electrolytic processes and reducing furnaces are unable to add only the thermodynamically required electricaVchemical energy due to process inefficiencies. Electrical work in excess of AG for the reaction may be used to supply process heat, or excess chemical reducing agent burned to supply process heat. Besides the thermodynamic and economic drawback, this inefficiency results in excess C02 emissions derived from the combustion of fossil fuels. With these practices, energy becomes an important cost element of the metal produced. Highly-concentrated solar energy has the demonstrated potential to separate these two forms of process energies, allowing the addition of only the thermodynamically required high-quality energy while high-temperature solar process heat is provided to the reactor. Examples of metal oxide reduction processes that have been studied experimentally in solar furnaces include the production of Fe, Al, AI/Si alloy, Mg, Zn, Tic, Sic, CaC2, TIN, Si3N4, and AIN by carbothermic reduction of their oxides, and the high-temperature solar- electrothermal reduction of ZnO.

Jan 1, 1999

By Elburt F. Osborn

The phrase "Clean Synthetic Fluid Fuels From Coal," implies that it is possible to obtain adequate and dependable supplies of fuel without sacrificing the quality of our air, water, and land. Because of the long lead times needed to develop technical feasibility, into commercial reality, however, vigorous efforts must be made now in order to do it. The available options for clean fuels include many exotic sources, like solar and geothermal power, fuel cells, and thermionic and thermoelectric systems. To solve the energy crisis, however, we have three basic energy criteria-abundance, reliability, and commercial availability by 1985. Only processes based on converting coal and oil shale to clean, synthetic fluid fuels can meet all three.

Jan 9, 1974

By Fathi Habashi

New technology first introduced by Nippon Steel Corporation at Kitakyushu in Japan in 1976 now used at a number of plants in other countries, known as dry quenching of coke, uses nitrogen in a closed circuit to avoid environmental emissions. In addition, heat is recovered in the form of steam, from the red-hot coke. In steel plants oxygen is used extensively and therefore by-product nitrogen from air liquefaction can be effectively utilized in this way.

Jan 1, 2014