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By Håkan Tyni, Jan Björkman, Per-Olaf Samskog, Irving Wigdén

Process automation can provide better utilization of capital investments. Furthermore, it is a necessity for securing the high demands of product quality. In this paper, process automation in underground mining as well as in the beneficiation plant will be discussed. The development of reliable broadband communication systems for real-time transfer of image, audio and data have enabled remotely controlled LHDs and drilling rigs. In the beneficiation plants, model-based expert control systems far on-line dynamic process optimization and control have been installed in unit operations such as grinding, flotation and induration.

Jan 1, 2000

By T. R. Ellis

"In August 2013, the Appraisal Practices Board of the U.S. Appraisal Foundation issued its “APB Valuation Advisory #4 - Identifying Comparable Properties,” which contains analysis and examples that may suggest a broader meaning of the term “comparable properties” than is current convention in real property value appraisal in the United States and internationally. The advisory is directed at the appraisal of real property of all kinds, including interests in mineral properties, as indicated by the inclusion of two mineral property appraisal papers in the appendix that lists suggestions for further reading.This paper firstly reviews as background the historical meaning of a comparable property, with its perceived constraints, against real-world examples of transacted mineral properties that are adjusted to subject properties to provide market value indications. The advisory’s findings are then examined and evaluated as to whether they may influence and benefit the work of mineral property appraisers, particularly in situations where their sales comparison analyses may be challenged. The conclusion is that the combination of constraints that the advisory’s findings specify for use of the term “comparable” will for mineral properties be met infrequently or rarely. As a result, mineral property appraisers are advised to avoid using the terms comparable or “comp” when referring to transactions of mineral properties that they analyze to derive data for appraising the value of their subject mineral properties. IntroductionA mineral property appraiser rarely finds a sale of a mineral property that meets the literal meaning of the term “comparable sale,” by being directly comparable to the subject property of the appraisal in all factors of significance in the determination of the value of the property interest being appraised. Real estate appraisers have long used a more liberal interpretation of the meaning of comparable sale and its commonly used abbreviation, “comp.” Real estate appraisers compare sales to their subject property on the basis of price per hectare or acre of land and price per square meter or square foot of building floor area. Adjustments totaling to within the range of +30 to -30 percent from the sale property to the subject, before factoring in the property area, have generally been viewed as appropriate for the sale to be considered a comparable sale."

May 1, 2016

By M. Tokoglu

Accurate estimation of resources is one of the major challenges in mineral project evaluation. Contemporary mineral resource estimation practice calls for contribution from several disciplines and execution of several interdependent tasks. 3D estimation domain modelling is obviously one of the most essential components of such a substantial process which forms the basis of this research. The study constitutes a comparative analysis of four major domain modelling techniques; (i) explicit modelling, (ii) implicit modelling, (iii) indicator kriging, and (iv) conditional simulation. It involves comparison of outcomes for alternative scenarios to assess the implications of the modelling decision on resource estimates of a polymetallic massive sulfide deposit located in western Turkey. Thus, identical grade estimation method and parameters are considered to identify the discrepancies arising only from the choice of the domain modelling approach and underlying assumptions. Economic implications are demonstrated in the form of range of outcomes for the extends of the ultimate pit, ore tonnages (min:37.0 Mt, max: 46.7Mt), waste tonnages (min:201.2 Mt, max: 251.2 Mt), stripping ratios (min:5.18, max: 5.71), and total pit values (min: $1.05B, max: $1.45B). Examination of solid models as well as cross-sections revealed that major discrepancies are observed beyond outlying drillholes. Therefore, it has been proposed that assumptions regarding extrapolation distance is the main source of mentioned dissimilarities. Key words: Domain modelling, explicit modelling, implicit modelling, indicator kriging, conditional simulation INTRODUCTION Resource estimation is apparently a challenging process calling for extensive expertise and input from several sources, each of which introducing its related uncertainties. In the last decades, substantial role of quantitative analysis of several forms of risk and uncertainty in evaluating projects’ upside potential and downside risks has been realized. Studies indicated that mining companies have been severely impacted because of not meeting project expectations. As noted by Vallee (2000) “… in the first year of operation after start-up, 60% of mines surveyed had an average rate of production less than 70% of designed capacity”. Several other studies on mining projects also revealed that uncertainties related with the resource model are one of the major contributors of mentioned shortfalls. In this perspective, quantification of uncertainties associated with each component of estimation process is critical. 3D estimation domain models capturing major mineralization controls are the fundamental components of contemporary mineral resource estimation. Domain models are key guiding tools for estimation and are products of a complex process involving many unknowns and assumptions. There exists a number of 3D modelling alternatives which are distinct with respect to complexity, time and effort involved. Acknowledging potential influences on downstream mining practices and relavent economic implications, risks and uncertainties associated with 3D domain modelling are critical yet poorly studied aspects.

Jan 1, 2019

By Mokka N. Rao

In this experimental investigation, the principal operating parameters of the spirals HC 1870 and HG 8/7 are determined for the hydrogravimetric separation of the friable siliceous iron minerals of the Piar Distric, Venezuela. Mineralogical characterization including optical microscopy of feeding materials and the products after separation are presented. Comparative analysis is made of effectiveness of productivity between the two spirals.

Jan 1, 1999

By T. Klemetti

Moisture deterioration of clay-rich roof rocks causes high numbers of roof falls in coal mines in humid summer months. Rocks with high moisture content are generally weaker and can further deteriorate when subjected to wetting and drying cycles. As a result, it is important to evaluate the moisture-sensitivity of roof rock prior to mining. The National Institute for Occupational Safety and Health (NIOSH) has evaluated three moisture-sensitivity index tests on roof rocks from 23 U.S. coal mines. The three tests were the University of Kentucky Weatherability test (Weatherability test), the Consol Energy Water Sensitivity test (Water Sensitivity test), and the NIOSH Immersion test (Immersion test). Of these three tests, the Weatherability and Water Sensitivity tests are more reliable in classifying the moisture-sensitivity of roof rocks. Disclaimer: The findings and conclusions in this report have not been formally disseminated by the National Institute for Occupational Safety and Health and should not be construed to represent any agency determination or policy.

Jan 1, 2009

By R. Venugopal, V. K. Saxena, S. K. Tripathy

"This study was carried out to understand the impact of variation in material morphology on the efficacy of microwave pretreatment. Three different types of mineral matter – coal, iron ore and manganese ore – were treated with microwaves at different energy levels, from 180 to 900 W, for different time durations of one to five minutes. The treated samples were subjected to microscopic, milling and liberation studies. Coal is a porous and amorphous material with low dielectric constant, and grinding of the microwave-pretreated coal samples resulted in an 18.18 percent reduction in the 80 percent of passing particle size, or d80, and a 17.1 percent increase in carbon recovery. The microwave-pretreated soft and friable manganese ore samples showed a 47.82 percent reduction in d80 during grinding and higher manganese recovery of 42.46 percent during liberation analysis. The microwave pretreatment and milling of hard and banded iron ore reduced the d80 by 20.83 percent, but no improvement was observed in mineral liberation. Coal showed better results during treatment at lower energy levels of 180 W for one to three minutes, whereas the minerals needed higher energy of 900 W for five minutes. Particle size analysis indicated rapid size reduction up to an energy input of 25 Wh. This effect diminished with increased energy input.IntroductionComminution is an important unit operation in mineral processing plants for the purposes of size reduction and mineral liberation. But most comminution technologies are energy inefficient and only a small amount of energy is consumed in real size reduction, with the rest wasted. High-grade mineral resources have been exploited on a large scale for the last century, and the upgrading of low-grade resources is now required to fulfill the needs of industry. Pretreatment methodologies for comminution will play a crucial role in the upgrading of low-grade mineral resources. Researchers have studied various pretreatment methods to develop an energy-efficient and techno-economically viable solution to improve mineral liberation and product fineness with minimum energy consumption. Most of these studies were focused on the use of chemical additives, thermal, ultrasonic and microwave treatment, and electric disintegration (Klimpel and Austin, 1982; Norgate and Weller, 1994; Gaete-Garreton, Vargas-Hermandez and Velasquez-Lambert, 2000; Wilson et al., 2006; Kumar et al., 2010; Wang, Shi and Manlapig, 2011; Singh et al., 2012)."

Jan 1, 2017

By Joseph Githiria, Khadija Omar Said

Mineable material is defined using cut-off grade either as geological or economic cut-off grade. Both geological and economic cut-off grade affects the output generated in an open-pit mining operation. It distinguishes the amount of ore sent to the mill for processing and waste to the dump. This consequently affects the overall profits generated from the operation hence the need for cut-off grade optimization. There are several mining parameters that are considered in a typical cut-off grade model. They include economic, geological, and operational parameters. They have a significant effect to influence the cut-off grade selected in mining operations at any given period. Some of the parameters are stochastic in nature by having a random probability distribution that may not be predicted precisely. When selecting cut-off grades in a mine operation, the mining engineers must consider the dynamic nature of the operational parameters in order to maximize the net present value of the project. Modifying Lane’s cut-off grade model which was developed in 1964 to incorporate the stochastic parameters in the approach helps improve the net present value as shown in the paper. The modified Lane’s approach is developed into a stochastic computer-aided application code-named NPVMining. Using NPVMining, selected stochastic parameters are considered in this exercise to show the effect on the output (net present value). The selected parameters (price and grade-tonnage) are varied by ± 10%. NPVMining has a graphical user interface that makes it easy to use and displays results in a user-friendly way. It gives the user the choice to manipulate the data depending on the study being undertaken or any other factor affecting the specific mine. This paper analyses the effect of each of the selected mining parameters on cut-off grade using NPVMining to show the significance of monitoring their variance.

Jun 25, 2023

By Leandro de Arruda Santos, Lorena Isabela de Oliveira Ribeiro, Jéssica Dornelas Silva, Pedro Damas Resende, João Victor Lucas Amim, Suzanny Cristina Soares Martins, Vicente Tadeu Lopes Buono

O objetivo do presente estudo foi avaliar a resistência à fadiga de duas ligas de NiTi diferentes sob condições de teste controladas por deformação a 25°C por meio de testes de fadiga por flexão rotativa. Além disso, as propriedades mecânicas, térmicas e estruturais dos fios foram caracterizadas por ensaios de DSC, DRX, MEV/EDS e tração. Os resultados revelaram que ambos os materiais são superelásticos à temperatura ambiente e, portanto apresentaram composição basicamente austenítica de sua matriz. Os resultados de ensaio de tração são condizentes com a caracterização térmica e estrutural, pois os materiais apresentam recuperação total de forma após ciclos de carga e descarga em tração. Ambos os materiais são ricos em titânio, um deles apresenta camada de óxido superficial enquanto o outro apresenta acabamento superficial. Apesar das propriedades similares a amostra 1 apresentou média de 77 ciclos até a falha, enquanto a amostra 2 resistiu a 1827 ciclos..

Oct 25, 2019

By P. Gelfi, G. Hill, A. Showell, V. Martins, R. Dunne, R. Jenkins

Carbon attrition losses are not usually a prime consideration for CIP equipment selection and CIP plant design. However, the costs as a result of carbon attrition and associated gold lost with carbon can be high. Recorded carbon losses for Newcrest operating gold plants were shown to vary widely from plant to plant. The Tuckabiana plant recorded an overall loss of only 0.3g carbon /t ore which is very low by industry standards. A comparative carbon management study was undertaken by Newcrest to highlight the reasons for the excellent record of Tuckabiana operation compared to other Newcrest plants. This paper discusses the results of the comparative study and high­lights areas of concern with respect to carbon attrition.

Jan 1, 1995

By Mark W. Booth

THIS paper deals with the subject of inbye power as the mechanical . engineer sees it, and invites discussion, particularly from the electrical engineer. At the outset, it will be necessary to clear the ground a little by some definite statements. In this question of compressed air versus electricity for the transmission of power and driving of machinery in underground workings, we must see that there are definite fields that compressed air on the one hand, and electricity on the other, can fill to much greater advantage than the other, and in which there can be little or no direct competition, at least for the present. It is under conditions where these fields overlap, and as to where the line must be drawn between the two, that the respective merits of each must be considered. Steam was the first means used to transmit power from the surface of a mine to drive underground machinery, and so long as distances were short and means possible to ensure fairly efficient use of the steam, and where the fire hazard was not in evidence, it gave fairly efficient service. I have in mind an instance during my own connection with the mines-a duplex pump at the shaft bottom at Princess colliery, driven by steam, and which used the steam compound and condensing; and, but for the mechanical difficulties, it was a not inefficient proposition. The steam was taken direct from the surface boiler-plant through a line down the shaft, and used directly at the pump, being in effect a straight conversion from coal to steam to work done. It was the mechanical arrangement, and failure of the pump in that direction, that led to its removal and replacement by something better in the way of an electrically driven turbine pump. Given modern mechanical arrangements, such as a steam-turbine drive on a high-speed turbine pump, and all other parts made in accordance with best practice in the art of steam generation and use, a steam-driven unit fully as economical would have been obtained. But the central electric supply station, and all that that means or promises (not always the same), turned the scale against steam.

Jan 1, 1936

By M. L. Requa

IN the fall of 1910, the Nevada Petroleum Co., operating in the Coalinga field in California, determined to drill a number of wells with rotary tools, in order to prove conclusively the relative value of the rotary as compared with the standard rig. At that time, the rotary was but little known in California and its proposed introduction met with considerable criticism on the part of the operators and quiet opposition among the standard drilling crews. There were few men available who were competent to handle a rotary outfit, and these few had had but little experience in California fields. Machines as then built were much inferior to those now used, being lighter in construction and of a poorer quality of material. The shells encountered at depths between 1,700 and 2,000 ft. seemed to be too hard to permit of successful drilling, and at these depths the rig was changed over to standard tools and by them completed. Because of the heavy depreciation, the time lost in converting from rotary to standard, and the comparatively small profit, it was concluded that unless in the future there was some material improvement in rotary rigs, nothing would be gained by drilling with rotary tools upon this property. Little or no drilling has been done upon the property since that time, but in the meantime a large number of men have been trained in the use of the rotary; in fact, many standard-tool men have abandoned standard drilling and, starting in as roustabouts, have become thoroughly competent rotary operators. The improvements in the machinery have been such as to remove many of the objections and the rotary drilling of to-day is in every way superior to that of 1910. In contrast, a well drilled recently by the Kern Trading & Oil Co., in the east side Coalinga field may be cited. The first 2,500 ft. was drilled in 24 days and it is confidently expected that the water string will be set with a rotary at 3,400 ft.-a record obviously far beyond that made in 1910 by the Nevada Petroleum Co.

Jan 2, 1915

By Neil C. Hario

The purpose of this paper is to explore the various designs and design alternates available for large fine crushing plants, and to discuss objectives and criteria upon which these designs are founded. Common practice for size reduction of run-of-mine or run-of-pit ore in preparation for subsequent treatment utilizes a three-stage system. First stage, or primary breaking is generally carried out with jaw or gyratory crushers. The usual output from this stage provides a feed for fine crushing in the size range of 6 to 10 inches. This discussion is limited to the process of fine crushing, and we will further limit it to what is commonly called secondary and tertiary crushing. We define a large crushing plant as one with a minimum capacity of 2,000 tons per hour. Generally, these plants utilize cone type crushers to reduce ore for rod, ball, or pebble mill feed.

Jan 1, 1970

By Z Li, Z Yan, M Yang

Recycled cement paste (RCP) is a kind of CaO-rich recourse, which is separated and recycled from waste concrete. Due to its chemical composition, RCP could partially replace lime as a flux and be loaded into electric arc furnace (EAF) steelmaking process. Rapid RCP assimilation and liquid slag formation have significant effects on EAF steelmaking process. In this study, the dissolution behaviours of RCP and lime at temperatures of 1400°C to 1500°C were investigated using static dissolution experiment. The dissolution rate, interfacial microstructure, as well as dissolution mechanisms were discussed. It was found that the dissolution rate of RCP was much higher than that of lime. RCP could be completely dissolved into slag in 60 secs at 1500°C. The dissolution rate of lime was in range of 3.910-4 g/(cm2ꞏs) to 2.610-3 g/(cm2ꞏs), while that for RCP was in range of 1.510-3 g/(cm2ꞏs) to 4.910-3 g/(cm2ꞏs). As for lime dissolution, a dense layer of dicalcium silicate (C2S) generated at the dissolution interface, and the diffusion of Ca2+ in C2S layer was the limited step for lime dissolution. Some of calcium ferrite could be observed at the interface between lime and C2S layer. As for the RCP dissolution, there is no obvious product layer of C2S formed at the dissolution interface, Fe2+ continuously diffused into RCP layer during the dissolution, and small amount of FeOꞏMgO solid solution generated and gathered at the dissolution interface. The dissolution rate of RCP in EAF slag was quite higher than that of lime, partially add RCP as flux in EAF could accelerate the slag formation process.

Aug 21, 2024

By George J. Karabin

Over the past few years, the use of fully grouted bolts to support the roof of underground openings has increased dramatically. While conventionally anchored bolts effectively reinforce the strata of over 80 percent of mine workings, the use of resin grouted bolts in areas of severe roof conditions has resulted in a substantial reduction in roof falls and an overall improvement in both safety and production. The Roof Control Group of Pittsburgh Technical Support Center, Mining Enforcement and Safety Administration, has conducted numerous field and laboratory investigations to isolate parameters which contribute to the effectiveness of both conventional and resin bolting systems. Specially developed strain-gamed resin bolts, compression pads and differential sag stations installed during the mining cycle have generated data reflecting the loading characteristics and resulting roof stability associated with each type of support. Additional investigations have produced optimum installation parameters of the two systems including the effectiveness of thrust/torque controls for conventional bolts and various bolt/ hole diameter combinations for fully grouted rods. Theoretical analyses, coupled with the actual field and laboratory findings and numerous installation observations have facilitated basic comparisons of the working mechanisms and failure modes of both resin and conventional systems.

Jan 1, 1976

By James F. Archibald

A research effort has been undertaken, under WSIB sponsorship, to characterize the support capabilities of conventional and innovative spray-on lining materials for mitigating dynamic failure effects created by simulated rockbursts. Conventional spray support media, such as shotcrete and fibrecrete linings, and a variety of new spray-on lining materials (TSL?s), typically polymer-type thin coatings, were subjected to simulated rockburst influence. For baseline comparison, conventional rockbolt and boltand- mesh support products were also evaluated. Observation of lining performance was undertaken through completion of field scale support and rock detonation trials. Controlled blasting tests were conducted at the Queen?s University Explosives Laboratory to examine the effectiveness of the variety of surface coating agents for modifying dynamic rock spalling processes. All tests were performed upon largely undisturbed and homogeneous rock materials in highly repeatable fashion. Both conventional and innovative TSL-type surface lining materials were subjected to ?rockburst? exposure in rigorously-controlled blast trials. All blasts were observed seismically and photographically to provide detailed information concerning rock motion, surface fracturing, ejected fragment motion and support liner survivability characteristics. These material comparison trials were performed to assess the relative effectiveness of a wide range of currently-available area support techniques for suppressing hazards associated with dynamic rock ejection. The results of this study validates that thin, sprayon linings may be equally as effective, and often better, than conventional support materials at mitigating rockburst or like damage in highly stressed mine environments.

May 1, 2003

By Christiana Mystrioti

Greece is the only EU country with extensive nickel laterite deposits. Since the 1960s, the Greek laterites are treated for ferronickel production via a pyrometallurgical route, which involves pre-reduction of the ore in rotary kilns and reduction smelting in electric arc furnaces. Due to the rising cost of energy and the decreasing grade of mined laterites, the pyrometallurgical treatment is economically marginal. For this reason, alternative treatment processes are currently under investigation. Potential applicability of hydrometallurgical treatment, using either H2SO4 or HCl, under atmospheric pressure conditions, for Ni and Co extraction from two low grade laterite ores, was examined in the present work. The two samples were selected to represent the different mineralogical composition of the saprolitic and limonitic ore deposits of the Greek laterites. The investigated parameters were temperature (65–90 °C), acid concentration (1–4 N) and solid to liquid ratio (10–30% w/v). The results indicated that HCl was more efficient than H2SO4 for the treatment of the saprolitic ore; Ni and Co extractions were very high for both elements, up to 98% and 96% respectively, while H2SO4 could leach efficiently Ni, up to 100%, but extracted only 34% of Co. Hydrochloric acid was also more efficient for the treatment of the limonitic ore, with Ni and Co extractions up to 98.3% and 87.6% respectively. With H2SO4 the maximum extractions were 71.3% for Ni and 52.1% for Co.

By P. B. Liebermann

THE resistance to motion offered by mine cars is caused principally by: Rolling friction, flange friction, bending rails, bearing friction and wind resistance. With proper construction and with a fair amount of attention and care, that is, under favorable conditions, the first three items cannot be greatly improved. The wind resistance ordinarily is negligible on account of the slow speeds commonly used. The bearing friction, however, is a variable item, depending upon the design, the bearing material, the lubrication, the location (whether in wheel-hub or on car-body) and the alignment. Under the most favorable conditions the bearing friction will reach a lowest possible value. By the development of a successful anti-friction mine-car bearing this lowest value has been improved to such an extent as to affect the whole system of mine haulage. After being satisfied of their durability and certainty of operation, any investigation into the advantages of anti-friction bearings for mine cars will have to be based upon reliable information as to the saving in power of such bearings. While numerous tests have been made in this direction, the results have not always been convincing, principally because of the rather crude methods that were employed. These crude methods are the main cause of the wide variations existing in regard to the exact amount of the frictional resistance. Frequently an ordinary spring balance is used and the pull necessary to move a certain car or train of cars is obtained by a number of readings. Such spring balances necessarily have a coarse graduation and the continuous vibration and fluctuations to which they are subjected make them highly dependent upon the individual observer. Further, they must be frequently calibrated. Sometimes these tests were made without regard to acceleration, speed or even grade.

Jan 6, 1916

By Herbert A. Stein, John B. Murdock

Perlite is a natural volcanic glass which expands into an insulation material upon the application of heat. This paper discusses the operating characteristics of eight different types of furnaces for the expansion of perlite. It also includes a section on the theory of perlite expansion which serves as the basis for the authors' analysis of the furnaces.

Jan 1, 1950

By V. K. Alves, P. Lacoste-Bouchet

"In order to improve ball milling efficiency in pellet plants, Companhia Vale de Rio Doce (CVRD), experiments new technologies in Santa Luzia (M.G. – Brazil) research center facility. Pilot grinding tests have been conducted with small grinding media, size distributed from 5 to 12 mm (millpebs). Tests have been conducted on an ore from CVRD’s Usina 5 Nibrasco, in Vitória, Brazil. A sample of the regrind circuit feed was obtained and used in comparative grinding tests with two types of grinding charges: 100% balls and a blend of 70% balls and 30% millpebs by weight. According to the balls charge, the grinding media mixture has showed the following benefits: reduction of the power draw, increase of the mill capacity, reduction of the circulating load and a slight increase of the ore blaine. Following the results obtained, CVRD is going to further explore the regrinding potential of millpebs.INTRODUCTIONCompanhnia Vale de Rio Doce (CVRD) is the largest mining company in Brazil. CVRD is involved in iron, base metals, gold and bauxite industries. Moreover, CVRD operates several pelletizing plants in Brazil and in other countries.CVRD’s Center for Mineral Development (CDM) is equipped with a comminution laboratory where studies are carried out that are aimed at the optimization of existing plants at several mining sites as well as the technical and economical feasibility of new projects. The laboratory is equipped with a complete pilot plant with several mills and classifiers, enabling continuous grinding tests in grinding circuits of almost any capacity and characteristics.In January 2004, CVRD undertook to conduct pilot tests at CDM for evaluating the effect of small grinding media on ball milling efficiency. Generally speaking, it is not unusual for operators to add oversize grinding media in a conventional regrind mill. This fact originates mainly from prohibitive prices of grinding media below 25 mm due to a production capacity decrease of grinding media producers. The size of the grinding media is an important variable affecting ball milling efficiency. Use of oversize balls decreases the number of contact surface between which particles can be caught and broken."

Jan 1, 2005

By Çisem Tuba, Ismail Girgin

"Comparative atmospheric H2SO4 and H2SO4 + H2O2 leaching experiments were performed using a Turkish lateritic nickel ore containing 1.52% Ni. In the leaching tests; acid concentration, temperature and leaching time were considered as main variables and the dissolution behaviour of the ore were studied by Ni, Fe, Co and Mg analyses. The dissolution values in the H2SO4 leaching experiments were observed to increase up to 60% (w/w) acid concentration and a temperature of 95°C. Increase of H2SO4 concentration above 60% at 95°C caused decreases in all the dissolution values and this was attributed to the formation of Fe2(SO4)3 and Fe2(SO4)3•HSO4•H2O type compounds. At the considered optimum H2SO4 leaching conditions ([H2SO4]= 45%, T=95°C, t=45 min); dissolution values reached for Mg, Ni, Fe and Co were determined as 99.12%, 95.58%, 92.63% and 78.37%, respectively. An activation energy of 30.57 kJ/mole was determined for nickel dissolution from the evaluation of the kinetic data obtained for H2SO4 leaching showing that the dissolution was controlled by external diffusion and chemical reactions. Caro’s acid solutions were prepared at H2SO4/H2O2 mole ratio of 3 for varying initial H2SO4 concentrations and leaching tests were performed at 25°C. Co behaved very differently and a dissolution value of 83.94% was obtained even at 5% acid concentration in 60 minutes reaction time. Complete dissolution of Co was obtained after 30 minutes of reaction time at 60% initial H2SO4 concentration and the corresponding dissolution values for Mg, Ni, and Fe were reached to 96.16%, 94.27% and 89.46%, respectively. Although the H2SO4 + H2O2 leaching experiments were conducted at 25°C, it was realized that the temperature of the leaching medium was increased to 122°C after four minutes of reaction time due to probable exothermic reaction(s) at 60% initial acid concentration."

Jan 1, 2014