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By Alejandro R. Alonso, Lizet Alvarado, Gretchen T. Lapidus

"Cobalt and lithium recovery from spent Li-ion secondary batteries has been increasingly studied in recent years due to the high value of both metals and the low proven reserves for lithium. The standard method employed until now has been the deactivation and crushing of the batteries, followed by leaching of the L1C0O2 spinel from the battery cathode using acid solutions, such as 1.5 to 2.0 M HC1 or H2SO4, in a temperature range from 120°C to 250°C. Once leached, the cobalt is separated by electrodeposition and the lithium by precipitation, using large amounts of carbonate to bring the solution to alkaline pH values. In the present work, citric-thiosulfate solutions are used for the spinel leach at room temperature, favoring a reductive environment at room temperature, which stabilizes the cobalt(II) as cobalt citrate and lithium(I) at pH 5, and recovers approximately 99% of both metals.IntroductionThe Li-ion batteries industry has become an important economic sector in recent years. This type of battery is the most promising system for energy storage, because of its high efficiency in charge-discharge cycles, and its adaptability to many configurations. The demand will probably increase because of the need for mobile energy sources in many types of devices ranging from cell phones, tablets, and laptops to medical, navigation and sophisticated communication equipment and even in automobiles.One major problem related to the use of these batteries is the method employed for recycling the components, mostly cobalt and lithium. Currently, there are two processes employed on an industrial scale: the Sony/Sumimoto process, used since 1990 [1] and the Toxco Process [2]. In the first case, incineration is used to open the batteries and at same time volatilize the organic solvents. After that, the metals (copper, iron and aluminum) are physically separated. The cobalt and lithium are recovered as oxides and then thermally treated in order to recycle them for new batteries manufacture."

Jan 1, 2012

The detailed work done by Stillwell and Edwards on the occurrence of cobaltite and safilorite-Iollingite at the South Mine, followed by its presentation as a paper to the Institute, calls for, a few notes on its occurrence elsewhere in the Broken Hill field. No massive cobaltite similar to that in the South Mine veinlet is known except from the Consols Mine (as mentioned in the paper). Fine grained cobaltite has, however, been found in low-grade ore from the North Mine. Microscopic grains occur in a mineralized green feldspar pegmatite. The feldspar has been replaced in part by graphite, and the cobaltite occurs in association with the graphite. In its hardness, pinkish-white colour, and resistance to the standard etchingqeagents it is similar to the South Mine cobaltite; it is etched by acid permanganate solution. An interesting feature of this occurrence is the way in- which some of the minerals (notably galena) have forced apart the graphite lamellae in crystallizing, forming lenses enclosed by the curved cleavage surlaces 0;[ the graphite.StillwelI and Edwards cite a note by G. Smitht for the statement that "cobaltite has been recorded from the Australian Broken Hill Consols Lode in the vicinity of the rich silver deposits, though not in contact with them."Smith, however, is here referring to the oxidized zone. Elsewhere in the same article he states "... a deposit of cobaltite in a very much altered condition was found. This was impregnated with silver, and assayed as high as 3,000 ounces," Of the cobaltite in the unoxidized zone, Smith simply states that it became rarer with depth.Cobaltite has also been recognized by Mr. H. F. Whitworth, M.SC., Curator of the Mining Museum, Sydney, in specimens from Burt's Copper Mine eight miles south of Broken Hill.

Jan 1, 1944

By Chris L. Powell, Russell J. Denny.

"The remotely located Cockatoo Island iron ore mine off the Kimberly coast in Western Australia, which has been in operation since 1951, was recently expanded up to 50m below sea-level using staged construction of a rock-filled seawall around the open cut mining operation. The most recent stage of the seawall expansion required a seepage reducing cut-off barrier to be installed through the seawall into underlying seabed sediments. A line of grout holes at 1m centres was proposed to form the seepage barrier, with grouting extending 17m below the top of the seawall. Top hammer drilling techniques were used to penetrate the 12m deep rockfill to seabed level, and permeation grouting carried out within the rockfill to fill voids and stabilise material around grout holes. The local 10m tides meant that tidal washout of fines and grout would be a major risk, and so a combination of cementitious and chemical grout was used to create rapid gel times. Following permeation grouting, holes were re-opened to allow jet grouting to hydraulically mix and grout permeable seabed sediments below the seawall. Using the duplex jet grout system in a single pass to 17m below platform level, the jet grouting was extended upwards into the seawall fill itself to overlap with the earlier permeation grouting. Finally a soil/cement mixed capping trench was installed using slurry trenching techniques with soil/cement/bentonite mixed backfill in order to complete the grout treatment. The approach taken allowed considerable onsite flexibility in technique. An automated slurry batching plant allowed adjustment of mixes to suit the varying subsurface conditions which were encountered during the works.IntroductionLate in 2013 Wagstaff Piling was engaged to install a seepage barrier through a rockfilled seawall built to allow expansion of sub-sea iron ore mining operations on Cockatoo Island off the remote Kimberley coast in the North West of Western Australia. Earlier stages of seawall construction had used a variety of different construction techniques with varied success, and the history of sub-sea mining on the island had been plagued with failures, including failures in the slope of the seawall itself, hanging wall failure underneath and inside the seawall, and footwall failures as the ore was mined leaving the rock face inclined at 55 degrees, parallel to the bedding. The current expansion, known as the Stage 4 expansion, was more tightly constrained by the pit geometry and available materials than previous seawall expansion stages that adopted clay core and sheet pile seepage barrier solutions. In Stage 4, an innovative grout curtain seepage barrier solution was selected to ultimately provide the necessary cut-off to allow access to high grade ore, while protecting the mine from inundation by the sea."

Jan 1, 2016

The promotion of good standards of reporting of the valuation of mineral assets in- public documents has been of concern to professional mining industry bodies, the securities industry, and. Government regulatory bodies for some time. This concern led to the National Companies and Securities Commission Release 149 (1990b) which laid down standards for Expert Reports on mining and petroleum securities, and other assets. The formation of the Australian Securities Commission provided an opportunity for a timely revision of Release 149 and the Mineral Valuation Committee was established by The Australasian Institute of Mining and Metallurgy in 1991 to review the existing code, and to develop an appropriate new Code and Guidelines.

Jan 1, 1994

By Gerardo Muñoz

All along this century CODELCO's smelters have been operating on conventional technology, which Codelco has streamlined by using oxygen, developing oxy-fuel burners for reverberatory furnaces and introducing oxygen smelting of concentrates in converters (Teniente Converters). Chuquicamata began capturing sulfur from its first Teniente Converter in 1985. Since then, it has implemented a program allowing to gradually increase such capture. In 1994 a Frame Law on the Environment was enacted in Chile. By virtue thereof and of CODELCO's corporate environmental policy, an investment program aimed at capturing more than 95% of gaseous pollutants in all its smelters in a term not exceeding twelve years was established. The above entails a substantial improvement of the operational management as regards fugitive gases capture and treatment. This paper describes the way CODELCO is to deal with this challenge with a view to fully complying with environmental regulations and obtaining the required environmental certifications of its operations.

Jan 1, 1996

By Jae-Ho. Lee

Mercury is a toxic contaminant encountered in the extraction of gold from mercury-containing ores. It is found in the leach solution of CIP circuits and in the cathodes of the electrolyte cells used to electrodeposit the gold. The research conducted has examined the potential for selective removal of mercury from synthetic Au-Hg-CN electrolytes containing only gold, only mercury, and both gold and mercury. Cyclic voltammograms were obtained for mercury- coated copper electrodes with these cyanide electrolytes. Exchange current densities were determined from the voltammograms in the low overpotential region. Laboratory scale batch- electrolysis at constant current was also conducted for the electrolytes containing only mercury and both mercury and gold, at 20 and 50°C and from which the kinetic behavior associated with the process was analyzed. The surface of cathode before and after electrolysis was also characterized and a copper mercury intermetallic (CyHg,) was identified. Gold codeposited with mercury during the later stages of electrolysis. The results of this work corroborate that the mercury-amalgam copper electrode offers a viable electrochemical technique for the selective removal of mercury, however a high-surface-area cathode-cell would have to be utilized to provide for the desired selectivity.

Jan 1, 1994

By Carlos León, Carlos Espinoza, David Machín

Antamina ha desarrollado una estrategia de relaves bajo una óptica de manejo socio - ambiental responsable cumpliendo con las normas internacionales y nacionales con prioridad en las personas directamente. Para tal fin, Antamina en su búsqueda óptima de nuevos sitios de relaves investiga una solución innovadora definida como Codisposal, la cual consiste en depositar relaves deshidratados en los vacíos de los botaderos de desmonte. Esta idea se inició con una evaluación a nivel scoping hace cuatro años, la cual ha llegado actualmente al nivel de estudio de Pre-Factibilidad Gate 2.

Sep 29, 2023

By John V. Beall

Hard as the Revett quartzite are conditions governing the deep mines of the Coeur d'Al6ne. In fourscore years of mining, heat and pressure have been the rewards of preseverance. Such obstacles are the natural concommitant to search for ore at depth. But high cost and shortage of miners is a creeping frustration of the decade. These grim observations were made on a trip to the mines of the Coeur d'Al6ne in the first week of May. But the bouncy optimism of competent mining engineers and geologists overrides by far the tough conditions. This is the story of what they are doing. I think they are setting the stage for the wonder mines of tomorrow. I didn't meet all the people or see all the mines, so there are unfortunate gaps in the story. Then too, sometimes the muck and water blotched my notes, or I couldn't write fast enough or I was too tired. No matter. There is much to tell and, because it is basically a human story, I am flouting the rules of technical journalism and couching it in the neglected "I" person. First then, a little history . . . .

Jan 7, 1966

By J G. Shellnutt, Y Iizuka, T W-Y Hsia, T-C Liu

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The formation of magmatic oxide ore deposits hosted in chemically-evolved layered gabbroic intrusions is attributed to a variety of petrological processes, but there is little to no consensus on the general applicability of each model. Complicating the matter further is that many layered gabbroic intrusions are spatially and temporally associated with alkaline A-type granites, suggesting that there is a petrogenetic relationship between the two types of chemically different rocks. Our experimental results show that petrological modelling using a starting composition of high-Ti basalt from the Emeishan large igneous province can produce evolved silicic liquids that resemble the compositions of microgranular enclaves from the syenitic unit of the bimodal, oxide ore-bearing Baima igneous complex. The experimental results confirm that bimodal gabbro-granitoid complexes can form from a common parental magma and that early crystallisation of Ti-rich magnetite can explain the formation of the oxide ore deposits in the lower parts of the layered gabbroic intrusions. We conclude that crystallisation of a typical high-Ti basaltic parental magma can produce world-class giant magmatic oxide ore deposits and that the occurrence of some alkaline granites may be an indicator of their presence.CITATION:Shellnutt, J G, Hsia, T W-Y, Liu, T-C and Iizuka, Y, 2015. Cogenetic formation of the peralkaline syenite and oxide ore-bearing layered gabbroic intrusion of the Baima igneous complex, Emeishan large igneous province, south-west China , in Proceedings PACRIM 2015 Congress, pp 317–324 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By Pravin Mathur

"Praxair's CoJet® technology was introduced in 1997 to effectively inject chemical energy in electric arc furnaces. Coherent jets were invented as a revolutionary means of injecting oxygen and other gases into the EAF and into converters. Today, steel makers have widely accepted this concept in over 70 EAFs worldwide. Indeed, the whole industry has shifted to this new standard for chemical energy input in EAFs. CoJet® technology has also been implemented successfully in BOF converters.This paper will review the principles of coherent jets as applied to steelmaking. The key learnings garnered from several furnaces are also reviewed. In addition, while the CoJet® program has been widely accepted worldwide, based on steady feedback received from customers and the market place, several programs are underway in development and commercialization. These enhancements and new applications of CoJet® technology are also overviewed in the paper."

Jan 1, 2004

By Qiang Zhong, Bin Xu, Qian Li, Yong-bin Yang, Tao Jiang, Yan Zhang

The occurrence of different ringing behaviors in oxidized pellet kiln for two kinds of coal (A and B) with similar properties, is difficult to explain based on the relationship between kiln ringing and coal properties. In this paper, the interaction of coal ash with pellet scrap powder was considered by studying the cohering behavior of powders consisting of them. The results showed that the cohering briquette strength of pellet scrap powder increased considerably when mixed with a small amount of coal ash; a maximum could be reached when the mass percent ratio of coal ash was 1.5%; the strength of powder mixed with coal B ash was always higher in same firing system. This obviously illustrated that coal B caused a more serious ringing problem. The relevant mechanism was that the stronger reactivity of coal B ash made cohering briquette have a more perfect crystallization and a more compact structure.

Jan 1, 2015

By Diana Diaz, Rakshith Shetty, Vitaly Proschenko, Mike Mooney

Cohesive clay soil poses a significant risk to earth pressure balance tunnel boring machines (EPBM) due to unstable face pressure, clogging potential, high cutterhead torque, poor muck flow, low advance rate, etc. This paper details the performance measures desired when EPBM tunneling in clay soil, and the scientifically-supported conditioning methods to transform in-situ clay to a muck with such characteristics, giving particular attention to ground conditions. The paper then examines TBM data from multiple clay soil projects in the context of these performance measures to demonstrate the influence of cohesive soil conditioning on EPBM performance.

Jun 13, 2023

By F. W. Jr. Sperr

THE byproduct coke oven is the most important artificial source of fuels for metals melting. Its products are solid, liquid, and gaseous in form. The amount of coke and primary byproducts obtained per ton of coal varies with the nature of the coal. The following represents the results obtained in many plants: Metallurgical coke (over 3/4 in.) 69 per cent. of coal Domestic coke (1/2 to 3/4 in.) 2 per cent. of coal Breeze (under 1/2 in.) 4 per cent. of coal Surplus gas, cubic feet per net ton 6600 Gas for heating ovens, cubic feet per net ton 4400 Tar, gallons per net ton 9 Ammonium sulfate, pounds per net ton 25 Benzols, gallons per net ton 4 All of these products, except ammonium sulfate, have important fuel value. Part or all of the metallurgical coke may be crushed or screened to furnish additional domestic coke. If producer gas is used, there will be a surplus of 11,000 cu. ft. of coke-oven gas per net ton of coal. The use of coke in the metallurgical industries has been retarded by the mental attitude of writers who disregard the dependence of coke quality on the conditions of its manufacture. Terms like "byproduct coke,"' "beehive coke," "48-hour coke," and "72-hour coke" are only generally descriptive and tell nothing of the coke quality. For example, one writer1 stated that in brass-foundry practice, Connellsville coke is considered much superior to byproduct coke on account of the high sulfur content of the latter. Another2 says, "At equal prices for hard Connellsville coke and for byproduct coke at the foundry door, the hard coke is unquestionably cheaper. It will melt more metal per ton than the byproduct coke and requires less labor, as the byproduct coke is less dense and burns faster, thus requiring more frequent firing." A little study of the conditions under which coke is manufactured will show the error in mak-

Jan 10, 1920

By J. D. Davis

Coke Since the beginning of manufacturing of metallurgical coke in the United States, which dates from about 1859, Pennsylvania has main tamed supremacy in coke production Available statistics for the year 1880 show an output of 3,338,300 short tons, which was neatly trebled by the end of the succeeding 10 years. From this time on the increase was steady, though not rapid, and in 1922 the total production was 13,991,892 tons, which is approximately 37 per cent of the total coke production of the United States. The main reason for the rapid development of the coke industry in Pennsylvania lies in the abundance of coals particularly adapted to beehive coking, for which purpose the Pittsburgh bed in the Connellsville district has long been looked upon as standard At first practically all metallurgical coke was made in beehive ovens, the only exception being the short lived and wasteful method of coking in piles, byproduct owns did not make then appearance until after 1893 The suitability of a beehive coking coal cannot be accurately predicted from its chemical analysis, but it can be said, perhaps, that the volatile matter should be about 32 per cent, and that the oxygen content should not be mole than 10 pet cent or less than 4 per cent The sulphur and phosphorus content should be small-not over 1 25 per cent sulphur and under 0 02 pen cent phosphorus-and the ash content should not be over 7 per cent The Pittsburgh bed at Connellsvnlle fills these requirements well, as may be seen from the following representative analysis. Analysts of coal from Pittsburgh bed Moisture 1 70 Volatile matter 31 10 Fixed carbon 59 80 Ash 7 40 Sulphur 0 85 B t u 13,990

Jan 1, 1928

By John D. Price

In the constant search for ways and means of improving the quality of coke and thus making its use at the blast-fornace more satisfactory and economical, it has become increasingly evident that the present laboratory tests do not show the full picture of a coke's value as a blast-furnace fuel. This fact was recognized by Dr. A. C. Pieldner thirty-five years ago: (Ref. 1) here is perhaps no phase of fuel technicology which has aroused more discussion or regarding which there is more difference of opinion than the properties of coke which make it most suitable for blast-furnaces and other uses." Dr. Fieldner followed this assertion with a statement to the effect that men who write on this subject today (1923) have, because of conflicting experimental evidence brought forth in recent years, far less positive opinions on the matter than did writers of some years past. One is led to wonder if these statements are not just as true now as they were when first made.

Jan 1, 1959

By T. H. Wilson

In 1901, the Crow's Nest Pass Coal Company, Limited, began producing industrial coke in 212 beehive ovens at Michel colliery. By 1908, 486 ovens had been installed and in that year 147,623 tons of coke were produced. Coke manufacture has been continuous from 1901 until the present time (1946), with total production of 2,795,402 tons. At present writing, only 100 beehive ovens are operating and production is reduced to 1,800 tons per month, due to the shortage of suitable labour. These ovens are drawn by hand, on contract, and the workmen are exposed to considerable heat. A man draws three ovens in eight hours, thereby producing approximately 1072 tons of coke per day. In addition to the inefficient and costly method of drawing coke in beehive ovens, tremendous losses are experienced in the wastage of gas and tar, which are driven off into the atmosphere. Also, the yield of coke per ton of coal fed to the ovens is low as part 9f the carbon is utilized in producing heat to carbonize the remainder of the coal. A recovery of only 55 per cent of the carbon, as coke, is obtained. The coking process takes place from the top of the charge, which is 21/2 feet deep, downward to the floor. Six and a half tons of coal are charged and 3.6 tons of coke are drawn from the oven after 72 hours' carbonization. The beehive ovens using Michel coal produce a very hard and tough coke, large in size and of silvery appearance, which has served the requirements of both foundry and smelter for many years. In 1938, the Company made a careful study of coking processes with a view to introducing a more economical method than beehive ovens and one that would be less dependent on skilled labour, the supply of which was rapidly diminishing at that time. Various methods of by-product coking were investigated, and it was decided that the Curran-Knowles process offered the greatest possibilities because of the low capital investment in relation to output and also because the horizontal oven design was suitable for an expanding coal. Consequently, a test on Michel B seam coal, supervised by Mr. E. Burrough, of the Fuel Research Department, Ottawa, was run in the Curran-Knowles plant at West Frankfurt, III. The results of this test led to the construction of a ten-oven battery of 32 ft. 6 in. by 8 ft. 3 in. Curran-Knowles ovens at Michel, which were completed in November, 1939. This battery was built as an experimental unit, with provision for an additional ten ovens if the coke proved satisfactory for the market. In 1942, an expanding coke market led to the construction of a second battery of ten ovens, which were completed in April, 1943.

Jan 1, 1947

By Huanyu Zhang, Quanqiang Ma, Huiqing Tang

Improvement of the coke quality for blast furnace (BF) iron making by hydrothermal oxidation treatment on coke quality was investigated. Results show that, under subcritical condition, sulfur removal rate is 15% and the weight loss is 3%; under supercritical condition, both sulfur removal rate and mass loss rate increase with the increase of H2O2 concentration. In the experimental conditions, sulfur removal rate and mass loss rates were 45% and 17%, respectively. Hydrothermal oxidation treatment could reduce the CO2 reactivity of the coke and the treatment under supercritical condition is more effective. Hydrothermal oxidation treatment could improve the graphitization of the coke and smoothness of pore boundary in the coke and the treatment under supercritical condition is more effective.

Jan 1, 2016

By Mariano de Córdova

In this paper, the coke oven life prolongation technology is reviewed from different points of view: blend design; battery heating; operational control; refractory maintenance. A summary of major inspections in critical areas, for the evaluation of the battery conservation situation is presented. A discussion on tools for the diagnostics of the degree of damage is carried out.

Aug 16, 2017

By Richard J. Wilson

The importance of coal as a major source of energy used by the steel industry has been increasing due to the gradual changeover from steel- making by the open hearth process to steelmaking by the basic oxygen process. Since the production of steel by the BOF process increases the demand for hot metal, there is a growing need to ensure the supply of coke required for the production of hot metal. Coal used for cokemaking has become, therefore, an increasingly important raw material for the steel industry in recent years. Our current projections indicate that coal will be the source of 71% of the total energy requirements of Inland Steel Company in 1985. As a result of the energy shortages of the last few years, various conservation programs have been initiated by the steel industry to reduce the consumption rate of fuel. The efforts to conserve energy have been successful to a great extent due to the rapid advances made in the technology of ironmaking that facilitated gradual reductions in the quantity of coke used per ton of hot metal produced in the blast furnaces. The decrease in the consumption rate of coke was made possible by the use of improved raw materials, such as iron ore pellets and fluxed agglomerates, the operation with high blast temperatures, the injection of auxiliary fuels, and the enrichment of the blast with oxygen. It is expected that additional reductions in the fuel consumption rate will be possible in the ironmaking operations of the large blast furnaces that are being equipped with facilities for proper burden distribution and for operation with higher blast temperatures at high top pressure. The purpose of this paper is to show the effects of coke quality on the production of BOF steel. The importance of coke quality will be pointed out by discussing the effects of the physical strength of coke on both the blast furnace productivity and the steelmaking operations of an integrated steel plant, such as Inland Stee1 Company.

Jan 1, 1980

By John S. Alexander

THE typical block coal of the Brazil (Indiana) District differs in chemical composition but little from the coking coals of Western Pennsylvania. The physical difference, however, is quite marked ; the latter has a cuboid structure made up of bibuminous particles lying against each other, so that under the action of heat fusion through- out the mass readily takes place, while block coal is formed of alternate layem of rich bituminous matter and a charcoal-like substance, which is not only very slow of combustion, but so retards the transmission of heat that agglutination is prevented, and the coal burns away layer by layer, retaining its form until consumed. This property permits the use of raw block con1 in the furnace but theo-

Jan 1, 1876